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By Lev Malytin, Alexander Dyachenko, Roman Kraydenko

"A new method of processing beryllium raw materials based on interaction of beryllium mineral with ammonium fluoride was developed. Possibility of extracting ammonium tetrafluoroberyllate from bertrandite and phenakite minerals is proved. The developed technology allows replacing the outdated sulfate technology developed by Materion Corporation. INTRODUCTION Beryllium is a strategic metal, which is produced only in three countries: the USA, China and Kazakhstan. The world production of beryllium amounts to only 300 tons per year. More than 75% of the world beryllium production is manufactured from oxide beryllium ores in the USA by Materion Corporation. In Russia there is a large-scale beryllium ore deposit «Ermakovskoye» containig over 1 million ton of ore. Concentration of beryllium in ore amounts to 1,2%. Since the mineral base of ore is calcium fluoride, the sulfate technology of Materion Corporation cannot be used. After alloying and sulphuric acid leaching the fluorine-ion found in fluorite and beryllium together evolve into the aqueous phase. At the stage of Be(OH) precipitation fluoride-ion prevents complete isolation of beryllium into the phase of hydroxide, which increases the loss of beryllium. A new ammonium-fluoride method for processing high-fluoride beryllium ores has been developed at Tomsk Polytechnic University. The ammonium-fluoride method involves fusion of ammonium fluoride (NH4HF2) with a beryllium concentrate. The concentrate containing 10% of beryllium oxide and 25% of calcium fluoride is produced by flotation from the ore of Ermakovskoe deposit. The main component of the ore concentrate is fluorite CaF2, which does not react with NH4HF2. Beryllium in this concentrate is represented by two minerals: phenakite Be2(SiO4)2 and bertrandite Be4[Si2O7](OH)2. Ammonium fluoride, unlike sulfuric acid, does not react with calcium fluoride and is not consumed for decomposing the mineral base of the concentrate. Ammonium fluoride is an accessible and environmentally safe reagent, worth up to $ 1,200 per ton. The total amount of ammonium fluoride is recycled and is used for decomposing a new batch of beryllium concentrate."

Jan 1, 2018

By Lev Malytin, Alexander Dyachenko, Roman Kraydenko

"A new method of processing beryllium raw materials based on interaction of beryllium mineral with ammonium fluoride was developed. Possibility of extracting ammonium tetrafluoroberyllate from bertrandite and phenakite minerals is proved. The developed technology allows replacing the outdated sulfate technology developed by Materion Corporation. INTRODUCTION Beryllium is a strategic metal, which is produced only in three countries: the USA, China and Kazakhstan. The world production of beryllium amounts to only 300 tons per year. More than 75% of the world beryllium production is manufactured from oxide beryllium ores in the USA by Materion Corporation. In Russia there is a large-scale beryllium ore deposit «Ermakovskoye» containig over 1 million ton of ore. Concentration of beryllium in ore amounts to 1,2%. Since the mineral base of ore is calcium fluoride, the sulfate technology of Materion Corporation cannot be used. After alloying and sulphuric acid leaching the fluorine-ion found in fluorite and beryllium together evolve into the aqueous phase. At the stage of Be(OH) precipitation fluoride-ion prevents complete isolation of beryllium into the phase of hydroxide, which increases the loss of beryllium. A new ammonium-fluoride method for processing high-fluoride beryllium ores has been developed at Tomsk Polytechnic University. The ammonium-fluoride method involves fusion of ammonium fluoride (NH4HF2) with a beryllium concentrate. The concentrate containing 10% of beryllium oxide and 25% of calcium fluoride is produced by flotation from the ore of Ermakovskoe deposit. The main component of the ore concentrate is fluorite CaF2, which does not react with NH4HF2. Beryllium in this concentrate is represented by two minerals: phenakite Be2(SiO4)2 and bertrandite Be4[Si2O7](OH)2. Ammonium fluoride, unlike sulfuric acid, does not react with calcium fluoride and is not consumed for decomposing the mineral base of the concentrate. Ammonium fluoride is an accessible and environmentally safe reagent, worth up to $ 1,200 per ton. The total amount of ammonium fluoride is recycled and is used for decomposing a new batch of beryllium concentrate."

Jan 1, 2018

By I. Yu. Rasskazov, A. V. Rasskazova, N. M. Litvinova, N. A. Lavrik, V. G. Kryukov

The possibility of the intensification of the gravity processing of complex iron-manganese ore, which contains the finely dispersed inclusions of gold and platinum is shown. Clear mineral fractions of precious metals were sorted out of the different types of ores (quartz-braunite and carbonate- magnetite ore, ferruginous quartzite, carbon-containing shale, breccia-limestone and dolomite breccia). Composition and structures of precious-metals particles was detailed. The industrial content of platinum and gold was found. Precious-metals mineralization is character for all types of ores. High content of platinum is indicated in the carbonate-magnetite (up to 11.3 mg/kg) and quartz –braunite (up to 10 mg/kg) types of ore. Gold is presented in the ferruginous quartzite (up to 1.29 mg/kg) according to the data of the reduced mineralogical analysis. The composition of native platinum depends on the type of the ores: 1) quartz-braunite type contains isoferroplatinum (Pt3Fe) with Cu, Rh, Ir, Ru; 2) carbonate-magnetite type contains isoferroplatinum with Cu, Sn, Ni, Rh, Ir, Os; 3) pyritic-carbon ore contains isoferroplatinum with Sn, Ni; 4) ferruginous quartzite contains isoferroplatinum without admixtures. The ultrasonic treatment of mineral aggregates (P = 41.5 Watt, I = 15 W/cm2) made possible the liberation of fine particles of precious metals. Smooth-shaped or crystalline mineral aggregates are effectively liberated after acoustic treatment. Their surface is freed from impurities. The aggregates with the complex form and structure, which consist of the numerous plates and the grains, are not effectively liberated from impurities. It is shown that the ultrasonic treatment of aggregates with the fine inclusions of precious metals contributes to the liberation of the particles of platinum and gold and intensification of the gravity processing of refractory ore. This approach contributes the increase of the raw-material base of precious metals.

Jan 1, 2018

By Y. Nahmad- Molinari

We present a novel on line inductive sensor for the determination of the quality of the concentrates of iron ores. This device is coupled with a cheap USB Data Acquisition System that makes it versatile enough to simultaneously control up to seven fluxes at a very low cost (< $300 US dollars), and achieves a resolution better than 0.5 % on the determination of the magnetic iron content in the concentrate. A RLC circuit with its inductive element placed surrounding a sample of pure magnetite concentrate is tuned at its resonance frequency, by means of adjusting, the feeding voltage of a voltage-controlled oscillator (VCO) and several samples with mixtures of different contents of silica and magnetite are placed in order to get a calibration curve. After some signal conditioning, a National Instruments USB-DAQ NI-6008, acquires the amplitude of the signal via USB port on a PC using a Lab-View program designed for such purpose, in which the calibration curve is used for on-screen data presentation directly in percent of magnetite content. The implementation of this device for control purposes on line directly placed on the concentrators would allow better efficiency of the process and higher quality of the final concentrate by con-trolling; the rotation speed, the rising or dilution water fluxes or bypasses towards milling recirculation cycles.

Jan 1, 2014

By E. V. Bratygin, S. P. Elnikova

"In the article carrying out technique of experiments for estimation of power efficiency of process of crushing in cone crushers «in a layer». The conformity of the granulometric characteristics of the crushed products obtained as a result of the tests, the theoretical equations for the size characteristics, and the choice of the optimal equation for the prediction of the granulometric characteristics of the final products obtained by crushing ""in a layer"". Optimization of granulometric composition of power of crushers working ""in a layer"" is carried out with the purpose of reduction of the electric power consumption at reception of a product of required quality. As a result of the experiments, dependencies are obtained, the relevance and applicability of the crushing process ""in the layer"" for obtaining crushed stone of improved quality is proved. INTRODUCTION A number of equations have been proposed for calculating the breakage energy. These include equations by Kirpichev and Kick, Rittinger and Bond (Bogdanov, Olevsky, 1982). Another equation for calculating the specific breakage work in breakage by impact and in stratum was proposed by Devyatkin (Boiko, 2003). In these equations, the breakage energy is proportional to the particle size raised to some power. In the equation proposed by Devyatkin, the ore piece thickness or the feed average diameter is used. The relationship between energy and breakage can be expressed as an equation (Lynch, 1981; Tikhonov, no. 3, 2008) where k is a coefficient characterizing the energy parameter depending on the strength of the feed, l is size in microns. The Rittinger formula is obtained for n = 2, the Kirpichev-Kick formula for n = 1, the Bond formula for n = 1.5. For n = 3 or higher, the equation describes fine and ultrafine grinding. R. Hookey proposed a formula (Lynch, 1981, Tikhonov, no. 3, 2008), where the size exponent n is substituted by a size function In all of the above equations, a single value of the feed and product size is used; for example, in the Bond equation, size is defined as the particle size of the 20% oversize (P80 and F80). However, a single size value can represent multiple distributions, making that the Bond method inappropriate for determining the size (Lynch, 1981). Describing an equation for estimating the grinding energy will allow to design the electric drive and ore preparation circuit for the given breakage method."

Jan 1, 2018

By V. Avzian Belozersky reg 453524, Vasily V. Lodeischikov, Adolf F. Panchenko, Til E. Vidusov, Olga D. Khmelnitskaya, Vladimir E. Dementyev

"Presently, there is a number of gold deposits which cannot be developed using the conventional technologies with acceptable economic indices due to low gold content, high depth of ore occurence and other conditions. For such ores, an innovation technology of underground gold leaching in the place of their occurrence is of special interest. The technology excludes ore mining and hoisting to the surface. This enables the production cost of 1 g of gold to be considerably reduced in comparison with conventional methods of gold recovery.The Maminskoye deposit oxidized ores were chosen as the subject of underground leaching because they are ideally suited for this purpose due to their composition and hydrological parameters. The ore reserves within the underground leaching block are 90, 000 t with 0.7 g/t average gold grade.An experimental system for underground leaching with a throughput of 15 cubic m solutions per hour was developed. A combined filtration-and-infiltration system of the ore massif development by holedrillingwhere pregnant solutions are air-lifted was worked out.The underground leaching flowsheet includes Au dissolution by chlorine-containing solutions, Au adsorption from solution onto active carbon, carbon concentrate ashing and calcine melting to produce Dore metal."

Jan 1, 2003

By Graeme J. Jameson

In conventional flotation machines, the recovery is strongly related to particle size. As particle size increases, the recovery also increases, reaching a maximum in the range 20 to 120µm. Beyond this range however, the recovery declines quite quickly. The reason for the decline in recovery observed with coarse particles can be traced to the effect of turbulence. Bubbles trapped in turbulent eddies rotate rapidly, and when the centrifugal force on a particle exceeds the retaining forces due to surface tension, the particle detaches. Since the centrifugal force varies as the cube of the diameter of the particle, and the attachment force varies simply as the diameter, being proportional to the length of the contact line, it is clear that detachment forces will predominate as the particle size increases. The corollary is that the recovery of coarse particles can be improved if the level of the turbulence in the cell can be reduced to a minimum. In this paper, a new type of flotation machine will be described, in which the particles to be floated are suspended in a fluidized bed. An up flow of fluidizing water is provided, by recycling liquid from the top of the cell. The recycle stream is aerated in a high-energy device that disperses the air into fine bubbles that capture the fines and ultrafines. Results are presented for several minerals and coarse coal. Keyword: fluidized bed flotation

Sep 1, 2012

By Tsuyoshi Hirajima, Hideyuki Okamoto, Himawan .. T. B. M. Petrus, Keiko Sasaki

"Flotation of arseno bearing minerals from their copper ore has been an interest due to the increasing awareness on protecting the environment by minimizing the possibility of exposed arsenic compound. Some approaches have been proposed, but the mechanisms of separations have not yet fully understood. In this study, oxidation using oxygen was applied. Instead of the complex copper ore flotation results, pure single mineral of tennantite and chalcopyrite foatability was conducted using Hallimond tube. Resembled with the flotation results of copper concentrate containing tennantite, the separation possessed the best result at alkaline condition (pH 11) at where the arsenic content was reduced from 3300 ppm to 1800 ppm. In order to be able to understand the mechanism of the separation atomic force microscope (AFM) was utilized. AFM images showed changes in morphology and behavior when minerals were treated in both acid and alkaline condition. It was found that the morphological change showed the reaction products representing the rate of reactivity of tennantite and chalcopyrite. From the measured force of adhesion, it can be observed that in alkaline condition the surface of both minerals is more hydrophilic than that in acidic condition possessing higher value. This is in accordance with the X-ray photoelectron spectroscopy (XPS) spectra in which hydroxide moieties occupied the mineral surface in alkaline condition while elemental sulfur is in acidic condition."

Jan 1, 2014

By Milind Chikhale, Yogesh Reja, Keshav Tyagi

"Using computer models for process design is a well-established practice in the mineral industry. In recent years, there has been emphasis on modeling of processing plant as a whole. This paper covers development of a model for iron ore processing plant. Basic purpose of this model is to use simulation for efficient plant design and help in minimizing risk at the very initial stage of project. Feed to the plant is Hematite iron ore from a deposit located in Eastern India. Major processes in plant include multi-stage crushing, screening, grinding, classification, gravity and magnetic separation. Models for different process equipment were developed using METSIM and Bruno simulation software. Customized black box models and known mathematical models were used for predicting behaviour of processes. Data needed was identified based on the model type. The required data was arranged as per project requirement and processed for development and validation of model. Equipment models were developed and validated on the basis of process design basis, theoretical and empirical data from technical references, and bench scale and pilot scale testwork results. Validated process circuits were assembled to simulate and represent the entire plant process. The result shows expected variation in plant output as a result of variation in the feed. Study concludes by discussing potential applications of the model in plant design."

Jan 1, 2014

By Anuttam Patra, Romain Bordes, Andreas Fredriksson, Tommy Karlkvist, Krister Holmberg, Kota Hanumantha Rao

Almost all of the flotation reagents used today were discovered by continued application of empirical methods and/or trial and error experimentation. Moreover, with the metal-ion specific approach used so far, it is difficult to separate the minerals containing the same constituent metal ion. A critical assessment of molecular recognition processes involved in biomineralization suggested the possibility of using reagents which are surface specific. The concept that the molecules consisting of two or more functional groups having appropriate spacing between those so as to achieve structural/stereochemical compatibility during interaction with the mineral surface exhibit structure-specificity is thought to be extended to the design of specific collectors in flotation processes. In the present study, for the first time, a rational design of surface active molecules, and thereby the recognition of crystal faces (of minerals) by these molecules through structural and stereochemical matching is being utilized successfully to selectively float various minerals. For this purpose, carboxylate-based collectors (for mineral specific flotation of calcium minerals) as well as xanthate-based collectors (for mineral specific flotation of sulphide minerals) with a fixed alkyl chain length but having two functional groups with varying geometrical distances (separated by a spacer of one, two and three carbon atoms) between them have been synthesized. In this article, we have discussed the design, synthesis, purification of these novel mineral specific collectors as well as their important solution parameters in relation to flotation processes.

Jan 1, 2014

By David I. Verrelli, Boris Albijanic

"Froth flotation is an exceedingly complex physicochemical process. The convenience of distilling much of the complexity of the bubble-particle interactions into a single parameter has led to the continuing popularity of the classical ‘induction time’ to quantify the threshold for bubble-particle attachment to occur. Despite this popularity and the simplicity of the concept, there is no single universal method of evaluating the induction period. In this paper, we begin with a critical review of the available techniques for estimating the induction period. These are: back-calculation from experimental (micro) flotation tests; pushing a particle toward a stationary bubble (or vice versa) using an atomic force microscope (AFM); pushing a bubble toward a stationary bed of particles in the ‘Induction Timer’; pushing a bubble toward a stationary solid surface using the ‘integrated thin film drainage apparatus’ (ITFDA); and dropping particles onto a submerged stationary bubble using the ‘Milli-Timer’ device. Each one of these methods has advantages and disadvantages, and the best choice depends on the application. In the experimental section, we present quantitative comparison of the induction periods estimated using two different techniques, namely the Induction Timer and the Milli-Timer. The same particles were tested in each device, under the same conditions. It was found that by tuning the operation of the particle pick-up device, similar estimates of induction period could be obtained to the estimates made by direct observation with the Milli-Timer. In the former device a bubble is driven toward a particle bed at a controlled rate, whereas in the latter a particle’s motion is governed by the hydrodynamics. The potential to match these presents an intriguing prospect for better understanding the bubble-particle interaction, and the possibility to ‘calibrate’ the simpler Induction Timer against direct observations."

Jan 1, 2014

By K. Sasaki, H. Miki, Y. Muta, T. Hirajima, G. P. W. Suyantara

"Selective flotation of chalcopyrite and molybdenite is continuing problem since its selectivity is not perfect and current NaHS process needs closed system flotation plant because of hydrogen sulfide emission on acidic condition. Some alternative additives investigated as chalcopyrite became hydrophilic and molybdenite kept hydrophobic. XPS analysis indicated chalcopyrite became hydrophilic since iron and copper sulphate, hydroxide was covered on the surface whereas molybdenite kept hydrophobic since only molybdenite can be seen. Flotation experiments of chalcopyrite and molybdenite mixture sample indicated excellent separation that 95% of molybdenite can be recovered as froth and 93% of chalcopyrite can be recovered as sink. Flotation experiments with real bulk flotation concentration indicated similar separation result compared with current NaHS additive system. Possible mechanisms and detailed phenomenon were investigated based on the surface analysis and thermodynamic calculation etc. this alternative additive is easy to handle compared with NaHS since it does not emit effluent gas and commercially preferable.INTRODUCTIONMany copper mine often associates molybdenite (MoS2) as trace mineral. It is important to separate molybdenite and copper mineral efficiently since molybdenite is valuable mineral and also contamination of molybdenite into copper concentrate decrease concentrate value. Conventional separation of copper sulfide and molybdenite has been achieved with sulfide bulk flotation followed by selective molybdenite flotation with NaHS addition since NaHS works as a depressant for copper sulfide (Bulatovic, 2010; Ansari and Pawlik, 2007b). However, this current process shows imperfect molybdenite recovery (Liu et al., 2012, Zanin et al., 2009) and depressant such as NaHS needs to be used under specific flotation plant since it might be environmental contaminant (Ansari and Pawlik, 2007a). there are still unknown on the effect of depressant NaHS, but one of the theory is NaHS reductant effect. It is worth to investigate the effect of other reductant as depressant on chalcopyrite. On this research, typical reductant, Na2SO3 are added to utilize for selective flotation of chalcopyrite and molybdenite."

Jan 1, 2018

By Grigori I. Voiloshnikov

"The long-term studies on development of the technology for precious metals recovery using activated carbons executed by Irkutsk Research Institute of Precious and Rare Metals and Diamonds (IRGIREDMET) were finished by successful introduction of ""Carbon-In-Pulp"" process in Russia (1984).The review of some studies, accompanied by development, testing, introduction and subsequent improvement of considered technology, carried out by IRGIREDMET is submitted in this paper.The basic regularities of gold and silver adsorption onto activated carbons from cyanide, thiourea, chloride and other solutions are investigated using various phisical-and-chemical methods ( X-ray photoelectron spectroscopy, Voltammetry, X-ray microanalysis etc.). Using voltammetry it was found that gold cyanide is adsorbed onto activated carbon without chemical changes and partial reduction of gold is possible only during drying of carbon samples before analysis. Metallic gold and silver may be dissolved in boiling cyanide solution at argon atmosphere when they are in contact with activated carbon surface. Gold adsorption mechanism for activated carbons has great differences from that for the ion exchange resins. So the most probable mechanism for gold adsorption from cyanide solution is adsorption of neutral molecules Me n+[Au(CN)2-]n.X-ray quantitative microanalysis technique was developed to investigate gold adsorption kinetics onto spherical activated carbon. Gold profiles in granules of activated carbon for various adsorption conditions were tested (carbon particle size, mixing efficiency, adsorption time etc.). Mathematical methods were used to determine gold diffusion coefficient within activated carbon granule.The properties of various types domestic and foreign activated carbons were tested and the demands to activated carbons suitable for gold extraction were determined. As a result foreign and Russian activated carbons AG-90, AG-95 were recommended for use at Russian gold plants. Domestic adsorbents are cheaper in comparison with foreign activated carbons. The methods to restore carbon adsorption activity including acid treatment and thermal reactivation were tested and implemented."

Jan 1, 2003

By S. Kelebek, A. Khan, J. Caceres, D. Beckett

"Pyrrhotite in nickel-copper sulphide ores is nickeliferrous and intimately associated with pentlandite. Due to its low nickel content, pyrrhotite rejection is an important step in processing of these ores. In our laboratory, various reagents were investigated for their effect on pyrrhotite depression. Among these, a combined use of triethylenetetramine and sodium metabisulphite was found highly promising.The work described in this paper has two parts. The firs part is a summary of results obtained on process samples from the pyrrhotite rejection circuit at Falconbridge’s Strathcona Mill. The second part involves simulation of the circuit performance based on the reagent conditions used in the experimental work and the concept of split factors.Two sets of reagent conditions were evaluated. The first one involved baseline conditions, simulating the current reagent performance. The second one simulated the impact these new reagents can have on the circuit performance.The simulation results obtained under baseline conditions indicated a good agreement with the current circuit performance (Figure 1). The simulation results suggest that at practically the same pentlandite recovery and tailing grades, the circuit concentrate nickel grade can be doubled through effective pyrrhotite rejection by these new reagents (Figure 2)."

Jan 1, 2003

"The effect of operational conditions, such as air flow rate, impeller speed and solid concentration, as well as the effect of solids concentration and frother dosage, on the bubble size distribution produced in a lab scale flotation cell, were investigated. The cell was operated under batch conditions. The measurement of bubble size was accomplished using an automated photographic technique. The technique enabled fine and coarse bubble distributions to be measured in two-phase (liquid-gas) and three-phase systems (solid-liquid-gas). In each experiment, around ten thousand bubbles were characterized.This paper discusses the main results obtained using the new photographic technique and compares these with previous findings available in the literature. The results indicate that photographic techniques combined with digital imaging processing might become a standard technique for measuring bubble size distribution in flotation machines.HUT BUBBLE SIZE ANALYSERThe importance of having precise and reliable equipment for measuring bubble size distribution in industrial flotation machines has been widely recognized. The measurement of bubble size, particularly in three-phase systems, is rather complex due to the opaque nature of the pulp. However photographic techniques combined with ingenious sampling techniques are utilized for overcoming this difficulty. The technique named HUT, combines previously developed visualization methods with digital image processing procedures. In this technique bubbles and aggregates are exposed to a monochrome progressive scan camera. The acquired images are directly stored in a computer connected to the camera for post-processing. The sampling apparatus consists essentially of a vertical tube for collecting bubbles, a viewing chamber and a collection chamber, where particles carried by the bubbles are released. The function of the collection chamber is to maintain the viewing chamber clear for imaging purposes. Each image is automatically processed off-line, using digital image tools. In this paper the advantages and limitations of this new technique are described."

Jan 1, 2003

By D. B. Sundar Ramam

In the recent past, a paradigm shift in terms of resource utilization and beneficiation practices is experienced by the Indian mining and mineral sector. Depleting iron ore reserves coupled with increasing demand for low-alumina iron ore fines to improve blast furnace performance in terms of productivity and reduced slag rate necessitate intensive beneficiation of iron ore. The task is even difficult for Indian iron ores, which are generally high in iron content and at the same time characterized by aluminous gangue. In 2006, M/s Tata Steel commissioned a state-of-the-art Jigging Plant (Batac Jig) at Noamundi Iron Mine (NIM), mainly to reduce alumina in iron ore fines. The jigging plant is incorporated in the existing beneficiation circuit to treat ?10+0.5mm size fraction of classifier fines. Over the course of plant stabilization while the plant could deliver desired ore upgradation and average product alumina, variability in terms of alumina content has been a concern. This paper discusses a case study of process parameters optimization in jigging operation to achieve consistent product quality while improving the effectiveness of gravity concentration for the beneficiation of Noamundi iron ore also to take care of inferior plant feed (input) grade year on year. The operating variables used to optimize jigging operations include bed height, pulsion and suction time, particle size, strokes, and plant throughput rate.

Sep 1, 2012

By T. A. Penzov

As a result of recent scientific and experimental studies new technical devices have been developed for monitoring and control the process of grinding. The description of microprocessor module MILLCONT 1 for control of the loading of the mill and microprocessor density control module DENSIMETER is given in the paper. The improved variant of the automatic system for ore grinding control in single-stage ball mill working in close cycle with a classifier with above mentioned technical means is shown in the paper. The loops for measuring and stabilization of the basic technological parameters (density of the ready pulp ? and fineness of grinding of the pulp ß) are described in the paper. The nowadays economic results in ore grinding process automation are given as well.

Jan 1, 2014

By Luís Marcelo Tavares, Juliana Segura

Comminution is one of the most energy consuming stages in a mineral processing plant. This consumption is not only related to the power supplied to equipment, but also to the indirect or embodied energy, mainly associated to materials that are worn during operation, including grinding media and liners. Until recently, preparation of iron ores in Brazil did not use comminution intensively, given that plants mainly produced sinter feed, natural pellet fines, besides lump ore. However, with decreasing ore grades, size reduction now occupies a centre stage in nearly all new plants. Technologies used up to date for processing low-grade iron ores in Brazil, in particular itabirites, have consisted of three or four stages of crushing followed by ball milling. A number of new plants are either being built or are currently being designed that will process the same type of ore, so that engineers are investigating alternative comminution routes. The paper analyses comparatively four comminution routes for processing a particular itabirite ore, many of which using technologies and layouts that have not yet been used in such application. Using data from bench scale and/or pilot-plant tests, the different routes are compared on the basis of sustainability principles in accordance to the Brazilian energy matrix, which is quite particular. It is concluded that if the sustainability criterion is used, then the optimal route would correspond to a circuit that uses HPGR technology with truncated feed followed by ball milling. Given the particular case of itabirite iron ores and specially to the one in the present work and the source of Brazilian energy, it is evident that indirect energy expenditure in comminution plays a significant role in greenhouse gas emissions when compared to direct energy, being the reason for the great attractiveness of HPGR technology. Evidently that these will have to be balanced against CAPEX, OPEX, NPV and other qualitative criteria, which can certainly lead to a different optimal circuit.

Jan 1, 2014

By Andrzej Luszczkiewicz, Tomasz Chmielewski, Jan Drzymala, Andrzej Konieczny, Rafal Kaleta

Properties of the sedimentary Polish copper ore mined from the Legnica-Glogow Copper Basin (SW Poland) by KGHM Polish Copper S.A. were presented and currently used beneficiation technologies were described. Due to a unique lithological layered structure of the polymetallic deposit and existing mining system, the ore currently processed in the three KGHM concentrators is very complex with variable content of the carbonate, sandstone and shale fractions. The mined copper ore contains from 0.8 to 1.8 % Cu and Ag, Pb, Zn, Ni, Co, V and Mo as accompanying metals. The paper presents difficulties in upgrading the LGOM ore and selected possible solutions and development concepts of its processing. The first one is a chemical treatment with controlled amount of sulfuric acid of special product of flotation such as for instance middlings. The acid treatment leads to increased liberation of copper minerals and better further processing. Another concept is atmospheric leaching in oxygenated sulfuric acid and ferric ions solution as the major unit operation applied to selected low grade final flotation concentrates or flotation by-products. The third approach, based on copper ore pre-flotation with a frother to partially remove Corg, is also considered.

Jan 1, 2014

By Glasswell K. Nkonde, Fredrick Chileshe, Steven Simukanga

Improving food security by increasing crop output is a primary objective for most countries in the sub- Saharan region. Most soils in the region are deficient in phosphorus an important nutrient after nitrogen in plant growth. Phosphates are therefore used together with nitrogen and potassium based fertilizers in improving crop production. Zambia like many other countries in the sub-Saharan region imports phosphate fertilizers for use by its farmers. However, indigenous phosphate deposits of igneous origin exist in Zambia of which the main ones are Chilembwe in Petauke district, Mumbwa sugarloaf in Mumbwa district, and Nkombwa Hill in Isoka district. If commercially exploited, these deposits could become a ready source of inexpensive phosphate for the local farming communities in the country. Previous research has shown that partially acidulated phosphate rock (PAPR) produced using Chilembwe phosphate rock is just as agronomically effective as the imported superphosphate fertilizers on food crops in most of the Zambian soils. PAPR is produced by reacting finely ground phosphate rock with only a fraction (usually 50%) of the stoichiometric quantity of the sulphuric acid required to fully convert the apatite in the rock to monocalcium phosphate thus making the process cheaper in terms of acid consumption than the poduction of single superphosphate where the apatite in the rock has to be fully converted to monocalcium phophate. The factors that affect the percentage of available P2O5 in the PAPR produced include particle size of phosphate rock, degree of acidulation, concentration of acid, process temperature profile, residence time and drying temperature. These factors were studied in a 25kg/hr PAPR pilot-plant in the School of Mines at the University of Zambia using Chilembwe phosphate rock. The PAPR pilot-plant consisted of a rotary drum granulator as the main reactor, a rotary drum dryer and a triple deck vibrating screen. Ground phosphate rock was reacted with sulphuric acid and water in the granulator to form a granular product which entered the drier. The dry product was screened into three size fractions. The 1 – 4 mm size fraction was the final product whilst the –1mm size fraction was recycled. The +4mm size fraction was sent to a crusher while the crushed PAPR was sent back to the screens.

Jan 1, 2003