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By R. Wirth, B. Orberger, C. Wagner, A. Tudryn, B. Baptiste, S. Miska, Université Paris-Sud

Banded iron formations (BIFs) comprise complex textures and mineralogy, which result from fluid-rock interactions related to high and low temperature alteration. The initial iron oxy hydroxide mineralogy and associated phases such as carbonates, quartz, apatite and phyllosilicates were transformed leading to an upgrading of these BIFs into the world’s largest source of iron ore. In low-grade BIFs, a large part of the iron is related to micro- and nano- metric iron-bearing inclusions within micrometric quartz and/or carbonates (mainly dolomite). We studied laminated jaspilitic BIF samples from a drill core containing 26.71 wt.% total iron, 0.2 wt.% SiO2, 0.32 wt.% MnO, 15.46 wt.% MgO, 22.32 wt.% CaO, 0.09 wt.% P2O5, < 0.05 wt.% Al2O3, 0.15 wt.% H2O and 34.08 wt.% CO2 (Aguas Claras Mine, Quadrilatero Ferrifero, Brazil). Bright rose coloured dolomite and quartz bands alternate with massive specular hematite bands. Raman spectroscopy, X-ray diffraction and FIB-TEM analyses reveal that the micro- and nanometric inclusions in dolomite are mainly hematite and minor goethite, partly occurring as clusters in voids. Curie Balance analyses were carried out at different heating steps and temperatures on whole rock samples and a synthetic mix of decarbonated sample and pure dolomite. X-ray diffraction on the products of the heating experiments shows that that hematite is stable and new phases: magnesioferrite (MgFe2O4), lime (CaO), periclase (MgO), portlandite (Ca(OH)2) and srebrodoskite (Ca2Fe2O5) were formed between 680°C and 920°C. These finding gives hints to optimizing the beneficiation process, as the presence of hydroxyl ions bearing goethite micro- and nanoinclusions lowers the sintering temperature. Prior separation of coarse hematite and barren dolomite and quartz, followed by lower temperature sintering of the inclusionbearing dolomite/quartz leads to transformations into phases with higher magnetic susceptibilities (such as hematite and magnesioferrite). The entire Fe and Fe/Mg oxide feed (the priorly separated fraction added to the sintered fraction) can then pass through wet-high intensity magnetic separation after crushing.

Jan 1, 2016

By S. W. Marcuson, P. J. Mackey

The Canadian non-ferrous mining and metallurgical industry has made great strides in environmental protection during the past half century. The path taken by the copper-nickel smelting industry in reaching today’s level is traced in this paper. Following the practice at early copper smelters in Wales and in the US, Canadian smelters originally used tall stacks to disperse furnace of-gases. This was the normal mode of operation and was accepted by society and by Government. Gradually, Government regulations required fixation of sulphur dioxide emissions and Canadian companies responded with significant technical developments to achieve this result. The initial development in Canada of the first new technologies such as the Cominco Flash Suspension Roaster and the Freeman Flash Smelting Process - both representing early versions of the modern established flash smelting technologies - and then later technologies such as the Inco Flash Smelting Process and the Noranda Process, both of which continue to this day, are discussed in this paper in terms of their contributions to the development of environmentally friendly plants. The evolution of these and other technologies is also discussed. Some comments regarding how the industry will face the future are also included.

Jan 1, 2015

By S. McCalpine, W. Muir, P. J. Downey

"Golden Bear Operating Company Ltd. (GBOC) was a joint venture between Chevron Minerals Ltd. and North American Metals Corp. that was formed for the development of the Golden Bear Project. The mine is located at Muddy Lake, Western British Columbia, approximately 80 km northwest of Telegraph Creek and 135 km west of Dease Lake (see Figure 1). Road access to the mine was developed by Golden Bear and consists of a radio controlled 155 km gravel road originating at highway 114.A feasibility study was completed in 1987 and project approval was finalized in 1988 with Golden Bear issuing a ""Request For Proposal"" for detailed engineering in May 1988. Golden Bear also commenced negotiating with vendors at this time for the supply of the two principal process equipment packages: the dry grinding and classification system and the whole ore roaster package.Process plant engineering and plant construction was completed in October 1989 with plant startup commencing in November 1989. Two months into the commissioning phase it became apparent that the plant, as designed, would not achieve the anticipated production targets.Kilborn Engineering Pacific were subsequently contracted by GBOC to review and modify the plant design, assist the operating personnel with plant commissioning and startup and provide operator training.This Paper describes some of the problems encountered during the startup and the plant modifications incorporated to achieve design parameters."

Jan 1, 1992

By D. Fodor

In Romania, there are significant lignite and brown coal reserves hosted by different regions of the country. The most important lignite bearing zone of the country situated in the North ? West part of Oltenia region and which covers a surface area of 2,500 km2 and host a total reserve of 3.0 billion tons of lignite, of which more than 95% can be exploited by open cast method. The paper deals with the existing geological and mining conditions of the zone , the distribution by mining basins and exploitation perimeters, the open cast working technologies and the economic outcomes obtained throughout the time. Years ago, for the improvement of the economic situation as a whole and in each unit, a large production reorganization, technology update and modernization process was started up. There are described the rehabilitation measures of the technological lines and modernization of the equipments of the production flow-sheet, measures developed at present, too and which will still continue in future. There are mentioned the equipments considered, the components under modernization and the economic outcomes obtained so far. At the end of the paper there are presented the future actions for the equipment modernization and perspectives of the lignite deposit exploitation to meet the national economy requirements of solid fuels.

Aug 1, 2013

By C. Droun

"Low back pains account for about 13 per cent of all compensation claims made to the Quebec Workmen's Compensation Commission and cost the employers a sum exceeding ten million dollars. The frequency and cost of these health problems in Quebec metal mines are proportional to the provincial trends. An elaborate review of the literature on the causes, nature and prevention of low back pain is made in this presentation. A prevention program for low back pain has been designed in cooperation with a team of seven medical specialists and two physiotherapists for the Quebec metal mines. The program is especially designed for persons who have had low back pain, in order to prevent a recurrence, and for persons beginning to feel chronic difficulties. It is based on existing programs at the Hawthorne Plant of Western Electric Company and at Minnesota Mining and Manufacturing, but it requires a much different approach because of the nature of medical care available at the mining sites. The program is difficult because it involves a change of attitude for every employee and every supervisor. The program, so far, is beneficial because several men are now seriously engaged in an active program of reconditioning and because the problem of low back pain ie beginning to be seen from a new angle."

Jan 1, 1973

By F. Qi, T. Frišcic, C. Mottillo

"One of the principal goals of modern industry is to minimize the environmental impact and increase the materials- and energy-efficiency of transforming raw materials into valuable products. This paper will highlight our latest laboratory-scale research in low-energy, low-solvent reactivity of metal oxides and their conversion into popular metal-organic frameworks (MOFs), zeolitic imidazolate frameworks (e.g. Basolite® Z1200 component ZIF-8), and metallodrugs (e.g. bismuth subsalicylate, active component of Pepto-Bismol®). Mechanochemical ion- and liquid-assisted grinding (ILAG) and ""accelerated aging"" techniques will be presented, along with novel low-energy and solvent-free approaches, inspired by geological weathering processes, for converting metal oxides into metal-organic materials. INTRODUCTIONThe development of environmentally-friendly processes, which would in the same time be more materials- and energy-efficient than the existing ones, is one of the central concerns of modern chemical research. In that sense, the focus of the chemist has been mainly on the preparation of carbon-based organic molecules and adaptation of traditional organic synthesis to the recently delineated ideals of Green Chemistry. However, there is a growing realization within the chemistry community that significant energy, materials, and ecology-related benefits can be achieved and, indeed, targeted in the transformations of materials that are typically associated with inorganic chemistry and minerals processing. The principal aim of this highlight contribution is to illustrate how, through the use of approaches associated with solventfree chemistry and mechanochemistry (James et al., 2012), one can develop a clean and efficient system of chemical and materials transformations involving oxide precursors that normally belong to the realm of inorganic chemistry and mineral processing. In particular, this contribution will provide an overview of the recently developed mechanochemical and solvent-free reactivity of metal oxides towards small organic molecules. These mechanochemical reactions, including the methods of liquid-assisted grinding (LAG, Frišcic & Jones, 2009) and ion- and liquid-assisted grinding (ILAG, Frišcic, 2010), have so far provided a radically different means to construct advanced metal-organic materials (e.g. porous metal-organic frameworks, [MOFs] or metallodrugs) by rehabilitating metal oxides as precursors, eliminating the use of bulk organic solvents, and avoiding the use of high temperatures."

Jan 1, 2012

By Sherwin F. Kelly

"THE TITLE I have chosen is certainly not one of those self-explanatory ones. I shall endeavour to make its significance clear during my remarks but, in the hope of minimizing that inevitable exodus which follows a good lunch such as this, I am going to withhold the final key to its meaning until the very last sentence of this talk.Some explanation is due at the beginning, however, so for those of you unfamiliar with Spanish I will explain that casa means house, or home. The casa about which I am going to talk necessitates a wide .and generous interpretation of the word, because I am using it to indicate principally that portion of the North American continent which is the home, in the western hemisphere, of British and American ideals of justice and freedom, the dignity of the individual and his right to exercise private initiative .and engage in private enterprise. In a wider sense, I am including the entire western hemisphere, which may yet stand as the last bulwark of political and industrial democracy.As for the treasures of which I am about to speak, may I remind you that there are no• material treasures but those derived from the earth, and they are derived by one of two processes, -mining and farming. These two fundamental industries are the basis, and the sole material basis, of our welfare, our wealth, our very existence. From farming, whether it be farming of the land. or farming of the sea, we obtain the food to keep us alive, healthy and able to work."

Jan 1, 1955

By C. F. Gleeson, D. G. Sheehan

"The results of humus and overburden geochemical surveys over the Doyon, Bousquet and Page-Williams gold ore deposits are presented.These studies show that humus sampling for gold gives negative results over the Doyon deposit. The lack of response is probably caused by the presence of 1 m of relatively impermeable glaciolacustrine clay and silt that overlies 1 m to 2 m of till over the surface expression of the ore zone. By contrast, positive responses for gold occur in humus samples over the Page Williams A and C gold deposits. The ""A"" ore zone is covered by several metres of exotic calcareous till over 0.5 m to 1 m of older, locally derived till. Anomalous values for gold in humus range from 10 to 35 ppb over the orebody. Overburden over the ""C"" ore zones is much thinner, generally it consists of less than 2 m of sandy till. Trenching humus anomalies that range from 10 to 1360ppb Au uncovered the gold mineralization. The geochemical dispersal trains in till from the Doyon orebody and the Page-Williams ""A"" zone are relatively short (i.e. less than 200 m) because both deposits occur in the lee of bedrock highs that shielded them from extensive glacial quarrying. Dispersal trains from all three pyritic gold deposits can be defined using either the fine fraction or heavy mineral fraction of the till.The intensity of the gold in till anomalies over the ore zones is variable. Therefore, it would be misleading to attach rigid significant threshold gold values to overburden drilling results. Each case must be evaluated based on bedrock topography, sample density, overburden type, thickness of till, as well as size, type and orientation of the target exposed to glacial erosion."

Jan 1, 1987

By J. -P. Saindon, L. D. Nel, A. E. Hall, S. G. Hardcastle

"This paper reports on an investigation into gas and dust concentrations in Ruttan Mine&apos;s exhaust air. The values obtained indicate that there is excellent potential to recirculate approximately 25% of the hot exhaust air into the intake air to reduce winter heating costs. Contaminant concentrations vary significantly during the course of the working shift and decrease in the mine exhaust system as the air returns to surface. A proposed on-line control system is outlined which would permit recirculation to be implemented with a pay-back period of less than two years. IntroductionIncreased energy costs and depressed mineral prices have resulted in mines, which use winter ventilation air heating, reviewing their systems to try to reduce costs. Heating costs can be significant, for example, Potash Corporation of Saskatchewan spends an average of $580,000 per mine per year and Ruttan mine spends approximately $IM per year on propane for its direct-fired heating system.Several method s of reducing heating costs have been considered and the following have potential application.Heat Exchange Between Exhaust andIntakeThis is usually accomplished by run-round glycol systems. The system is limited by ice formation on the coils in wet exhaust air and by the low exhaust air temperature, usually l0ºC. It also requires close proximity of the intake and exhaust airways to ma~e the cost of the connecting pipeline and pump systems economic . A feasibility study by Inco&apos;s Thompson operation reported that a proposed system of this type had a 19-year payback period and was, therefore, uneconomic. Potash Corporation of Saskatchewan is currently investigating plastic heat exchangers for a trial system because of corrosion on metal exchangers. It has the advantage of a 17°C exhaust temperature and relatively dry exhaust air.Waste Heat ReclamationThe waste heat from compressors and hoists can be used for heating in some mines. The feasibility of such a system depends on the individual layout and the proximity of the heat source to the inlet airway. Other mines have considered using the exhaust air in greenhouses to provide a cash crop."

Jan 1, 1988

By J. P. Landriault, F. W. Harrison

"Zinc-iron alloy coatings can be produced by either thermally alloying hot-dipped galvanized steel or by electro deposition. Stelco Inc. produces a thermally alloyed Zn-Fe alloy-coated steel, which is mechanically wiped to remove free zinc.A more extensive use of Zn-Fe alloy-coated steel has been predicted for unexposed autobody and structural part applications, since this material is characterized by good spot weldability and formability, and provides superior corrosion resistance under automotive primers.This investigation has examined the coating composition, corrosion resistance, spot weldability and formability of Stelco&apos;s Zn-Fe alloy-coated steel and found its properties to be similar to those of Zn-Fe alloy-coated steel produced by post coating annealing.IntroductionRecently, there has been increased automotive interest in galvanneal, which is characterized by good spot weldability, good paintabilityt and good corrosion resistance when primed. Stelco produces a thermally alloyed zinc-iron coated sheet product similar to galvanneal. However, this product is produced by mechanically wiping the free zinc from the surface of hotdip galvanize to expose the underlying zinc-iron alloy.The surface of Stelco zinc-iron alloy-coated sheet is matte gray and has longitudinal streaks which result from contact with Kevlar wipers during production (Fig. I). This paper describes the coating composition, corrosion resistance, weldability, formability and surface appearance of Stelco zinc iron alloy coatings and, wherever possible, compares these properties to those of galvanneal."

Jan 1, 1987

By Ronald E. Hamilton

"An attempt to review the recent literature on comminution reveals at once that the subject has many ramifications and that the applications are so diverse that there are very few general statements which can be made.It. seems reasonable to start classification on the basis of size of material as Input to the comminution process. However, we find that this can only be done in a very imprecise manner.The initial step of breaking rock from its natural state of very large pieces in geological formations into sizes suitable for processing is accomplished by blasting. This step in the process has not been ex-amined in this project except to note that great changes have been made during the last decade or so in the explosives used, and in the method of handling them. We should determine what effect changes in mining methods can have on the need for crushing.The second step in the process is usually primary crushing, performed by gyratory or jaw crushers. The largest chunk which can be fed to a jaw crusher depends on the size of the machine, and should be larger than the largest fragment produced in the miring process. It is obvious that the larger the crusher, the less care required in mining to en¬sure the absence of rocks too large to be crushed. The optimum size of crusher to minimize overall cost of mining and reduction is not at all obvious, and no information on this point has come to light in this investigation.It is rather generally accepted that size reduction is most efficiently done in small stages, and that different machines have different opti¬mum size ranges of feed. For example, crushers are preferred for sizes above about 1"", rod mills for the range between 1"" and 0.1"", ball mills are preferred from 0.1""down to perhaps 10 microns, and vibratory mills, or jet mills, below 10 microns."

Jan 1, 1976

By I. S. Parrish

The Sullivan Mining Group has been exploring the mineral deposits of the Mount Pleasant area of southern New Brunswick since 1967. Sullivan geologists have logged over sixty miles of drill core, mapped over five miles of underground workings and studied numerous surface exposures. Several mineralized zones have been defined and two higher-grade porphyrytungsten bodies delineated. Within these bodies, wolframite occurs as disseminated specks and grains up to one-half inch in diameter. The host rock is a brecciated rhyolite porphyry that has intruded quartz-feldspar porphyry of Mississippian age . The host rock is itself intruded by an acid porphyry called transition rock and is underlain by a microgranite. The mineralized zones, host rock, transition rock and microgranite are all thought to be derived from the same magma, and to represent progressive fractions from that magma.

Jan 1, 1978

By J. A. Stewart

"A common problem in the mining industry involves the overloading of established conveyor systems. This overloading can have a number of causes, such as new production technology or a changing market condition which increases demand. An overloaded system usually spells disaster and leads to clean-up problems, equipment failures and lost production. The Cape Breton Development Corporation&apos;s Lingan Mine had a serious overloading situation on its underground coal clearance system, and equipment was being damaged and production was being lost. It was rectified, in part, by increasing the coal clearance capacity through the use of booster conveyors. This paper discusses the problems which led to this situation, the booster concept and the installation of the first unit at the Lingan Mine.IntroductionThe Lingan Mine is a submarine coal mining operation with an annual production of 1.5 million tonnes from three advancing longwalls. Coal is conveyed 3400m up a 13% slope to the surface. Designed and installed in the early 1970s, the system&apos;s 820-tonne/hour design initially proved adequate; however, by the late 1970sthe system was handling surge loads of 1640 tonnes per hour due to the introduction of new face equipment.The coal clearance system consisted of three 485-Kw, two 210-Kw and one 105-Kw conveyors. Each conveyor was designed for 820 tonnes per hour using 1050-mm, Type 10 belt with a 35-degree troughing profile.There were many effects of the overloading on the system:• Loading beyond the physical capacity of the belt resulted in spillage along the conveyor, which increased operational and maintenance costs.• Overloading of the drive components resulted in premature equipment failures.• Spillage at the drive pulley often resulted in damage to the belt and pulley lagging and, under extreme conditions, the conveyor would require partial unloading before it would operate. This was a particular problem under wet conditions because the 485-Kw conveyor drives were fitted with single-drive drums."

Jan 1, 1982

The construction, commissioning and operation of a continuous pilot-scale selective agglomeration (oil agglomeration) unit are described. This plant has been used to recover fine coal from an effluent stream that is produced by a jig plant which scalps the coal from a New South Wales (Australia) colliery. The reject slurry is extremely fine (66.5% minus 53 um) and has an ash content of approximately 40%. The pilot plant can treat up to 0.3 tonne/h of this slurry, producing average product ashes as low as 9.1% and tailings ashes greater than 80%. The average yield observed was62%, which corresponded to a recovery of coal material of 88%. The operation of this pilot plant yielded data that enabled an economic assessment of this type of processing to be carried out. This study showed that selective agglomeration is an economically viable process for eliminating the substantial losses of coal to tailings ponds and minimizing consequent disposal and environmental problems. A commercial plant has been constructed and commissioned on the basis of the data obtained from this pilot-scale operation.

Jan 1, 1979

By Benjamin A. Allou

La seule production de columbo-tantalite réalisée en Côte d?Ivoire est effectuée dans les éluvions et alluvions du gisement d?Issia, localisé au Centre- Ouest de la Côte d?Ivoire. Même si un lien direct avec les roches granitiques est suspecté, aucune attention particulière n?a été accordée à l?étude de la minéralisation primaire en relation avec l?évolution des granites et des pegmatites associées. Ces granites, qui sont en intrusion dans les roches sédimentaires du Protérozoïque inférieur, comprennent : le granite orienté à deux micas (Lobo), le granite orienté à muscovite dominante (Bitapia) et le granite porphyroïde non orienté à muscovite dominante (Issia). Les résultats de cette étude indiquent que les pegmatites à Nb-Ta-Be-Li sont liées au granite de type Issia. Les observations de terrain et les analyses sur roche totale des granites montrent que: (1) les trois principaux granites de la région sont de type- S et peralumineux dans leur composition, (2) ils ont été formés pendant la période tardi- à post-Éburnéenne, (3) le granite d?Issia fut le dernier à se mettre en place. Les pegmatites liées au granite d?Issia ont été classées en quatre types : Apegmatites stériles; B- pegmatites à Be; C- pegmatites zonées à Nb-Ta-Be; et Dpegmatites zonées à Be-Nb-Ta-Li. Les pegmatites zonées comprennent les zones suivantes: I- zone à aplite; II- zone graphique; III- zone à albite, microcline, béryl et columbo-tantalite; IV - zone à microcline massive; V- zone à quartz. Ces pegmatites présentent une zone d?altération métasomatique externe. La minéralisation de Ta, Nb et Be est liées à la zone III des pegmatites de types C et D, et celle de Li est associée aux greisens qui peuvent être observés n?importe où dans les pegmatites de type D. Les données de terrain et de laboratoire indiquent que le granite d?Issia est la roche parentale des pegmatites à éléments rares de la région. Les pegmatites minéralisées sont distribuées seulement autour du granite d?Issia et les patrons des terres rares des granites et ceux des pegmatites à éléments rares sont très similaires. Les analyses de la composition totale montrent un lien génétique entre le granite d?Issia et les pegmatites à éléments rares. Il est suggéré que les pegmatites ont été formées durant le transport et la cristallisation fractionnée du magma.

May 1, 2003

By G. R. Brough

"Today it is more important than ever to get the maximum possible return on capital invested in the processing industry. To this end the plant is often operated continuously and the choice of equipment is, consequently, extremely important.Screening spans a wide range of particle sizes and there are many different types of screening elements. The following types are common:1. Cloths and elements of rubber.2. Wire mesh screens with round wires.3. Wire mesh screens with profiled wires.4. Perforated steel plates.5. Elements of plastic.6. Gratings of steel beams.7. Gratings of iron rods.We would like to deal with two of these types namely rubber and briefly on plastics.We first introduced rubber screens to the Canadian Mining Industry in November, 1963. This stemmed from a conversation with the superintendant of one of Canada's largest screening plants containing 48 vibrating screens, with an average wire cloth life of 10 to 12 days. We contacted the manufacturer of rubber screen cloths who had supplied rubber screens to a mine in Northern Sweden for a 50,000 ton per day plant in 1951."

Jan 1, 1983

By E. J. Sun

The ADS system was developed to reduce accidents related to haul trucks operating under low visibility conditions in surface mining and construction sites, which is based on the GPS, mesh-wireless networks, and the Google-Earth 3D graphic engine as the graphic interface and mine-mapping server. This system has the capability to pin-point and track vehicles in real time using a 3D interface, which is based on user-based AutoCAD mine maps using the Google-Earth graphics interface. All equipped vehicles are shown in a 3D mine map stored in a local server through a wireless network. When low visibility conditions are present, the system indicates available exit/escape routes for driver safety. The research results indicate that the ADS system potentially increases reliability and reduces uncertainty in open pit mining operations by customizing the local 3D digital mining map, constructing the truck 3D models, tracking vehicles in real time using a 3D interface and indicating available escape routes for driver safety.

Oct 1, 2009

By B. Tanda

A process has been developed at Curtin University whereby glycine is used in an alkaline environment to leach gold, silver and copper from their ores, concentrates, process intermediates and wastes. Copper mineralisation investigated includes various oxides, sulfides and native copper. The leach process utilises an oxidising environment such as oxygen. Glycine is a non-toxic, non-volatile, edible, low cost reagent which is produced in large industrial quantities for use in several industries. Glycine and its copper and precious metals complexes are stable over wide pH, Eh and temperature ranges. Other than losses in leach residues, the glycine is recovered and recycled for leaching. Iron dissolution is insignificant in the pregnant leach solution. Iron in pyrite remains unaffected, whereas iron associated with base metal sulfides (e.g. chalcopyrite and bornite) is converted to a readily filterable iron hydroxide. Efficient separation of copper by solvent extraction and conventional electrowinning has been shown to be feasible for a number of organic extractants, whereas gold and silver glycinates adsorb very well onto carbon allowing CIP/CIL/CIC (carbon-in-column) based processes. The process is ideal for ores containing acid-consuming gangue, concentrates with high arsenic or halide contents and for copper-gold ores with significant sulfide mineralisation. The process eliminates many of the problems associated with the processing of copper-gold-silver ores, such as elemental sulfur formation, silica gels, unwanted metal co-dissolution, and jarosite precipitation. The reagents used and process residues are much safer and environmentally benign than conventional process options. The processing technology can be applied to in-situ, heap and vat, or agitated tank leaching at temperatures ranging from ambient to below 100?C at atmospheric pressure and is currently being commercialised. This paper will focus on copper leaching and recovery and iron rejection from a chalcopyrite flotation concentrate.

Jan 1, 2016

By C. J. Brown

Controlling the level of impurities in copper refinery electrolytes is essential to achieving acceptable cathode purity. Purge of electrolyte is not an entirely satisfactory solution since the cost of neutralization, waste disposal, and replacement acid can be appreciable. The APU® process utilizes ion exchange resin to sorb sulphuric acid while rejecting metal salt impurities. Extensively employed for recovery of waste pickling and anodizing acids since 1977, the system is now being used at several refineries for removal of contaminants such as antimony, bismuth, iron, and nickel. The purified acid, which is recovered from the resin by water elution, is recycled back to the refinery tank-house, while the metals are typically recovered from the de-acidified by-product solution by precipitation.

Jan 1, 2005

By J. S. Roberts

"Campbell mines has been in operation since 1948. Part of the process consists of roasting of a flotation concentrate which contains arsenopyrite.At present operation level the milling rate averages about 850 t.p.d. and about 48 t.p.d. of concentrate is roasted. The gas emissions at present contain between 3 and 3.5 t.p.d. of arsenic trioxide, about2 - 2.5 t.p.d. of particulate matter and between 19 - 25 t.p.d. of sulphur dioxide. The particulate is extremely fine calcine dust and it assays about 4 oz. Of gold per ton.Until 1974 the gas was discharged untreated through a 125' stack.UntreatedThe decision was made in 1972 to erect a gas treatment plant, construction ran through 1973 and operation began in 1974. The cost of the installation was about 1.3 million dollars.On investigation the process technology, it was apparent that the plant operated by giant Yellowknife for the same purpose was the model we should study. I would like to acknowledge the fine cooperation we had from giant, the plant that emerged is very similar to theirs and incorporates some improvements suggested by them and based on their operating experience.The plant is designed to remove arsenic and solid dust and it has no provisions to remove sulphur dioxide.We depend upon the 125' stack to assure adequate dilution. Because of the nearby airport the stack cannot exceed 125'. A stack burner is provided that can ""y used to heat the stack gas and carry it higher into the atmosphere when there is an inversion condition.The removal of arsenic from hot gas is fairly simple. The sublimation point is about 425°f, a few degrees above this point the arsenic is a gas and a few degrees below it condenses into a solid form. The arsenic could have been removed by simply dropping the temperature below the condensation point and collecting all the solids in a baghouse. This would have removed the possibility of recovering the gold in the calcine dust and would have produced an impure and more bulky arsenic material to be placed in safe storage. The decision was made to collect the solid dust in a hot electrostatic precipitator operating above the sublimation point and subsequently lower the temperature below the condensation point and collect the arsenic in a baghouse."

Jan 1, 1976