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By R. Farhat

Coating systems that yield a thermally grown oxide (TGO) protective layer have been proposed as a potential method for extending the lifecycle of components exposed to high temperature corrosion. This is particularly relevant to the petrochemical industry, where any reduction in corrosion rates can yield substantial cost reductions. The primary goal of this project is to develop a coating repair procedure and to investigate the oxidation performance of the repaired location. Electrospark deposition (ESD) was used to repair spalled segments of TGO grown on MCrA1Y substrates using various electrodes possessing mixed crystal structures. Specifically, electrodes of NiCoCrA1Y (BCC-FCC mixtures) and CoNiCrA1Y (FCCBCC mixtures), were deposited and oxidized to develop the TGO using a heat treatment of 24 hours at 1000°C in air. This presentation will focus on the microstructural evolution of the base metal and ESD repair on damaged area, in both as- deposited and oxidized forms. Results of SEM and XRD analysis will be presented.

Jan 1, 2011

By M. Boussuge

Ceramics and refractories have many common constituents and consecutively exhibit several analogous properties. For example, concerning the thermomechanical properties this paper will focus on, the type of creep that can be observed in both materials is often the same (kinematic hardening). Changes in microstructure (phase transformation, dehydration, sintering, crystallisation,...), induced by heating and/or cooling, can also drastically modify the mechanical behaviour of ceramics and refractories. But the coarse granulates, the porosity and the impurities contained in industrial refractories may lead to specific responses of this material to thermal and/or mechanical loadings. In particular, some differences can be observed with technical ceramics in the main type of damage observed in service : diffuse damage in refractories (microcracking) and localised damage in ceramics (macrocracking). In this paper, the possibilities of transferring a part of knowledge from ceramics to refractories will be discussed, in the field of thermomechanical properties : experimental characterization techniques, mechanical behaviour models. Finally, some problems caused by scale effects and by the integration of thermomechanical properties of refractories in the numerical simulation of industrial structures will be evoked.

Jan 1, 2004

In recent years, China and India have emerged as major players in the copper sector. Over the last decade, around 50% of additional global refined copper usage growth can be attributed to them. The paper provides an overview of the current and future copper supply and demand situation in both countries. Results from two market studies commissioned by the International Copper Study Group (ICSG) are complemented with recent copper statistics on North-East and South-East Asia, as well as further sectoral analysis. Developments and trends in copper mining and metal production, semis production, and major end use areas are highlighted. While providing insights into sectoral patterns and growth trends, the paper provides the basis for comparing structure and output of the copper sectors in some of the major copper-using countries in Asia. Afterwards, the current copper reservoir in use associated with infrastructure, buildings, industrial equipment, transportation systems and households is assessed using the ICSG Copper Flow Model. Finally, the identified copper flows are analyzed regarding the potential impact on the future world supply and demand situation.

Jan 1, 2007

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By K. G. Eriksson

"The first tentative test made to try rubber lining in grinding mills was made in the early twenties. However, because of poor rubber compounds and design the results did not prove to be promising.In the early sixties successful trials of rubber linings were carried out as a result of a cooperation between boliden AB and Skega AB.One of the reasons rubber was not used earlier for linings was the difference in wear characteristics between rubber and steel. The ability to successfully develop rubber mill liners depends on three factors:l. Design2. Material (rubber compounding)3. Experience (knowledge)DESIGNThe main difference between steel and rubber, in material aspect, is the elasticity and the low tensile and shearing strength of rubber. It is necessary to take maximum advantage of the elasticity and to reduce tensile and shearing forces by minimizing the sliding of the mill charge. This is accomplished by using the Lorrain type of liners, i.e., lifter bars and plates. It is, however, necessary to keep a certain balance between lifter bars to optimize liner life and grinding performance."

Jan 1, 1983

By K. L. Eastwood

The ISA PROCESSTM cathode plate is characterised by its copper coated suspension bar, coupled with a blade employing austenitic stainless steel alloy 316L. The blade material has become the mainstay of the technology and has been closely copied by competing cathode designs. Improvement to the cathode plate design remains a key area for research, and ongoing developments by Xstrata Technology's ISA PROCESSTM have recently been commercialised. Two such developments are the ISA Cathode BRTM and ISA 2000 AB Cathode. The ISA BR cathode is a lower resistance cathode that has proven to enhance operating efficiencies. The AB cathode was designed to improve stripping inefficiencies in the ISA 2000 technology. These developments have now had time to mature and their long term performance will be discussed. Rising material costs and the desire to extend the operating boundaries of the standard 316L cathode plate has triggered a number of significant advances. These involve the use of different stainless steels as alternatives in some operational situations. The technical aspects and results of commercial trials on this development will also be discussed in this paper.

Jan 1, 2007

By P. V. Barr, Y. -H. Li, A. P. Watkinson

Subsequent to a campaign of pilot-kiln trials of firing bio-oil and natural gas, scale-up to commercial lime kilns was made using an in-house mathematical kiln model. Both dry limestone and lime mud kilns of 3.5 m OD. by 100 m length were used for bio¬oil firing simulations. Comparisons were made against natural gas firing on the basis of specific firing rate, off-gas volume, energy consumption and overall lime quality. Model simulation results indicate that conversion from natural gas to bio-oil with no productivity loss will increase energy comsumption by about 7.5% and total off-gas volume by about 8%. Alternatively, a 6% decrease in productivity would be expected if off-gas volume is maintained constant. The calculations are sensitive to deviations in the lower heating value (LHV) used in the simulations. A 5% increase in the LHV of the bio-oil, which could result from a 3% decrease in the moisture content, reduces the energy penalty to 2% coupled with a slight reduction in off-gas volume.

Jan 1, 2004

By K. Karan

Oxygen reduction reaction in PEM fuel cell cathodes involves participation of three reactants - oxygen, hydrogen ions, and electrons. Electrochemical reaction in the catalyst layer is, therefore, influenced by how these species are transported to the reaction site. The two-phase boundary locations at which percolating networks of ionically conducting electrolyte and electronically conducting Pt/C meet are feasible reaction sites. The electrolyte phase also provides pathway for the transport of dissolved oxygen. Most of the 3-D models describe the catalyst layer as an ultra-thin layer, thereby, losing useful information on the distribution of electrochemical reaction rate. In this paper, we extend our previous work on 2-D cross-the-channel modeling of PEMFC cathode based on agglomerate catalyst layer. In particular, we take a closer look at the influence of proton conductivity on the reaction rate distribution in the catalyst layer. As well, we re-examine the role of anisotropic transport coefficient of the porous transport layer (PTL), commonly known as the gas diffusion layer, on the current density distribution under the channel and the rib of the flow-field plates. Results from both a 2¬D and a 3-D models will be presented.

Jan 1, 2005

By M. D. Viera

The purpose of the study is to show, through real cases of companies in Chile, the different problems concerning valuing or economically appraising a mining ore resource with the traditional techniques. The study demonstrates that, with the risk analysis and real options theory application, one could determine the most probable value for a mining resource or mining business, and the risks cover of uncertainty scenarios. The study discusses different methods and criteria employed in the ore resource evaluation or mining assets. It also shows a comparative analysis of the different methods in order to explain various distortions, errors, risks and imprecisions of each of them. the companies are becoming aware of the risks' importance and the impact they have on the commercial value and resource estimation models. Now, the real options are the techniques that somehow make it possible to value and control the risk cover of the business. The company valuation could help respond questions like: ? How much is my business worth? ? How much has the investment profitability of my business been? What could be done to improve this profitability and create value?

Jan 1, 2007

By Jean-François Doyon

Les aspects environnementaux des activités minières d?exploitation réalisées sur le territoire québécois sont encadrés par divers cadres légaux, réglementaires ou autres (directive, politique, guide) tant au niveau provincial que fédéral. Ces cadres s?appliquent à l?un ou l?autre des trois grandes étapes du projet, soit lors de l?étude d?avant projet, pendant l?exploitation ou à la cessation des activités d?exploitation. Comme la réglementation environnementale est de plus en plus nombreuse, ces dernières années, cette présentation vise à exposer les principaux cadres provinciaux et fédéraux actuellement en application au Québec pour le secteur minier et à en dégager les particularités. ABSTRACT The environmental aspects of mining activities carried out across Quebec fall within the scope of various legal, prescribed or other frameworks (directives, policies, guides) at provincial and federal levels. These frameworks apply to one or another of the three major steps of a project: preliminary design, mining and closure. As the number of environmental regulations has greatly increased during the past few years, the object of this presentation is to state the main provincial and federal frameworks currently applicable in Quebec for the mining sector and to identify their special features.

Nov 1, 2002

By I. M. Santos Moraes

The control of minor impurities (mainly As, Sb and Bi) in copper refineries has been a great challenge. Caraiba Metais' copper refinery produces a very high quality copper, registered in LME as grade A, and recognized as amongst the top ten in the copper world. At Caraiba's Tankhouse Bi and Sb are controlled by means of electrolyte bleed-stream removal after partial decopperizing in a set of electro-winning cells (liberators). Another way of reducing the Sb and Bi content in the electrolyte is by means of the arsenate precipitation chemistry. It is well known that the use of high arsenic concentrations in copper refinery electrolyte has the advantage of causing most of the bismuth and antimony to report in the anode slimes. However, the use of such mechanism of control may contribute to other undesired problems such as antimony and bismuth precipitation in the bulk of the electrolyte, what may cause severe contamination problems. This paper describes a period when some cathode contamination with Sb occurred at Caraiba Metais' Copper Refinery. It also presents an analysis of several process parameters related to the problem, the possible causes for the contaminations as well as the actions taken to correct the problem.

Jan 1, 2007

By M. Stelter

Since the first years in copper electrorefining natural products have been used as so called "additives" in the electrolyte. Glue as one of these additives offers a lot of different reactions with the metal ions and also with other additives like thiourea in the electrolyte. For a deep understanding of the effect of these additives it is important to know the routes of possible reactions in the electrolyte as well as the basics of electrocrystallization. Using this knowledge the interpretation of nodulation or inclusions of electrolyte in the cathodes in copper electrorefining is easier than before. Setting up on physical and chemical properties of the electrolyte and the additives practical investigations of the effects of additives in copper electrorefining and their impacts on copper crystallization and cathode quality are presented in this paper. Chemical deposition of glue against time and temperature are only few of the effects that are mainly caused by the use of natural products. In fact parameters like anodic and cathodic polarization are strongly affected by the additives as well as the effects of the additives are strongly affected by current density. This second part of the paper presents results concerning interactions of the above mentioned parameters.

Jan 1, 2007

By H. T. Michels

Recent laboratory studies show that several bacteria, known to be human pathogens, die when they come in contact with copper and copper alloy surfaces. The amount of live bacteria drops by several orders of magnitude, to zero, on copper alloys in a few hours. In contrast, no reduction is seen in the concentration of live organisms on stainless steel during the six-hour test period. Aluminum painted and coated surfaces and plastics would show behavior similar to stainless steel and show no effect. Coatings and other surfaces claiming to be antimicrobial showed little to no effect. These results suggest the selection of copper alloys for surfaces exposed to human touch can materially assist in reducing the transmission of infectious organisms. In order to make antimicrobial claims in the United States, the approval of the US Environmental Protection Agency (EPA) is required. The EPA-required efficacy testing is described and the test results are summarized. It is anticipated, that once regulatory approval is obtained, that this will facilitate the introduction of antimicrobial copper alloys in hospitals, nursing homes and other healthcare facilities, as well as schools, and public buildings. Some of the application and barriers, to entry into the healthcare markets are mentioned.

Jan 1, 2007

By L. Byszynski

The results of a three month evaluation of the application of EMEW® technology at the KGHM Glogów II Smelter tank house bleed stream are presented. The current, conven¬tional electrolyte decopperization process has some limitations, including: only a fraction of its production is commercial grade cathode copper, significant operating costs, low current efficiency, low current densities resulting in low copper depletion rate, and arsine gas and sulphuric acid emission. The EMEW® cell technology developed by Electrometals Technologies Ltd. can overcome many of these limitations. Tests were performed on a pilot EMEW® installation comprising 30 cells at ambient temperature on electrolyte bleed, using current densities between 100 and 600 A/m2 , with copper concentrations between 45 and <1g/dm3. Results showed that a high grade copper can be obtained to the level of 7 g/dm3 of copper concentration in electrolyte. The use of EMEW® technology allows the direct and efficient recovery of over 85% of the copper contained in the bleed electrolyte. Glue & thiourea addition were tested in order to improve the parameters of the copper depletion process. The behavior of Arsenic and Bismuth was observed and a means for their elimination from the system proposed. On-line copper concentration monitoring is proposed to improve control and performance.

Jan 1, 2007

By P. Bonadia, A. Tabereaux

Nearly all aluminium smelters are increasing the potline amperage to achieve higher aluminium production. In some instances the higher amperage operation has a significant negative impact on shortening the lifetime of aluminum electrolysis cell cathodes due to loss of the protective sidewall cryolite ledge freeze and too rapid penetration of the cell bottom refractory lining by cryolitic bath components due to the higher temperature isotherms. Thus Cathodes require careful thermal modeling of the cathode relining designs and improved refractory materials to allow greater heat loss from the sidewall to preserve a stable sidewall ledge freeze at higher amperages, and the selection of optimum refractory barrier materials to control the penetration and reaction of bath into the cathode bottom refractory and insulation lining. This requires an understanding of the reaction mechanisms and product formation for molten NaF enriched bath and alumino-silicate refractories. It is desirable to use dense, low porosity refractory fireclay firebricks, or similar materials with a sufficiently high silica content to promote the formation the mineralogical phase albite, NaAlSi3O8, that significantly increases the viscosity of the melt which slows the diffusion of reactive species in the melt and thereby retards further bath penetration.

Jan 1, 2004

By M. Fooladi Mahani, M. R. Izadpanah

The knowledge of the thermal shock resistance of refractory materials is of outmost importance due to their wide range of applications in various industries, namely; ceramics, oil refinery, thermal insulation, nuclear power, chemical and petrochemical industries. Thermal shock resistance is measured in terms of the number of cycles that a refractory material can withstand when subjected to sudden temperature changes. This property is measured experimentally by heating a sample of the material and cooling it in a known environment then the number of cycles it withstands this treatment without spalling is a measure of its thermal shock resistance. Although this method of experimentation has long been the practice, but it is both expensive and time consuming. Various studies have been carried out to predict this vital property, however, the rang of applications are limited. The present study employs a test rig by which temperature distributions in magnesite samples are accurately measured. This information plus other results obtained from relevant tests on related properties are used to develop a model which predicts the number of quench cycles withstand by different materials when subjected to sudden temperature changes. The comparison of the theoretical values using the solution of the presented model with experimental data for different materials having different thermal resistance shows a closed agreement.

Jan 1, 2004

By Par G. Jönsson, Joachim von Scheele, D. S. Sarma, Mukul Goyal

Dust from flue gas cleaning systems at iron and steel production is frequently considered as a waste problem, but it is actually a potential raw material source. By using a technology like the oxyfuel based OXYFINES technique, it can be melted into a suitable form. The product from this processing, however, needs to meet the requirements of a recyclable raw material, here particularly a top-charged blast furnace feed. The present work has been focused on characterization of the product produced from these dusts by OXYFINES technology. The investigation has been carried out on samples of processed dusts from a European integrated steel mill. It was done by means of chemical analysis, density measurement, light optical microscopy, X-ray diffraction, scanning electron microscopy combined with energy dispersive spectroscopy, and micro indention hardness measurement. Special attention was paid to the presence of zinc, an element that might be harmful while recycling the material (e.g., in a blast furnace). The results show that the product contains four different regions with different morphologies and properties in the material, which are discussed in detail. The overall conclusion is that by processing the dusts in this way, a raw material suitable for recycling in a blast furnace can be obtained.

Jan 1, 2004

By D. L. Johnston

"The avenues and degree of participation by aboriginals in the Canadian minerals industry have changed significantly during the thirty years of the author&apos;s career in that industry.The typical 1950s cycle of mineral industry involvement of a local non-Europeanized aboriginal was as an individual employee. The employment relationship would begin with the best of intentions by both parties of permanence and terminate when the pioneering employee was unable to reconcile the attendance behaviour required by the employer and the social-sharing behaviour demanded by family and friends.Cominco Ltd. has been a mine operator and developer in the North since the 1920s. Cominco&apos;s early experiences with employment of non-Europeanized natives at the Con Mine in Yellowknife, Northwest Territories from 1938 to 1986 was a negative experience from both the employee and employer ends. A series of classic failures in employment of individual aboriginals was a large part of the history. A few Metis or natives from other areas were the permanent aboriginal employees at Con (2010). Racial prejudice was overt on the street in Yellowknife and, it can be assumed, in the workplace, as well.The history of aboriginal employment at the Pine Point, Northwest Territories operation (1964 to 1988) was somewhat better but also frustrating. The mine was equidistant (80 km) from the Dene communities of the Hay River Indian Reserve and Fort Resolution, both on Great Slave Lake. Despite a large aboriginal presence and many well-intentioned efforts, employment of aboriginals at Pine Point never got much beyond ten per cent. These would have been half local and half northern prairie aboriginals. One continuing success story was the railcar loading and covering crew led by Ed McKay, a local aboriginal. This predominantly aboriginal crew did its own recruiting and several are on Cominco pension."

Jan 1, 1995

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By Graham A. Davis

The definition of sustainable development is often taken from the so-called ?Brundtland? report, requiring that activities of the current generation not detract from the potential welfare of future generations. Mining is often held up as unsustainable in this regard since the extracted resource is nonrenewable. Yet Brundtland?s definition of sustainable development also requires that the current generation address the disparity in welfare across the globe, a facet of Brundtland?s report that most have ignored. This paper examines the impact of mining on the welfare of the poor. It finds that poverty levels in the poorest mining and oil intensive economies are lower than expected given these economies? geographical location and level of income, and that extractive activities are therefore completely consistent with sustainable development.

May 1, 2004