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By H. R. Kempthorne

"The Property of Bevcon Mines Limited, including a recently acquired adjoining south group, occupies an area of 2,625 acres in northeast Louvicourt township, Abitibi county, Quebec. It is situated 17 miles east of Val d'Or at the junction of provincial highways 58 and 59.Gold was first discovered in the area in 1931 by the late S. B. Jowsey on the present property of Buffaddison Gold Mines adjoining to the west. However, it was not until the winter of 1944-45 that diamond drilling encountered encouraging results on the Bevcon claims. During the period 1946-1948 a shaft was sunk to 1,000 feet and considerable development undertaken from the 500-foot to the 1,000-foot levels. Between 1947 and 1950 approximately 24,000 tons of dump ore and 48,000 tons of ore by stoping were milled at Perron Gold Mines. The favourable results of these tests prompted the decision to construct a milling plant at Bevcon. The mill began operating in July 1952, and presently has a capacity of 800 tons per day. In 1953 the shaft was deepened to 1,600 feet and is currently (1955) being driven to 2,225 feet.Total production of gold to the end of 1954 has been 101,024 ounces from the milling of 697,427 tons of ore of an average grade of 0·163 ounces per ton.GeologyThe Bevcon orebodies occur in a granodiorite stock which has an east-west length of approximately 4 miles and a maximum width of 1 1/2 miles. The property covers the central portion of the stock and its contacts with the Keewatin volcanics. Approximately one-third of the northern contact and one-half of the southern contact are contained within the Bevcon claims. The granodiorite has been cut by acid (feldspar porphyry) and basic dykes trending east-west. A younger diabase dyke, 300 feet wide, strikes northeasterly across the property 1,000 feet east of the shaft.The main ore zone, striking east-west, lies between the more northerly porphyry dyke and the north granodiorite-greenstone contact. It has been extensively sheared, fractured, altered, and mineralized by gold-bearing solutions. It is approximately 2,000 feet Jong from the west boundary towards the diabase dyke. The shaft is centrally located and passes through the south contact of the ore zone at the 500-foot level. The zone increases in width and trends northerly with depth, due to the porphyry and greenstone contacts having average dips of 80 degrees and 70 degrees respectively to the north. Thus on the uppermost or 500-foot level the width is 150 to 200 feet, and at the present bottom level at 1,600 feet the width is 400 to 500 feet.Another gold-bearing zone has been indicated 200 to 400 feet south of the main ore zone by limited surface drilling."

Jan 1, 1949

By Grant Arnold

Le Camp Minier de Matagami est situé dans la ceinture volcano-sédimentaire Harricana- Turgeon appartenant à la Province du Supérieur, sous-province de l?Abitibi, au Québec. Les gisements de métaux de base polymétalliques sont retrouvés exclusivement dans les deux domaines lithotectoniques comprenant l?association basalte-rhyolite (Matagami-Brouillan et Joutel-Raymond). Tous ces dépôts, à l?exception de ceux de Selbaie, sont de type exhalatif et représentent des dépôts volcanogènes à Zn-Cu, typiques de l?Archéen. Le complexe volcanique de Matagami est constitué principalement de deux phases de volcanisme tholéïtique. Les dacites et les rhyolites du Groupe de Watson, représentent la phase la plus précoce et celles-cis sont recouvertes par la seconde phase qui est constituée majoritairement de roches intermédiares à mafiques intercalées d?horizons felsiques, formant le Groupe de Wabassee. Un sédiment chimique sulfuré, la Tuffite Clef, marque le contact et l?hiatus entre ces deux groupes. Cette tuffite est reconnue à la grandeur du flanc sud du camp minier et représente l?horizon favorable à explorer puisque sa déposition a correwspond à une période d?intense activité hydrothermale. Le complexe volcanique de Matagami est limité au nord et au sud par des bandes sédimentaires orientées est-ouest, connues respectivement sous les noms de Groupe de Matagami et Groupe de Taïbi. Le Complexe intrusif de la Rivière Bell, qui occupe la base du Groupe de Watson, est un complexe lité consistant en une séquence stratifiée gabbroïque avec localement des niveaux stratiformes à concentrations d?oxydes magmatiques, la bordure de ce complexe est marquée par la présence d?un horizon granophyrique. Cette intrusion synvolcanique prétectonique, représente probablement la source de chaleur étant à l?origine de l?activité hydrothermale observée dans les roches volcaniques sus-jacentes. Suite à un levé aéroporté, le camp minier de Matagami a vu le jour en 1956 lors de la découverte du dépôt de Mattagami Lake, un gisement volcanogène de 25.6 millions de tonnes. Depuis ce temps, un total de neuf gisements ont été exploités et un dixième, Bell Allard, est présentement en production. En date du 31 décembre 1999, la production historique du camp s?élevait à plus de 41 millions de tonnes. Cette présentation mettra l?accent sur la géologie des récentes découvertes dans le prolifique camp minier de Matagami. Les ressources publiées pour le dépôt Persévérance sont de 947,000 tonnes titrant 19.12% Zn, 1.37% Cu, 32 g/t Ag et 0.40 g/t Au. Deux autres découvertes, Équinoxe et Persévérance Ouest contibueront à la ressource globale. Les trois dépôts sont situés au niveau de la Tuffite Clef même si les roches sus-jacentes ne sont pas celles typiquement observées dans les autres dépôts du flanc sud. Ces découvertes sont le résultat d?un programme d?exploration ciblé et soutenu, démontrant ainsi la possibilité de découvrir de nouvelles ressources même dans les camps miniers comme Matagami qui ont été explorés intensivement depuis plus d?un demi-siècle.

May 1, 2001

By Karl J. C. Harries

"The following is an outline or check sheet of some things that might be looked at when considering the concept of a royalty or royalty provisions. It is not intended as a guide to what is right or wrong (that is for the parties to decide). It does not replace the discussions in this work and is not intended to be a complete or exhaustive compilation of matters to be considered. It presumes that you are familiar with the basic concepts of royalties and has been included as an aide memoire only. Use it as such, with caution and common sense, and amend it to suit your needs. Remember also that brevity can result in inaccuracy or imprecision. This is a danger in many points below.The section references are for the sections where the matter is the main subject of the section – see the index for other sections.Royalty TypesNet Proceeds [§§ 5.8.; 11.4.]• No accepted or understood meaning within industry.• Literal meaning, if not defined, would imply “net operating profit”.• Often defined as net profit with revenue base of proceeds from sale of product.• Should not be used without detailed and clear definition. Net Operating Profit [§§ 5.8.; 11.4. – referred to only]• Net profit without recoupment of pre-production expenditures.• Revenue base: usually proceeds from sale of product.• Operating costs deductible.• Some reserves may be permitted.• Recoupment of some post-production capital expenditures may be permitted.• Not often seen as basis for royalties in Canada."

Jan 1, 2003

By J. B. Evans

"THE OPPORTUNITY to participate in a CIM seminarconcerning the direction of mining engineer trainingis perhaps fortuitous as it comes at a time when theengineering schools which have invited inspection byCanadian Accreditation Board of the Canadian Councilof Professional Engineers are examining theirrespective curricula.Currently there exists considerable soul-searching in various engineering schools across Canada where questions such as the following are being posed.- Have we achieved the correct balance between subjects related to technical methodology and subjects devoted to conceptual planning and design?- Should we include ""applied humanities"" in our program? (Whatever ""applied humanities"" might mean!)- Should courses covering pollution control, ecology, economics, technical writing, professional conduct and ethics be offered as compulsory subjects, as electives, or not at all?- Is it a better scheme to have students complete an Arts or Science degree before entering engineering?- Do we place too much emphasis on pure mathematics and sciences with the result that insufficient time is available for instruction in the engineering applications of these subjects?- Should English expression and/ or literature be included in the engineering programs and, if so, should these subjects be presented by the English department or by English lecturers captive to the engineering school? - Is the present program directed primarily at research activities rather than preparing engineers for their future roles in industry? - Should we teach our own versions of mathematics and physics? - Do we have sufficient engineers on the faculty strength or are we overloaded with Ph.D.'s from the pure sciences? - How flexible should the program be, what should the compulsory vs elective course content be, and what freedom of choice, if any, should be given with respect to elective courses? - To what extent should students contribute to faculty decisions?- How far should we pursue computer science subjects and do we need to make our students proficient in computer programming? - How far should operations research and mathematical models be carried in the undergraduate program when the students have limited experience in the real engineering world? - Realizing that an engineer never completes his education, should the undergraduate program cover ""bare bones"" engineering and should instruction in particular disciplines be left to graduate schools and / or industry?"

Jan 1, 1972

CAT offers three different methods to accomplish crowd & retract on an electric rope shovel Rack and pinion Rope crowd HydraCrowd The presentation will compare the three systems and introduce the benefits of the Hydracrowd

May 1, 2013

By Bong Sun You

AZ31 magnesium plate of 300mm in width and 40mm in thickness was produced by horizontal continuous casting machine, and its microstructures were analyzed on the surface and in the plate interior. The defect formation on the surface and subsurface, such as side cracks, buckling, pores and segregation, was very sensitive to the casting condition and processing parameters. Especially, casting speed and secondary cooling were the most dominant parameters to control the solidification behavior of magnesium melt, for example the position and shape of the solid/liquid interface in the mould. The cyclic marks on the surface were obvious because the plate were drawn by 4-step cycle and can not be removed. The average grain size of as cast plate measured as 50-65µm at the near surface and 300-400µm in the center of the plate was relatively small because secondary cooling water was applied to control the surface quality resulting in rapid solidification of the melt in the mould.

Jan 1, 2006

By David W. Smith

"This paper is devoted mainly to a discussion of the hydrocarbon potential of the offshore, with a few brief remarks concerning the inorganic mineral potential.OFFSHORE OIL AND GAS POTENTIALIN ORDER TO HAVE HYDROCARBON ACCUMULATIONS, we must satisfy three basic requirements. First, we re-quire a sufficient thickness of sedimentary rocks which contain some porous and permeable formations to act as reservoirs. Second, we require some type of trapping mechanism, such as faulting, folding or stratigraphie trapping. Finally, we require that large quantities of hydrocarbons have been generated within the sedimentary rocks and have migrated to the traps."

Jan 1, 1969

By V. H. Valenzuela

Materials in process or in stocks are quite relevant items in almost every plant, particularly in mining operations, where efficiency in rate of recovering material of interest becomes a key issue when production costs are evaluated. A manager requires information to do an effective use of the resources, especially when raw materials are involved. Losses associated to leaking, efficiency in the transformation process, performance of equipment, and operating conditions are a short list of items which must be properly identified and evaluated. Operations supervisors require information in order to keep key process variables under control. Because of these information needs, it is absolutely necessary to carry on a series of activities related with installation and maintenance of measuring equipment, sampling equipment, sample preparation, chemical analysis, statistical analysis, data handling and reports generation. These pieces of data must be managed on a wise manner in order to get the most of it, keeping always on mind data reliability. Normally, information related with metallurgical balance and even more, the metallurgical balance concept, is handled under an accounting criteria which does not allow dealing with the real world. This situation happens because the criteria utilized do not consider aspects such as bias and uncertainty associated with every measurement that affect the quality of the information and therefore conclusions drawn from it. The purpose of this paper is to give a few rules, necessary to follow, in order to develop an adequate Metallurgical Balance System for an operational point of view. The Gaussian approach for error propagation is used as a basis, allowing one to know the actual uncertainty of the balance and the way how it can be improved. A few real applications of this concept are listed, detailing experiences obtained from practice.

Jan 1, 2007

By D. W. McDonald

Coal mining and railway transportation are so closely en-twined and so dependent one upon the other that the failure of one would mean the total collapse of the other. With this indisputable fact in mind, there is no doubt that the operator of each is deeply interested in the other's success. Railway transportation began at the mouth of a coal mine. The first railway car was the English coal-wagon, a crude box on four wooden trowlets, running on wooden rails and holding 1,600 pounds. This was operated by gravity or horse-power in England to convey coal from the mines to the rivers. The first coal-cars used on Nova Scotia railways were of 4 tons capacity with side doors and "V" shaped centres. Then followed flat-bottom, 4-ton cars that operated on tipples, the car bei.ng held in tipple by a chain passing over the top and fastened on either side. Next came the 6-ton car with drop-bottoms, then the 10, 15, 30-ton cars, and now the modern 50 and 100-ton steel cars, equipped with automatic couplers, brakes, and rachet dumping device. Contrast the first coal-car with a modern luxurious pull-man or a I 00-ton coal and ore car, and you have a record of progress in railway transportation. The development of the steam locomotive was no doubt the greatest factor in this progress, but let us not forget that the foundation of all industrial development was and is coal. and that development in mining and railway transportation should keep abreast.

Jan 1, 1924

By H. A. Wentworth

The Central Manitoba mining district, as spoken of in Manitoba, refers to that portion of the country lying between lake Winnipeg on the west and the Ontario boundary on the east, and from a few miles north of the Wanipigow (or Hole) river on the north, to a few miles south of the Bird river. It embraces two known mineralized belts; the gold area in the north, extending from the shores of lake Winnipeg almost to the Ontario boundary (in a slightly southeasterly direction) a zone some eight or ten miles wide and perhaps forty miles long, lying (for the most part) north, and parallel to, the Manigotagan river; and the Bird river copper and coppernickel deposits, an area not yet clearly defined, but in general lying immediately north of, and roughly parallel to, the Bird river. To the south of the Bird river is a somewhat differently mineralized area, numerous pegmatite dykes being found, with minerals typically associated with such rocks. More specifically, the known gold deposits are largely segregated in the above belt; (1) around English brook; (2) along the north shore of Wanipigow lake; the Rice lake area (about midway of the belt); and the Long Lake-Bulldog lake area, at the eastern end of the belt. Not all the known gold occurences are found in these segregations, but the density of claim staking in these areas is perhaps an indication of the greater number of prospects found in them to date.

Jan 1, 1925

By L. Dufourm

This paper presents a review of plant layout considerations incorporated into recent designs of SAG/Ball mill circuits for two medium sized concentrators. The plant layouts presented and the design concepts discussed, relate to smaller SAG circuits, but can equally apply to larger milling circuits. Included are design concepts and ideas introduced by the various project teams, and the focus is on the primary factors of any layout design which are safety, constructability, operability, and capital cost.

Jan 1, 2012

PROFIL D'ENTREPRISE Léandre Gervais & Associé(e)s est une société d'experts-conseils en ingénierie de la structure, de la mécanique & de la tuyauterie, et de l'électricité et de l'instrumentation. Nous offrons des services hautement spécialisés à notre clientèle des secteurs industriels des mines et de la métallurgie, au Québec, au Canada ainsi que dans plusieurs autres pays du monde. Notre mission est d'assurer à nos clients un ensemble de services d'ingénierie de haute qualité contribuant à la mise en oeuvre et à la réalisation de leurs projets d'affaires. Léandre Gervais & Associé(e)s emploie 36 employés à temps pleins et opère à partir de Val-d'Or, province de Québec. SERVICES OFFERTS Nous avons réalisé de multiples mandats pour notre clientèle de différent pays du monde dans les domaines d'expertise les plus variés : ?Études de faisabilité ; ?Ingénierie conceptuelle ; ?Ingénierie de détail ; ?Gestion de projets ; ?Ré-ingénierie de la maintenance.

May 1, 2001

By D. Houghton

"I am very pleased to be a member on this panel today because abrasion and wear in mills has been part of my life over the past forty years. My presentation will deal with the role Ni-Hard has played in combating wear and abrasion in mills. Before Ni-Hard came along, unalloyed white iron was used in ball mills and one of the most popular types of white iron liners was the pocket liner. Slide #1 illustrates the design of the pocket liner used at Dome Mines in their 5' x 22' pebble mills. The pockets filled with grinding media and it was on this that the wear took place. The concept is not unlike the new magnetic liner which utilizes the ore and grinding media to form the wearing surface. In this slide please note the tapered pocket type of cored bolt holes. If cored bolt holes do not fill with grinding media there could be excessive grooving or wear at that area. Therefore all cored bolt holes should be tapered in this manner.Before Inco patented the name Ni-Hard several foundries were making the alloy iron under different brand names such as Diamond Alloy, Mitchelloy and Specialloy. In the early days some of the Ni-Hard was poor quality. Inco provided foundries with technical knowhow and provided assistance to licence them to sell under the name of Ni-Hard. This was in the late 1920's. The material we are discussing is Ni-Hard type I with the following analysis (slide #2). It is a martensitic white iron with BHN of 550 - 600 and is a relatively easy alloy to produce in either a cupola or electric furnace. The annual average production of Ni-Hard in North America is 90,000 tons with mill liners making up 25,000 tons and grinding media 30,000 tons, according to Warren Spear of Inco."

Jan 1, 1983

By Richard Wells

Peabody Energy is the largest pure-play publicly traded coal company in the world. We have been in business 129 years and like most of the coal mining companies in the United States, since 1969 the majority of our safety improvement efforts had been driven by compliance with the various versions of the Federal Mine Safety and Health Act and the supporting federal regulations. In 2004 Peabody Energy management came to the understanding that in order to achieve our goal of zero incidents, that focus must change. This paper will describe the elements of the journey we began at that point to make the transition to a behavior and systems-based approach to safety management and our efforts to win the minds and hearts of our employees. This journey is undertaken with the goal of making safety truly a way of life for all Peabody Energy employees.

Aug 1, 2013

By A. F. Robertson

FOR several years, the rock-burst question has been given serious consideration by the operating staff at Wright-Hargreaves mine and, as a result of observations and experiences, several different methods of mining have been developed which are now in use in various parts of the mine. These are described in the following pages. It should be emphasized, how-ever, that these methods, and the views expressed in this paper, are based solely on conditions at Wright-Hargreaves mine. Such conditions may or may not be similar to those obtaining in other mines in the Kirkland Lake area, where ore occurrences, veins, wall-rock, faulting, intrusives, etc., may be entirely different. Size and shape of ore-bodies, composition of the ore-bodies and their surrounding rocks, locations of intrusives and sedimentary rocks, and direction, dip, and strength of faults, all introduce problems that are peculiar to each individual mine. Ground failure' in coal and metal mines is not at all unusual. A variety of systems of mining have been developed to delay movement of large or small blocks of ground, or, in some instances, to take advantage of the fact that ground movement, due to mining operations, is unavoidable. Ground failure may be either slow collapse or it may take place with explosive violence. It is principally with the latter condition that we are concerned in the mines of the Kirkland Lake district.

Jan 1, 1939

By J. A. H. Church

MR. J. A. H. CHURCH: The salient feature would seem to be that the thickness of the seam, in our coals at any rate, is the main factor in predisposition to spontaneous ignition. The evidence, incomplete it must be admitted, in the Saskatchewan and British Columbia fields, and complete in the Alberta field to my mind, shows this up very strongly. The German report on the upper Silesian coal fields definitely fixes the critical thickness at 13 feet, the British report goes far beyond this figure by stating that liability to ignition increases with the thickness of the seam over four feet. Before discussing the Alberta fires it would be well to note an error on page 12 -the probable cause of the fire in the Frank Mine should read "Spontaneous near fault. Heating first discovered 1909". Of the six fires attributed to spontaneous ignition all the seams were identical or in excess of the critical thickness mentioned in the German report. If there be any reason in the foregoing it is high time some forethought were taken to adopt some definite system of laying out the workings of such seams not so much on the outcrop districts as with a view to the future operation to the dip. Seams approaching 13 feet in thickness which to date have shown no disposition towards heating during the extraction of the outcrop areas may well cause infinite trouble or indeed total loss when the ventilating pressures increase as increase they must to the dip. This state of affairs can be combatted only by the adoption of a correct system of working and the provision of numerous airways of as large an area as may be compatible with the physical characteristics of the particular seam.

Jan 1, 1923

By Pierre Gaucher

It is possible to selectively mine an orebody by combining the use of the SSW probe with any bulk mining methods as well as narrow vein exploitations. In other words, thanks to the use of the SSW probe, mining operators will be able to reduce and control dilution that is generally associated to every mining operation. Already, quick and substantial savings have been obtained. Falconbridge mines have demonstrated in Sudbury and Raglan operations, that the SSW probe can log nickel, copper and iron sulphides in blast holes. They have raised the grade and reduced dilution by outlining the limits of the ore zones before selectively loading explosives in the blast holes. By lowering the probe in a blast hole, a profile of the ore content is instantly measured and recorded. Logging cored diamond drill holes at the mine have demonstrated that the ore content (nickel, copper, cobalt, PGM) as assayed is proportional to the intensity of the probe?s electromagnetic response (EM), probably because the nickel / pyrrhotite ratio is uniform within a given orebody. The probe also measures the intrinsic conductivity of the sulphides and the percentage of magnetite. All probe readings are displayed and automatically stored at a 10-cm interval within the same reading unit. A 30-meter blast hole takes less than 2 minutes to survey. The whole instrument is light (12 kg) and very simple to use. One operator can carry the SSW system and survey either down or up-holes. The probe works from ?40°C to +50°C. Plotting the measurements of the SSW probe in blast holes (2-3-4-6-10 inches in diameter) before blasting allows to determine the exact shape of the orebody within the waste rock and uneconomic low-grade ore. Thus, only the portion of the holes that contains ore is blasted. The dilution is then much reduced and, by leaving the waste and low-grade ore in place, the mine saves on transportation, blasting, crushing, backfilling, milling, etc. Thousands of dollars are thus saved. Some savings may also be achieved during the development of stopes by guiding development drifts and by replacing diamond drilling by percussion drilling. In some circumstances, when the probe shows that some of the rich ore was not drilled-off, additional blast holes will allow to recover pockets of rich ore that otherwise would have been abandoned in the walls of a stope.

May 1, 2001

By Karl J. C. Harries

"9.1. INTRODUCTIONIn Chapter 5 of Volume I royalties are dealt with and several topics would appear to be duplicated in this Volume. However, Volume I may be looked upon as a general guide, whereas this Volume is a reference volume. It deals in considerable detail with specific provisions and concepts relating to royalties between private parties. This does not, however, mean that Chapter 5 can be ignored. It should be looked upon as a source of general information concerning royalties between private parties and as a negotiating aid intended to give an overview of various topics. You may well find that in its general approach it will lead you to ask a question which, hopefully, will be dealt with in this Volume .It should be remembered that royalty agreements are agreements with a particular focus, and so the concepts set forth in Chapter 1 apply to them. This chapter addresses a few considerations specific to royalties that will usually form part of an agreement rather than a stand-alone agreement.9.2. FORMAT FOR ROYALTY PROVISIONSIn many of the cases where royalties arise, they are adjunct to, or part of, other arrangements. For example, a royalty may form part or all of the consideration to be given to an owner upon purchase of his property, or it may arise if a joint venturer ceases to contribute to the venture and has his interest converted to a royalty.1 It is with such situations that this section primarily deals; if the royalty is contained in an agreement that is singularly, or primarily, concerned with creating it, then it is just a normal agreement.Commonly, by the time the right to receive the royalty arises, at least some of the other provisions of the agreement have been performed and/or become redundant. For example, in an option agreement the royalty will be a continuing obligation of the optionee, usually arising only after the option has been exercised.2 In a joint venture agreement, a royalty will often arise where the interest of a non-participating venturer has been diluted and converted to a royalty, in which case the recipient will usually become a passive party, entitled only to his royalty, and most of the rights that he enjoyed as an active venturer will cease to be effective."

Jan 1, 2003

By M. P. Rennick, D. M. Burton

The Murray Brook massive sulfide deposit, which was the first geochemical discovery in the Bathurst camp, is one of the largest sulfide deposits in the area. The massive sulfides are hosted by quartzose metasedimentary rocks in the lower part of the Ordovician Tetagouche Group. This thick succession of sedimentary rocks is overlain conformably by felsic volcanic rocks, and is structurally overlain by mafic volcanic rocks. The massive-sulfide body is polydeformed, but primary metal zoning is still discernable and may permit future exploitation of discrete lead-zinc and copper zones. Although it was discovered in 1956, the deposit was not developed until 1989, when Murray Brook Resources commenced processing of gossan containing precious metals. Recovery of gold, silver, and mercury is accomplished by indoor vat leaching on a year-round basis.

Jan 1, 1992

The mechanism of thiosulfate decomposition and the products formed were investigated in the presence of pyrite or pyrrhotite in copper-ammonia solutions used for leaching gold. The presence of the sulfides significantly increased the decomposition of thiosulfate. The sulfide-surface-catalyzed oxidation of thiosulfate to tetrathionate by dissolved oxygen or the cupric tetra-ammine complex was proposed to be the dominant thiosulfate decomposition mechanism. The catalysis of the sulfides in this reaction could originate from their strong affinity for aqueous sulfur species and their semiconducting properties. Oxygen was found to be the initial driving force for thiosulfate decomposition in the absence of cupric ions and the driving force for the continuous decomposition of thiosulfate in the presence of cupric ions. Under an oxygen free atmosphere, the decomposition of thiosulfate was limited to reduce the cupric ions and the catalytic effect of the sulfides was also marginal. The dominant oxidative product of thiosulfate was trithionate in alkaline solutions especially in an oxygen rich or cupric ion rich environment. Tetrathionate was found in relatively smaller amounts in an oxygen and cupric ion deficient environment. Tetrathionate was not stable and would further decompose after extended periods. Trithionate concentrations increased almost linearly with time.

Jan 1, 2005