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By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By J. G. Patterson

"The depressive action of sodium cyanide on chalcocite has been investigated and found to be unstable. Flotation results show that with the addition of sodium cyanide to the system chalcocite is initially depressed but rapidly recovers with time, provided there is sufficient oxygen present.lt is proposed that the unstable depression is due to the reaction of cyanide with adsorbed xanthate and copper ions at the chalcocite surface to form soluble copper complexes. When all the free cyanide has so reacted, xanthate anions can then re-adsorb on the chalcocite surface and the flotation will recover. Results are presented to verify the the above mechanism."

Jan 1, 1968

By A. Bauer

This paper describes the trends in recent years in explosives formulated to produce larger blast-hole spacings and over-all lower drilling and blasting costs in hard formations. A consideration of current rotary drilling costs per ft of hole and per ton of muck versus hole diameter indicates that it is now possible that we shall see much further use of lower-energy-content, lower-cost slurries and dry mixes, and larger-diameter and, in many instances, cheaper blast holes. These will be drilled on current or slightly larger blast patterns to yield the same energy input per ton of rock and similar fragmentation at lower costs.

Jan 1, 1968

By K. Reipas

"Westmin Resources Ltd. operates the 3300 TPD H-W underground copper/zinc mine on Vancouver Island. Ore storage underground is handled in a 6000 tonne coarse ore bin and a 3000 tonne fine ore bin. Both of these bins have experienced significant wear since excavation and construction in 1985. Wear problems have included both deteriorating rock walls as well as worn out steel liners and concrete at the discharge points from the bins. Extensive rehabilitation work was completed in 1993.The basis o/this paper is the rehabilitation work done on the coarse ore bin. The design and installation of ground control measures are discussed. The bin access methods used to allow the work to proceed quickly and safely are also presented. This involved the use of a Tekfoam safety bulkhead to protect workers.IntroductionMine DescriptionThe H-W mine was commissioned in 1985. Mine access is by vertical shaft with most production areas at a depth of about 500 m. Host rocks are composed of andesite and rhyolite. Mine capacity of 3300 tonnes per day is achieved mainly by longhole open stoping methods, complemented by room and pillar mining. Metals recovered from the massive sulphide ore are copper, zinc, gold, and silver. Mineable reserves at January I, 1994 were 9.7 million tonnes."

Jan 1, 1995

By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

By H. F. Zurbrigg

"The Frood-Stobie Mine is by far the largest metal producer in the Sudbury area. Its efficient development was made possible by the consolidation of three mining properties that covered parts of the same ore body. They were known as the Frood Mine, the Frood Extension, and the Stobie Mine.The southwest or Frood portion of the orebody was discovered by Thomas Frood and A. J. Cockburn in 1884. Cockburn's interest was acquired by J. H. Metcalf and W. B. McAllister and patents were issued to Frood, Metcalf, and McAllister in 1884. The property was purchased by the Canadian Copper Company (lnco) in 1886.James Stobie discovered the northeast or Stobie part of the orebody in 1885. In 1886 Stobie and Rinaldo McConnell applied for the location and patent was issued in 1886. They sold the property to the Canadian Copper Company (lnco) the same year.The Frood Extension property included very little of the ore zone at surface but it covered ore down the dip from Frood. Frank Cochrane was granted title to the property in 1908 and sold it to the Mond Nickel Company in 1910. The title was transferred to the International Nickel Company in 1929 at the time of the Inco-Mond merger.Prior to 1930 the three properties produced a total of about 1 ,000,000 tons of ore from mining done during the periods 1887-1903, 1913-1915 and 1925-1929. Since 1929 the Frood-Stobie operation has produced more than 120,000,000 tons of ore, about half from open pits and half from square set and blast hole stoping. The current production rate is in excess of 6,000,000 tons per year.The principal products from the ore are nickel and copper. The by-products are iron ore, cobalt, platinum, palladium, rhodium, ruthenium, iridium, gold, silver, selenium, tellurium, and sulphuric acid."

Jan 1, 1949

By David J. Morrison

Scarcity of truck tyres, increasing cost and decreasing availability of labour, increases in fuel costs and project budget blowouts have changed the paradigm behind mining equipment selections. The cycle of commodity changes have occurred in parallel with the increasing maturity of continuous mining machinery, mobile in-pit crushing systems and very large scale conveyor belt systems. This paper will consider the merits of operating continuous materials handling systems, mobile in pit crushing systems, relocatable crushing systems, relocatable conveyor systems and automated waste handling systems in place of the more conventional approach of truck haulage.

May 1, 2007

By Robert Marchand

_ North-western Quebec _ Bousquet mining district _ 21 M oz mining camp _ 100,000 t/yr (400 t/d) _ Shrinkage : 52 % _ Longhole : 40% _ Development : 8% _ 5 days/week _ 120 employees _Discovered in 1936. _12 changes of ownership. _Exploration & development : 1987 _Commercial production : 1990 _Shaft deepening : 1995 _Internal shaft : 1999

Oct 1, 2001

By Osamu Inoue, Takashi Yamashita, Takashi Ikemoto

The expansion project in Naoshima smelter and refinery to meet enhancing recycling business of E-scrap was successfully completed in 2016 to have a capacity of 110,000 tpa of E-scrap treatment. Increasing treatment of E-scrap has raised the Ni content of copper anode to 4000 ppm on average, which is double the level of 10 years ago, and to 6000 ppm or more occasionally. The tank house has refined such copper anode to copper cathode with starter sheets. Since most Ni in Copper anode dissolves in copper electrolyte, the Ni content of the electrolyte has increased to 27 g/L and more. Ni accumulated in the electrolyte has increased power consumption during the electrolytic refining of copper, although cathode quality has been controlled satisfactory so far. In order to ensure sustainable operation while growing E- scrap business, the NiSO4 process has been expanded recently so as to recover Ni in the electrolyte more and the pressurized-leaching technology will be introduced to the slime leaching process so as to enhance the capacity of slime treatment and to improve Ni recovery in the near future. INTRODUCTION In recent years, the treatment amount of E-scrap at Naoshima smelter and refinery has increased according to the growth of its recycling business as shown in Figure 1, while impurities from E-scrap have concentrated in copper anode as well. Especially, Ni content in anode has been increasing remarkably since 2012, causing to raise Ni content in the electrolyte as shown in Figure 2. The increment of Ni content in copper anode and electrolyte has adversely affected the electrorefining process, slime leaching process, and NiSO4 crystallization process at the tank house. Such severe conditions provided opportunities to redesign the tank house to establish a robust process to which more Ni is acceptable.

Jan 1, 2019

By Yi-xin Zhoa

The characteristics of coal bumps are analyzed based on the microseismic data from No.8935 workface in Xinzhouyao coal mine, Datong Mining Group. The geology of this workface is characterized by the thick sandstone roof and coal seam, both with relative higher stiffness and strength. In order to investigate the mechanism and precursors of coal bumps occurred in No.8935 workface, the locations of microseismic, the relationship of microseismic energy and frequency and the spectrum of microseismic signals are analyzed. The result shows that the coal bumps in No.8935 workface were mainly induced by the seismic caused by roof failure. The coal pillar near the goaf is more easily to bump. The statistics results indicate that the coal bumps were mainly occurred in the gate road near the pillar, less than 50m ahead of mining face and located in the hard roof adjacent with coal seam. Moreover, the frequency, energy, b-value and frequency spectrogram of microseismic events were found to decrease before coal bumps. It was found that the frequencies of the microseismic events before coal bumps mainly concentrate upon 5~60Hz. The sudden decreasing of frequency and increasing of amplitude of microseismic events can be regarded as a precursor of coal bumps.

Aug 1, 2013

By M. G. Mena, M. S. Mena-Junio

Silver (Ag) filler is the most attractive choice among all the conductive fillers of die attach materials for the attachment of silicon devices because of its balanced properties and relatively low cost. However, a major problem of silver is that it electrochemically migrates in the presence of moisture and applied bias. In microelectronic devices, silver migration can occur between adjacent conductors/electrodes, which leads to the formation of dendrites and eventually results in short-circuit failure. In order to assess the reliability of these conductive fillers, an investigation for two types of Agfilled die attach materials was done using the water drop test at room temperature and using a 1000 hour temperature-humidity-bias (THB) test under 85 ºC and 85% RH conditions. Four different bias/voltages and six different electrode distance spacing were used. Both dendrite and cloud/lace-like growths were observed as a result of the electrochemical migration of silver, Water drop test results revealed that increasing the applied bias/voltage and decreasing electrode spacing causes migration to occur faster, thus resulting into shorter time to fail (TTF). It was also observed that the growth rate of the dendrites from the cathode increased linearly as the dendrite approached the anode, probably due to a combination of increased ion availability and electric field. A minimum applied bias of 3 volts was required for migration to occur in Epoxy A as compared to 2 volts for Epoxy C. The higher migration voltage requirement for Epoxy A was attributed to the higher volume resistivity of the said epoxy. In addition to the minimum voltage requirement, it was observed that a minimum electric field of about 1 volt/mm is required for migration to occur. The 1000 hour THB testing did not result into any failures. It is surmised that the presence of condensed moisture is another requirement for migration. Such condition is not present during the THB testing.

Jan 1, 2012

By K. .. Sadayappan

The increasing cost of selenium made the conventional low lead alloys such as EnviroBrasses not economically viable. Efforts were made to develop newer alloys without selenium for plumbing applications. Recently a new copper alloy, C89836, was introduced. This paper discusses the properties of the new alloy including mechanical properties at ambient and elevated temperatures as well as corrosion behaviour.

Jan 1, 2007

Cominco began investigations about ten years ago relative to noise abatement in underground operations. As a result of intensive research, this study has advanced so that the practice now has wide application. Automotive mufflers are used on vane-type blasthole diamond drills. Exhaust hoses are attached to longhole percussion drills. Hand-held drills, such as airlegs and stopers, are equipped with mufflers which are either part of the drill, as received from the manufacturer, or are light rubber de-vices developed, fabricated and installed by Cominco. Ear defenders are in general use. The paper reviews details of practices employed, and assesses the success achieved. Noise is generally associated with some of the basic equipment used in mining. About ten years ago, in order to improve on this situation. The Consolidated Mining and Smelting Company of Canada Limited began investigations relative to noise abatement in its underground operations. As a result of intensive research, this study has advanced to the point

Jan 1, 1964

By Frederick J. Browne

Water, water everywhere, but not a drop (fit) to drink! Trite, but how often only too true? What is there met with in mining which, under various circumstances, may be said to be the most sought-for and highly-prized and also the most objectionable and most feared? Water! What visions that combination of five letters brings to all thoughtful minds? Up to near the end of the eighteenth century water was thought lo be an element but was then discovered to be the result of the combustion of two volumes of hydrogen with one volume of oxygen, and water so produced is chemically pure. Pure water is a clear and colourless liquid when seen under ordinary conditions, but appears bluish when seen through a long tube, and this same bluish tint may be observed in many lakes, especially those of glacial origin. A story often told describes a prospector in the desert who, failing to find water to replenish his canteen, suffers torture and death under fearful circumstances. Then again we may recall the flooding of mines, where water poured in so quickly that there was no opportunity of saving the unfortunate workmen. Instances might be multiplied without number showing that either the lack or excess of this essential fluid has taken heavy toll of human life. In all branches of mining and associated industries water must be dealt with to a larger extent, from an economic point of view, than any other substance, and very often the purity of the water is a matter of considerable importance.

Jan 1, 1925

By D. H. Rousell

"Rocks of the Whitewater Group (Aphebian age) oc ithin the Sudbury Basin and consist of three formations rre, from oldest to youngest: Onaping, heterolithic breccias lus an igneous-textured component; Onwatin, argillite and siltstone; and Chelmsford, greywacke with minor argillite with siltstone. Mineralization in these rocks is as follows:1) Sulphides are disseminated throughout the Onaping Formation. Pyrrhotite, the major sulphide mineral, occurs mainly as fragments; other sulphides are chalcopyrite, sphalerite, galena, pyrite and marcasite.2) Zn, Pb, Cu, Ag and A u mineralization in the Vermilion member, a carbonate-chert unit near the base of the Onwatin Formation (Vermilion and Errington mines).3) Pyrite and minor base metals in the Onwatin Formation .4) Mineralized quartz veins, located at or near the base of the Onaping Formation, include such deposits as Moore Lake (Pb, Zn and Ag), Foisey (Zn, Pb), Papineau (Cu, Au and Co) and Proulx (Pb, Zn, and Cu). Quartz-carbonate veins in a meta-gabbro sill contain Cu, Zn, As and Au. Material from quartz veins from two former ""gold mines"" (Gordon Lake and Creighton) yielded no Au values.5) Anthraxolite veins in the Onwatin Formation .The mineral occurrences can be explained in term of either the volcanic theory or meteorite-impact theory of basin formation. According to the latter theory, the sulphide fragments in the Onaping Formation may have been formed by the brecciation of sulphide-rich pods located in the upper mantle and at the base of the transient crater; some of the sulphides may have been derived from target rocks of the Huronian Supergroup. The Vermillion-Errington deposits may represent sedimentary exhalative deposits of the Remac type; mineral-rich brines, trapped at the base of the transient crater, rose upward and precipitated the mineralized carbonate-chert under reducing conditions. These conditions continued throughout the deposition of the upper Onwatin Formation but pyrite was the only sulphide that formed.The quartz veins were emplaced during the time of basin deformation. Metamorphism remobilized and concentrated carbonaceous material in the Onwatin Formation 10 form the anthraxolite veins."

Jan 1, 1984

By W. de Klerk, M. B. Thorpe

Golden Star Resources Bogoso operates in Ghana’s Western Region. The gold recovery plant includes; a flotation circuit producing a concentrate for the BIOX® process that oxidizes sulphides before a CIL circuit; and a dedicated CIL circuit. BIOX® uses bacteria, therefore water from the BIOX® and CIL plants remained separated; CN water could not be introduced into the flotation / BIOX® circuit. The operation built a process water inventory with high TDS and installed a process water treatment plant (PWTP). Water was released in compliance the permits but containing some thiocyanate. The PWTP brine was returned to the TSF, further exacerbating the TDS. The operation experienced a drought removing the traditional water sources; the team evaluated the options to maintain production - various water streams were laboratory tested provided options for water use. The paper presents the story (treatment chemistry and process chemistry) of continued operations by treating stored water and PWTP discharge water with peroxide; brine usage within the CIL circuit, which increased gold recovery (laboratory testing) and reduced the TDS. Water flows were further modified to include hydraulic tailings re-mining to a CIL circuits. Details of the recovery, basic chemistry and costs savings are provided.

Jan 1, 2014

By P. E. Fox, R. S. Cameron

"The QR gold deposit lies in the Cariboo plateau region of central British Columbia. The deposit was discovered in 1977 and since then a mineable reserve of 1.3 million tonnes grading 4.7 g/t Au has' been outlined in three separate zones. Soil sampling of glacial tills followed by diamond drilling of favourable host rocks proved to be key exploration techniques.The deposit is situated in the southern Quesnel terrane along the eastern fringe of the Intermontane Belt which here comprises a sequence of basic and intermediate volcanics and a series of stocks of alkaline affinity; generally diorite, monzonite and syenite. Hornfels and epidote-rich ferromagnesian exoskarn and sulphide-rich mantos have developed in a metamorphic aureole formed around a central diorite stock. Gold-rich zones lie along the outer periphery of the aureole where bodies of gold-bearing epidote-rich skarn and auriferous mantos rich in epidote and pyrite have formed in beds of calcareous tuffite lying at the top of a thick basaltic sequence. The deposit is regarded as' a subclass of gold skarn deposits. Diagnostic features are its association with alkalic intrusive rocks in a subvolcanic setting and the presence of oxidized, epidote-rich mineral assemblages.IntroductionThe QR gold deposit lies within the Cariboo plateau region of central British Columbia, 58 km southeast of Quesnel. The deposit, owned by Kinross Gold, was discovered during a regional reconnaissance program by Dome Exploration (Canada) Limited and Newconex Canadian Exploration in 1977. Considerable exploration and development has been done since that time. Mineable reserves of 1.3 million tonnes grading 4.7 g/t Au have been outlined to date in three zones."

Jan 1, 1995

By Wei Yun-Jie

Columnar jointed basalt is a fractured rock, with a lot of small spacing structural planes and poor integrity of the rock mass. On the basis of the comprehensive study of the columnar shape of Columnar joints, rugosity of the fracture surface and the chemical composition of basalt, columnar joints of Bai hetan dam area were formed as a result of the cooling and shrinkage effect of magma. Columnar joints basalt are mainly chlorite, kaolinite, epidote, tremolite chemical reactions and the content of columnar joints are mainly chlorite by slice identification and chemical analysis. Columnar joints basalt showed high uniaxial tension test, low coefficient of friction and high cohesion by indoor physical and mechanical test. Columnar joints rock mass showed high strength and large deformation by field shear test and deformation test. Columnar joints basalt can be used directly as a foundation of dam as long as we follow the rules and reduce disturbance strictly.

May 1, 2009

By D H. Sharp

The Quebec Cartier Mining Company produces iron concentrate for twelve months of the year from Port Cartier. This J>Ort is designed to handle ship varying in size from 3,000 to 100,000 d.w.t., requiring 50 feet of water at low tide. The harbour was built on shore for reasons of economy and layout, after considering many more conventional offshore designs. It provides for heavy oil bunkering, tanker off-loading, a heavy lift derrick and freight handling, besides ship loading and mooring. The weather for the previous fifty years was studied to enable wind and wave conditions to be accurately assessed for design purposes, and to determine probable lost time due to adverse weather conditions through-out the year. The first ship to be loaded was 60,000 d.w.t.; the second, 20,000 d.w.t. The latter entered the harbour after dark, under its own power, following a tug through the partly dredged narrow entrance. Large ships use tug assistance. Ships may leave the loading berth with the other berths occupied.

Jan 1, 1963

By R. J. Young, S. J. Tennant, A. D. Drummond

"Gibraltar Mines is located on the western slope of Granite Mountain, 230 air miles north of Vancouver, B.C. and 38 miles north of Williams Lake, B.C. There are four mineable zones within the copper-molybdenite deposit: Gibraltar East, Gibraltar West, Pollyanna and Granite Lake. Open-pit reserves are 358 million tons which average 0.37% Cu and 0.016% MoS2 at a 0.25% Cu cut-off. The Granite Mountain pluton is one of the several Jurassic-Cretaceous intrusions which outcrop along the east side of the Fraser River fault system between Williams Lake and Prince George, B.C. The original Granite Mountain quartz diorite has been metamorphosed by a cataclastic deformation which foliated the rock on a regional scale. Attendant to the development of the foliation, the rock was saussuritized such that the present mineralogy is compatible with that of the greenschist facies. The presence of garnet-bearing assemblages is explained by a restricted increase in water pressure. Pre-mineral intrusive phases within the saussuritized quartz diorite are: (1) leucocratic quartz diorite, (2) aplite and (3) quartz-feldspar porphyry. A late chloritized hornblende dacite dyke is post-mineral. Quartz-feldspar porphyry and leucocratic quartz diorite are locally present on the inner sides of the Gibraltar East, Pollyanna and Granite Lake pits. Their presence suggests a core around which occurs an elliptically shaped sulphide-bearing stockwork. The stockwork, which comprises four ages of vein development, is imposed on and partly controlled by the regional foliation of the samssuritized quartz diorite."

Jan 1, 1973