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By D. H. Ryan, B. Abdul, M. Pernechele, E. Asselin

Hydrometallurgical processing of sulphide concentrates at medium temperature (150°C) produces residues, which contain valuable metals (Cu, Ni) as well as sulphur and iron bearing minerals and phases. The low solubility of iron during the medium temperature processing of sulphide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. A better understanding of the formation and structure of these iron precipitates may elucidate key factors that would ultimately result in lower valuable metal losses and more stable leach residues. Residues from two medium temperature leach processes were characterized by Mössbauer Spectroscopy. Some portions of the Mössbauer Spectrum were suspected to be linked to jarosite but could not be positively identified as such. There was a broad range of disorder and substitution present in the material and solely attributing it to jarosite proved difficult. Various synthetic jarosites with Cu substitution were precipitated for Mössbauer analysis. These were then characterized by Quantitative X-Ray Diffraction (QXRD), Scanning Electron Microscopy (SEM), Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) and Mössbauer Spectroscopy. The Mössbauer Spectra of the synthetic jarosites is compared with that of the residues from medium temperature (150°C) sulphide concentrate leaching.

Jan 1, 2014

By Akihiko Nishiyama

Unmanned construction technology used for remote control operation of construction machines has some problems to solve compared with manned operation of construction machines, such as fatigue due to long-term operation or decreases in operational efficiency. To solve these problems, we recorded the viewpoints of operators in both manned and remote control operation and analyzed the differences. This paper reports on our discussion of improving the operability of remote control operation based on the analysis results.

Aug 1, 2013

By M. L. Haider

Introduction I Appreciate very much the opportunity of discussing with you tonight oil developments in western Canada. These developments are of importance to all of us, first because of their great economic significance to all of Canada, and second because of the location of the new oilfields. Situated as they are in the west and northwest, they are of considerable strategic value from the standpoint of continental defence. The story of oil development in Canada covers a span of almost a century, during which time success in finding reserves of petroleum was barely sufficient to maintain interest in continuing the search. Finally, in 1947, a well of the first importance was completed in Alberta and, judging by discoveries made since then, it appears that Canada, at long last, is to become an important producer of petroleum.

Jan 1, 1950

By J. E. Moyle

The costs of labour and electric power are of prime concern to almost all industrial enterprises, and various methods of reducing their impact on production costs are constantly being developed. Automation is one of these schemes, and has received a good deal of attention in the past few years. In the mining industry, compressed air is almost universally used, and its cost is significant. Although the compressor machinery now in use has achieved a high degree of development, the hazard of explosion and fire still exists in these systems. There is thus considerable resistance in some quarters to suggestions that such installations can be safely and successfully automated. The Milliken power plant consists of two 30,000 lb. /hr. fully equipped high-pressure boilers, four H.P. air compressors, a steam turbine for stand-by power, and several L.P. compressors and vacuum pumps. With the installation of automatic and protective equipment in the machinery section, the shift force has been reduced from three to two men.

Jan 1, 1963

By Robert J. Uffen

YOU will likely recall the accomplishments of the International Geophysical Year of 1957, with its polar expeditions, the discovery of the Van Allen radiation belts and the spectacular launchings of the first artificial earth satellites. Our know ledge of the exterior of the earth was greatly increased by this international, friendly, cooperative scientific investigation. The Inter-national Union of Geodesy and Geo-physics has now been joined by the new International Union of Geological Sciences in sponsoring a similar study of the earth's interior. The program will extend from January, 1962 until December. 1964, and is known as the International Upper Mantle Project. During the T.G.Y studies of the interior of the earth were relatively neglected, even though the same international •Cooperation in obtaining simultaneous world-wide observations, by similar instruments, is required to locate and study earth-quakes, for example, as it is to study the earth's upper atmosphere. The upper mantle is 1•emote from man, as it extends from a depth of about 10 km. to perhaps 1000 km., but its practical importance is great.

Jan 1, 1962

By M. Sakata, H. Hata, K. Haiki

"Most of the secondary ZnO contains fluorine (F) in large quantities. Serious troubles at the zinc electrowinning are occurred by the cathode corrosion caused by F, therefore we developed iron compounds as F-adsorbents used in zinc sulfate solution. The iron compounds can be reused repeatedly as F-adsorbents because they can adsorb/desorb F alternatively depending on the pH. Moreover, if the adsorptive capacity decreases, we can dissolve and re-synthesize them easily. In this paper, results of the experimental process which consists of five steps (leaching, F removal, Cl removal, purification and electrowinning) to produce high purity electrolytic zinc from the secondary ZnO are reported. INTRODUCTIONThe recycle material for zinc, secondary ZnO, contains large amounts of fluorine (F) and chlorine (Cl) which are halogen elements, compared with calcine obtained by roasting of zinc sulfide concentrate. The halogen elements cause adverse effects in the zinc electrowinning process and particularly F causes corrosion of aluminum cathode plates and eventually sticking of electrodeposited zinc and therefore, F concentration in the electrolyte is controlled to less than approximately 20 mg/L. There are several methods to remove F from secondary ZnO, such as leaching with Na2CO3 or NaOH solution [1-2], vaporizing in a rotary kiln by roasting at 1000 to 1200 degrees C [3-4]. However, up to the moment, there has been no effective method for the removal of F from zinc electrolyte and it has been a big obstacle in treatment of secondary ZnO in electrowining of zinc.The authors, therefore, developed an iron compound used as an adsorbent of F in the zinc sulfate solution [5-8]. This iron compound is Akaganeite that has a crystalline structure of ß-FeOOH. Akaganeite is synthesized by neutralization of FeCl3 solution containing a small amount of SO4 2- with Na2CO3. When this iron compound is immersed into weak acidified zinc sulfate solution, F in the solution is adsorbed. F adsorbed in the iron compound is removed by immersing in weak alkaline solution and the iron compound can be reused as F adsorbent."

Jan 1, 2012

The Curtin University Gold Technology Group has been involved in surveying, modelling and optimisation of batch centrifugal concentrator type gravity circuits and CIP/CIL circuits for nearly two decades. The most commonly asked question regarding gravity recovery is, “What is the benefit of a gravity circuit”, which can be hard, if not impossible, to quantify. With the help of the AMIRA P420 Project’s Integrated Liberation Leach Model (ILLM) it is now possible to evaluate the effect of gravity recovery on total gold recovery when changes are made to the grind size, gravity and/or leach/adsorption circuits. This paper demonstrates how the ILLM can be used to determine the net benefit of introducing or modifying a gravity circuit and assess the effect of operating conditions (grind size, coarse gold size distribution, leach residence time, carbon activity, etc.) on plant performance.

Jan 1, 2017

By C. McLachlan, J. R. Donald

"Positioned at the forefront of the seafloor minerals industry, DeepGreen Resources is on track to becoming a leading producer of base and strategic metals obtained from vast high-grade seafloor polymetallic nodule deposits. DeepGreen believes the seafloor minerals industry is an opportunity for developing a more environmentally and societally attractive way to produce cleaner base and strategic metals. Polymetallic nodules contain nickel, manganese, copper, cobalt and other base and strategic metals. Polymetallic nodules represent an exceptional multi-metal-bearing resource, and no current metallurgical operation or flowsheet exists that can recover the primary metallic values while managing the distinct mineralogy. DeepGreen Resources is developing a new process to maximize the business outcomes consistent with the highest environmental standards, including targeting a near zero waste facility. The present paper discusses the history, context and driving forces of polymetallic nodule project development. An overview of DeepGreen?s Nauru Ocean Resources Inc. (NORI) project is presented along with a literature review of polymetallic nodule processing and the on-shore project development scope and plan at DeepGreen Resources is outlined.INTRODUCTION AND CONTEXT Polymetallic Nodules in the Clarion-Clipperton Zone Containing nickel, cobalt, copper and manganese, polymetallic nodules occur in most oceans of the world. The nodules lie on the seafloor sediment. The largest deposit in terms of nodule abundance and metal concentration occurs in the Clarion-Clipperton Zone (CCZ) on vast abyssal plains at a depth of 4,000 to 6,000 metres. The CCZ is located almost entirely in international waters as presented in Figure 1. It has been estimated that the CCZ contains (International Seabed Authority, 2010): •,>21 billion tonnes of nodules; •,>270 million tonnes of nickel; •,>6 billion tonnes of manganese; •,>234 million tonnes of copper; •,>46 million tonnes of cobalt. There are several active hypotheses for the mechanism of formation of the nodules including precipitation, hydrothermal decomposition of basaltic debris, and involvement of microorganisms. Nodules require a nucleus to start forming, which could be a piece of pumice, a shark tooth, old nodule piece, basalt debris or even microfossils like radiolaria and foraminifera. Nodules form concentrically with layers of iron and manganese hydroxides around a core. Although composed mainly of Mn, Fe, silicates and hydroxides, it is the significant content of Ni, Cu, Co, Zn and Rare Earth Elements (REE) that is generating the economic interest in harvesting these deposits. Nodules vary in size from micro-nodules to about 20 cm, the common size being two to eight centimeters. A typical polymetallic nodule and polished cross-section is presented in Figure 2."

Jan 1, 2017

By Shamia Hoque, Charles Q. Jia

Smelter slags contain valuable metals such as Co, Ni and Cu in proportions of less than 1 wt% along with about 40 wt% of Fe and 15 wt% of Si. Although aqueous SO2 is a versatile lixiviant for transition metals, dissolving the slag in aqueous SO2 produces solutions in which Co and Ni concentrations are lower than that of Fe due to the low metal/ Fe ratio in the slag. To develop the options for increasing Co and Ni concentrations the solubility of slag in aqueous SO2 was studied experimentally and theoretically using OLI, a software package for simulating electrolytes chemistry. The modeling results correlated well with experimental results. The model suggested that the species dominating the system was FeSO3, which would precipitate out as FeSO3.3H2O when the concentration of Fe+2 reached 1.22 molal and the concentration of S032- was beyond 1.4 molal. In the experiments the influence of pH and solids loading were studied. The leach solution obtained after dissolution of slag at 50% solids loading had a pH of 1.85. On raising the pH to 3, precipitation occurred. Analysis of the solution collected after the addition of alkali showed over 50% reduction of Fe, Co and Ni. XRD analysis revealed the precipitate to be of amorphous nature due to the silica present. The analysis confirmed that the precipitate was mainly FeSO3.3H2O. The paper also discusses the potential impact of the slag on the environment.

Jan 1, 2004

By G. S. Hume

FOR MANY YEARS Canada lived in the hope of attaining a substantial production of petroleum and natural gas that, to geologists familiar with the sedimentary basins of this country, seemed an entirely reasonable expectation. There have been surges of exploration activity stimulated by oil and gas discoveries and development such as occurred in Turner Valley. However, it was not until the Leduc field in Alberta was found in 1947, and the significance of that discovery was realized, that the search became really intensive and continuons. Expansion now has become a matter-of-fact attitude based on results which would have been considered impossible of achievement a few years ago.

Jan 1, 1957

By John Tribe

"This paper gives the organizational history of Luscar Ltd. and its various coal producing operations. Each 0/ the operations is then described individually. They include the Bienfait Mine, the Boundary Dam Mine, the Diplomat Mine, the Luscar Mine and the Coal Valley Mine. The company's plans/or expansion are also discussed. IntroductionLuscar Ltd. is an Edmonton-based energy company formed in 1967 through an amalgamation of two pioneer coal companies-Mountain Park Collieries and Luscar Coals Ltd. In 1912, Mountain Park Collieries initiated the development of an underground mine in the Coal Branch area of Alberta. This mine necessitated the establishment of a townsite and the provision of rail access. The second operation, Luscar Coals Ltd., was established in 1921 at Luscar, Alberta. This was also an underground operation and required the development of a rail spur and townsite. The product from both mines was used to fuel railway steam locomotives until the 1950's. The market demand for coal decreased as the use of the diesel locomotive increased, so that these operations were finally closed in 1954. Through the amalgamation of the two companies in 1967, however, Luscar Ltd. was formed to become an active participant in the revival of coal operations. Western Canadian Luscar Ltd. is involved in the exploration, development, production and marketing of coal, coal products, oil and gas. Luscar Ltd. is currently participating in five producing mines (Fig. I). The Diplomat Mine, approximately 125 miles southeast of Edmonton, was in production when it was acquired in 1949 by Luscar Coals Ltd. In 1966, the Bienfait Mine and char plant were added. The Luscar Mine, which is a 50/50 joint venture of Luscar Ltd. and the Consolidation Coal Company of Canada, and is operated by Cardinal River Coals Limited, started production in 1969 on the original Luscar Coals Ltd. mine site. The Boundary Dam Mine was opened in 1974. Both the Bienfait and Boundary Dam operations are located in the lignite coal fields of southeastern Saskatchewan. The most recent addition to the group is the Coal Valley Mine, 40 miles southwest of Edson, Alberta. It commenced commercial production in July, 1978 under the operation of Luscar Stereo (1977) Limited."

Jan 1, 1980

By B. Stettner, J. Asante, S. Abraham

The levels of nitrogen in steel produced in various metallurgical vessels vary significantly. For example, the tap nitrogen levels in steel produced in the BOF are around 4Oppm, as compared to 70-100ppm in both DC and AC electric arc furnaces. Given the pressing need to reduce nitrogen levels in steel to satisfy customer demand, IPSCO Inc. has gained considerable experience in controlling nitrogen levels in steel over the course of the last three years. Hence, a cost effective process has been developed through an intensive nitrogen control program from steel melting in the EAF through to the continuous slab casting stage. This paper describes the practices employed at each stage of the steelmaking process that have enabled IPSCO Inc. to reduce and control nitrogen levels in steel.

Jan 1, 2004

By H. M. Woodrooffe

This paper deals with the laboratory facilities at the Mines Branch for carrying out research in the industrial minerals field, and also reviews current programs in ceramics and construction materials, in non-metallic minerals and in the milling of industrial minerals. It then discusses the application of these pro-grams to industrial problems.

Jan 1, 1967

By S. Dessureault

The relatively recent explosion of available data in all business sectors has induced a common expression of “drowning in data, starving for information.” The mining sector is affected by the information age through equipment-based sensors, process monitoring, and traditional enterprise data sources. Information technologists have developed techniques such as data mining that apply new and old statistical algorithms to large datasets. Mine planners and managers can apply these tools for improved planning and control, thereby increasing the use of the highly underutilized information system infrastructure in most modern mines. This paper describes the use of data mining and its enabling technology, data warehousing, in the development of an energy consumption model for large surface mines using real historical data.

Jan 1, 2007

By N. Ahern, L. Manoukian

"Cyanide is a leaching agent for precious metals commonly used in gold ore processing. Cyanide exists in various forms (including free, complexed as weak or strong complexes, and as ions such as cyanate and thiocyanate), so its detection, speciation and analysis in processing or environmental samples can be complex. This paper will review best practices for cyanide sampling and preservation in the field, interferences and pretreatment methods required prior to sample analysis and analytical methods that are used for cyanide species. Titrimetric, flow injection ligand exchange, spectrophotometric, colorimetric, potentiometric, amperometric, and chromatography techniques will be discussed and their chemistries, detection limits, advantages and limitations will be described.INTRODUCTION Cyanide is well known to be an extremely toxic species. Accurate cyanide measurement in effluent from mines is critical from an environmental perspective. Its measurement is also an important control parameter in the recovery of gold using cyanidation. Cyanide chemistry is diverse and complex, and cyanide analysis can be challenging as a result of and because of limitations in understanding of analytical methods. Various chemical mechanisms can form or destroy cyanide, and the sample matrix or preservation chemicals can also affect analytical results. These interferences make the collection of reliable cyanide measurements challenging and can start as soon as the sample is collected, during laboratory pre-treatment and during analysis. This paper reviews different methods of cyanide measurement. The basic chemistry of cyanide, best practices for sampling and preservation, as well as various methods of analysis will be discussed.CHEMISTRY The complexity of cyanide chemistry is well known (Beck, 1987; Delgado, Botz, Bucknam, Milasovljevic, & Staley, 2008; Botz, Milosavljevic, & Ward, 2013) and is attributed to the ability of cyanide to undergo: •,Volatilization •,Precipitation •,Adsorption •,Complexation with metals •,Oxidation to cyanate, ammonia, or cyanogen chloride •,Reaction with sulfur or sulfide minerals to form thiocyanate •,Redox reactions leading to the formation of cyanogen and cyanate •,Redox reactions (of some cyano complexes) •,Photochemical reactions (of some cyano complexes)"

Jan 1, 2017

By M. G. Manzone

Approximately two-thirds of the annual 210,000 tons at copper refined by AMAX Inc. at the United States Metals Refining Company in Carteret, New Jersey, comes from a wide variety of copper scrap ranging from low-grade smelter scrap to wirebar-grade material. The equipment and methods used to effect such large-scale metal recycling in an urban area and the measures taken to collect and recover metal values from smelter and refinery byproducts while protecting the environment from pollution are described and discussed.

Jan 1, 1977

By M. Kim, M. Ha

"The effect of red mud on the melting behavior of ferronickel slag was investigated by a laboratory-scale horizontal tube furnace. Melting and softening of slag samples fluxed with different amount of red mud was examined by in-situ visualization technique at temperature range from 1400 to 1550°C. FactSageTM 7.0 was used for the thermodynamic calculation of multi component system of ferronickel slag and red mud. Liquid phase area was extended to lower temperature by adding red mud indicating its suitability as a flux material. X-ray diffraction analysis confirmed the dependency of the phase changes on the red mud content. Microscopic observation by scanning electron microscope (SEM / EDX) clarified the phase transformations from olivine to spinel along with red mud additions.INTRODUCTION Ferronickel smelting by submerged arc furnace (SAF) is an energy intensive process performed at high temperature range 1500–1600°C. During the smelting process of saprolitic nickel laterite ore with a nickel content of 2.2–2.3 pct, a large quantity of ferronickel slag is being produced that account for 97 pct of ore charged. To achieve ferronickel grade of 15–20 pct Ni, electrical energy of 80 to 85 MW is used for the melting and reduction of nickel oxide (NiO) and iron oxide (FeO) in the ore (Rodd et al., 2010). Unreduced components, mostly MgO, SiO2 and partly FeO are removed from the furnace in a liquid slag form by a tapping operation. Due to the high melting temperature, forsterite (Mg2SiO4) based slag containing approximately 10 pct FeO requires typical process temperature of 1600°C. Flux in metallurgical process is a medium that decreases melting and operating temperatures while it increases fluidity of the liquid slags. Calcite and fluorite are examples of flux materials used for the ironmaking, steel refining and continuous casting process. Oxide systems based on CaO - CaF2 - SiO2 - Al2O3 - MgO cover most of the slag composition in ferrous metallurgy accordingly. Crucial operating factors for ironmaking and steelmaking slags are basicity (typically CaO/SiO2 ratio), viscosity and impurity levels. These are extensively controlled by the fluxes. General metallurgical fluxes such as limestone, dolomite and calcium fluoride are abundant in nature and supplied to steel mills at low prices. Meanwhile, in copper flash smelting process, silica is supplied with copper concentrate to remove iron oxide (FeO) generated from sulfide oxidation. FeO - SiO2 binary system formulates eutectic area at 25–38 pct of silica that has low melting temperature below 1205°C. Fayalitic system (Fe2SiO4) that has low viscosity (0.1 Pa·s) (Park et al., 2011) facilitates easy separation of slags from molten sulfide mattes. Recently, copper plants actively utilize recycled raw materials as a flux. Various recycled glasses are ground and fed to copper smelting process as a partial replacement of silica ore. Applying industrial wastes to smelting processes is advantageous since the operators can reduce the production cost remarkably. Not to mention the consumption of recycled materials can ultimately minimize the environmental risks and the waste management costs. The authors, therefore, investigated the reasonable waste materials that can be effectively used for ferronickel smelting process. Prerequisites for potential fluxing materials are non-recyclable property, low transportation cost and excellent performance as a flux."

Jan 1, 2017

By B. Courtaud, L. Donati, V. Weigel

As a growing mining company, ERAMET is looking for new positions in the strategic metals market. In this context, the Gabonese Maboumine pyrochlore deposit is currently being studied for the recovery of niobium, tantalum, rare earths and uranium. This ore shows mineralogical and chemical characteristics that make it challenging to process by existing practices, from both technical and economic points of view. ERAMET has developed since 2008 an innovative hydrometallurgical process, which has been successfully operated at a pilot plant scale (more than 35 weeks in continuous). The upstream part of the process aims to dissolve valuable elements in sulphuric acid. The first step is dedicated to dissolve the ore matrix, leaving the pyrochlore unleached. The second step consists in chemically breaking down pyrochlores in order to form soluble species of the valuable elements. After dissolution, the valuable elements are separated into different flows: niobium and tantalum are recovered and transformed as commercial ferroniobium on one side, and rare earths and uranium remain in the solution to be recovered in the downstream part of the process. The main goal of this paper is to discuss the upstream part of the process, which has given successful results.

Jan 1, 2014

By D. M. Morrison

"Microseismic systems at five mines in the Sudbury Basin provide the basic data for Falconbridge Limited's rockburst research. Daily and long-term analysis of this data as well as underground observations has confirmed the fault-slip mechanism of rock bursting at three mines. A detailed analysis of the complete history of Falconbridge Mine is being conducted and Distinct Element numerical models are being used to simulate both the stick-slip behaviour of faults and the dynamic effects of the induced vibrations on rock and backfill. University research includes acoustic tomographic imaging of the rock mass based on seismic wave propagation and collection of full micro seismic waveforms to allow application of advanced seismic and statistical analysis techniques. INTRODUCTIONFalconbridge Limited currently has five mines operating in the Sudbury Basin: East, Lockerby, Onaping, Fraser, and Strathcona Mines, which along with the Falconbridge open pit produced 2.8 million tonnes of ore in 1986. The underground mines range from about 600 m to 2000 m below surface and one of the consequences of mining at these depths is the occurrence of rockbursts.Research into rockburst phenomena at Falconbridge began over 25 years ago and research is continuing in an effort to avoid the problem by improved mine design, to protect mine openings from damage by design of effective support systems and to better understand the processes which precede a major fault slip rockburst. Since the early 1980s, significant progress has been made due principally to micro seismic monitoring and advances in microcomputer technology coupled with detailed underground investigations.It is now possible to identify the fault-slip mechanism as the cause of many of the rockbursts which occur at Falconbridge mines. By gaining an understanding of effect of mining-induced stresses on the pre-existing geological structures, areas which may experience rock bursting can be identified and can be protected against severe damage by appropriate support techniques."

Jan 1, 1989

By Zhen Lei

In Alberta, Canada, heavy industrial projects are constructed using a prefabrication approach: spools and pipes are produced in the factory, and are assembled into modules that are transported to the industrial plants for installation by mobile cranes. Planning the onsite mobile crane operations is critical to the project budget and schedule. However, due to the large magnitude of industrial projects, manual heavy lift planning is tedious, and the results are not particularly responsive to site changes. This paper introduces an integrated mobile crane management system developed by PCL Industrial Management Inc., in collaboration with the University of Alberta, which investigates crane location selection and path checking for field module assembly. The project information is stored in a database, and the proposed system retrieves data, performs the calculations, and records the results back to the database; the calculations involve automatically selecting locations for the mobile crane, considering the crane capacity, lifting range and utilization. Lift paths for modules are checked for feasibility based on selected locations, satisfying the site and crane configuration constraints, and crane walking paths are planned if needed. The designed system is tested in an industrial project to validate the effectiveness of the system.

Aug 1, 2013