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By T. Guan, G. Fu, X. Zhou, L. Deng

"Currently, tailings water is required to be recycled in minerals processing plants. When the flotation tailings water of complex copper-sulfur-tungsten polymetallic ore is reused to the flotation of copper-sulfur ore, a portion of tungsten would be lost in copper concentrate or sulfur concentrate due to the addition of the collectors used for oxidized ore which are also effective for the sulfide minerals in the process of tungsten flotation. At the same time, the technical index of copper concentrate and sulfur concentrate would be seriously affected by tailings water. Our experimental researches of many years show that the copper concentrate with a grade of 18.36% Cu at a recovery of 76.67% is obtained for the raw ore containing 0.60% Cu, 18.99% S, 0.16% WO3 in small locked cycle test using recycled water, through simple pretreatment of the tailings water from tungsten flotation and adding special regulator CW and new tungsten collector TM. The result is close to the performance without using tailings water. And, in the continuous pilot experiment which was continuously conducted for 4 days with the same technology, the following results was obtained: the copper concentrate with a grade of 21.74% Cu, the recovery was 71.55%; the sulfur concentrate with a grade of 45.16% S, the recovery was 80.10%; the tungsten concentrate with a grade of 42.63% WO3, the recovery was 54.62% relative to raw ore (the recovery relative to scheelite was 76.47%). The throughput of the continuous pilot experiment is 1.0~1.2 t/d, and the raw ore contains 0.56% Cu, 18.80% S, 0.14% WO3 on average.INTRODUCTIONMining industry is one of the most important developing fields, it supplies raw materials for industrial production as well as discharges much waste water. Tailings water is the main source of beneficiation waste water, it would result in severe environmental pollution if discharged directly. Generally, the tailings water would bring undesirable effect on flotation index after simple pretreatment by lime (Kalin, Fyson, & Wheeler, 2006). On the other hand, the treatment of tailings water through ion-exchange (Cui & Liu, 2015) before recycling is of high cost. Generally, in the flotation of Cu-S-W polymetallic ore, when the tailings water from tungsten flotation is treated simply by lime and recycled to the flotation of sulfide minerals, the flotation index of sulfide minerals decreases, and a portion of oxide mineral would be lost in the sulfide concentrate. As a result, the recycle rate of this kind of tailings water is relatively low, some of the tailings water is discharged after simple treatment and then environmental pollution is caused subsequently. One of the effective ways to improve beneficiation performance and increase the recycle rate of tailings water is to conduct research on developing recycle technology for flotation tailings water of complex copper-sulfur-tungsten polymetallic ore."

Jan 1, 2016

By N. Manopulo, J. Maier, L. Tong, C. Becker, P. Hora

The contribution presents a new finite element approach in which the common updated Lagrangian formulation is replaced by a spatial flow formulation applying a special arbitrary Lagrangian-Eulerian for-mulation (ALE). The description separates spatially the process in a die inside zone and in a profile zone. For the description of the inside zone, where the filling process occurs, a special Euler time independent mesh is applied. By this formulation the mesh has to be generated only once, which simplifies the generation of spatially optimized meshes. For mapping of the material flow during the filling process the method uses a flow surface traction method as applied in casting simulations. A further strength of the new method is the computational efficiency which allows the modelling of extrusion process with the highest complexity with a response time of 12 hours, which is important for the industrial optimization process.

Jan 1, 2015

By T. A. Chepushtanova, I. U. Motovilov, V. A. Luganov, G. D. Guseynova

"Kazakhstan has significant reserves of oxidized nickel ore with low nickel content. Processing of such ores is effective via pyrometallurgical technologies such as smelting to ferronickel or matte with consecutive extraction of metals from melting products. There are also many options for direct hydrometallurgical processing. However, they do not provide high nickel recovery.We studied extraction of nickel and cobalt by using combined technology of low-grade ore processing from the Shevchenko Kazakhstan deposit, which includes smelting to poor matte followed by hydrometallurgical processing of the matte. The nickel content in the initial ore was 0.75–0.9%. Pyrite concentrate of Sokolov-Sarybai Kazakhstan deposit containing 0.17% cobalt and 0.06% nickel had been used as a sulphidizer at smelting.As a result of the study, we were able to extract up to 98% of the nickel and up to 80% of the available cobalt. Obtained matte contained 3.1% nickel, 0.29% cobalt, 71.6% iron and 24.3% sulfur. Matte leaching was carried out by hydrochloric acid. The iron content in the pregnant solution was 170–185 g/dm3. Nickel and cobalt precipitation from the pregnant solution was carried out by hydrogen sulfide. Initial matte or cast iron was used as neutralizers during the process. Practically complete precipitation of nickel was achieved at 3–5% excess of neutralizer at 333–343°K in 4 hours; up to 95% of cobalt precipitation was achieved in 50% excess of neutralizer at 363°K in 8 hours. The purified solution contained 200–600 mg/dm3 of nickel, 80-100 mg/dm3of cobalt and 175–185 g/dm3 of iron. The purified solution allows to obtain iron oxides by high-temperature hydrolysis, and to regenerate hydrochloric acid.As a result of non-ferrous metals precipitation we obtained sulfide concentrate with concentration of Ni up to 25% and concentration of Co up to 5.5%. The technology is recommended for semi-industrial testing."

Jan 1, 2016

By G. B. Harris

A new process for the recovery of copper and associated base metals from a polymetallic massive sulphide ore is described. The massive sulphide contains copper and especially nickel sulphide in a mineralogical form which negates both good recovery and high grades in concentrates using conventional flotation methods. Flotation concentrate processing and smelting from this ore is therefore probably not an economically viable option. Utilising the properties of high concentration chloride brines, a flow sheet has been developed and tested whereby the recovery of all of the metals and some of the power requirements for the plant itself can be derived from the ore. The new process overcomes the less-amenable-to-flotation ore characteristics, and provides the opportunity of economic processing in remote locations where the dependency on fossil fuels is both a logistical and an economic concern. The Ferguson Lake deposit of Starfield Resources in Nunavut, Canada, is the subject of this paper, which focuses on the leaching and copper recovery unit operations of the proposed flow sheet.

Jan 1, 2007

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

"For the Kazchrome DC Ferrochrome plant, SMS-group specifically designed an electrode column that would minimize downtime. Special features include the possibility for on load electrode jointing, on load slipping, and back-slipping. Electrode consumption is strongly related to furnace load and impedance, and is very low at high loads, which makes the graphite electrode an alternative to consider even in AC applications. The electrode could also be applied in other DC applications, as for example TiO2 slag, the novel Conroast process, or (twin) DC FeNi furnaces, and could possibly be installed during bigger shut downs. This paper will describe some of the design considerations and operational performance data on this novel column in the FeCr industry that could also be of interest for the FeNi or PGM industry if these would continue to develop towards DC technology.INTRODUCTION Every DC furnace has a cathode and an anode. The anode applied is commonly known as the Concast design, though the original design was by ABB who handed it over to Concast, subsidiary of the SMS-group. Some well-known DC furnaces outside the steel industry where the Concast bottom has been installed are listed in Table 1 as well as a few other key design features.Sidewall cooling and some other data have been left out for reasons of space, and being a lesser relevant design feature to this paper. HES stands for Hollow Electrode System, in which feed is charged through an electrode. Table 1 is built up chronologically according to first start-up date. Below comments are given to briefly explain some of the columns in Table 1: •,“Arm” in the “Cathode” column means that the design of the cathode holding and regulating mechanism consists of an electrode arm as depicted in Figure 1. •,Charging is relevant as some operations started with HES charging, whereas recently most new operations have started without HES but only charging chutes, of which at least some are close to the electrode and possibly others installed closer to the sidewall. •,“Dome” in the “Roof” column means that the design of the roof involves a center piece that can be exchanged if worn. •,The optimal roof design still seems to be a topic of debate, where no design is without problems."

Jan 1, 2017

By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

By L. G. Morrell

Introduction A Self-Dumping cage which combines the features of a small skip and a cage has been used in a vertical winze between the 2,000 and 2,500 levels at the Coniaurum mine for the past three years, during which time its success has been demonstrated by uninterrupted service and low maintenance charges. lt was designed by John Reddington, mine manager, and was built under his supervision in the Coniaurum mine shops. Being new in many of its operating features, a small-scale model was made and tried before the final construction was undertaken. The mechanical performance of the model suggested a few minor changes that were incorporated in the final drawings. During its three years of use, the automatic dumping device has saved the expense of deck-handling of the cars. This actually represents a gross economy of something over four times the cost of construction and installation, which totalled $1,325. The cage, empty, weighs 2,200 pounds, of which 500 pounds represents the weight of the dumping accessory and necessarily heavier construction. Besides a considerable financial saving, the time saved in unloading increases the daily hoisting capacity of the winze. In raising ore from the 2,500 level, five minutes are required for a complete trip. Allowing one minute for the alternative of decking, we believe that the automatic dumping has increased the capacity of the winze hoist nearly 20 percent.

Jan 1, 1933

By Ferrin Prince

New Gold?s New Afton mine is an 11,000 tonne per day block caving mine, located 8 km west of the city of Kamloops, British Columbia. The reserve is estimated at 52.5Mt with grades of 0.65 g/t Au and 0.93% Cu. Block caving requires a considerable amount of infrastructure development before production can begin. Each excavation had its own challenges, often further complicated by interactions with the caving stresses and fault structures. The main areas of interest were: the production crusher complex, the surface to underground infrastructure, and the footprint interaction with the faults. The ore zone at New Afton is bounded by two very weak fault zones, with large fault affected areas and associated splays. The resulting rock mass rating (RMR) is 35-50, with some areas significantly weaker due to clay infill. These conditions created a unique and decidedly difficult environment in which to develop New Afton?s infrastructure. Despite these difficulties, the mine began production on schedule in July 2012. The main production crusher for the mine is a gyratory crusher that allows for direct truck dumping, with a smaller jaw crusher in series to facilitate the initial development and production. The crusher chamber was redesigned several times to minimize the chamber volume, resulting in a 40% decrease in volume without losing functionality. After drilling and geotechnical testing, the location of the crusher was changed to eliminate the threat of fault affected ground in the area; the entire complex moved a short time before mining began on the chamber. The mining techniques used enabled tight control of the crusher pocket excavation, while also allowing for the timely completion of the chamber. The locations of the surface to underground infrastructure were tightly constrained by geology, surface infrastructure, and an existing open pit. The VR5 raise was drilled and abandoned part way through the reaming process when the drill string became stuck in fault gouge material. It was relocated and successfully completed. The VR7 raise hit a region of poor rock strength and deviated more than 11 m. Poor ground conditions caused a 130m section of the raise walls to fail. An innovative rehabilitation program was undertaken to re-establish the raise for ventilation. A surface to underground slick line was also installed to ease the material movement underground. A layout of the Extraction level was changed from herring bone to straight through drawpoints that resulted in a net reduction of 1.3 km of development. The Apex level was added to aid in the breakage over the major apex pillar and allow for geological mapping. A portion of the caving footprint is located within the footwall fault. The low strength, high clay content, and small joint spacing of the material resulted in blast-hole cut-off and drift deformation. Drift rehabilitation was a key factor in the successful development of the cave footprint. Innovative drilling and loading techniques were used to keep the holes open and to impede movement along the joint structures.

Aug 1, 2013

By L. Narhi, K. Haavanlammi

"Approximately two thirds of annual nickel production is used as a raw material in the making of stainless steel, and about 60% of these nickel products are in the form of metallic nickel such as nickel cathode or briquettes. In the stainless-steel production process nickel is blended with iron and chrome-based raw materials, and metallic nickel is typically only required for final steel fine-tuning. Outotec offers a new FeCrNi technology to enhance the nickel value chain for stainless steel producers. This involves the use of an HPAL-based intermediate nickel product (e.g., mixed hydroxides or NiO) as raw material in the Outotec FeCrNi process, for the production of a FeCrNi Master Alloy. The new process, designated as the FeCrNi process, offers multiple benefits compared to existing technologies such as: higher tolerance for impurities in the HPAL intermediate product, avoiding the need for further nickel refining, and the improved recovery of all metals in the FeCr process. The complete new FeCrNi value chain is based on proven technologies such as HPAL and the Outotec FeCr-process. This new innovative and promising value chain offers improved efficiencies for the HPAL based nickel production process combined with excellent sustainability aspects.INTRODUCTION In today’s global economy there is a constant need to improve the efficiency and sustainability of the metals production. The requirements for modern metal refining are tightening and cost efficient, safe and sustainable operation is the precondition for all investment. Outotec is offering now a novel way to combine FeCr and Nickel production to create a completely new value chain to source nickel to stainless steel. BACKGROUND Nickel The current nickel mine production is in the level of 2,000 tons annually and it is split 44% from sulphide based deposits and 56% from laterite deposits (Figure 1). Most (40%) of the nickel is refined to pure nickel metal whereas other products are FeNi (19%) and Nickel Pig Iron NPI (20%) (Roskill). The remaining part, roughly 21%, is nickel chemicals and intermediates. Most of the new investments in nickel are in the direct shipping of laterite to produce nickel pig iron. HPAL process is considered in few projects but no major HPAL projects have been started since the Ambatovy plant in Madagascar. Ambatovy reached the commercial production in 2014. The main primary nickel used is stainless steel manufacturing. In the year 2016 about 68% (~1,360 kt) of primary nickel production was used in stainless steel."

Jan 1, 2017

By S. McPherson, M. Chalkley, R. Ellenwood, W. Nicot

"The Moa JV was formed in December 1994 as a 50/50 joint venture between Sherritt Inc. and General Nickel Company S.A. of Cuba. The joint venture consists of the mine and Pedro Sotto Alba processing plant in Moa, Cuba and the Corefco refinery in Fort Saskatchewan, Alberta, Canada. Throughout its now nearly 23-year history, the Moa Joint Venture has faced a number of global, operational and process challenges. Global challenges have included high input costs such as for fuel oil and sulphur, as well as low nickel prices. Operational and process challenges have included increasing ore haulage distances, decreasing ore Ni + Co grades, and increasing ore impurity contents. For example, increases in impurities such as Mg and SiO2 in the ore result in increasing acid demand in leaching and decreasing solids content of preheated leach feed slurry, respectively. In spite of these challenges, the mixed sulphide production capacity from the Moa Joint Venture has increased from 12,500 to 37,000 t/y Ni + Co since 1994 by judiciously targeting expansion projects and by continuously performing process and operational improvements.INTRODUCTION The Pedro Sotto Alba high pressure acid leach (HPAL) plant at Moa Bay, Cuba has a long history (Maslenitzkiy, 1969; Chalkley, 1996; Carlson, 1960; Roy, 1961; Carlson 1961). The plant was constructed by Moa Bay Mining Company and started up in late 1959 after several years of process development by Freeport Nickel Company, including operation of a 10 t/d plant in Hoskins Mound, Texas and a 50 t/d plant in Port Nickel, Louisiana (Southwick, 2004), as well as development work by Chemical Construction Company (Chemico) to precipitate metal sulphides (Roy, 1955a; Roy, 1955b). The Moa plant had an original reserve of 50,000,000 t of ore, graded at 1.35 wt% Ni, 0.146 wt% Co, 3.70 wt% Si, 1.00 wt% Mg and 4.5 wt% Al. At original design rates of 2,000 kt/y of ore, the design capacity of the plant was around 25,000 t/y Ni + Co as a mixed sulphide product, which would be shipped to the Port Nickel Refinery in Louisiana for processing. In 1960, the plant changed ownership and was restarted in 1961 under Cuban management. Between 1961 and 1989, the plant was also supported by involvement from the former USSR, supplying spare parts and consumables. In 1994, Sherritt Inc. partnered with the General Nickel Co. S.A. of Cuba and formed the Moa Joint Venture. This joint venture includes the mine and Pedro Sotto Alba HPAL processing plant in Cuba and the Corefco refinery in Fort Saskatchewan, Alberta, Canada. Under this partnership, ore is processed in Cuba to produce a nominally 55 wt% Ni and 5 wt% Co mixed sulphide product that is shipped to Canada and processed by Corefco to produce class 1 nickel, high grade cobalt and byproduct ammonium sulphate fertilizer."

Jan 1, 2017

By C. Xiao, F. Mohamm, A. Borsoi

"Nitrogen compounds produced by cyanide destruction and/or blasting are often a cause of concern for environmental compliance and at times, for water re-use in metallurgical circuits. Natural attenuation in tailings ponds and wetlands is not always sufficient to ensure compliance and/or achievement of overall water management objectives. This paper provides a general overview of active treatment methods for nitrogen management followed by an investigation of selective adsorption combined with electro-oxidation as the potential treatment method for thiocyanate. Results from bench scale treatability study are presented. The concept of holistic assessment of nitrogen management at mine sites using Risk Adjusted Life Cycle Cost is introduced and discussed in the context of gold mining operations using sodium cyanide.INTRODUCTION Unlike metals, nitrogen compounds present in mine waters originate entirely from anthropogenic sources rather than mineral deposits. Table 1 summarizes the main sources of nitrogen compounds reporting to mine wastewater.The best management practice related to the use of ANFO involves minimizing contact between ANFO and water, control and monitoring of blasting to reduce the occurrence of misfires, and reducing the consumption of blasting reagents for a given ore body. The most common practice for the management of NaCN is the incorporation of cyanide destruction in the metallurgical flowsheet and the use of tailings impoundments and holding ponds for natural attenuation of cyanide destruction residues such as NH4-N and CNO. At most mine sites there is no active management of NO3-N and SCN in wastewater. While current practices have produced satisfactory results, new enhanced methods to manage nitrogen compounds at mines are needed due to: 1) Increased scrutiny over the adverse effects of nitrogen compounds released into the environment; 2) New effluent standards; and 3) The shift away from wet tailings towards dry stack systems resulting in diminished natural attenuation and dilution of nitrogen residues prior to effluent discharge or water re-use in mineral processing."

Jan 1, 2017

By D. Shen, J. Cheung

Variable reactance arc control by the SPLC (Smart Predictive Line Controller) has been installed at many different mining sites and steel processing plants around the world. Since its first installation 18 years ago, many advances have been made to both the technology, and to its integration with furnace processes and plant operations. The SPLC has helped to improve electric arc furnace stability by reducing electrode movement while maintaining flat line arc power. Stable furnace operation at higher average power increases productivity. This paper summarizes the progression of electro-technology at Hatch since the 1970s, including fixed and variable reactance, digital electrode regulation, and fast variable speed hydraulics for Soderberg electrode, as demonstrated and benchmarked through projects and lessons learned over the years.

Jan 1, 2015

By M. J. Bunyard, I. Mullany

"The pressures on mine operators are varied and constantly increasing, declining ore grades, more remote locations and increasing environmental concerns. The challenge facing the mining industry is to find new ways to process ores which are more efficient and less costly and to control them better. This requires a fundamental rethink in the way in which projects are developed, it is no longer good enough to just copy what has been done before. The process starts with the surfacing of the primary underlying constraints for the project and the establishment of new design principles to address these. The generation of new design criteria and processing options follows the well-established path of brainstorm, focus, brainstorm, refocus and economic evaluation. The aim is process intensification, doing more with less, as early as possible and better use of plant data. The methodology requires a complete geometallurgical understanding of the orebody to facilitate the evaluation of viable processing options. Examples of early stage processing considered are blast optimization and ore sorting to reject waste and reduce processing costs. Mine to mill integration, which starts with the optimization of blasting for separation, offers another way to significantly reduce operating costs and increase efficiencies.VALUE MODEL The mining industry has, over the past decade, experienced an unprecedented cycle of increased commodity prices and investments in new mining and processing capacity followed by a market collapse and fall in prices and confidence. Whilst there are now some signs of a return to investment in new capacity, the metals and mining industry is still wrestling with eroding margins and investor demand that companies achieve the full value of their assets. Metals and mining companies must work on all available levers to deflate their costs back to more manageable levels and capture the full value for their products. Levers include optimizing external spending, re-thinking make vs buy trade-offs, debottlenecking, improving availability and operating time of key equipment, more accurate and agile planning processes, value-in-use optimization, and tighter performance management. Figure 1 is a diagrammatic representation of a company’s value model. The three goals of a successful mining enterprise are social acceptance, environmental acceptance and sound financial returns to shareholders. Some of the KPI’s used to measure the success or not of achieving these goals are shown in the translation layer."

Jan 1, 2017

By D. Tao

Froth flotation is widely used in the coal industry to clean -28 mesh or -100 mesh fine coal. A successful recovery of particles by flotation depends on efficient particle-bubble collision and attachment with minimal subsequent particle detachment from bubble. Flotation is effective in a narrow size range outside which the flotation efficiency drops sharply. A fundamental analysis has shown that use of picobubbles can significantly improve the flotation recovery of particles by increasing the probability of collision and attachment and reducing the probability of detachment. A specially designed column with a picobubble generator has been developed for enhanced recovery of fine coal particles. Picobubbles were produced based on the hydrodynamic cavitation principle. Experimental results with one metallurgical coal and one steam coal have shown that the use of picobubbles in a 2" column flotation increased fine coal recovery by 10-30%, depending on the feed rate, collector dosage, and other flotation conditions. Picobubbles also acted as a secondary collector and reduced the collector dosage by one third to one half.

Jan 1, 2006

By Chuanhui Cao, Shimei Liu, Xiaojing Li, Yueyuan Zhou

"Force analysis on weakly-magnetic particles and non-magnetic particles in magnetic field are presented, using a kind of permanent magnetic drum magnetic separator, which is designed with strong specific magnetic force and open magnetic system. Its surface peak intensity reaches to 1.0T, and the distribution density of capture line is 1.25×103/dm2. Qualitative analysis on the particles including its magnetic property, particle size, motion speed, magnetic field intensity, etc. is also presented to calculate the separating parameters for the drum separator. Experiment was conducted for the separation of fine weakly magnetic minerals for example ilmenite. The practicability to separate the minerals using separator designed with open magnetic system has been proved, providing an economic way for efficient separation of micro-fine weakly magnetic minerals and upgrading of non-metallic minerals. INTRODUCTIONMagnetic separation is a mineral processing method based on the differences of magnetic properties between minerals in inhomogeneous magnetic field (Sun, 2007). Currently for separation of micro-disseminated weakly magnetic iron ore, electromagnetic high intensity magnetic separators with closed structure of magnet system are often used. And for the separation of strongly magnetic minerals such as magnetite, low intensity drum magnetic separators with open magnet system are often used. In order to lower the operation costs and improve energy efficiency, it is important to develop efficient high intensity permanent magnetic separator with open magnet system, to some extent replacing high intensity electromagnetic separator.Oberteuffer (1974) discussed the magnetic force and competing forces in magnetic separators which compete with the magnetic forces and act on all of the particles which travel through the separator are those of gravity, hydrodynamic drag, fraction, and inertia in magnetic separation."

Jan 1, 2016

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By S. W. Marcuson, P. J. Mackey

The 1973 Oil Embargo and succeeding disruptions in supply had a profound effect on energy costs and consumption patterns in the developed world. This was especially true in the USA where post World War II growth, fueled by low-cost imported oil, left the country dependent on uninterrupted oil shipments from the volatile Middle East. In this atmosphere, Professor H.H. Kellogg of Columbia University, convinced of the necessity of good environmental stewardship by the writings of the era’s leading environmentalists, developed a methodology for evaluating energy and process efficiency of metallurgical processes and wrote a series of papers describing and applying the techniques. One of these, "Energy Use in Sulfide Smelting of Copper" is recognized as a seminal work which both described the state of energy usage in copper smelting in the mid-1970’s and portended future developments. The background to these papers is examined and the current and past Cu-Ni matte smelting practices in Canada are examined in the context of the results. Data from early 20th century publications describing reverberatory and blast furnace operation is employed to show that energy consumption for much of the century was several multiples higher than that calculated for best reverberatory operation in the 1970’s.

Jan 1, 2015

By Jan Butra

In copper ore mines located in the Pre-Sudeten Monocline the deposit mining using room and pillar systems has been carried out for more than forty years. When implementing mining systems in deep copper ore mines it appeared to be necessary to adapt them to variable geological conditions and natural hazards. In the initial period of exploitation there were mainly caving and rockburst hazards. The adaptation of room and pillar system was connected with a state of knowledge in the scope of identifying, forecasting and controlling rock mass hazards. The new solutions allowed the safe and efficient exploitation of a blanket deposit of variable thickness from about 2 to 15m, seated on progressively increasing depth. They included exploitation in constrained conditions, such as in protective pillars. In the exploitation period, technical and organisational activities aimed at rockburst hazard control were introduced including active methods for controlling rockburst hazard and procedures for conducting mining works in the rockburst hazard conditions. When mining at a depth exceeding 1,200 m, the exploitation method and technique are additionally affected by thermal hazard and by gas and rock breakout hazard. New solutions of the room and pillar system and a longwall system with mechanical mining have been developed for exploitation in the associated hazard conditions. The require application of many innovative solutions in the scope of mining process and ore haulage mechanisation, excavation support and forecasting and control of existing hazards. The main purpose of these solutions is to conduct the safe and economically effective exploitation of the deposit.

Aug 1, 2013

By A. Navarra, C. Arrancibia, R. Yañez, C. Acuña, F. Valenzuela

"Discrete event simulation (DES) is a suitable framework to evaluate and optimize the dynamics of sulphide smelters. In particular, iron-nickel-copper-cobalt sulphides undergo continual oxidation within a roasting or smelting operation, followed by batch oxidation within the converting operation, thus producing iron-free Bessemer matte (or blister copper, in the case of copper smelters); this semi-finished product undergoes further processing to produce nickel, copper and cobalt products, and to recover precious metals. The juncture between continuous smelting and batch converting is often an appropriate focus for the earliest phases of DES development, since it is typically a major bottleneck within nickel and copper smelters; later phases may include increasing levels of detail for auxiliary unit operations, as well as plant logistics. Moreover, DES can support matte-slag chemistry, including Gibbs free energy balances to determine the iron speciation within the slag. DES is therefore capable of linking the fundamentals of oxidation reactions to the intricacies of plant dynamics.INTRODUCTION Discrete event simulation (DES) is gaining acceptance within the extractive metallurgy community, as a technique that quantifies the system-wide performance of metallurgical plants under conditions of uncertainty (Wheeler & McGinty, 2015). In particular, over 90% of smelters that process nickel-copper-cobalt sulphides and copper sulphides exhibit similar semi-continuous dynamics (Crundwell et al., 2011b; Schlesinger et al., 2011b), in which the converting aisle produces batches of material that are sent for further processing (Figure 1). Thus the tools and practices that are developed for a specific sulphide smelter are often relevant to numerous other smelters.The juncture between continuous smelting and batch converting has long been a focus for discrete event simulation (Welgama et al., 1996). Nonetheless, the broad acceptance of DES in nonferrous smelters has been hindered by interdisciplinary barriers that divide industrial and metallurgical engineers (Navarra et al., 2016; Noorossana et al., 2012); this divide has been less severe in steel plants (Hollocks, 2006). In recent years, DES has been used in copper smelters to analyze crane-and-ladle motions (Coursol et al., 2009a), reverts production and consumption (Noorossana et al., 2012), and innovative control systems (Herrera et al., 2016); additionally, DES models have accounted for shutdowns and random breakdowns to provide realistic assessments of copper smelter capacities, thus guiding equipment upgrades (Campbell et al., 2013; Coursol et al., 2009a). All of these studies feature a Peirce-Smith converting aisle similar to Figure 1 that, under normal operations, constrain the smelter throughput, and are thus a bottleneck (Campbell et al., 2013; Navarra et al., 2016)."

Jan 1, 2017