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By Jun Wang, Bo Zhang, Wenqing Qin, Guanzhou Qiu, Xiaozhen Ma, Key Lab of Biohydrometallurgy of Ministry of Education, Fen Jiao, Central South University, Yansheng Zhang

"Arsenic contained in minerals sulphides such as enargite and tennantite can represent not only a significant penalty element in base metals production, but also a disadvantage to the environment through producing the toxic emissions to the atmosphere. The achieving separation of arsenic bearing minerals either at an early stage in floatation or from the floatation concentration is significantly beneficial to the economic. However, there was no feasible commercial method of separation at the flotation stage because of its similar flotation properties with many other copper sulphides. In this work, the selective floatation of enargite from copper sulphide concentrate containing maily covllite, chalcoctie, bornite and enargite was investigated. A low arsenic concentrate with As 0.2%, Cu 22% and a high arsenic bulk concentrate with As 7.65%,Cu 33.65% were obtained. It was indicated that Ca(ClO)2 is the effective depressor and the optimum floatation condition was obtained. Most enargite could be floated at pH 11 and controlling the pulp potential at 290 mV SHE. Furthermore, the arsenic removal from the high arsenic bulk concentrate by hydrometallurgy methods was study. The results showed that the reaction temperature and the concentrations of NaOH were the most important variables affecting the rate of arsenic removal. A low arsenic concentrate with As 0.24%, Cu 37.80% was obtained in the optimum leaching condition.INTRODUCTIONArsenic is mainly produced as a by-product of base metals smelting, in particular copper concentrate. China has imposed an upper limit of 0.50% arsenic for concentrates entering (Long et al., 2012). Arsenic amount of copper concentrate within 0.40% has also been imposed in China, and above which will be introduced about 50 RMB penalties per ton for each 0.10% increasing by smelters now. Therefore, it is necessary to remove arsenic from the copper concentrate.In copper concentrate, arsenic is mainly in the form of arsenopyrite (FeAsS), enargite (Cu3AsS4) or tennantite (Cu12As4S13). There are two types of arsenic in the separation of copper and arsenic: arsenopyrite and arsenic bearing copper mineral. It is easier to separate arsenopyrite from the copper sulphide by flotation in comparsion with the separation of enargite or tennantite from non-arsenic copper minerals (Pineda et al., 2015). The main difficulty in the separation of arsenic copper mineral from non-arsenic copper sulphides is their extremely similar floatability, which depends on the fact that tennantite and enargite contain high copper content (Pineda et al., 2015)."

Jan 1, 2016

By C. S. Gibson

"MOST of the mines in the Province of Ontario in Canada are multi-level operations in steeply dipping veins; yet there is an appreciable number whose de-posits are relatively flat-lying, ranging up to 45° inclination.The veins vary in width up to several hundred feet and may or may not be branching systems. The depths of mines range from a few hundred to 8,000 feet, approximately. The primary products of the underground group are asbestos, gold, silver, cobalt, copper, nickel, iron, uranium, talc, fluorspar, gyp-sum and salt.There are a few open-pit mines. The majority are temporary in type because, as the outcrops are removed, mining is continued be-low surface. Primary products of the open pits are copper, nickel, iron, magnesium and nepheline syenite.The industry as a whole employs about 50,000 persons, approximately 60 per •cent of whom have dust-exposure occupations. The definition of a dust-exposure occupation and the requirements for •dealing with same are set forth in The Mining Act of Ontario.Results of extensive and continuing studies on the incidence and progression of silicosis have been reported periodically for years past, in annual reports of the Mines Accident Prevention Association of Ontario and in papers presented at Conferences sponsored by Mcintyre Research Foundation of Toronto, all of which have been published. The information provided therein proves the effectiveness of the means being used to prevent silicosis and allied disorders."

Jan 1, 1960

By Tyler J. Irving

"In June, 2018 Lalor Mine experienced a catastrophic blade failure of its No. 2 main exhaust fan. Over the following weeks several key changes were made to the auxiliary ventilation system to allow for continued production while the exhaust fans were repaired. Issues encountered during the period of reduced ventilation, and how they were addressed, are analyzed. The suspected causes of the exhaust fan blade failure and how risk was mitigated during the reconstruction are discussed. Key findings and lessons learned are summarized.INTRODUCTIONLalor Mine, owned and operated by Hudbay is an underground zinc, gold, and copper mine located in northern Manitoba. The mine workings extend to a depth of 1090 metres below surface and is ventilated using a push-pull system. The mine exhausts through the main exhaust raise; equipped with two, 2,500 HP fans and upcasts through a portal located at the neighboring mine, Chisel North. Air is supplied to Lalor Mine through four intake fans: The Production Shaft Downcast (two, 250 HP), Lalor Downcast (one, 400 HP), and Chisel Downcast (one, 600 HP) fans (Figure 1). In June 2018, Lalor was scheduled to produce approximately 4,000 tpd.On June 20, 2018 at 2:52 pm Lalor Mine experienced a fault on the Variable Frequency Drive (VFD) for Exhaust Fan No. 1. Time would be needed to complete the necessary repairs. The No. 2 exhaust fan was ramped up from 525 rpm to 800 rpm, 90% of its capacity, in order to maintain underground ventilation. At 4:46 pm, approximately two hours after the rpm was increased, exhaust fan No. 2 experienced a catastrophic blade failure. The forces from the blade failure resulted in the top half of the fan housing being thrown 50 metres from where it was installed; with several large sections of fan blade being thrown further (Figure 2)."

Jan 1, 2019

By K. Chattopadhyay

Fluid flows in metallurgical reactors play a vital role on liquid metal cleanliness for both ferrous and non-ferrous metallurgy. Thus, it is absolutely critical to understand different fluid flow mechanisms, and the use of computational methods to model the complex non-isothermal, turbulent, single- and multiphase-flows, has to be appreciated. The present case study emphasizes on controlling the flow of liquid steel in a tundish and enhancing liquid metal cleanliness. CFD modeling was used to build a robust mathematical model, and effects of flow control furniture and non-isothermal conditions were analyzed. The mathematical model was validated against water model experiments. Parameters that were conducive for inclusion removal were identified and implemented in the plant. Some flow control devices could increase inclusion removal to a great extent compared to the existing configurations. In cases, where a hot ladle was poured into a relatively cooler tundish, inclusion removal was better, whereas results were catastrophic in cases where colder liquid was poured from ladle to the tundish. Similar techniques can be applied for other liquid metals including light metals and non-ferrous metals.

Jan 1, 2015

By J. Talja

"Non-ferrous metal concentrates contain typically 7 – 12% water when received at the smelter. Removal of this water prior to smelting is always economically feasible because unnecessary heating of vapour (from 100 °C to 1200 °C) in the smelting furnace can thus be eliminated. This results in major reduction in CO2 emission and direct annual savings of several millions of dollars due to improved energy efficiency. Next step to further improve the energy efficiency, to gain substantial savings and simultaneously cut emissions is to select modern technology for the drying process. Consequently, all CO2 emission will be completely eliminated (from 40,000 tpy down to 0 tpy), NOx emission will be negligible, and the SO2 emission will be reduced by over 99 %. Switching of conventional direct heated drying technology to modern indirect steam drying brings, in addition to dramatic emission reduction, additional savings due to further improved energy efficiency. Direct energy savings count for 900 – 1300 MJ/t H2O, which depending on the concentrate feed rate and its moisture load can be worth several millions of dollars every year. Additional savings in operational expenses related to drying and gas cleaning may be worth a few million dollars more. Sustainability is a key issue today, and major savings together with significant emission reduction are readily available by proper technology selection for concentrate drying. INTRODUCTIONSustainability is a decisive principle in any process industry accompanied with emissions and high amount of energy. This is of significant importance in metal processing, including concentrate drying, where minimum impact on the environment, people and community are targeted, and all this with minimum cost, effort and resources. Therefore, special attention is paid to high energy efficiency, low energy consumption with preferable utilization of waste energy, safety issues, availability, level of maintenance, cost of maintenance, and emissions among other things.Non-ferrous metal concentrates can be dried using various techniques. Conventional drying based on direct heating, and use of fossil fuels for drying energy has almost entirely been replaced by steam drying. It is based on indirect heating and it has become the most dominant drying technology for copper concentrates during the last decade with over 90% of the market share of all new dryer installations. Among the steam dryers the Kumera Steam Dryer is the most pre-dominant technology with some 70% of all new dryer installations world-wide."

Jan 1, 2012

By M. Reda

Inorganic oxidizing agents of the type MeOx-z such as Chromate, Vanadate, Tungstate, and Molybdate... etc. are widely used as corrosion inhibitor. In non acidic solution these oxidizing agent are reduced on the surface of the meta, according to OX + m e + p H20 Red + n OH" In which y = (n-m)/m. The purpose of this publication is to show that for many metals the value of y for any oxidizing agent determines the possibility of that oxidizing agent being an inhibitor or activator for the corrosion process. The inhibition efficiency for other ions such as Pertecnetate and Tellurate which have not been extensively studied can be predicted. A mathematical, equation was derived to express the relationship among the concentration of oxidizing agent, degree of retardation of the corrosion process I cord cor ° (ratio of corrosion current in the solution containing inhibitor to the base solution) , ionic strength of the solution and the coefficient y. The validity of y and the mathematical, equation were verified by many experimental, works on various metals such as zinc, aluminum and steel. Al, the above research works are based on the published research works of Prof. Mikhailoviskii (from 1979 til, 1998) from the Russian Academy of Science.

Jan 1, 2010

By A. Rodriguez-Prado, R. L. Legge, W. C. Lennox

ABSTRACT It is possible to adequately describe chemical reduction of hexavalent chromium, Cr(VI), in industrial and mining wastewater in constructed wetlands by applying different kinetic models (e.g., halforder, second-order). Accounting for hydraulic transport of contaminants in reduction equations can also improve such description. The authors developed an explicit advection-dispersion bulk flow equation and applied it to model Cr(VI) reduction in laboratory wetland mesocosms. The results indicated that the model adequately described wetland exit Cr(VI) concentrations and Cr(VI) reduction, representing an improvement over the commonly used graphic method and potentially improving the wetland design.

Jan 1, 2014

By L. R. Bower

"This paper describes a highly versatile variable speed unit with a torque multiplication feature as a direct replacement for a fluid coupling .The unit is comprised of a modulating clutch with torque converter and lock-up options.The UCD does not start or stop the motor. This is carried out in the normal manner.The UCD continually monitors and rapidly regulates the output speed to the requirement of a set point demand from input signals or a pre-set program with full manual override.The pre-set program can include start and stop ramps, top speed and minimum speed regulation and also mid-speed set point with security for man-riding, etc. Speed variation is from zero to 100% on a constant duty basis.The input signals can be from any source, e.g. belt weigher. load profile bunker probes, mine monitoring system, etc.The UCD when fitted with a torque converter has a torque multiplication feature which automatically provides a starting torque up to two and a half times greater than the full load torque without exceeding the normal motor power levels.IntroductionIt is common practice in the mining industry to drive conveyors, whether they be belt or chain, through a transmission system incorporating a fluid coupling between the driving motor and gear-box .However, there are drawbacks and in an effort to attain a better degree of drive and control, two-speed motors - inverters cycle- converters - hydrostatic drives, etc ., have been introduced."

Jan 1, 1986

By Magella Pelletier

"IntroductionDepuis une vingtaine d'année, les nombreux travaux de géochimie effectués par l'industrie privée et les milieux gouvemementaux ont permis:• de découvrir de nombreuses zones minéralisées a valeur économique;• d'identifier et de vérifier certains patrons de dispersion géochimique au-dessu s de secteurs minéralises déjà connus;• de favoriser le développernent des techniques analytiques;• de forcer le développement d'une mise en carte des résultats d'analyse, qui soit plus adéquat afin de permettre une meilleure interprétation géochimique.L'une de ces cartes géochimiques qui permet le mieux de mettre en valeur les données analytiques et qui fut instaurée au debut des années 80, est la carte d'interprétation géochimique par pondération.Cette carte numérique semi-quantitative, qui est construite à partir des données de base et de l'importance des éléments indicateurs pour une substance donnée, permet d'identifier et de définir des zones possédants de fortes probabilités pour la recherché de sources minéralisées."

Jan 1, 1987

By F. E. Senftle

Introduction The usual laboratory methods of uranium analysis are either tedious, time-consuming chemical procedures or elaborate physical methods requiring sensitive equipment. There is thus an urgent need for a method of estimating the uranium content of ore samples by approximate analysis in the field. When a new property is being developed, it is desirable to know, with the least possible delay, the uranium content of channel samples in order to guide the diamond drilling and digging operations. Prospectors, too, require approximate analyses of their hand specimens to evaluate their discoveries. To satisfy the demand for these types of analyses, several field procedures have been tried. Two general plans can be followed. One is fast but will yield only a rough estimate. The other is slightly longer but, if done carefully, will give an assay probably within 10 per cent of the true value. For field operation it is necessary to strip the more accurate laboratory methods of analysis of all refinements because of the limited equipment and skilled techniques at hand. Most of the corrections normally applied, with the exception of that for equilibrium, will not alter the gross analysis to any appreciable extent. When uranium atoms in pitchblende disintegrate, they break down into other radioactive elements, and eventually the number of elements being formed is equal to the number breaking down. The ore is then said to be in equilibrium. Certain geological processes, however, such as leaching, may selectively remove some of these elements and hence reduce the radioactivity of the ore sample. The ore is then said to be out of equilibrium. The field analysis may then be in error by as much as 50 per cent since the apparatus is calibrated with standards that are in equilibrium. However, such a large error due to loss of equilibrium is the exception, and in most cases uncorrected field types of analyr.is are justified.

Jan 1, 1949

By A. Galip Ulsoy

This review paper is intended to provide, the mineral process engineer with an introduction to the concepts, terminology and practice of mineral process control. It also provides an extensive sampling of the vast body of literature relevant to this topic. The topics discussed include the principles of automatic control, instrumentation, mineral processing unit operations, process modeling and simulation, and process and plant control.

Dec 1, 1981

By P. Reyes

The start up and operational optimization of the No. 3 Oxygen Plant at the Caletones Copper Smelter of the Codelco - Chile El Teniente Division is summarized. In addition, the economic impact of such optimization on the production cost of oxygen and others aspects associated to the operational robustness as well is detailed.

Jan 1, 2007

By J-g. Cui, X-b. Guo, J-j. Wang, J. Qiao, H. Tian

"Rare earth elements have unique properties because of the special electronic structure. In this paper the improvement of refractory material performance by the light rare earth oxides was introduced. The experiments showed that adding a bit of rare earth oxide could obviously improve the performance of the refractory material. INTRODUCTIONIn recent years, refractory materials are widely applied in the steel smelting process as a ladle lining material. In China, although the total production of fire-proof material exceeds normal demand, but the quality and variety of fire-proof material still have a big gap with world advanced level. A number of refractory products need to be imported from abroad. With the rapid development of domestic steel production, the ladle lining with refractory is gradually running after the world advanced level on production technology, production variety, and quality level. It replaces some imported products meeting the needs of the development of the iron making production. Therefore, there is an important significance to research on solving the problems of the ladle refractory reasonably and avoiding or reducing blind and not proper use of the imported refractory ( Jing, 2007).On the other hand, rare earth oxide has some special excellent properties. Firstly, they are very good refractory materials with their high melting point;Next, they have good resistance to water and alkali resistance function;Thirdly, it is easy for rare earth oxide to generated composite oxide reacting with other metal oxide,achieving the purpose to improving the material properties (Xu, 1978; Diao, 1979). China has a variety of rare earth resources,and rare earth resources is more advantageous in Baotou,taking up about 36 percent of world reserves,which is the world's top of rare earth mineral. In recent years the rare earth products output has risen sharply and many varieties and specifications have appeared. So it is necessary to study the new field of rare earth compound to open up new markets. Thus, it has a very vital significance to promote the further development of rare earth industry, adjust the rare earth products structure, ease the contradiction between supply and demand, and improve refractory products quality and grade in order to better serve the main body production.I In this paper, the experiments are mainly for 210 tons of Al2O3-MgO style series refractory materials belong to ladle lining bag from Baotou Iron & Steel Group Corporation Sheet Factory. The improvement to the effect of refractory material performance is explored by using light rare earth oxides as additives."

Jan 1, 2012

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

By J. D. Aitken

"DEFINITION OF THE REGIONTHE REGION considered in this paper is bounded on the south by the 60th parallel, on the north by the Beau-fort Sea and Amundsen Gulf, on the east by Archean rocks or by highly deformed Proterozoic rocks of the Canadian Shield (certain weakly deformed Proterozoic strata being regarded as belonging to the Great Plains), and on the west mainly by the Mackenzie and Richardson Mountains.Only the unmetamorphosed strata of the region are considered; that is, the geology of the crystalline basement is ignored.SIGNIFICANCE OF THE REGIONThe region is significant from three points of view -namely, the economic, the scientific and the social. It constitutes 46 per cent of the area of the Western Canada Sedimentary Basin."

Jan 1, 1970

By A. I. Collins, D. Danninger

Newmont has installed advanced control and online optimization on the dry grinding circuit and both roasters on its Carlin Trend refractory ore treatment plant. Subsequently, Newmont has developed a master plan for institutionalizing advanced control and optimization on all its processing units. Newmont is committed to a program of applying advanced control and optimization from crushing of ore to pouring of gold. This paper describes Newmont's experience with implementing advanced control and optimization and the benefits received. In addition, identification of advanced control and optimization opportunities and their economic justification is discussed.

Jan 1, 2005

By K. H. Singh, J. N. Szuck, J. A. Riddell

"Hydraulic rock drilling equipment has been in use at Falconbridge over the past two years in both production and development situations. This paper deals with the experience gained in the application of hydraulic drilling in the company's mines and discusses the benefits and problems encountered during their use. The paper primarily focuses on technical, operating, maintenance and economic aspects of the machines, and does not attempt to compare the performances of different machines from the various manufacturers.IntroductionThe Sudbury Operations of Falconbridge Nickel Mines Limited are comprised of five operating mines and two mines under development. All the production comes from underground mines, mostly at depths below 1000 metres. The company, faced with increases in operating costs and difficult mining conditions, has continued to seek solutions with the help of new mining technology.The development of electric-hydraulic drilling machines in Europe had been pursued with great interest and, in 1979, a decision was made to test these machines to prove their technical and economic viability under operating conditions. Since then, a number of electric-hydraulic machines have been evaluated in different situations and currently nine hydraulic machines are being used in the company's various mines. These machines are comprised of two-boom drilling jumbos for development, one-boom machines for longhole drilling and a large-hole-diameter drilling rig for blasthole drilling. One hydraulic jumbo has also been used in a cut-and-fill stope."

Jan 1, 1982

By M. A. Gomez, V. Yahorava, J. A. Strauss

"It is accepted widely that pressure oxidation (POX) is the most appropriate technology for processing of arsenic containing refractory gold ores. However, studies on the stability of various iron-arsenic precipitates formed during POX are limited. Since the behaviour of these phases could have significant practical implications for gold processing plants, it is important to study them in isolation. This paper compares two synthetic precipitates, basic ferric arsenate sulphate (BFAS) and basic ferric sulphate (BFS) in terms of their formation, behaviour during hot curing and cyanidation, as well as their environmental stability. BFS and BFAS were synthesised hydrothermally at 205°C and their mineralogy was confirmed using various techniques. During synthesis, the addition of H3AsO4 into an aqueous Fe2(SO4)3-H2SO4 mixture significantly decreased the iron yield to BFAS in comparison to BFS under equimolar initial iron and acid concentrations. The BFAS dissolution kinetics was slightly faster, as compared to BFS, during subsequent hot curing. Cyanidation test work on the washed synthetic precipitates indicated that the lime consumption of BFAS was three times lower in comparison to BFS, while cyanide consumptions were comparable. Fresh BFS and BFAS precipitates, as well as their cyanidation residues, were found to pass the respective environmental tests in terms of arsenic release.INTRODUCTION Pressure oxidation (POX) is generally viewed as the most appropriate technology for the processing of arsenic-containing refractory gold ores due to the stabilisation of arsenic in the leach residue (Dutrizac & Jambor, 2007; Gomez et al., 2008; Harris, 2003; Collins, Berezowsky, & Weir, 1988). Detailed laboratory studies indicated that several Fe(III)-arsenate type compounds may be formed under typical conditions of autoclave treatment of refractory gold ores (Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2010; Gomez, Becze, Cutler, & Demopoulos, 2011). The basic ferric arsenate sulphate (BFAS) phase (Gomez et al., 2008), also known as Type II ferric arsenate (Swash & Monhemius, 1994) or Phase 3 (Dutrizac & Jambor, 2007), is one of the most common arsenic-bearing products (Harris, 2003; Dutrizac & Jambor, 2007). BFAS precipitation is viewed as one of the best routes for arsenic stabilisation and performed equally well to scorodite during environmental stability tests (Harris, 2003; Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2011)."

Jan 1, 2017

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT The influence of using different extraction processes (caustic versus non-caustic) on thethixotropic strength of oil sands fine tailings is examined, as is the influence of adding a coagulant tocaustic fine tailings. The thixotropic strength of fine tailings at large void ratios manifests itself as a bonding or gel strength that has been widely noted both in the laboratory and in the field. This gel strength has a significant influence on preventing the initial consolidation or settlement of fine tailings. Differences between the fine tailings’ thixotropic strength development are explained based on their physical and chemical characteristics.

Jan 1, 2010