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By Seshadri Seetharaman, Nurni N. Viswanathan, Haijuan Wang

The present work aims at some process modifications in specified metallurgical processes, wherein CO2 can be used successfully as an oxidant for decarburization in steelmaking and applied in some non-ferrous metals production processes. During the decarburization of Cr-containing high alloyed steels, the present researchers investigated the possible use of CO2 instead of Ar-O2 mixture and could successfully decarburize the steel melt without significant loss of alloyed Cr to the slag phase. A mathematical model was developed based on the bubble formation accompanying the chemical reaction: C(molten steel)+ CO2(gas)= 2 CO(gas). The model predictions were tested by laboratory scale (1 kg) experiments carried out in an induction furnace and very good agreement between the model predictions and experimental results were observed. A national project has been sanctioned in China for the implementation of CO2 in decarburization of ferroalloys as well enable the addition of pig iron in the electric arc furnace process when the scrap supply is limited. New processes have been developed for the utilization of CO2 in the case of non-ferrous processes. A novel method of treatment of Al dross by leaching with water and capturing the evolved NH3(formed by the hydrolysis of AlN) has shown very promising results.

Jan 1, 2015

By W. Beres

Many non-commercial operators are currently faced with the need to operate fleets of legacy gas turbine engines. How long such engines can be kept in service safely, without replacing a significant portion of their aging structural components, has become a growing concern to engine life-cycle managers, due to uncertainties in the remaining lives of critical components of these engines. This paper describes the application of the damage tolerance methodology to predict safe inspection intervals (SII) for critical components of gas turbine engines, using components of a turboprop engine for a transport aircraft as examples. High temperature components of this engine are made of advanced aerospace alloys. The methods of predicting three-dimensional fatigue crack growth at the critical location of turbine discs and spacers using both commercial and in-house developed algorithms are presented. Sensitivity analyses are performed to determine the effect of variations in material parameters on the predicted safe inspection intervals. In addition, spin rig tests performed for both turbine discs and spacers are described. Finally, crack growth rates predicted by numerical analyses are compared to those obtained from spin rig testing and the damage tolerance of the turbine components is assessed.

Jan 1, 2015

By Chi Zhang, Junyi Wu

"The use of permanent stainless steel cathodes for electrorefining and electrowinning of cathode copper had been introduced to the market long time ago and now is a well-accepted technology worldwide. During the last decades, the Chinese copper refinery industry had been growing rapidly and many large scaled production plants had been built. In the modern refineries, permanent stainless steel cathodes are introduced and used instead of traditional starter sheets. The most common steel grade used is austenitic stainless steel S31603 (316L/1.4404), while both S30403 (304L/1.4404) and N08904 (904L/1.4539) have been used depending on the actual working conditions, especially with regarding corrosion environment. While 316L permanent cathode functions well in many plants, different kind of problems, such corrosion and deformation, have been reported. There is therefore an increased need for more suitable material. New stainless steels, such as duplex stainless steels, with better properties have been tried and introduced into the application of permanent stainless steel cathode with satisfied results. The article introduces first the Chinese copper refinery industry and properties of duplex stainless steel in general, and then describes the development of using permanent duplex stainless steel cathode, including the actual working conditions, production of cathode sheets as well as the experiences of application in details. After more than one year’s usage, the advantages of permanent duplex stainless steel cathodes are clear seen.INTRODUCTIONChina has become a major player in the international copper market, accounting for around 40 percent of global refined copper demand. Despite the slowdown of the Chinese economy, the consumption of copper products will still increase, but with a medium and/or low growth which will be the new situation for the coming years. The average growth rate is expected to be around 5 percent per annual. In the coming Five-Year plan for National Economic and Social Development a number of initiatives will be finalized which will require massive amounts of copper. In 2015, the expected consumption of copper products will be over 9 million metric tons. The main driver of the consumption is the electric power industry which accounts nearly the half of the total consumption; followed by cooling application with 15% and transportation with nearly 10%, see figure 1."

Jan 1, 2016

By David Forrester

"At the 95th CIM Annual General Meeting in Calgary, 1993, a paper entitled “Progress on Futuristic Mining Technologies” was presented(Matthews and Sarin), in which they outlined the goal of continuous excavation of hard rock and some of the technologies being developed to achieve it. The subject continues to be featured in periodic reviews and articles in the literature, (Gertsch, 1994; E&MJ, 1995). Matthews and Sarin note the considerable success of the development and application of continuous mining technologies in the soft rock under-ground mining industry, especially those in coal and potash, with major benefit to overall production, productivity and economic viability. It is the belief that similar achievements can be realised in the underground hard rock mining which continues to drive the development of hardrock continuous mining technology.This overview has been prepared specifically for this issue of the CIM Bulletin. It attempts to tie together current advancements in continuous mining in soft rock (where remote control and automation are already well established) with the background and status of development in hard rock continuous mining. Following a brief review of key factors and machine types, soft rock aspects are discussed, then a more detailed review is given of hard rock technology, with particular reference to Canada’s HRDK Mining Research Ltd. and their key role.The mining industry has long been at the forefront of technology development, for example, the application of the early steam engine to reach reserves at greater depth for dewatering mines in the industrial revolution. By necessity, the individual characteristics of seams and orebodies dictate the mining method, continually presenting mining engineers with new challenges. One of these is the extraction process itself and the goal of replacement of the drill-blast-muck cycle by continuous excavation. Very soft rocks have always been mineable using some form of cutting, even with primative tools. However, as the challenge has been taken up, technologies have evolved to steadily increase the hardness of rock that can be mechanically excavated. It may surprise some readers that at least three machines have successfully cut and loaded rock with an unconfined compressive strength (UCS) of 250 Mpa to 300 MPa (36 000 to 43 500 psi) in field trials (Table 1)."

Jan 1, 1996

By K. Eklund, T. Ahokainen

The Flash Smelting process is the most used production method for primary copper in the world. The basic idea of the Flash Smelting is to utilize the thermal value of sulfidic concentrates and melt the reaction product, in controlled conditions, without a need for external energy. This basic principle is utilized both in matte smelting and in Direct-to-Blister Flash Smelting Processes. In this paper, the behavior of normal (CuFeS2) concentrate of FSF-process is compared to the behavior of high grade feed material produced by Outokumpu Concentrate Upgrade Process with the aid of computational fluid dynamics (CPD) simulation using add-in subroutines developed by Outokumpu Technology. Results consist of the information concerning the behavior of the suspension, reaction efficiency and other parameters concerning the reactions of the feed material. It will be shown that, using the Upgrade Process, the throughput of copper from the Flash Furnace can be almost tripled.

Jan 1, 2007

By H. A. Khorami, T. Wong, B. Velapatino, E. Asselin, T. Donnelly, E. Bryce, R. Dixon

A copper–nickel concentration gradient alloy was designed and fabricated through a powder metallurgy (PM) process. Copper and nickel powders were mixed with different weight ratios from 0 to 100% copper in 10% increments. Each powder mixture was poured inside a cylindrical die and compacted between two punches using a hydraulic press machine at pressures up to 70 MPa, resulting in approximately 1 mm thick layers (discs) of pressed Cu–Ni powder. These 11 Cu–Ni compacted powder layers, i.e. 0–100% Cu with 10% increments, were then compressed together with pressures up to 420 MPa to form a green part. The green part was sintered in a vacuum furnace at 1000°C for 10 hours to form a solid mass (PM part) of Cu–Ni concentration gradient alloy. In the sintering process, Cu and Ni particles fused together and formed a single piece due to diffusion of the atoms across the boundaries of the particles. The diffusion of atoms also converted the stepwise concentration change into a uniform concentration gradient. INTRODUCTION Copper has numerous applications in different industrial sectors due to its superior physical, electrical, mechanical and chemical properties such as its excellent thermal and electrical conductivity, resistance to fatigue, high ductility, and resistance to corrosion. Moreover, copper and its alloys have natural antimicrobial properties. This has opened up new applications for copper–based self–disinfecting surfaces in healthcare in an effort to mitigate healthcare–associated infections (HAIs). HAIs affect millions of patients each year, leading to significant morbidity and mortality as well as financial losses to healthcare systems (World Health Organization, 2016). HAIs spread through three main routes: (a) iatrogenic in which HAIs are a direct consequence of medical encounters and/or treatment; (b) person to person where organisms are transferred between healthcare workers, patients, and visitors; and (c) environmental where transmission occurs via contaminated surfaces and equipment (e.g. doorknobs, railings, toilets/commodes, medical carts). The use of antimicrobial copper–based materials on high touch surfaces could diminish pathogen transmission via this latter rout. This has subsequently led to the development of a variety of copper–based materials for use in healthcare settings and promoted the investigation of the antimicrobial efficacy of copper–based materials.

Jan 1, 2019

By Victor F. Hollister, Robert W. Hodder

"The petrology and mineralogy of porphyry copper deposits are thoroughly described in recent literature and cited as the definitive characteristics for this type of deposit. The magmatic-hydrothermal aspect of genesis is also dealt with in detail. However, descriptions of their internal structure and regional setting are not as rigorous, and the genesis of this structure is simply stated as the release of high fluid pressures in a cooling magma emplaced along large fault zones. Genetic relationships between internal structure, regional setting and the tectonic evolution of continents has been alluded to infrequently in the past, but can now be considered together within the developing concept of orogeny at the margins of drifting crustal plates.Tensional structures, on both local and regional scale, and a Triassic to Tertiary age are described for porphyry copper deposits. We contend that such structure and age are distinct and unifying characteristics for this type of deposit and are genetically related to major crustal movements. British Columbia has porphyry copper deposits contemporaneous with plutons 180 to 200 million years old and 40 to 60 million years old. The former age group correlates with early stages of the continent's westward drift, and the latter group with a change in tectonic style during late development of the Canadian Cordillera. Hence, one can in British Columbia reflect on the genesis of a deposit's structure in the broader context of tectonic evolution. Such consideration should lead to more definitive criteria for area selection in exploration."

Jan 1, 1972

By R. Esteban, D. Runnels, S. Girgin, J. Torrealba-Vargas

"Each mineral processing project requires early testwork to evaluate the economic potential of a deposit. The testwork needs to be efficient and it should provide enough information to obtain key parameters, first for a high level flowsheet selection at the conceptual and PEA stages and then, for later stages, to confirm the flowsheet selection and optimize the metallurgical efficiency of the plant. The testwork should consider all rock types or lithologies present, and carry out testwork for the purpose of sizing the major processing equipment.A successful project requires that the project stakeholders develop an efficient sample collection program to produce enough material for a scoping and pre-feasibility level program. This involves the participation of a team of geologists, mining and metallurgical engineers in the project, as early as possible, to define the deposit characteristics that need to be validated.The project schedule requires a close control of the testwork scope, procedures, and timing, but also the efficient analysis of results to provide indications of red flags that could impact circuit design as early as possible.In some cases, projects are put on hold due to fluctuations of the world economy until the return of more favorable conditions. In that scenario, prior data analysis of former testwork results could reduce significantly the amount of testwork required to restart a project. The paper will also present examples where the analysis of former testwork data was used to reduce the amount of new testwork in addition to presenting examples of latest projects where the above-mentioned test program approach was followed."

Jan 1, 2016

By A. O. Dufresne

WITHOUT transportation, mining would be quite impossible. Any person familiar with the operation of a mine knows full well that from the minute ore is blasted, it is kept moving until it reaches the treatment plant. In the mill, by means of conveyors and elevators, the ore is brought from receiving bins to one machine after another until finally its valuable mineral is separated from the gangue. The finished product must then be shipped -either by boat, rail, or motor trucks to industrial centres, where it undergoes further treatment and transformation into finished commercial goods. Everybody appreciates that the winning of an or-e includes, amongst various operations, the moving of large quantities of material of generally low value. Transportation, therefore, must be considered One of the most important factors in the economics of mining. My assignment, this afternoon, is not to treat of that phase of transportation as it directly affects mining operations, but rather to consider some of the aspects of overland transportation and its influence in bringing about the development of mining camps in Canada. I shall take the liberty of rapidly surveying conditions facing prospectors, mine developers and operators from the time a region is still in a pre-pioneering stage until such time as a mine starts shipping its concentrates.

Jan 1, 1956

By Richard J. Wardle, Ambrose F. Howse

The industrial minerals industry in Newfoundland and Labrador is a significant contributor to the provincial economy. The variety ofcommodities produced reflects the diverse geological environment from which they come. A highlight of the past decade has been the continuing development of dimension stone quarries, with producers now active in anorthosite, gabbro, granite and sandstone. Other dimension stone prospects have been identified and are in various stages of assessment and development. Western Newfoundland hosts a large resource of limestone, dolomite and marble. It provides raw material for industries that produce Portland cement, agricultural limestone and aggregate, as well as chemical-grade limestone and dolomite products. In western Labrador, dolomitic marble is quarried for use in the production of self-fluxing iron ore pellets. The recent opening of a new gypsum quarry at Fischells Brook signalled the beginning of a new era in the commercial production ofgypsum, a commodity which the province has produced since the 1950s. Hopefully it will emulate the nearby Flat Bay Quarry (now closed) which was a long-time exporter to markets along the U.S. eastern seaboard, in addition to supplying local demands. Oil production and continuing exploration in the Newfoundland offshore has renewed interest in local barite deposits for potential use in drilling fluids. Already there has been some production from the Collier Point deposit, and at Buchans, an existing plant is being refurbished to recover barite from a large tailings pond. Emerging new industries include the development of an antimony mine in central Newfoundland, the development of silica deposits near Labrador City for silicon metal production, and reactivation of the St. Lawrence fluorspar mine. The province has many deposits with development potential such as rare metals at Strange Lake, white marble at Roddickton and salt deposits near St. George's Bay region.

Jan 1, 2001

By A. G. Matyas

Process improvements which have reduced the lead content of slag from the Brunswick lead blast furnace are described. Microscope examination and electron microprobe analyses, supported by the results of slag settling and viscosity tests, showed that typically about 70% of the lead in the lead blast-furnace slag was present in the form of entrained prills of metallic lead. The total lead content was found to increase with the magnetic susceptibility of the slag. Measurements in the furnace settler indicated the presence of a magnetite-rich layer between bullion and slag, arising from high magnetite levels in the slag. This layer was believed to inhibit the settling of entrained lead from the slag. Tracer tests showed that the average slag residence time in the settler was less than 2 minutes. Improvements in coke quality and sizing, which led to a reduction in the slag magnetite content, and the installation of a larger settler and a continuous Roy tapper, have all contributed to a significant decrease in the slag lead content.

Jan 1, 1977

"THE Canadian Advisory Committee on Coal Research, which is commonly known as CACCR, has been in existence for the past five years and has held annual meetings during that period. This Committee is comprised of representatives from: the Mines Branch, Fuels and Mining Practice Division, Ottawa; the Geological Survey of Canada; the Dominion Coal Board; and the Provincial Research Councils and Foundations. It embraces all coal research in Canada that is sponsored, for the most part, by Government funds.To bring the country's coal research activities to the notice of the Canadian coal industry, the Coal Research Committee of the Coal Division, C.I.M., passed a resolution at the 1964 business meeting in favour of recommending the publication of an annual research report prepared by the CACCR. The first such report was published in the September, 1964, issue of the C.I.M. Bulletin; the second appeared in the November, 1965, issue of the same publication."

Jan 1, 1966

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami, G. P. Cole

"The past several decades have seen a steady increase in the use of atmospheric monitoring systems (AMS) in underground mines as sensor technology has advanced and costs for this technology have decreased. The AMS is a reliable tool for early mine fire warning by detecting gaseous products of combustion in underground mines. During a mine fire emergency, mine decision makers rely heavily on the prompt and accurate knowledge of the ventilation and fire situation in the mine, such as fire location, fire size, and the spread of smoke to make effective and efficient decisions on firefighting strategies and miner evacuation. Meanwhile, a prediction of the potential for fire development at a later time, such as whether the currently designated mine escapeways will be contaminated by smoke and toxic gases with the progress of the fire, is critical for effective decision-making to save lives that are in danger. The AMS monitoring data, including carbon monoxide (CO) concentration, airflow rate, smoke, etc., can provide information as to whether the smoke has reached the locations where AMS sensors are installed and if a mine-wide smoke spread has occurred. The National Institute for Occupational Safety and Health (NIOSH) has undertaken a task to integrate real-time AMS monitoring data with the mine fire simulation program, MFIRE, to simulate and predict the spread of smoke and toxic gas in a ventilation network based on the real-time AMS data. This paper reports the developed real-time method for characterizing the size and location of an underground mine fire and for predicting the spread of contaminants throughout the mine ventilation network using sensor data from the AMS.INTRODUCTIONNIOSH conducts research to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions in underground mines. The advancement of senor technology and the increasing demand for real-time mine parameters monitoring have led to extended applications of atmospheric monitoring systems (AMS) in underground mines worldwide. In the United States, AMS is primarily used for early mine fire warning by detecting carbon monoxide (CO) in fire hazard areas, such as belt entries. Mine fires can grow rapidly, and time is the critical element. Prompt detection, timely and accurate warnings to those miners potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground mine fire (Conti et al., 2005). The early detection of a mine fire could gain time for the first responders to put out the fire before it develops into a disaster. An AMS system with CO sensors has especially played an important role in the early detection of mine fires. The continuous monitoring of an underground mine atmosphere with an AMS could generate a large amount of data in a mine fire event. However, the current application of AMS is mainly limited to sending out an alarm when monitored CO concentration exceeds a certain level. An opportunity arises as to whether these data can be further used in fire emergency response. In order to make effective decisions on firefighting strategies, mine workers’ seeking refuges, evacuation and escape, and the timing on when to send rescuers, decision makers need accurate and timely knowledge of the ventilation and fire situation in the mine. Information about the fire intensity, where in the mine the smoke and toxic gases have spread, and whether designated mine escapeways have been compromised by smoke and toxic gases from the fire would greatly increase the effectiveness of these decisions. However, the monitored AMS data only provides atmospheric conditions in the vicinity of sensor locations. What is concluded from the monitored AMS data highly depends on the decision makers’ capability and experience. Predictive insight into fire growth and smoke transport would greatly help decision makers during a fire emergency."

Jan 1, 2019

By A. A. Tytko, T. S. Golosinski

"The paper discusses the accuracy of magnetic inspections of corroded hoist ropes. It quantifies the error of measured LMA (loss of metallic area) caused by presence in the rope of ferromagnetic products of corrosion. The paper concludes that in mining practice this error is not significant. Hoist Rope Corrosion and its AssessmentCorrosion is one of the most common forms of wire rope wear. For ropes working in wet mine shafts, ropes used by the fishing industry and, in general, ropes working in humid and chemically active environments, corrosion wear is usually the prime reason for rope discard. In most mining applications, rope corrosion is accompanied by fatigue cracking of wires, abrasion of external wires, internal nicking and other forms of wear.Quantification of corrosion damage in ropes using standard inspection procedures and examination methods is very difficult. Qualitative comparisons are sometimes used to describe the degree of rope corrosion to compensate for the lack of quantitative measures (SABS 0293, 1996). If available, the results of magnetic examinations of ropes may be of help in assessing their corrosion weakening.Magnetic rope examination requires that the rope first be magnetized. After that, the rope magnetic flux and the leakage flux along the rope are measured. The first is assumed to be directly proportional to rope metallic area (LMA) and its changes are indicative of the rope’s loss of breaking strength (LBS). Existence of the second indicates existence of local faults (LF) in the inspected rope. As the corrosion of rope results in development of corrosion cracks and in loss of rope metallic area, both the LF and the LMA should be used to quantify the level of rope corrosion. More specifically, the changes to the amplitude of the LF signal are considered to provide qualitative information on rope corrosion (Hansel et al., 1990), while those of the LMA signal are believed to provide quantitative information (Geller and Rousseau, 1990; Golosinski, 1996)."

Jan 1, 1999

By D. E. Smith, M. K. Murthy

"The commercial potential of a silica-kaolin deposit that occurs on the banks of and close to the Missinaibi River in the District of Cochrane, Ontario, is under evaluation by Algocen Mines Limited. The geological features of the deposit, as well as its probable origin, are described. Mineralogical analysis of the deposit samples indicates that the principal minerals are quartz and kaolinite clay; it is estimated that about 20 per cent of the deposit is kaolin clay. The impurity minerals present are: a slightly magnetic Fe-Ti oxide mineral, goethite, muscovite mica, tour-maline, staurolite, anatase and zircon. Laboratory research studies are in progress to develop and evaluate suit-able methods for the separation of silica sand from kaolin. Results to date indicate that good-quality silica sand with an Fe,03 content in the range of 0.012 to 0.025 per cent can be produced. It appears that the clay portion can also be beneficiated to yield products meeting commercial requirements. It has been possible to beneficiate a portion of theetlay to obtain the particle size distribution now specified by industry. However, research is continuing to develop suitable separation and beneficiation methods which can produce kaolin clay meeting all the commercial requirements."

Jan 1, 1970

By Zihe Ren, Edouard Asselin, Marcus Tomlinson, Tianbi Zhang, Jing Liu

"Raman spectroscopy is used to quantify the extent of disorder in the carbonaceous matter associated with preg-robbing ores. Previous studies of Goldstrike ores showed that the height and width of the peaks for the “D” (disordered) and “G” (graphite) bands, the so-called “Raman ratio” had a strong correlation to the preg-robbing value (PRV) measured for various ore samples. A brief literature review on Raman spectroscopy as it applies to preg-robbing ores is presented. Further, recent studies, presented here, have shown no correlation between the Raman ratio and the PRV for a wide variety of ores. This suggests that the extent of organic carbon crystal disorder is not the main factor in determining preg-robbing characteristics.INTRODUCTION Valuable base metals, such as nickel, cobalt, molybdenum, vanadium and tungsten, are used in a wide range of important technological applications. The demand for many of these metals has increased significantly over the last few decades, driven especially by economic expansion in Asia generally and China in particular. This has led in turn to a large growth in the output of mines in order to satisfy this increasing demand, as shown by the data in Table 1 (USGS, 1994, 2014). These data reflect an even longer trend of growth of these metals, with nickel, for example, showing an average rate of 5.3% per year from 1980 until 2015 (International Nickel Study Group, 2017). This rapid and sustained rate of growth means that annual mine outputs for nickel, tungsten, molybdenum and vanadium have had to double roughly every 11 to 14 years, whilst cobalt mine output has had to double roughly every 7 years, over the period from 1994 until 2014. With the average working life of a nickel mine being between 17 and 22 years (Statista, 2017), this means that from the time a nickel mine opens until it closes, the industry needs to find the equivalent of another three or four mines of a similar output to satisfy this relentless growth in demand for the metal."

Jan 1, 2017

The primary steel industry of the Prairie Provinces consists essentially of three companies whose total annual melting capacity, as of January 1, 1963, was 333,000 net tons. These companies have steel rolling facilities. In addition, there are five other companies producing steel castings by melting scrap in electric furnaces which, with the plants having rolling facilities, gives a total annual furnace melting capacity of 380,000 tons. Since 1954, the annual production of steel ingots and castings has ranged from a low of 66,588 tons, in 1954, to a high of 211,138 tons in 1961. The present facilities on the Prairies for making steel ingots from scrap, and rolling them to produce light merchant mill products, appear to be sufficient for many years ahead. Steel scrap, as electric furnace feed to make steel ingots for the present line of products, will probably continue to be available at reasonable prices either on the Prairies or from the north-central United States. It is recognized, however, that residual elements in scrap may be-come of greater significance and necessitate more rigid control of scrap quality.

Jan 1, 1963

By G. F. Liu, S. Owada

Platinum Group Metals (PGMs), Pt, Pd, Rh, have been widely used as a three-way catalyst to clean discharged gas from automobiles and therefore a considerable amount of the spent catalysts is generated annually. This paper proposes a novel concentration technology of PGMs by utilizing the double-deck structure of PGM bearing alumina-ceria and cordierite phases. The applied technologies are a combination of heating-quenching, selective grinding and screening for separating alumina-ceria phase from cordierite. Temperature change as a function of quenching time and the thermal stresses applied to both phases were simulated and calculated by FEM, and it was clarified the mechanism of micro-cracks generation at the phase boundary and micro-cracks in alumina-ceria phase, which indicated that separation of alumina-ceria phase from cordierite and selective breakage of alumina-ceria phase could be achieved in the subsequent selective grinding with an attritor. This process could concentrate 46 wt% of alumina-ceria phase into fine fractions with 86 % recovery efficiency. The remaining alumina-ceria phase can be further recovered by applying flotation and so on.

Jan 1, 2015

By F. Baczek, S. S. Rocks, D. Chaiko, T. Walters

The atmospheric leaching of chalcopyrite concentrates using acidic ferric sulfate lixiviants is well known to suffer from slow leach kinetics and poor copper recoveries. A number of approaches have been proposed for improving both leach kinetics and recoveries in this system. Many of these, while effective, suffer from high CAPEX and/or OPEX. As many mine sites begin transitioning from heap leaching of copper oxides to processing of primary copper sulfides, cost-efficient leach processes that are compatible with existing SX/EW processes will be needed to maintain existing cathode production. To this end, FLSmidth is exploring process options and reactor technology for the hydrometallurgical processing of primary sulfides. One approach that appears to be highly effective at increasing copper recoveries takes advantage of the enhanced reactivity of transitory, surface-defect structures generated during particle fracture. Significant process efficiencies are gained by matching the rate of grinding to the rate of electrochemical leaching in Mechano-Chemical leach processes. The patent-pending FLSmidth® ROL process uses a Stirred Media Reactor (SMRt reactor) to achieve copper recoveries of 97+% in 6 hours or less. This approach overcomes many of the surface passivation problems that have hindered other atmospheric leach processes. New insights to leach mechanisms are presented.

Jan 1, 2015

By A. E. Wraith, R. Harris, J. Qiu, R. Parra

Small pilot scale experiments have shown that it is possible to almost fully eliminate the minor elements (ME), namely As, Sb, Bi and Pb contained in smelter dusts by vacuum calcination of mixtures of the dust with sulphidizing agents such as dirty copper concentrate or elemental sulphur at 900 °C and 80 +/- 30 Pa for 90 minutes. The products of this calcination are a residue comprising a purified mixture of copper containing compounds along with the gangue constituents and a high sulphur condensate comprising a mixture of the minor element compounds. In particular, the Cu:ME ratios of the concentrate and dust were increased from 250 and 50, from 28 and 12 and from 36 and 8 to roughly 3000, 3000 and 100 for the calcine, for Bi, As and Sb, respectively. It has also been calculated that (i) the copper content of the vacuum calcine may be recovered by feeding it into a Peirce-Smith converter during its slag blow, and (ii) the resulting recycling could increase the minor element treatment capacity of a smelter by 100 % while also reducing the blister As content by a factor of three. The experimental results are briefly discussed and a treated dust recycling option is examined. Example operating conditions are presented and available commercial technology for the vacuum calcination of the mixtures is reviewed.

Jan 1, 2007