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By O. G. Olvera

"Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Typical cyanide operations show poor performance and require oxidative pretreatments to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. This work focuses on evaluating the effect of the addition of a carbon resin as a sulfur collector on the oxidation of different arsenopyrite concentrates under atmospheric tank leaching (ATL) conditions. The addition of the resin improved the oxidation of sulfides and favored the formation of elemental sulfur over the generation of sulfate. The use of AF5 in ATL resulted in higher gold recoveries under standard cyanide carbon-in-leach and thiosulfate leaching.INTRODUCTION Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Gold is not readily accessible to solutions in these types of ores and typical cyanide operations show poor performance, thus making the use of oxidative pretreatments a requirement to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. The use of carbonaceous materials to enhance the dissolution of sulfides is not novel, and leaching additives such as coal, activated carbon and carbon powder have been considered for the improvement of bioleaching, atmospheric leaching, and pressure oxidation leaching processes. However, this type of technology has been focused mainly on the recovery of copper from copper concentrates containing chalcopyrite with less attention paid to other sulfides."

Jan 1, 2017

By Owsiacki. Leo

Both the 8 and A-C ore zones of the Heath Steele Mine contain extensive areas of brecciated ore. This texturally distinct ore type has been tentatively defined as a fragmental or conglomerate massive sulphide. It consists of subangular and round fragments of pyrite up to 30 em in diameter, smaller quartz clasts and chloritized, mineralized, lithic fragments in a faintly banded matrix of pyrrhotite and chalcopyrite. The chalcopyrite is concentrated in the pressure shadows of the fragments and appears to reflect remobilization and recrystallization during a deformation which postdates the formation of the clasts. A generally conformable relationship with the underlying banded pyrite-sphalerite ore, discordancy with the host banded argillites, spatial distribution and similarity to Kuroko ores suggest that the fragmental ore is of primary origin and that breccia formation is probably due to soft-sediment slumping or sliding initiated by volcanic explosions, as hypothesized for similar massive sulphides in various Japanese mines. It is nevertheless recognized that certain structural features in some clasts may result from deformation preceding the formation of the breccia, and at this stage a tectonic origin cannot be completely eliminated.

Jan 1, 1979

By P. T. O'Kane

The PLATSOL® process, initially developed for the treatment of the NorthMet Cu/Ni/PGM concentrate, has seen over the recent years its applicability extended to include numerous other Cu/Ni concentrates of the same type, as well as other precious metals-containing feedstocks. However, several concentrates were found refractory to the typical PLATSOL® conditions, more particularly so the platinum. Attempts to extend those conditions, such as higher temperatures (250°C), longer retention time, increased oxidation conditions, higher chloride additions, were not successful. Detailed mineralogical investigation of those PLATSOL® leach residues indicated the main refractory mineral to be cooperite (PtS). Further metallurgical investigations showed that a thermal pre-treatment of the concentrate effectively unlocked the refractory platinum minerals for the subsequent leach. Temperatures between 400 and 750°C were tested, with the optimum being found around 650°C. The kinetics of the pre-treatment process were fast, and one hour at temperature proved sufficient. Under those conditions, PLATSOL® extractions were re-established around 95% for both platinum and palladium. From a mineralogical examination of the calcine, it was shown that the effect of the pre-treatment was to transform the cooperite and other refractory sulphides into metallic platinum and alloys, amenable to the PLATSOL®. The implications of the pre¬treatment step for the processing of PGM concentrates arc briefly discussed.

Jan 1, 2004

By W. A. Lang

COAL of sub-bituminous rank underlies much of the plains area of Alberta. This coal is geo-logically young, and occurs in Belly River and Edmonton strata of Up-per Cretaceous age. Generally, the seams are flat-lying, but in some areas they may dip as much as 5 degrees. The overburden, composed mainly of glacial clays and sand-stones, may vary in depth from a few feet to several thousand feet. Recovery of the coal has 'been by drift, slope, and shaft underground mines, and by open-pit stripping operations. Production has been obtained from a large number of mines, most of which have been relatively small and with preparation equipment limited to a loading tipple with screening facilities, and a picking belt where high-ash materials can be removed from the larger sizes. The coal has been sold for domestic and industrial space-heating, for production of process steam, and for power generation. In re-cent years competition from natural gas, propane, and oil has seriously interfered with the production and marketing of sub-bituminous coal, especially with the disposal of the smaller sizes at a realistic price.

Jan 1, 1958

By A. Rao, J. A. Davidson, B. L. Jones, K. W. Bowes, D. Craib

Supported by ANSTO, Groundwater Science and Inception Consulting Engineers, Boss has embarked on a series of technical projects aimed at reinforcing the Project’s capability to meet its export permit production capability. This paper will focus on three aspects of this technical program: Reducing the cost of resource expansion through smart use of low cost, surface target generation techniques; Improving the rate of uranium leaching and solution stability (gypsum, jarosite) through lixiviant chemistry modifications; and Development of an ion exchange (IX) process to increase production capacity, and integration of IX and the current solvent extraction circuit with the existing uranium precipitation and product preparation circuits.

Jan 1, 2020

The topic of the relationships between energy and particle size has had two very active periods -the first in the early thirties, when the relative merits of Rittinger's and Kick's proposals were vigorously debated; the second in the early fifties, when Bond's Third Theory was published. This second stage has produced several contributions that have provided a clearer picture of energy /size correlations in comminution. Derivations of a general relationship have been made from single-fracture experiments and from the rate of comminution, and both methods arrive at an equation of the type E = AK-11? The constant A in the equation may be regarded as a grindability parameter. In some respects, an understanding of the phenomena associated with comminution is still lacking, and research in this field should therefore be expanded. T HE SEARCH for a relationship between the energy consumed in comminution and the size of the broken product has been long and varied, and many

Jan 1, 1964

By G. Lucas

"Material substitution occurs continuously in response to competitive and economic pressures. Technical development can accelerate or slow substitution by improving the performance of the invading or defending material. The choices are seldom simple and have to be made in the context of continuous commercial change.The development and commercialization of a new aluminum material is examined. The material has been introduced into· several different markets, so it is possible to compare and contrast the degree of success obtained in each.IntroductionAluminum-based materials have been in use for over one hundred years and , therefore, the development of a new family of alloys is rare. In the early 1970s, Dr. L.R. Morris and his coworkers at Alcan' s Kingston Research Centre started work on what was, at the time, something of a scientific curiosity-a family of alloys strengthened by an unusual mechanism.This paper deals with the development and commercialization of what became known as the Alcan 255 alloys"". These alloys have found uses in several markets, usually as improved substitutes for existing materials. Forecasting the usefulness of a substitute material in an existing marketplace is difficult, in part, because even material users are seldom able to specify precisely their requirements. This uncertainty can cause the failure of some substitutions but can also lead to opportunities which were not initially obvious.Technical BackgroundPure aluminum is a soft, weak material. It can be strengthened by the addition of various alloying elements and by work hardening. Alloying elements usually act by forming solid solutions which are stronger than the pure metal or by precipitating during heat treating or aging and so preventing the easy movement of dislocations during deformation. Elements which can perform either role had been investigated for decades and were thought to offer little chance of technical breakthrough in 1970. An outgrowth of the then new and exciting research on directional solidification seemed, however, to offer such promise.Some aluminum-iran-manganese alloys will solidify under certain conditions as 'coupled growth' eutectics (Figs. I and 2). The microstructure shows one phase growing as long rods through the other. This is an uncommon structure and it was investigated to see if it had equally unusual properties. On deformation by rolling the rods were broken up into small equiaxed , evenly-spaced particles (Fig. 3). Materials with this structure were found to be stronger than other alloys with similar amounts of alloying addition, and to resist thermal softening remarkably well. This combination of properties was thought initially to be due directly to the particles by a dispersion strengthening mechanism, but later this was found not to be strictly true."

Jan 1, 1987

By R. Bashir, J. F. Hatley

ABSTRACT Northern Saskatchewan boasts some of the world’s largest known high-grade uranium deposits. The successful mining of these deposits cannot be accomplished without overcoming technical challenges, however, which include high grade of the uranium ore, specialized mining methods to deal with groundwater at high pressures, and poor ground conditions. This paper discusses the various mechanisms of inflows at three of Cameco Corporation’s sites in northern Saskatchewan. The risk of inflows is quantified in terms of unique challenges due to hydrogeological conditions, rock mass integrity, and uncertainty in geological conditions. Strategies in the case of an inflow are also briefly described.

Jan 1, 2013

By G. R. McMeekin

"THE TOPIC suggested for my contribution to this Symposium was ""Lead-Zinc Smelting - 40 Years of Pollution Control"". The history of the development of smelting industry at Trail and the control of sulphur dioxide could make quite an interesting historical study. However, in the field of environmental control, the public is not particularly interested in what you did yesterday, but rather what you are doing today and what you are planning to do tomorrow. I can't fault this approach, but because there are some subject lessons that history can demonstrate, I would like to tell enough of the story (under three headings) to bring a focus on matters of contemporary concern in regard to public relations and ecology. The three general headings suggested are: (1) time before the capture of by-product sulphur; (2) the capture of sulphur; and (3) the ecological and public relations conclusions from these."

Jan 1, 1972

By M. F. Goudge

MAGNESIA refractories and magnesium metal are both essential war commodities. The need for magnesium, which had just made its debut as a commercial metal a few years before the outbreak of the present war, is widely known because this new and valuable light metal has already received much publicity. Less widely known but equally important in the war effort are magnesia refractories. They are indispensable to the efficient functioning of the great metallurgical plants producing steel, nickel, copper, and other metals, where, because of their resistance to extreme high temperature and chemical attack, they are used in lining the furnaces, which are operated at a white heat. The demand for refractories in the metallurgical industries rose rapidly upon the outbreak of war, and now, in consequence of the continued great expansion under way in the manufacture of steel, nickel, copper, and other metals, the need for magnesia is greater than ever. Since 1915, part of the Canadian requirements of basic refractories has been supplied from the deposits of magnesitic dolomite in Argenteuil county, Quebec. The products from these deposits are excellent for many uses, but the magnesitic dolomite has too high a content of silica and lime to be used in making a type of magnesia brick required in nickel converters, and in the roofs of reverberatory furnaces used in the copper and steel industries. There is now a large and growing demand in Canada for bricks and shapes for these uses. This demand has always been supplied from the United States. Makers of these products in the United States, in turn, formerly imported most of the necessary high-grade, dead-burned magnesia from Austria and Manchuria. Not only are these sources closed, but refractory chrome ore from the Philippines is no longer available and chrome refractories may have to be in large part replaced by magnesia.

Jan 1, 1942

By Ben Habermann

"The object of the work described in this paper was to increase the understanding of the relation that capillary pressure of a rock, hydro-dynamics, and accumulation of oil in stratigraphie traps have to one an-other. The hydrodynamic oil-water tilt equation is derived by considering the two vector gradients involved: (1) buoyancy of oil in water and (2) hydraulic gradient.Recent theories show the necessity for oil to have a continuons phase in the reservoir rock in order to mi-grate; this fact applies to hydro-static as well as to hydrodynamic conditions. Hydrostatically, the displacement pressure of the rock deter-mines the amount of oil that can be trapped behind a permeability barrier. If the buoyancy of oil in water exceeds the displacement pressure, oil will migrate up-dip; an oil trap will be formed where displacement pressure is greater.In stratigraphie traps the pressure drop caused by moving water is positive when its direction is down-dip, helping accumulation; and it is negative when its direction is up-dip, forcing the oil into the tighter section of the reservoir. Theoretically, pro-vided we have data such as: (1) the displacement pressure of an up-dip permeability pinchout, (2) density difference between the oil and water in place, and (3) the direction and magnitude of the hydrodynamic gradient (if any), the possible extent of a stratigraphie oil accumulation down-dip can be predicted.To test the above theory sample cores from three wells in the Denver Basin were analyzed and the oil column that could be held under hydro-static conditions was calculated. After the hydrodynamic influence was considered, the results were compared with actual field data.The significant fact shown by this investigation is that the calculated oil column in one reservoir very closely approximates the actual extent of the oil column in a well. Also in accordance with the theory, the capillary pressure caused by the buoyancy of the oil column exceeded the measured displacement pressure on core samples from another productive field. For very tight shaly sand and questionable oil shows, the interpretation of data is very critical, as shown by experiments on core samples from a third field."

Jan 1, 1960

By John D. Campbell

Alberta Plains coals exhibit an almost rectilinear system of vertical fracturing called "cleat", which is best traced by mapping true bearings of underground coal mine rooms. The cleat pattern is approximately conformable with a pattern of surficial features and a pattern of bedrock jointing in the Alberta Plains, and with the trend of the Rocky Mountain Trench, but not with the distribution pattern of coal rank nor with the trend of the eastern boundary of the Rocky Mountains and Foothills physiographic province. The processes resulting in cleat remain in doubt, but cleat is always of practical importance in extracting coal from deeply buried deposits.

Jan 1, 1979

ABSTRACT This paper details the work of RISKGATE, the largest Australian Coal Association Research Program (ACARP) occupational health and safety initiative to date. The program is an interactive online risk management system developed to maximize health and safety performance in the coal mining industry by implementing continuous improvement in managing major unwanted events. The comprehensive knowledge base covers tires, collisions, fires, isolation, strata control underground, ground control open cut, explosions, explosives, manual tasks, and slips/trips/falls. All major Australian coal mining companies contributed topic experts to this broad industry initiative: nine coal mining companies, more than 80 experts, and more than 400 days of individual time for knowledge-capture workshops.

Jan 1, 2014

By J. C. Underwood

"The wear performance of grinding balls under conditions of impact and abrasion is affected by their chemical composition and structure. The selection of appropriate analyses and heat treatments that will provide both abrasion and impact resistance takes into account the effects of certain elements on structure and harden-ability, as well as the over-all effect of composition and hardness penetration on the residual stress pattern developed through heat treatment. Direct quenching from forging temperatures substantially increases hardenability over that obtained in reheat-quench practices, and can be done without undue risk of damage to the ball provided that the harden-ability bears the correct relationship to ball diameter.Average volumetric hardness and percent hardened volume are convenient parameters for quantitatively expressing the response to heat treatment and indicating anticipated wear properties. A number of factors which can lead to reduced wear life as a result of material or processing problems are reviewed and illustrated."

Jan 1, 1959

By S. J. Cook

The subject of capital and the Canadian mining industry is so broad as to be impossible of comprehensive treatment in brief form. The purpose of the present paper therefore will be only to outline in a meagre and somewhat sketchy way the nature and extent of the mineral industry in Canada and to point out those features which are likely to be of general public interest. Canada's mineral industry has a long and creditable production record. The? value of the output per capita rose from $2.23 in 1886 to a maximum of $26.40 in 1920 and the value of the products from ten million dollars in the former year to almost two hundred and twenty-eight million dollars in 1920. Compared with other primary industries and on the basis of the value of production, mining held third place in Canada in 1920, the premier position going to agriculture and the value of forestry production placing that industry second in the list. In the mineral industry, between six and seven thousand properties are operated annually giving employment to up- wards of sixty thousand employees to whom about seventy-five million dollars is paid in salaries and wages. During 1923, seventeen mineral products reached a production value of one million dollars or over in Canada and in order of the values assigned these were: coal, gold, nickel, cement, cop-per, silver, clay products, lead, asbestos, natural gas, stone, zinc, lime, cobalt, sand and gravel, gypsum and salt.

Jan 1, 1924

By P. Amelunxen

It is well-known that the particle breakage mode that occurs in a semi-autogenous mill is significantly different from that which occurs in a ball mill, enough so to warrant very different lab scale breakage tests and scale-up models. This phenomenon, at the plant scale, leads to changing process constraints depending on the particular properties of the ore. For example, hard or coarse ores might bottleneck the SAG/AG mill throughput, while the ball mills might constrain throughput when milling soft or fine ores. Because the power draw of a ball mill is fairly constant compared to that of a SAG/AG mill, periods of SAG/AG mill bottlenecks lead to increased ball mill circuit specific energy consumption and a finer grinding circuit product size, which together constitute a loss of efficiency of the overall process. Because HPGR circuit throughput is less sensitive to changes in ore hardness, this situation is less common or severe in those circuits. Furthermore, the ball mills are somewhat decoupled from the upstream crushing circuits through the use of surge bins, which also helps to mitigate this effect. As a result, ore hardness variability constitutes a significant cost penalty that should be applied to SAG mill/ball mill/pebble crusher SABC circuits when evaluating the relative economics of different grinding circuit configurations. Nevertheless, the issue is by-and-large ignored, because most current HPGR trade-off studies are based on averaged ore hardness parameters. This paper provides an estimate of the magnitude of this penalty for a typical operation by using Monte Carlo simulation methods and plant data from Freeport-McMoRan?s autogenous, semi-autogenous, and HPGR-based comminution circuits. A case study from an in-house 96K t/d sulphide project is presented to illustrate the concept. It was found that by including variability effects, the trade-off NPV of the HPGR circuit over that of the SAG mill circuit increases to $84 million from negative $33 million, effectively reversing the original decision of selecting a SAG mill circuit for the fixed hardness case.

Jan 1, 2012

By D. J. McCulla

Mineral development and utilization affect the health of the economy and the pattern of long-term development throughout Canada. There are many diverse opinions on the contribution of minerals to the economy, but there is a dearth of adequate quantitative information. This paper discusses some recent research and provides some new information.

Jan 1, 1977

By G. M. Ritcey

The recovery of copper from low-grade solutions res ulting from dump leaching is well known, whereas the recovery from highly concentrated copper solutions has not been practiced. This paper discusses the use of Ashland Chemical's Kelex 100, a substituted quinoline, for the recovery of copper from solutions resulting from leaching copper-nickel concentrates. A flow sheet is described, and an economic comparison shows Kelex 100 to be superior to either the LIX 64N or LIX 70 reagents of General Mills for the recovery of copper.

Jan 1, 1973

By Pizhi Zhao, Jingwei Zhao, Zhenshan Liu, Yiheng Cao

"A new Al-Mg-Si-Zn alloy designed for automotive outer panel was trial-produced with industrial procedure. The final product shows a strong planar anisotropy. X ray diffraction analysis shows such strong anisotropy is caused by the dominating cube texture component in the final product. The reason for such high cube texture component was investigated by tracing texture evolution starting from the hot roll slab. It is found that certain cube texture components already exists in the hot rolled slab. The density of cube texture component shows as a wavy change through the following1st cold rolling, inter-annealing, 2ndcold rolling and solution treatment. This study shows that the cold rolling in the laboratory can well represent the texture evolution during the industrial production. The results obtained by lab rolling hints that change of second cold rolling reduction has weak effect on the planar anisotropy, when the gauge of hot rolled slab and final sheet are fixed.INTRODUCTIONWith the rapid progress of light-weighting in the automotive industry, aluminum sheets get more and more application as closure panel and structure parts. Recently the dominating alloy for outer panel is 6xxx series, containing the main alloy elements Mg and Si. The popular gradesareAA6016,AA6111, AA6022, and AA6014. These alloys still cannot satisfy the various requirements from automotive manufacturers. Most suppliers of automotive aluminum sheets are developing their own specific grades according to the customer’s demand. To increase the baking response, anew Al-Mg-Si-Zn alloy was designed, concerning the high combination energy between Zn solutes and vacancies formed during the quenching stage of automotive sheet manufacture. This combination is helpful to the precipitation of ß”phase during the paint baking (Wang, 2015,2016; Yan, 2014).The plastic strain ratio (r value)is a key index of the formability of automotive body sheet. A high r value means a good formability. The r values in different directions can be used to evaluate the planar anisotropy of the metal sheets. The trial produced Al-Mg-Si-Zn sheet shows a strong planar anisotropy with respect to r values. Since the r value is tightly related with texture, the texture evolution from hot roll slab (HRS) to final T4P temper was analyzed with X ray diffraction (XRD) to find the reason for the high anisotropy. Besides, the cold rolling reduction (CRR) was varied in the laboratory to modify the texture distribution, i.e., the planar anisotropy."

Jan 1, 2018

By J. W. Matousek

The heat content of the waste slag from a typical smelting operation methods for estimating the thermodynamic properties of smelting slags, to include: -- heats of formation -- heat capacities (specific heats) -- heat contents -- melting temperatures -- heats of fusion The techniques are illustrated with the analyses of a nickel reverberatory furnace slag from Copper Cliff, an iron-making blast furnace slag, and a "lateritic" slag from a ferronickel operation in Colombia.

Jan 1, 2007