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By Edwin Ludlow

ROUNDING out a year of improved organization, substantial accomplishment and strengthened purpose, the American Engineering Council of the Federated American Engineering Societies held its first annual meeting at the Cosmos Club, Washing-ton, Jan. 5 and 6, Dean Mortimer E. Cooley of the University of Michigan, president of, the Council, presiding. Officers were-chosen, the work of the past year was reviewed and discussed, action was taken on important matters of public and technical service, new financial arrangements were put into effect, committees were named, new policies were sanctioned and old ones reshaped, and a broad and definite program was out-lined for the next twelve months. A leading event of the meeting was a dinner in honor of Herbert Hoover, who, addressing the members of the Council and their guests at the University Club, praised the work of the Committee on Elimination of Waste in Industry as a great and lasting public service, pointed the way for new engineering effort in the public interest, and expressed renewed devotion to the ideals of the Council. Resolutions of appreciation of the service of the Secretary of Commerce were presented to Mr. Hoover.

Jan 2, 1922

By Chung Yu Wang

STUDY of two recent papers and a recent book leads one to raise anew the question-Why are certain regions of the earth more mineralized than others?

Jan 5, 1953

Jan 1, 1956

Jan 1, 1957

By J. D. Livingston

THE hardening of alloys by the precipitation of a second phase has long been an important technological process. One approach towards improving our understanding of this phenomenon has been a correlation of mechanical properties with such parameters as particle size and inter par ticle spacing.' Several reviews of such data have appeared.2-4 A major limitation to this approach has been that for most alloys the particles are submicroscopic in size in the range of optimum hardness. Precipitation-hardening copper-cobalt alloys, therefore, are of interest, because the ferromagnetic properties of the precipitate make it possible to measure particle size, number of particles, and so forth, from magnetic measurements alone.5, 6 Livingston and Becker7 have applied these techniques to a study of precipitation hardening in an alloy of 2 pct Co in copper. It was found from magnetic measurements that nearly all the cobalt to be precipitated was out of solution within a few minutes at 600°C, whereas the peak in tensile yield stress was not attained until a much longer aging time. Thus during the first 1000 min of aging time at 600°C the Yield stress was increasing while a constant volume of precipitate was coarsening, i.e., while particle size and interparticle spacing were increasing. Peak yield stress was reached at an average particle radius of about 70A. The earlier study was confined to one alloy at one aging temperature, so that the volume fraction of precipitate was fixed and, therefore, particle size and interparticle spacing could not be independently varied. The work has now been extended to several alloys of varying percentage cobalt in copper, and to aging at various temperatures. It was hoped that such a study might clarify the relative importance to precipitation hardening of particle size, interparticle spacing, and volume fraction of precipitate. EXPERIMENT The alloys studied contained 0.7, 1.3, 2.0, and 3.2 wt pct Co in copper. They were prepared from electrolytic copper and electrolytic cobalt in a vacuum -induction furnace, worked to 3/8-in.-diam rod, and machined into tensile specimens with a gage section 1 1/2 in. long and 3/16 in. in diam. All specimens were given a solution treatment consisting of a 30-min anneal in nitrogen at 1000° C followed by a quench into iced brine. Subsequent aging was done in nitrogen and followed by a water quench. Average grain diameter was approximately 0.01 in.

Jan 1, 1960

By F. F. Schmidt, H. R. Ogden, E. S. Bartlett

ThE solubility of carbon in tantalum has been reported to be very low at temperatures below 1500 C,1'2 increasing to at least 0.02 wt pctl at the eutectic temperature of 2800°C. The solubility limits at low temperatures were based on metallo-

Jan 1, 1963

By Dean F. Winchester, C. D. Johnson

The so-called Rocky Mountain region is here made to include Colorado, Idaho, Montana, northern New Mexico, Utah and Wyoming, an area of great distances and relatively sparse population. Conditions of distance, transportation and markets have had their retarding influence on devolopment and production but the increase in facilities and markets in recent years has provided additional incentive for more thorough search for new productive areas and the more complete development of the known fields. The low prices of crude during the past year have offset, to a certain extent, the desire for increased production and much of the effort has been directed therefore to outlining new areas rather than to attempts to increase production from known fields and thereby add to the already sufficient supply above ground. During the year just closed the Rocky Mountain region has seen consistent efforts to outline new areas and these efforts have been reasonably successful. In this area a very large part of the land is government property, and by cooperation between the government, the private owner and the company it has been possible to carry on development in a scientific manner, providing for the maximum recovery of valuable products at least cost and at times when prices were best. Due to the fact that in the Rocky Mountain region costs of exploration and development are relatively high because of natural circumstances, it has been the policy of operators to drill test wells only on structures where they controlled a large proportion of the land. Even community lease programs have been effected in certain areas, thus obviating the necessity of offset drilling and the attendant uneconomical and even wasteful production. Oil production in the Rocky Mountain states has shown a slight increase during the year, the average daily production for November being 78,124 bbl. as against an average in January of 76,681 bbl. The total production during the first 11 months of the year, according to the U. S. Burcau of Mines, was as follows:

Jan 1, 1929

[1-Iron and Steel JOHN A. MATHEWS, Chairman RALPH H. SWEETSEH. Vice-chairman WILLIAM CAMPBELL. Vice-chairrmn MAX ROESLER, Secretary Iron Ore R C. ALLEN W. 0. HOTCHKISS MAX ROESLER ERNEST F. BURCHARD THOMAS T. READ DWIGHT E. WOODBRIDGE M. M. DUNCAN WILLIAM KELLY CARL ZAPFFE]

Jan 1, 1928

By H. S. Strouth

JAMAICA-bauxite and gypsum-but what else? J Does the Caribbean island have anything more to offer in the form of mineral wealth? One answer may be iron ore deposits which show enough promise to warrant exploitation in the near future by a company associated with Standard Ore & Alloys Corp. In addition, Jamaica is reported to have gold, silver, platinum, copper, lead, zinc, manganese, cobalt, and a great many nonmetallic minerals. Of these, only platinum has not been produced commercially in the past. Right now, Jamaican bauxite is getting most of the publicity, but not too long ago other mining operations were in progress. Lack of proper interest, insufficient roads, and scarcity of venture capital forced those mining properties to suspend production.

Jan 7, 1954

By Philip E. LaMoreaux

Fluoride, generally less than 0.5 ppm, is present in ground water from rocks of Paleozoic age and older, in northern and eastern Alabama. Some of the water-bearing formations in the Coastal Plain area of the State yield water with as much as 6.8 ppm fluoride.

Jan 1, 1950

By W. B. Watson

IN the USSR considerable technical improvements have been made in hydraulic methods of mining coal. In New Zealand coal mining by these methods is still comparatively crude. The Russian techniques are closely studied in New Zealand, and this description is based mainly on translations of technical articles. Fundamentally the methods in both countries are the same-chief developments in the USSR are the use of high pressure water jets, capable of winning all but the hardest coal without prior blasting, and hydraulic pipeline transportation where the gradient is unsuitable for flume transport.

Jan 4, 1958

By K. Osseo-Asare

The thermodynamics of solid-aqueous solution equilibria up to 200°C In the systems Me-NH3 H2 0 (Me=Cu, Ni, Co) are summarized with predominance area diagrams generated with the DIAGRAM computer program. The implications of the diagrams to ammonia hydrometallurgy are discussed.

Jan 1, 1981

By H. D. Wilde

GREAT emphasis is being placed today on petroleum as a source of chemicals. Such prominence is well merited, for rapid strides have been made in developing processes for the conversion of petroleum into synthetic chemical products, which are now being made on a huge scale. These marvelous accomplishments have resulted in some highly optimistic predictions as to what can be expected in the future. Many of these forecasts are well justified, but some writers, especially those contributing to the Sunday supplements and the popular-cience type of publications, have let their imagination run wild and present a rather distorted picture of the possibilities in this field in the postwar period. Commercial manufacture of synthetic organic chemicals had its beginning in England with the establishment of a plant by Sir William Perkin in 1857 for the manufacture of "Aniline Purple" or "Mauve." The preceding year he had discovered in the laboratory how this dyestuff could be made from aniline, one of the many derivatives of coal tar, and he soon made commercial application of his discovery. Influenced largely by his success, organic chemists began research on production of a vast array of synthetic dyestuffs, medicinals, flavors, scents, and explosives. Rapid progress was made and by the turn of the century hundreds of these products were being manufactured. Most of these synthetic chemicals were derived from materials obtained as by-products in the conversion of coal into coke. These by-products are generally referred to as "aromatics" and are obtained by processing coal tar recovered in the coking process, so they are popularly known as "coal-tar chemicals." During the early years of this century, coal-tar chemistry was the wonder of the age, and rightfully so, since the products so made seemed limitless.

Jan 1, 1944

By William E. Ford, Edward Salisbury Dana

WheweUite. Calcium oxalste CaCz04.Hz0. In small colorless monoclinic crystals. Optically +. j3 = 1.555. From haxony, with coal; also from Bohemia, and Akace. Oxammite. Ammonium oxelate, (N&)rC20r.2HzO. From the guano of the Gudape Isbnds, Peru.

Jan 1, 1922

PRESIDENT Willis McGerald Peirce New York City, N Y PAST PRESIDENTS D H McLaughhn, San Francisco, Calif L E Young', Pittsburgh, Pa VICE-PRESIDENTS A. B. Kinzell, New York, N Y H. W Thomas Ray, Arizona Philip Kraft, New York, N Y J L Gillsan Wilmington, Del M. L Haider, Toronto, Ont , Canada VICE-PRESIDENT and TREASURER Andrew Fletcher, New York, N Y

Jan 1, 1951

Sulfuric Acid and Phosphate Industries at Anaconda Reduction Works. BY E L LARISON (Contribution 70-Preprint 4400 words) In 1915 a 135-ton chamber sulfuric acid plant was built at the Anaconda Reduction Works to supply acid for leaching sand tailing Sulfur dioxide was obtained by roasting copper table concentrate Soon after, the flotation process, using acid as a reagent, together with development of a leaching and electrolytic process for zinc recovery, necessitated building a second acid unit of 50 tons' per day capacity, completed in 1917 Within a few months the zinc process was so improved as to consume no added acid Mean¬while research work was in progress on production of phosphate fertilizers using sulfuric acid and Idaho phosphate rock In 1920 a pilot plant was put into operation which treated 50 tons per day of phosphate rock to produce treble superphosphate containing 45 per cent available P205 In 1922 the original plant and process for leaching of sand tailing were abandoned in favor of a combination leaching and flota¬tion process In 1923 the sand leaching plant was remodeled into a treble super¬phosphate plant designed to treat 160 tons per day of phosphate rock. In 1924 the copper flotation process was put on alkaline circuit and acid, has not since been used as a reagent Practically all the acid produced is now used for making phos¬phate products In 1931 the use of copper concentrate as a source of sulfur dioxide was abandoned and an iron concentrate, floated from the copper concentrator tail¬ing, substituted

Jan 1, 1935

By C. A. Stickels, C. M. Yen

Secondary recrystallization was investigated in vacuum-melted electrolytic iron to which 70 pm N was vacuum-meltedadded. The secondary texture is "near {554}<225>" for material cold-rolled 75 to 90 pct, the sharpness of the texture increasing with increased rolling reduction and with decreased annealing temperature. At reductions of 95 and 97.5 pct the secondary texture is &apos;"near {322)(296)". Both secondary orientations also exist as major components of the primary re-crystallization texture. Development of a strong "near {554) (225)" secondary texture appears to depend on the evolution of the Primary texture to a transition texture depleted in orientations near the secondary orientation before the onset of secondary growth. A variety of qualitative experinzents have been used to show that nitrogen is important in limiling primary grain growth. The presence of nitrogen does not seem essential for the establishment of a transition texture, but a loss of nitrogen during annealing may facilitate growth of grains in the secondary orientation. Secondary grains we shown to form initially at the specimen surface. This is not thought to indicate that surface energies are important in the growth process. It is proposed that the quasi-two-dimensional character of surface grains permits discontinuous growth parallel to the surface before secondary growth of interior grains is possible. An earlier study of recrystallization textures in 90 pct cold-rolled electrolytic iron showed that secondary recrystallization occurred after annealing for several days at 700C1 This type of secondary recrystallization, which had not been reported previously, results in the formation of a strong texture, best described by the indices "near {554}(225)". The purpose of the present work was to investigate the effect of various processing variables on secondary recrystallization in this material and determine the mechanism of secondary grain growth. LITERATURE REVIEW An understanding of the mechanism of a secondary recrystallization process depends on knowing: 1) how grains in the secondary orientation come to be in the primary recrystallization texture; 2) why normal grain growth does not occur; and 3) what factors determine the strength of the secondary texture. For secondary growth of grains of a particular orientation, a certain minimum fraction of the grains must be in that orientation after primary recrystallization. This requirement is apparently satisfied "naturally" in certain systems, i.e., when the primary texture obtained by rolling and recrystallizing material initially randomly oriented contains a sufficient fraction of primaries in the secondary orientation. However, in other cases, e.g., {110}<001> and {100}<001> secondary growth in silicon iron,2 it is necessary to enhance the fraction of primary grains in the secondary orientation by rolling and recrystallizing textured material. In the present case, the "near {554}<225>" orientation is contained within the spread of orientations found in the primary recrystallization texture of iron or bbc iron-base alloys. In systems where the main driving force for secondary growth is the reduction in total grain boundary energy, secondary growth is observed only when normal grain growth is minimized. Four ways in which normal grain growth can be limited are: 1) Limitation by a strong primary texture. When a very strong primary texture consisting of a single component or twin-related components develop, most primary grains are separated from one another by relatively immobile small-angle grain boundaries. The classic instance of this is secondary growth into the primary cube texture in some fcc metals. 2) Limitation by precipitates. Precipitates present in the proper volume fraction with a suitable dispersion will limit primary grain growth. The role of MnS inclusions in impeding normal grain growth in Si-Fe is well-documented.5 3) Limitation by sheet thickness. Normal grain growth slows drastically when the mean grain diameter is of the same order as the sheet thickness. This effect has been used to obtain secondary recrystallization in thin sheets of high-purity silicon iron.&apos; 4) Limitation by solute impurities. It is well-established that certain impurity elements in solution can have a large effect on grain boundary mobility.&apos; However, there does not seem to be any secondary recrystallization process in which primary grain size stabilization has been shown to be due to the drag exerted on grain boundaries by dissolved impurities. In certain systems, e.g., secondary recrystallization in silver,&apos; the means by which normal grain growth is limited has not been identified, and solute-impurity limitation might be suspected. In order to understand the factors which determine secondary texture strength in three-dimensional growth, it is necessary to examine in more detail the current picture of general secondary recrystallization processes. Following Cahn,9 it is assumed that the primary grains have a range of sizes and that secondary growth of one of the large grains in this distribution is possible when it exceeds a critical size with respect to its neighboring grains. The critical size depends on the ratio ?S/?p, where ?s is some sort of average grain boundary energy between the potential secondary and the primary grains and ?p is some sort of average grain boundary energy between primary grains. For a constant primary grain size, the critical size for secondary growth increases as ?$/?p increases. May and Turnbull5 have incorporated the

Jan 1, 1969

By A. W. Demmler

RECENTLY, Chaudron,&apos; Montariol,2 and their co-workers published the results of their studies on zone-refined aluminum. They found their material to be capable of recrystallization at —50°C, but gave no data as to the percentage reduction or time required. Their material was found to be practically non-work hardening at room temperature, but after 96 pct cold work at a low temperature and storage in liquid nitrogen it was found to recrystallize to coarse grains in less than 3 hr at 20°C. Recently, a study was made of the room temperature recrystallization characteristics of zone-melted aluminum. An ingot 14 in. in length, with a 3hx3 in. cross section, was made in an extremely high purity graphite boat under an atmosphere of dried commercial argon. It was made by first passing the molten zone along the ingot of 99.99+ pct A1 15 times. At this point, the most impure 3 in. (the end toward which the eutectic forming impurities migrated) were replaced with more of the original starting material, and 15 more traverses were made. Each traverse of the zone along the ingot required approximately 3 hr. Three ingots were prepared in this identical fashion and the chemical analyses were made spec-trographically on two of these ingots, rather than on the one used in this investigation. The analyses were made at 1 in. intervals along the ingot, in duplicate. Over the purest 5 in. of the ingot, which were most important in this investigation, there was found an average composition of <0.00004 pct Cu, <0.0003 pct Fe, <0.0001 pct Si, and <0.0001 pct Mg. In addition, the following elements were not detected spectrographically even in the more impure end of the bar: manganese, zinc, nickel, chromium, titanium, vanadium, lead, tin, boron, beryllium, bismuth, gallium, zirconium, cadmium, antimony, cobalt, and molybdenum. The original ingot was given several cold reductions, with intermediate anneals in order to refine the grains. Owing to the extreme length resulting and the ease of deforming the material plastically, it was cut into eight equal lengths and identified as shown in Fig. 1, with the highest numbered section at the purer end (that enriched with peritectic formers). Section 6 was used in the exploratory work and was found to be of exceptionally high purity, giving more rapid rates of room temperature re crystallization than any previous aluminum studied at the Alcoa Research Laboratories. This fact suggested that the entire midsection of the ingot might be of very high purity. Accordingly, section 4 was chosen for the next study. A portion of it was rolled to cold reductions of 10, 25, 40, 60, 75, and 90 pct at room temperature, and the re-crystallization of each specimen was followed by X-ray pinhole transmission photographs. The other portion received the same treatment, except that both the specimens and the rolls were maintained at 160°F in the process of rolling. The latter ortion was retarded in its recrystallization as compared to the former, probably due to the stress relief effect of the warm rolling. Both of these portions of the fourth section were found to recrystallize at a considerably slower rate than did the sixth section.

Jan 1, 1957

By Roy J. Helfinstine

One of the most urgent needs in the field of coal combustion is the ability to predict the performance of a coal from knowledge gained from small-scale tests. Numerous types of analyses and tests are conducted on coal, including the proximate and ultimate analyses, heating value, varieties of sulphur, ash analysis, ash fusion temperatures, free swelling index, petrographic analysis, and Gieseler plasticity. The Illinois Geological Survey has made an intensive study of the value of these tests for judging the performance characteristics of the coal as actually utilized. To date, three reports 1 2 3 have been is- sued, and another is being prepared. The present paper briefly summarizes some of the results found in the studies.

Jan 1, 1949

By Staff

Concentrates at the rate of 1000 tons a day are being smelted by International Nickel Co.&apos;s new commercial flash smelting furnace. Developed by Inco, the process is a radical departure from the former practice which involved conventional smelting in coal-fired reverberatory furnaces. In the new process copper flotation concentrate and flux are injected horizontally with oxygen into a specially designed reverberatory furnace, and smelting temperature is maintained solely by the flash combustion of iron and sulphur while the particles are in suspension. The major benefits of this new process stem from two sources: 1)-Substitution of energy from local resources for imported coal; and 2)-Production of liquid sulphur dioxide, replacing equivalent imported sulphur. A measure of these benefits is afforded by considering the saving, in 1954, of 60,000 tons of coal and the production of 70,000 tons of liquid sulphur dioxide, equivalent to 35,000 tons of sulphur.

Jun 1, 1955