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By L. D. Jaffe

IN previous metallographic work on titanium and its alloys, difficulty has been encountered in distinguishing spheroidal particles of titanium hydride, dispersed in a-titanium, from other phases that may be present, such as p-titanium. This problem is common in examination of commercial unalloyed titanium.' In the course of an investigation of the Ti-H phase diagram, it was noted that titanium hydride, dispersed in a matrix of a-titanium, showed strong optical anisotropy when examined under polarized light. With sensitive tint illumination, particles of the hydride, when the stage is rotated, changed from bright yellow to bright blue in color. Since P-titanium is cubic, it showed no color change on rotation, remaining dark gray or blue-gray. Although a-titanium is hexagonal, it showed only a minor color change, going from pale pinkish-blue to pale purplish-blue. These colors could be modified somewhat by adjustment of the illumination. They were observed in specimens mechanically polished, both without etching and after etching with hydrofluoric acid-nitric acid mixtures in either water or glycerine. The strong color change of the hydride seems to offer a simple method for its metallographic identification. Optical anisotropy of titanium hydride is inconsistent with its accepted face-centered-cubic structure.' Samples of iodide titanium containing 6 to 40 atomic pct deuterium were prepared for diffraction studies. After deuterating and slow cooling' the samples were held 21 % hr at 400 °C, water quenched, held 61 hr at 100°C and quenched, then held 64% hr at 255 C and quenched. Debye ex-posures with MoKa X-rays and 1.111A neutrons were made at room temperature of samples as-deuterated and after the 100" and 255°C treatments. Table I shows the lines observed, in addition to those attributable to a-titanium. These data show that the hydride phase was not cubic, but probably tetragonal. The titanium atoms appeared to form a body-centered-tetragonal lattice complex, two titanium atoms per cell, with approximate dimensions: a = 3.12A, c = 4.18A, and c/a =1.34A. This is equivalent to a face-centered-tetragonal complex, four titanium atoms per cell, with approximate dimensions: a = 4.42A, c = 4.18A, and c/a - 0.946A. The presence of the 2.98 and 1.81A neutron lines indicates that the true Bravais lattice is not identical with this lattice complex, but may be primitive tetragonal with dimensions some multiple of those of the complex. The relative intensities of the hydride and a-titanium X-ray lines as functions of overall composition indicated that the hydride, presumably in equilibrium with the a at 100" to 255"C, contained more than 62 atomic pct H. Acknowledgments The experimental work covered in this report was done at Brookhaven National Laboratory, through the courtesy of D. Gurinsky. The cooperation of J. Sadofsky, 0. Kammerer, A. McReynolds, and A. Cendrowski is gratefully acknowledged.

Jan 1, 1957

This evening I intend to explain the position of the gold mining industry in the light of post war trends and events.I propose initially to comment on gold production throughout the World and then proceed to the state of the industry in Australia, with an account of the efforts made within the industry to maintain levels of production. This will be followed hy a statement on assistance granted to the industry by Federal and State Governments.Annual World gold production is estimated at 51,000,060 fine ounces, made up as followsSouth Africa - 27,300,000 fine ouncesCanada 4,200,000 " "U.S.A. 1,500,000 " "Australia - 1,000,000 " " Others 5,000,000 " "----- 39,000,000 " "Estimated Russianproduction - 12,000,000 " "Total 51,000,000 " "The opening up of new highly payable mines during the post war years has contributed to the preponderence of production in South Africa.In 1962 some 24 new mines produced 73 per cent of South Africa's gold, and contributed almost 90 per cent to the industrial profits.At the same time, 20 old mines were struggling to main...

Jan 1, 1964

By Xiang-yang Zhou

Keywords: Low-Grade Dolomite, Low CaO Content, High Specific Surface Area, MgO. A low energy consumption preparation technology of magnesium oxide with low calcium oxide content and high specific surface area from low-grade dolomite has been investigated. The optimum technical conditions for the preparation of magnesium oxide are the followings: dolomite is partially calcined at 750-800° for 2 h; the optimum solid-liquid ratio range in calcined dolomite slurry is 20-30 g?l?1; carbonation temperature, carbon dioxide pressure and end point pH value of carbonation are less than 40°, 0.4-0.6 MPa and 7 respectively during carbonation process; decomposition temperature of Mg(HCO3)2 solution is near 100°; calcination temperature of the precursor (i.e. precipitated basic magnesium carbonate) is less than 850°. More than 90% of magnesium can be extracted by the technology. The MgO product (CaO < 0.38%) with a specific surface area of near 50 m2?g?1 also can be obtained by the technology.

Jan 1, 2005

By M. Prats

Most of the information available on the heat efficiency of hot fluid injection processes, both water and steam, has been obtained from calculated temperature distributions in the pay zone and adjacent formations. The usual approach has been to write the heat balance equations in terms of the temperatures, and then to introduce whatever simplifications are necessary to help obtain an analytical or a numerical solution. In either case, the assumption has often been made that the vertical thermal conductivity in the flooded interval is infinite, so that the temperatures within the flooded interval are then independent of vertical position. Because it was first made by Lauwerier,l and has been used extensively since, this assumption will be referred to as the Lauwerier assumption. Excellent reviews of the literature on the heat efficiency of hot fluid injection processes have been given by Spillette,2 Flock et al.,3 and Ramney.4 Of course, the most significant contributions take into account the effect of a finite vertical thermal conductivity on the vertical temperature profile. The most general analytic expression for the heat efficiency of a hot fluid injection process is that of Antimirov5 who considers injection of a heated incompressible fluid into a reservoir through an arbitrary number of wells. The rate of heat injection into the reservoir, as well as the injection temperature, is an arbitrary function of time. The geometry of the horizontal flow is arbitrary, although the reservoir is considered to be of uniform thickness and properties and to be of infinite areal extent. Heat transfer within the reservoir is by horizontal convection and conduc- tion, and by vertical conduction. In the formations adjacent to the flooded interval, heat transfer is by conduction in any direction. Thus, the available expression for the heat efficiency due to hot water injection has been developed for rather general conditions. This degree of applicability has not been obtained for other thermal recovery processes. By making the Lauwerier assumption we have been able to obtain expressions for the heat efficiency that are essentially independent of the thermal recovery process, be it steam, hot-water, or underground combustion. Clearly, then, the approach followed here is more restrictive than that of Antimirov5 in that it uses the Lauwerier assumption. At the same time less restrictive assumptions are made about the horizontal heat transfer mechanisms, either in the flooded interval or in the formations adjacent to it. The main difference between our approach and that of other investigators is that the heat balance in the pay zone is expressed for the pay zone as a whole rather than for a volume element within it. The Lauwerier assumption is introduced after the problem is developed along these lines as far as possible. The details of the development of the heat efficiency are given in the Appendix, while the main features of the model are discussed in the next section. Results and their implications are discussed later in a separate section. The Model Certain assumptions have been made to determine

Jan 1, 1970

By R. J. McLeod

"CONTROL STRATEGYThe Lake Dufault Division of Falconbridge Copper Limited has been concentrating a complex copper zinc ore since late 1964. An ARL X-ray on stream analyzer was installed in 1966 for process control. A Digital Equip-ment Corporation PDP8 was added in 1968 for more complete control. To improve the system the computer was exchanged for a Moded PDP-81 in 1971.The new computer is time sharing with 8K core memory and 32K disc storage. A new interface was installed to accommodate 14 X-ray streams and additional analog signals for process control. The system gave us additional capacity and flexibility to make changes in operating programs and control strategy while on line. As the computer is used for process control a modified focal language was chosen as the operating language for ease of operation. This language is more suitable for process control than for statistical work.The main components of the control system are(a) Computer(b) Interface(c) Production Control X-ray Quantometer(d) Teletype terminals(e)Reagent feeders(f) Sample SystemThe operation of the system consists in the computer selecting the various streams to be analyzed by a PCXQ Quantometer. When the flowing sample is presented to the X-ray the intensities of the various elements are read by the computer from analog to digital converter, the assays are then computed. From the tonnage and assays the computer is programmed to determine the amount of reagent added to various parts of the circuit. The computer drives the feeders via the interface for the required amount of reagent. After following a certain sequence the computer prints out the performance and control data on an ASR35 Teletype. The data is printed out approximately every seven minutes. Any des¬ired changes in the program or strategy can be made during operation via an ASR33 Teletype connected to the computer."

Jan 1, 1973

By Randall Wheeler, R. Frank Chiappetta

2000 HIGH-TECH SEMINAR Blasting Technology, Instrumentation. and Explosives Applications - Orlando, Florida, USA July 24 - 27,200O 2000 BAI - PROTECTION AGAINST LITIGATION WITH GOOD PRE-BLAST SURVEYS, DAMAGE INSPECTIONS AND RECORD KEEPING 1 of 65 Good Record Keeping is Essential for: 1 ) Compliance with any prevailing Local, State or Federal Regulations, ordinances and permits. 2 ) Protection against potential litigation. 3 ) Balancing explosive consumption, use & costs. 4 ) Use in blast designs.5 ) Blast diagnostics & troubleshooting good/bad shots.

Jan 1, 2000

By Anil K. Beersing

Effective drainage systems are required for reclamation of mine-disturbed areas to control surface water runoff and avoid excessive erosion. For the conventional structural design approach, armouring material necessary to satisfy the design criteria should not move during the design flood event since displacement would uncover the erodible underlying materials. This paper discusses an alternative geomorphic approach for designing drainage channels and watershed landscape. The approach is based on quantitative studies of geomorphic processes operating in a watershed. A design based on the geomorphic approach replicates the configuration, channel regime, sediment volume and hydrology of natural and mature drainage systems. Movement of some armouring material is acceptable in such an approach because the channels are allowed to mature by natural degradation and aggradation, with erosion rates comparable to the natural environment. The key advantages of a geomorphic approach over a purely structural approach include reduced sizes of armouring material, geomorphologically sustainable landscapes, ?walk-away? or maintenance-free design and reduced liability in the future. The geomorphic approach is illustrated using the example of a coal mining operation in northwest U.S.A. The paper discusses field data collection, design criteria, typical design details, and construction methods.

Apr 1, 2005

By B. M. O'Harra

The residues resulting from the retort distillation of zinc ores have from 40 to 75 per cent of the weight of the original ore and contain from 5 to 15 per cent zinc . A rough estimate indicates that approximately 450,000 tons of residues are produced annually in the United States , containing about 36,000 tons of zinc . Besides the current production of residues there are at many smelter sites large accumulations from past operations which are available for treatment if this can be done profitably . In addition to their zinc content the residues contain much unconsumed coal , which has been carbonized during the distillation process , and those from most western ores also contain lead and silver . In this paper is summarized the information obtained in a survey , recently made by the Bureau of Mines , in cooperation with the Missouri School of Mines and Metallurgy , of processes which are in use or which have been suggested for the treatment of retort residues . The complete report of the survey is to be published as a Technical Paper of the Bureau of Mines .

Apr 1, 1923

By Shaw Bill

The paper describes of the JORC Code in terms its background working environment and reasons for success, and provides references to papers which cover the subject in more detail. It then discusses the two major developments in Australasian reporting standards in the last two years: the revision of the 1999 Code, and the introduction in early 2003 of the “ROPO” (Recognised Overseas Professional Organisation) initiative. The purpose of the JORC Code is to provide a minimum standard for reporting of Exploration Results, Mineral Resources and Ore Reserves in Australasia, and to ensure that public reports on these matters contain all the information which investors and their advisers would reasonably require for the purpose of making a balanced judgement regarding the results and estimates being reported.

Apr 22, 2003

A combined reflection seismic and magnetic survey off the south coast of New South Wales has revealed six distinct reflection horizons within the Lower Triassic-Upper Permian sequence, and has enabled the upper part of the lllawarra Coal Measures to be mapped in considerable detail. Large magnetic anomalies in the eastern half of the survey area appear to originate in the Gerringong Volcanic Sequence which forms the magnetic basement in the survey. Small residual anomalies in the western half of the area can be correlated with small scale faulting and folding in the upper part of the llawarra Coal Measures, as revealed by the seismic reflection survey.A synclinal axis striking at approximately 55&#176; has been mapped near the western margin of the survey area, and areas of faulting and folding have been outlined by combined analysis of seismic and magnetic results.

Jan 1, 1970

By Rajib K. Mohapatra, K. Vizaya Kumar

In any manufacturing organization internal logistics plays a vital role in improving and maintaining the productivity. In Ferro Alloys manufacturing organization where there is huge input of raw material in terms of ore, reductants and variety of fluxes amounting to about four times of the mass of alloy produced need to be handled from yard to furnaces , internal logistics requires utmost attention. Any deviation or mismatch between stock and requirement will affect furnace operation. Though the activities are being outsourced by most of the organization, these require close monitoring. This communication presents an optimization model which can work as a ready reference for the manager to decide upon the material quantity and the furnace to be fed with an objective of minimizing the cost of handling and zero production loss.

Jan 1, 2007

By M. C. Bétournay

Hydrogen fuel cells are a known technology, having been applied to stationary (e.g. equipment, buildings, and power plants) and vehicle applications (e.g. transit buses and space shuttles). There is currently a growing need to provide alternate power systems to diesel fuel for underground mining vehicles to improve underground air quality and reduce production costs and greenhouse gas emissions. To date, however, fuel cells have not been exposed to underground mine air and physical conditions. A testing program was carried out to provide information on the vulnerabilities of fuel cells as part of a number of proof-of-concept projects to apply hydrogen power to underground mining vehicles. The fuel cell type of choice for the industry, the proton exchange membrane, would function at the range of surface operations, and use hydrogen that is stored under low pressure and risk. A small fuel cell stack was tested in a cooperative project between CANMET, the Fuelcell Propulsion Institute, Inco, the Ontario Ministry of Labour, Sandia National laboratories, and H-Power. This article will review the tests carried out to measure the effects from high humidity, mineral dust, diesel emission gasses and diesel particulate matter, as well as from shock and vibration provided to the unit in underground conditions at Inco?s 175 Orebody minesite and Stobie mine. The test results provided will show that the unit was not affected by the underground conditions; physically and electrically, the unit performed without any reduction in operation or adverse effects imposed

May 1, 2005

By AJ Rorke, JD Botes

Presplit blasting in strip mines is aimed at creating a safer wall to work under during the coaling operations. Good quality presplits are also necessary for effective throw blasting and drainage of the blast block. A less obvious but important function is full coal recovery. Optimum Colliery has been experiencing rock freezing against the presplit highwalls. The rock formed in patches along the highwall and trapped coal beneath it. The material that was &ozen comprised the rock between the back row of holes and the presplit and was often up to 3 m thick (the stand off distance between the back line and the presplit). The cozen rock formed predominantly along the bottom halfor bottom two thirds of the highwall. Along the top portion of the highwall, the presplit crack was usually well formed with visible barrels. This problem, or similar variations of it, is common on many South African strip-mine operations. Investigative work was carried out at Optimum Colliery to correct the problem. This paper presents the information and measurements that were made and discusses the solutions that have been applied to solve the problem. It was found that there were two independent causes for the tiozen material, with each contributing more or less to the frozen rock along the highwall. It was found that the presplit was not forming properly in places, especially closer to the bottom of the highwalls. The reasons and the solutions are presented. The second cause was found to be associated with reduced detonation velocity in the back line holes coupled with low confinement from long delay periods. Emulsion explosive that is sensitised with air bubbles was found to be prone to this phenomenon near the back of high-energy blasts. A change in the explosive formulation in the back-line holes, together with reduced delays in the back line, has resulted in significant improvements. The details are presented in this paper.

Jan 1, 2000

By P. A. Plunkert, D. E. Morse, Pui-Kwan Tse, W. D. Menzie, Lucy McCartan, J. F. Papp

China’s burgeoning economy is responsible for a major share of recent world mineral consumption increases. In addition to factors traditionally recognized in market economies1 and factors unique to specific commodities, Chinese consumption now plays a major and increasingly important role in energy and mineral markets for many commodities, such as aluminum, copper, iron and steel, and oil. China has the world’s second largest economy after the United States. And its long-term importance to the minerals markets is even greater than indicated by its gross domestic product (GDP), which is currently less than two-thirds of that of the United States (Table 1). This is because China’s rising standard of living is accompanied by rapid industrialization and urbanization. Its consumption of mineral materials for infrastructure development for its very large population is significantly greater per capita than that of such developed economies as the United States, the European Union and Japan. In other words, China’s per capita production is rising at a rapid rate and will probably continue to do so for many years.

Jan 1, 2006

By M. W. Hildyard

A blast was engineered close to a tunnel in a deep-level mine with the purpose of studying the wave interaction with the tunnel. Numerical modelling of seismic wave propagation was used in both the forward planning and the back-analysis of this experiment. This paper presents the forward analysis. A likely model for a propagating blast was investigated and developed. This model predicts the influence of the velocity of detonation of the blast and the rise-time of the blast on the radiation pattern, and hence on the expected positions of maximum velocity at the tunnel surface. An attempt was made to quantify the parameters of the blast model, using waveform data from two other blast experiments. The blast model caused particle velocities which were an order of magnitude lower than these measured velocities. Large values for blast pressure were required to match the amplitudes of the recorded velocities. An alternative ?effective? source with a similar mechanism but increased diameter was proposed to account for the higher velocities. It was established that distant velocities scale with the square of the borehole diameter. A calibration blast at the experimental site was also modelled. Agreement in the waveforms was not sufficient for conclusive statements to be made about the validity of the source model. However, the modelled waveforms show an encouraging correspondence with some measured waveforms. This gave confidence that the model could be used to examine wave propagation around the tunnel, and allowed a scaled source to be developed for forward analysis of the main experiment.

Jan 1, 2001

By Christophe Thiébaut

Keywords: Pyrochemistry, Salts Treatment, Distillation The pyrochemical purification of metal generates spent salts. When this metal is an actinide such as plutonium, the slags cannot be discarded and are thus disposed in nuclear facility. In order to handle with these slags, the decision has been taken to reduce stored quantities. The development of a pyrochemical treatment is in progress in the CEA Valduc centre. The feed salt, typically composed of various Pu and Am species contained into monovalent or divalent chloride matrix, is first oxidized to convert the actinides into oxides. Then the chlorides are separated from the actinide oxides by vacuum distillation. Temperatures higher than 750°C for monochloride salts mixture NaCl/KCl and higher than 1100°C for divalent CaCl2 base salts, are required to produce an industrial flow of vaporization. Inactive qualification of the process for NaCl/KCl base salt has been carried out with lanthanide surrogates. Then, a pilot equipment, called distillator has been designed and built for production-scale distillation of NaCl/KCl and CaCl2 oxidized plutonium salts. Industrial flows of vaporization have been obtained with this pilot equipment : about 4 g/cm²/h for NaCl/KCl at 800?900°C and 1 Pa, and more than 1,5 g/cm²/h for CaCl2 base salts between 1000?1200°C at 0.1 Pa. The last step, now in progress, is the integration of the distillator into a glove box.

Jan 1, 2005

By Michael Amick

Over the last few years as the coal industry has seen an increase in the price of coal, a renewed interest in the additional mining of pre-law highwall sites has occurred. Much premium coal and property remains behind these pre-law highwalls but access to mining is limited because prior mining used auger machines to remove coal from under the highwall. Older augers seldom reached more than 200 feet and often no more than 100 feet but this zone of auger holes destabilizes the highwall to where additional mining is often unsafe. If the reserve is large enough, the highwall can be stabilized with common flyash and cement grouts to form a face-up for an underground mine but this expensive method is usually not practical for continuous use with a highwall mining machine. It is estimated there are hundreds of miles of highwall riddled with auger holes where the coal reserve available is ill-suited for deep mining for a variety of reasons. However, these same properties are ideal for additional mining with state-of-the-art highwall mining machines that have a reach up to 1200 feet, except to the relatively thin auger mined de-stabilized zone. The renewed interest in highwall mining these properties has driven research into finding an economical way to stabilize the highwall so the highwall mining machine can recover additional coal. This research discovered and fine-tuned a process that is economical and is successfully supporting the highwall at a highwall mining operation. This paper discusses the research involved in determining the strengths need, the methodology used to place any grouts, the effect on mining plans and the increased recoveries. ARMPS-HWM is used extensively in this research. The failure of the highwall, when not grouting, and the success, when grouting using the new materials and equipment utilized, confirmed the ARMPS-HWM method.

Jan 1, 2007

By Goldney L. H

The authors review the literature and discuss the application of methods to the design of thickeners for ilocculated metallurgical pulps. The use and evaluation of flocculents is described. Experimental data show that design based upon laboratory settlingdata is acceptable. The economic aspect of design is also discussed.INTRODUCTIONFor many years there has been little change in the methods for the design of thickener installations. While modifications have been made in the method of applying the data all methods have been based on the observee settling rate of the solids. The development of a theoretical approach based on physical data would involve so many variables which affect the settling rate that the more practical approach of direct observation seems unlikely to be replaced as the basis of design.The advent of synthetic fiocculents has introduced a modification in operation which affects design and should be considered. The authors review the subject and attempt to bring it up to date with present day procedure. Until recently the original work of Coe and Clevenger (1916) remained the basis of thickener design. They described their observation of the different zones encountered in settling, namely clarification, feed, transition, and compression or thickening- zones. The solids pass through the transition zone in settling from feed density to some higher density where settling ceases and &#183;some compression or compaction effect controls. the density obtained. The point at which the settling zone ceases to exist is known as the critical point.

Jan 1, 1959

By A. Garassino

A pile design was performed for a thermal power station in Egypt and more than 4000 piles were to be driven. Technical economical reasons suggested the choice of driven composite LACOR piles designed for very high specific loads. Some uncertainties on the behaviour of the pile soil system suggested to perform a test on an instrumented pile. Scope of the test was to verify the possibility of developping the required bearing capacity within the range of the allowable pile settlements values and the effect of the pile joint enlargement on that portion of skin friction to be developped by the upper pile section.

Jan 1, 1991

By M. C. Pietrobon

"A common problem in assessing the applicability of laboratory flotation data is determining how closely conditions during laboratory testing of the ore matches those that occur in a plant. Typical laboratory based investigations do not consider factors such as water quality, pulp temperature and the pulp chemical environment during both grinding and conditioning on laboratory flotation performance. Disregarding these important factors may seriously compromise the validity of conclusions based solely on laboratory experimental results. Furthermore, considering these factors during the flowsheet design stage in the development of new ore resources may reduce financial risk associated with building a new plant. A methodology is described here which embraces these factors in an attempt to bridge the gap between laboratory and plant. The methodology should be considered a vital first step in all laboratory based experimental programs and has implications for fundamental studies on the flotation behaviour of single minerals. This methodology increases the confidence with which findings of laboratory based studies can be transferred to the plant and highlights the effect of variables which may be accessible to manipulation in the plant.Pulp chemical parameters, such as pulp dissolved oxygen demand, pH, Eh, mineral oxidation and solution composition were manipulated in the laboratory by adjusting the duration of gas purging after grinding, the process water input and pulp temperature. A key finding was that matching of the laboratory pulp chemistry to the plant pulp chemistry was dependent upon oxidation after grinding. In turn, mineral oxidation was dependent upon the pH in grinding, water composition and the duration of oxygen purging after grinding. The methodology closely matched the dissolved oxygen demand and surface chemistry of laboratory and plant pulps."

Jan 1, 2002