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By J. E. House, J. L. Drobnick, R. R. Swanson, D. W. Agers

The paper describes an improved process for the recovery, purification, and concentration of copper values from acidic dump leach liquors. The process employs a new liquid ion exchange material (LIX® 64 reagent) capable of separating copper values from iron and other impurities common to dump leach liquors in the typical pH range of 1.4-3.0. Properties and performance of the reagent are discussed. Design scale-up information for both pilot plants and commercial installations, including preliminary economics, are presented. Economic considerations include the production of electrolytic copper from the purified copper aqueous concentrate. INTRODUCTION Since the commercial acceptance of the liquid ion exchange process in the mineral processing industry, it has been predicted that a wide selection of chemical reagents to efficiently and economically separate many metals in solution under a wide range of conditions would be commercially available. Several years ago, General Mills began a basic research and development program to determine if it were possible to develop a reagent to extract economically metallic ion from existing process streams. Progress toward reaching this objective was reported in late 1963, when development of quantities of LIX -63 reagent, a highly selective reagent for the extraction of copper, was introduced. The properties of this reagent are described in a previous paper.' The development work with this reagent indicated that perhaps the largest potential application for a copper extractant, the treatment of acidic dump leach liquors, would not be economically possible with LIX-63 because of limitations of the reagent to extract copper below a pH of 3.0. The relatively small pH adjustment required with LIX-63 would result in a significant processing cost and the undesirable precipitation of ferric hydroxide from the liquor. This pointed to the need for another copper extractant which would extract copper from dump leach liquors without pH adjustment. General Mills was successful in synthesizing a molecule which does not have the pH limitation of the LIX-63, yet possesses the selectivity-solubility properties required of a metallic extractant. The resulting LIX-64 reagent broadens the pH range from which copper can be effectively extracted and separated from other metallic impurities. Of special significance is the fact that the reagent, LIX-64 was developed by combining the technical requirements of a specific problem in hydro-metallurgy with theoretical organic and physical chemical principles.

Jan 1, 1967

By Sidney Katell

This report covers the period January 1962 through December 1962; it is a continuation of the series that began with the publication of Information Circular 7510 in October 1949. Also, it is the fourth in a series of reports prepared under a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers. The agreement provides for the publication of an annual cost bibliography with the work load evolved in the preparation shared equally. The abstracted articles, concerned with all facets of cost engineering in the field of chemical and petroleum plants and related subjects, are from tile following sources: 1. American Association of Cost Engineers Bulletin. 2. Bureau of Mines Information Circulars. 3. Bureau of Mines Reports of Investigations. 4. Chemical Engineering. 5. Chemical Engineering Progress. 6. Chemical Week. 7. Coal Age. 8. Coal Utilization. 9. Cost Engineering. 10. Hydrocarbon Processing and Petroleum Refiner. 11. Industrial and Engineering Chemistry. 12. Nucleonics. 13. Oil and Gas Journal. 14. Petroleum Management. 15. World Oil.

Jan 1, 1963

By Thomas M. Barczak

State-of-the-art longwall roof supports provide effective strata control, but failures of these support systems still occur. To identify failure mechanisms and the impact these failures have on the safety of the support system, the U.S. Bureau of Mines has been conducting research on shield mechanics in the Bureau's unique mine roof simulator, as well as field studies of in situ support loading and investigations of longwall failures, Three types of failures are discussed: (1) inadequate support capacity, (2) structural failure, and (3) instability. Hypothetical situations with proposed courses of action and case studies of actual longwall failures are described. This information is intended to assist the Mine Safety and Health Administration (MSEIA) and industry mining personnel in safety evaluations of longwall roof support systems.

Jan 1, 1989

By Sidney Katell

This report covers the period January 1962 through December 1962; it is a continuation of the series that began with the publication of Information Circular 7516 in October 1949. Also, it is the fourth in a series of reports prepared under a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers. The agreement provides for the publication of an annual cost bibliography with the work load evolved in the preparation shared equally. Tile abstracted articles, concerned with all facets of cost engineering in the field of chemical and petroleum plants and related subjects, are from tile following sources:

Jan 1, 1963

By L. C. Graton, Joseph Murdoch

I. Introduction......................... 26 1. The Relations of Scale in Geologic Work........ 26 2. General Characteristics of Copper Sulphide Ores..... 29 3. Scope of Present Study................. 31 11. Description of the Important Minerals............ 36 1. Pyrite....................... 36 2. Pyrrhotite....................... 41 3. Chalcopyrite...................... 41 4. Bornite........................ 40 5. Covellite....................... 50 6. Chalcocite....................... 52 7. Enargite...................... 59 8. Tetrahedrite and Tennantite.............. 61 III. Conclusions.......................... 62 I. Introduction. The Relations of Scale in Geologic Work. Many features of human accomplishment rest upon the possibility of representing natural objects on a scale of different magnitude from the actual one. Most drawings, for example, are of very different scale from that of the object depicted, and indeed are useful mainly 011 this account. More important than the question of mere convenience, however, is that of meeting the physical limitations of vision.' Thus, a mural

Jan 1, 1914

By O. W. Owings

"The handling and transportation of explosives and explosives supplies are inherently hazardous owing to their sensitiveness to impact and flame or electric arcs and sparks. Many accidents have occurred in the past during transportation of explosives, especially when they were carried by individual miners on man-trips. When electric haulage became the usual mode of transportation and shots were fired electrically, the hazards of carrying explosives and supplies on man-trips were fully realized, and in some mines all explosives were placed in one car, usually at the rear of the trip. Far-sighted managers saw the danger of this practice and provided separate trips for delivering explosives. This step was a definite advance in safety, but the latest achievement is the construction of special, rugged, nonconducting cars.Many coal-mining men have shown considerable interest in the construction of safe cars for explosives during recent months. Undoubtedly many others are interested in this phase of safety, therefore this circular is issued to give information on cars of this type now in use.Car A (fig. 1) is essentially a closed inner box separated from an outer box by an insulating lining of rubber. The double box is attached to a standard steel chassis that has spring journals and electric welding instead of certain rivets. The chassis is equipped with roller bearings. The over-all length from pin to pin is 11 feet, 9 inches; the wheel base is 54 inches, the track gage 42 inches, and the capacity eighteen 50-pound cases of permissible explosives. The box is 10 feet long, 6 feet wide, 3 feet high at the top of the arched roof, and 2 feet 9 inches at the edges. The top of the car is 46 inches above the top of the rail.The inner box is insulated from the outer box by two pieces of 1/4-inch switchboard.-insulating matting cemented together. To cover the top, two ends, two sides, and the bottom of the box requires 320 square feet of the l/4- inch matting.The walls are well-seasoned tongue-and-groove oak, 1 1/4 inches thick and 2 3/4 inches wide. A 1 1/4-inch air space is maintained by oak strips between the outer wall and the two thicknesses of 1/4-inch rubber matting. The inner box is made of 7/8-inch, well-seasoned, tongue-and groove oak fitted closely against the insulating matting. No nail, rivet, or bolt extends through the rubber insulation.The floor of the outer box is secured to the chassis by two sets of bolts through an intermediate piece of well-seasoned oak. One set of bolts is countersunk from the top of the intermediate piece of oak, and the other set is countersunk from the bottom. The countersunk portions are filled with ""insulate,"" an insulating compound. Adjacent bolts are at least 6 inches apart.The bed of the inner box is divided into six compartments by transverse strips of wood at the bottom and partitions near the roof. Each compartment accommodates three 50-pound cases of explosives. This arrangement prevents cases in adjacent compartments from touching, so that there is no possibility of end thrust of the entire load of explosives. Each inner compartment is 21 inches high, 5g inches long, and 16 1/4 inches wide. Separating strips at the floor are 3 inches wide and 1 1/4 inches thick. The outside dimensions of the 50-pound cases of explosives used are 17 1/2 inches long, 13 1/2 inches wide, and 12 1/2 inches high."

May 1, 1940

By David Siskind

The authors studied small seismic exploration blasts for vibration characteristics and effects on structures in Mexico. Obtained were 267 three-component recordings of ground vibrations and structure responses from 62 test blasts at six single-story masonry structures. Charges were 4.55 kg (10 lb) of Vibrogel expolsive at depths of 20 and 30 meters. Initial blasts were 240 meters distant and proceeded towards the structures to as close as 5 meters. All blasts were in soil media in two basic types of terrain, low saturated areas and upland dry areas. Structural inspections were before, during, and after the test blasts.

Jan 1, 2002

The Wamum and Idzan Creeks Prospect, located 79km W of Lae, Morobe Province, Papua New Guinea (PNG) was discovered by the exploration arm of Conzinc Riotinto of Australia Pty Ltd (CRAE). The detailed surface exploration and 11 vertical holes drilled by CRAE, combined with the recent work by Highlands Gold Limited, indicate the occurrence of porphyry copper-gold mineral- isation and associated alteration. The prospect occurs within andesitic volcanics of the Middle Miocene Langimar Beds. It is bounded by NE trending faults to the NW and SE. The alteration and mineral- isation is hosted in the andesitic tuffs adjacent to high level quartz diorite and hornblende diorite stocks. A NW trend to alteration and mineralisation is obvious in Wamum and Idzan Creeks. The main alteration type is propylitic with minor zones of potassic alteration. A late sericite-quartz-kaolinite-pyrite alteration overprinted the earlier alteration and mineralisation. Copper and gold mineralisation is related to a quartz-carbonate-chalcopyr-ite-pyrite (¦ bornite) vein stockwork and biotite ¦ K-feldspar alteration. The mineralisation system at Wamum and Idzan creeks is low in total sulphides. It is considered as a high- level fracture-controlled system with limited low grade Cu-Au mineralisation.

Jan 1, 1991

By M. Mirnezami, D. Lascelles, J. A. Finch, E. El-Ammouri

"In a previous publication, the depressant action of Mg above pH 10 on Cu-activated sphalerite was described (Lascelles et al., 2001). In the present communication, a second role, aggregation is introduced.Aggregation (i.e., the tendency of particles to cluster) is measured using settling rate and turbidity converted to an aggregation index (AI) where 0 corresponds to dispersed and 1 to aggregated. Surveys of Cu and Zn flotation stages at four concentrators showed the A1 increased significantly above pH 9. The metal ions identified in the process waters, principally Ca and Mg, were tested to determine which might be responsible. The presence of Mg was found to be the most important, 50 ppm Mg having a greater impact than 500 ppm Ca fkom pH 9 to 1 1. In one plant, poor repeatability in A1 was suspected to be related to varying Mg levels; doping with Mg significantly increased AI.In both aggregation and depression, therefore, the common feature is the impact of Mg at pH > 9. Over this pH range Mg forms a range of hydroxy species, including Mg(OH)2 precipitates. Suggested aggregation and depression mechanisms associated with these precipitates are introduced. Possible problems and opportunities arising from the findings are discussed.INTRODUCTIONProcess waters in flotation circuits contain a variety of metal ions that may introduce unwanted activation or depression. Two common metal ions are calcium and magnesium. Typical concentrations are in the range 50 ppm Mg and 500 ppm Ca (Marticorena et al., 1994, Basilio et al., 1996, Negeri et al., 1997, Nesset et al., 1998)."

Jan 1, 2002

By R. Ressel

Keywords: ferrovanadium, thermodynamics, phosphorus Recyclable material is rapidly gaining in importance as a source of raw materials in industrialized countries. This is also the case in the production of ferrovanadium, where, increasingly, materials such as discarded capacitors, spent catalysts, slag, dust and sludge are used. As the V-content in the raw material varies greatly, the demands on process technology are very high. The share of perturbing elements depends very much on the source of the raw materials, which, in turn, makes a corresponding optimization of the various refining steps necessary. The raw materials are mostly available as oxides, which means that carbon, silicon or aluminium are used as reducing agents. Thermodynamic calculations were used to show especially the behavior of vanadium and phosphorus at different process conditions.

Jan 1, 2005

By William J. Krisko

This contract final report summarizes the design, fabrication and testing of canopy air curtain devices under Bureau of Mines Contract H0232067. The canopy air curtain device is designed to reduce the level of respirable dust exposure to a continuous mining machine operator while having a minimum effect on operator safety, mobility and comfort and being compatible with mining equipment. This contract was devoted to the development of a device which utilizes an invisible curtain of air to envelope a mining machine operator's breathing zone with filtered air to provide respiratory protection. Various concepts were evaluated by means of laboratory tests. One concept was selected and was tested on various mining machines at underground sites by means of MSA personal samplers. The canopy air curtain was found to be effective. The percent reductions over the ambient dust concentrations were about 30 to 75 percent depending on the amount of time the operator spent under the air curtain. At one test site, the device enabled the mining machine to operate within compliance. Donaldson Company is presently working on the commercial production of the device.

Jan 1, 1975

By L. Yuan, A. Smith

In order to provide insights for the optimization of ventilation systems for U. S. underground coal mines facing both methane control and spontaneous combustion issues, a computational fluid dynamics (CFD) study was conducted to model the potential for spontaneous heating in longwall gob areas. A two longwall panel district using a bleeder ventilation system was simulated. The permeability and porosity profiles for the longwall gob were generated from a geotechnical model and were used as inputs for the CFD modeling. In this study the effect of methane emissions from the mined coal seam, including the longwall face and overlying rider seam reservoirs on the gob gas distribution was considered. The spontaneous heating is modeled as the low-temperature oxidation of coal in the gob using kinetic data obtained from previous laboratory-scale spontaneous combustion studies. Unsteady state simulations were conducted and the effects of the coal’s apparent activation energy and reaction surface area on the spontaneous heating process were also examined. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health.

Jan 1, 2007

By P. C. Holloway, A. Tshilombo, T. Xue, M. J. Collins, R. Lopetinsky, I. Mihaylov, I. M. Masters

The Voisey’s Bay deposit contains a trace amount of cadmium, which reports to solution during pressure leaching of the nickel concentrate at Vale’s Long Harbour Hydrometallurgy Plant, and must be removed to produce high quality nickel cathode. In 2006, Vale approached Sherritt Technologies to collaborate on the development of a process for removing cadmium to low levels (<1 mg/L) in the nickel raffinate. Following successful bench scale and pilot plant testing at Sherritt’s laboratories, the cadmium removal process was then moved through engineering and construction, culminating in the successful commissioning and startup of a cadmium removal circuit at the Long Harbour Hydrometallurgy Plant in 2017. This paper presents the results of this collaboration and the challenges that were encountered through each stage of development, as well as current results from operation of the commercial cadmium removal circuit. INTRODUCTION Vale’s Long Harbour Processing Plant, with a nameplate capacity of 50,000 t/y nickel, began operation in 2014. In addition to electrolytic nickel rounds, the plant also produces electrolytic cobalt rounds and copper cathode. The Long Harbour Processing Plant uses a unique hydrometallurgical process developed by Vale Base Metals Technology Centre, as shown in Figure 1, to treat a nickel sulphide concentrate produced at the Voisey’s Bay mine and mill located in northern Labrador (VBN concentrate) (Stevens et al., 2009).

Jan 1, 2019

By Shaw-Shong Liew

This paper presents the design concept using floating piles to support 2500Ton oil storage tanks on a very soft alluvial clayey soil of about 40m thick in Riau Province of Sumatra, Indonesia. The floating piles of various penetration lengths were designed to support seven numbers of such storage tanks seating on a 20m diameter and 500mm thick reinforced concrete (RC) circular raft. The pile points have been strategically located at the RC raft. Varying pile penetration lengths have been designed to minimize the angular distortion of the thin RC raft and the out-of-plane deflection at the tank edge. Vibrating wire strain gauges were installed at different levels inside the ø350mm prestressed reinforced concrete piles to measure the load transfer profile during the static load tests and water-loading test. The installation and interpretation of the instrumentation are described and discussed. Boreholes, in-situ tests like piezocones, vane shear tests and standard penetration tests, and laboratory testing were carried out to obtain geotechnical parameters for the pile designs. Static load tests were also carried out on the spun piles of varying lengths of 24m, 30m and 36m respectively. It has been demonstrated that the floating pile system can be a cost effective design to support heavy structures on very soft compressible deposits with satisfactory performance. Finally, the design concept validated with the results of instrumentation is discussed.

Jan 1, 2002

In 1960, the Secretary of the Interior, acting under the provisions of Public Law 454, 80th Congress, appointed a Lignite Advisory Committee to aid in programming research on coal (lignite) of the north-central area. The chairman of this committee is the Secretary of the Interior or his delegated representative, and in all meetings held during 1960 and 1961, the Director of the Bureau of Mines, Marling J. Ankeny, has presided. The members of this committee were R. W. Rovelstad, President, Baukol-Noonan, Inc., Noonan, N. Dak. W. E. Keller, Vice President, Northwest Division, Truax-Traer Coal Co., Minneapolis, Minn. A. M. Cooley, Professor of Chemical Engineering, University of North Dakota, Grand Forks; N. Dak.

Jan 1, 1963

By Zia Zafir

Design of the deep foundations for the loads imposed by lateral spread include the estimate of the pressure applied by the liquefied material as well as amount of anticipated displacement. In the absence of a non-liquefiable cover over a liquefiable layer, it is possible to design the foundation system just for the additional pressure applied by the flow slides. On the other hand, if a non-liquefiable layer exists above the liquefied zone, the foundation should be designed for anticipated movements. To completely account for liquefaction and/or lateral spread and their interaction with the deep foundation system, a coupled soil-structure interaction (SSI) analysis should be performed. However, a complete SSI analysis may not be feasible for most of the projects. This paper will present recent advances in analysis techniques and simplified methods to design deep foundations for liquefaction and lateral spreading. In addition, a case history of the Rancho California Bridge in southern California located within 1 km of the active Elsinore fault will be presented. One of the bridge abutments is underlain by potentially liquefiable layers. The pressure applied by the liquefiable layer was estimated to be greater than the shear capacity of the 36-inch CIDH piles designed for the abutment. However, with limited ground improvement and more careful analyses incorporating structural effects of CIDH piles, resulting design and construction resulted in a factor of safety greater than 1 against slope failure. The recommended approach was generally consistent with the recently published, and AASHTO sponsored, NCHRP 12-49 project regarding seismic design guidelines for new bridges and the effects of seismic displacements against bridge foundations.

Jan 1, 2006

"The Ernest Henry Mining (EHM) ore body is an iron oxide copper gold deposit with an average grade of 1.1 percent copper, 0.5 g/tonne gold and 22 percent magnetite. At the end of 2009, EHM converted the ball mill media charge from forged steel to high chrome media. At high pH values (above 10.5), forged media is passivated, so as the pH of the system drops the media corrosion rate increases and floods the system with corrosion products, affecting flotation. As the high chrome media is much more inert, pH has less of an effect on copper flotation response. Given this, the pH in the roughers was dropped from 10.6 to 9.6 and it was found that there was a slight increase in copper recovery and no statistical change in either the rougher or final copper concentrate grades for copper and gold. With the reduction in pH, there was a noticeable reduction in lime usage from 0.85 kg of lime per tonne of ore processed to 0.55 kg/t. This reduction in lime is equivalent to approximately $700,000 per annum at current production rates.INTRODUCTION The Xstrata Copper Ernest Henry Mine (EHM) is situated 38 km north east of Cloncurry, Australia. The mine began as an open-cut operation in 1998 and transitioned to a multi-sourced operation in December of 2011, utilising ore from the newly completed underground mine in addition to ore mined from the Mount Margaret Mining operations. EHM produces a combined copper gold concentrate containing 25 000 t of copper and 35 000 oz of gold annually, utilising a three stage grinding circuit along with a four stage flotation circuit. In addition to this EHM also produces 1 000 000 t of magnetite concentrate annually via a further grinding and three stage magnetic separation circuit. Based on metallurgical test work performed by Magotteaux between 2002 and 2008, the step to change from forged steel media to 18 percent chrome media was taken in 2009 in a bid to alter the pulp chemistry to improve the flotation performance in the plant (Greet, Kinal, Twomey, & Peatey, 2010). This plant trial resulted in: • Increased dissolved oxygen levels within the pulp, • A ball mill discharge Eh shift of 25 mV to more oxidising pulp potentials, and • An EDTA extractable iron percentage reduction. These improvements in the pulp chemistry resulted in an increase of 1.7 ± 0.6 percent in copper recovery and an increase of 2.9 ± 1.7 percent in gold recovery. As the plant trial using high chrome media was successful, the use of the media was adopted as the standard for the ball mill. This implementation opened the door for further process improvements around the flotation circuit."

Jan 1, 2014

The development and introduction of a preventive maintenance scheme in the coke ovens department, coal preparation section, of The Broken Hill Proprietary Co. Ltd., Newcastle steelworks, is described together with its operation and the results achieved during the first 12 months.&apos;fhe scheme consists essentially of an engineering analysis of the plant to establish maintenance schedules, and to record the details on reference cards.Items are reviewed progressively and a weekly work schedule is prepared, from which work orders are passed on to the maintenance foremen. These foremen in turn originate action orders and issue inspection sheets as required. Results are then reported back to the maintenance planner and used to revise norms, practices, and cycles.INTRODUCTIONWhat is maintenance? Some people consider maintenance to be the work involved in putting things together again after they have fallen apart. The author regards it as the mechanical care and repair of plant machinery and equipment to keep it operating in sound mechanical condition, without undue interference with production processes.Maintenance may be organized or haphazard, and, too often, what has been fondly imagined to be nicely controlled and organized maintenance proves, under pressure, to be more correctly described as haphazard. Haphazard maintenance deals with breakdowns as they occur, and frequently finds itself confronted with more breakdowns than can be handled. Even organized maintenance, if not based on sound planning, can, at times, be found in a chaotic state, because of unexpected and unanticipated breakdown.Properly planned and scheduled maintenance permits an orderly and controlled approach to the problem of maintain...

Jan 1, 1961

By K J. F Logan, P W. Leaman, B A. Tucker

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Nam San copper-gold deposit was discovered in 2011 and is a likely blind extension of the Permian age Phu Kham structurally deformed porphyry/skarn copper-gold deposit.The Nam San mineralisation is hosted within a dominantly sericite altered schist unit located to the north of the current Phu Kham open pit operation and is overthrust by an allochthonous barren cover sequence of limestone, granite and sandstone. Reinterpretation of the Phu Kham geology developed the concept of a possible telescoped porphyry copper-gold system at depth. Initial drilling intersected remobilised copper mineralisation in a basal conglomerate, confirming the concept. A reconnaissance vector array induced polarisation (IP) survey identified a deep chargeability anomaly from which a drilling target was developed from 3D inversion modelling of a detailed follow up dipole-pole-dipole anomaly. Drilling of the chargeability anomaly intersected the blind Nam San copper-gold mineralisation beneath the thrusted cover sequence.The key discovery parameters are the result of an integrated exploration program that included reinterpretation of the local stratigraphy, which developed the concept of a deep blind orebody, IP surveys capable of penetrating through the barren cover and a commitment to a deep directional drilling program to test these concepts and targets. The inferred resource remains open at depth, and further assessment will most likely be through underground development.CITATION:Leaman, P W, Tucker, B A and Logan, K J F, 2015. The discovery of the Nam San copper-gold deposit, Phu Kham, Laos, in Proceedings PACRIM 2015 Congress, pp 515–520 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Levent Ozdemir, Robert J. Evans, Russell J. Miller, William Sharp

This paper describes the specifications and capabilities of a 6 ft (1.83 m) diameter laboratory rotary cutting machine which was designed and fabricated under a Bureau of Mines (USBM) contract awarded to the Colorado School of Mines (CSM). The machine will be used for carrying out research and development programs aimed toward improving the design and operation of mechanical tunnel, raise and shaft boring equipment.

Jan 1, 1983