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By Robert L. de Beauchamp

The Bureau of Mines reviewed aluminum chloride technology to determine the problems associated with its preparation from minerals, and to ascertain the best areas for research to solve these problems. Commercial AlC13 production processes are described and the ?state of the art? for the preparation of AlC13 from aluminous materials is evaluated. Areas for further research are indicated.

Jan 1, 1969

By William G. Pariseau

A small displacement-small strain finite element technique utilizing the constant strain triangle and incremental constitutive equations for elastic-plastic media that are nonhardening and obey a Coulomb yield condition has been applied to the analysis of gravity flow initiation in a V-shaped hopper containing a powder under lunar environmental conditions. Three methods of loading were examined. Of the three, the method of computing the initial state of stress in a filled hopper prior to drawdown by adding material to the hopper layer-by-layer is superior (as expected). Results of the analysis of a typical hopper problem show that the initial state of stress, the elastic moduli, and the strength parameters have an important influence on material response subsequent to the opening of the hopper outlet.

Jan 1, 1971

By E. S. Shedd

Misch metal was electrowon from a treated bastnasite concentrate in a REF3-LiF-BaF2 electrolyte at 950° C. The metal was prepared and tapped from a 1,000-ampere cell, and nearly 100-percent utilization of the rare-earth oxide was achieved. Prolonged operation in a smaller cell (40 amperes) indicated that the composition of the misch metal product was reasonably constant, and no significant increase of impurities, with the exception of carbon, was noted.

Jan 1, 1970

By R. F. Droullard

The Bureau of Mines has developed test facilities for use in a research program that deals with radiation hazards in mining. This report describes the radon test chamber located at the Denver Research Center and the Twilight experimental mine located near Uravan, CO.

Jan 1, 1984

By R. L. Montgomery

Heats of solution of yttrium chloride and oxide in hydrochloric acid were measured by Bureau of Mines researchers. Using the heat of combustion of yttrium mentioned in the literature, the Bureau calculated the heat of formation of yttrium chloride to be -239.16 + 0.50 kcal./mole. The Bureau experiments gave evidence that the heats of solution of yttrium chloride from the literature are mostly too low because of water and/or oxychloride impurities. Heat of combustion of yttrium (8)3/ and its heat of solution in hydrochloric acid (2, 14) have been measured. The earlier heat of solution measurement (2) is unreliable because of possible potassium contamination (4). Heat of solution of yttrium chloride has been measured by three researchers (3, 9, 15), who obtained widely different results. Spedding and Flynn (14) report the heat of formation of yttrium chloride as -232.69 kcal./mole from their solution studies. The present work was designed to check the reported heats of solution of yttrium chloride and to determine the heat of solution of yttrium oxide. The latter measurement would allow the results of solution and combustion data for yttrium to be intercompared.

Jan 1, 1960

By R. E. Brewer

Published investigations show that many different chemical reagents have been used in determining the constitution of coals , but only a few studies have been applied directly in evaluating the effects of such reagents on the carbonization products of coal , Most of the treatments have been so drastic that any permissible conclusions that may be drawn are inferential in respect to any favorable effects on the yields and composition of the usual carbonization products .

Sep 1, 1943

By G. E. McElroy

This report discusses the construction and use of an all-pressure psy- chrometric chart in which the requirements of simplicity of appearance and absolute accuracy have been waived, to a certain extent, to provide for the rapid determination of psychrometric data and for the rapid solution of air- conditioning problems of major interest to the mining industry. Many mines in which air-conditioning problems are important are situated at elevations far above sea level and embrace great differences in elevation - in excess of 8,000 feet in certain mines → throughout their airflow circuits. Under these conditions, the effects of variations in the pressure of the at- mosphere upon the physical properties of the mixture of air and water vapor of which it is composed are considerable and should be taken into account in the solution of problems. The simple types of psychrometric charts in common use, such as the Carrier, Bulkeley, Hill, and Goff (American Society of Heat- ing and Ventilating Engineers Guide), are not generally suitable, in that they are drawn for a single barometric pressure 29,92 inches mercury.

Dec 1, 1947

By Robert M. Doerr

Isothermal oxidation kinetics were determined for three grades of Ni and for 99.99 percent Co in Ca and in air from 800° to 1,200° C. The oxidation reactions followed approximately the parabolic rate law. For 99.99 percent Ni in 02 at 1,200° C, the parabolic rate constant was 2 mg cm-2 hr-2. For 99.99 percent Co in dry air, the constant ranged from 1 mg cm-2 hr-2 at 800° C to 18 mg cm-2 hr-2 at 1,200° C; for 99.99 percent Co in 02 the constant was 2 mg cm -2 hr-2 at 800° C and 10 mg cm-2 hr-2 at 1,000° C. For 99 percent Ni in dry air, the constant ranged from 0.2 mg cm 2 hr-2 at 800° C to 3 mg cm 2 hr-2 at 1,200° C. By X-ray diffraction measurements, only divalent oxides were found in the scales. Volumetric and quartz-helix gravimetric methods were used. The volumetric apparatus was designed to permit less stringent restrictions on the corrosion specimens; it was also more convenient to use. The agreement between the weight gain determined gravimetrically and the 02 consumption determined volumetrically was not good enough for direct comparison of gravimetric and volumetric results.

Jan 1, 1963

By L. A. VANFLEET, Allen D. Look

The ever -present danger of mine fires and the possibility of hazardous atmospheric conditions in underground mines make a well-equipped mine rescue station a valuable asset to any mining district . Rescue equipment without proper maintenance provides only false security , because neglect may make the apparatus unfit for use in an emergency . Promptness in fighting mine fires is important ; frequently the first 30 minutes of action are worth many hours later . Likewise , the equipment will be of little value if enough men trained in its use are not readily available . This circular points out how such protection has been provided in an Arizona mining district by establishing a well- organized , adequately equipped , central mine rescue station. ·

Aug 1, 1950

By L. S. Sundae

The Bureau of Mines conducted a series of tests to compare the cutting forces required by radial and point-attack bits when making similar cuts. Three radial and four point-attack bits were tested in two coal mines using the Bureau's in-seam tester to measure coal-cutting forces in situ. Tests were also conducted to investigate the effects of weathering and cleating. The test results show that in each case, at a specific clearance angle, the radial bits required less tangential and much less normal force than the point-attack bits. The resultant of the cutting forces for some types of cut was 50 pct less at mine 1 for radial cuts compared to cuts with the best point-attack bit, and 40 pct less at mine 2. There was some difference between three types of radial bits, but it was not as significant as the difference between each type of point-attack bit. Cutting coal perpendicular to the cleat planes required less cutting and normal force than the same type of cuts parallel to the cleat planes. Test results showed no effect due to weathering on cutting force data. Cutting parallel increased forces only because cuts were made in the rock band.

Jan 1, 1987

By W. A. Grosh

The Piquette Mining and Milling Co, operates a zinc mine and concentrating mill in the Upper Mississippi Valley zinc-lead district near Tennyson, Wis. The principal ore mineral is zinc sulfide, which occurs in limestones and dolomites of the Decorah formation. Exploration in the district is by churn drilling from the surface. An adit at the base of the ore zone provides access to the mine. A room-and- pillar mining method with irregular pillars is used. Drilling is done with Jumbo-mounted drills. The broken ore is loaded by crawler-mounted front-end loaders into diesel-powered trucks for haulage direct to the mill.

Jan 1, 1959

By James A. Browning

Conventional flame channelling operates continuously at over 120 db --flame-drill channelling at a maximum of 95 db. The latter process was developed under this program. Individual drill holes are spaced to leave narrow rock webs. Sound and dust passing from the hole are effectively treated by a muffler and water injection.

Jan 1, 1980

By D. J. Bauer

The Bureau of Mines demonstrated the feasibility of fractionating lanthanide nitrates with a tertiary amine on lanthanum-cerium and thulium-ytterbium pairs. Optimum values were determined for pH, phase concentration, and percent chelation of metal ions in the aqueous phase. Percent extraction is markedly dependent on the concentration of lithium nitrate in the aqueous phase. Selective masking of the heavier element in each extraction system with DTPA or EDTA aqueous-phase chelating agents resulted in lanthanum-cerium separation factors of 8.5 and thulium-ytterbium separation factors of 3.4.

Jan 1, 1966

By F. G. Horino

The Bureau of Mines conducted compressive strength tests on model pillars of selected rock types with each pillar containing a critically oriented plane of weakness. The objective of these tests was to determine if a significant increase in the strength of the model pillar could be obtained by either (1) installing tensioned rock bolts through the pillar and normal to the plane of weakness, or (2) wrapping tensioned steel wire ropes around the pillar at uniformly spaced intervals along the pillar. Equations based on Coulomb's failure criterion are developed to predict uniaxial compressive strength of model pillars that are either rock-bolted or wire-roped. Laboratory compressive strength tests on unbolted and bolted model pillars of sandstone, marble, Indiana limestone, and oil shale containing a plane of weakness oriented at 45° showed that the bolted pillars are stronger than the unbolted pillars by 84, 31, 52, and 28 pct, respectively. Laboratory compres-sive strength tests on nonroped and roped model pillars of Texas limestone, sandstone, and granite containing planes of weakness showed that the roped pillars were stronger than the nonroped pillars by factors ranging from 1.01 to 2.41, depending upon the angle of the plane of weakness and the rock type. Rocks with a low Young's modulus benefited most by the wire-roping technique.

Jan 1, 1971

By J. L. Johnson

The U.S. Bureau of Mines investigated the recovery of tin and silver from the Coal Creek deposit in the Talkeetna Mountains, AK. Approximately 5 million st of reserves grading 0.2 pct Sn with silver credits of 0.2 tr oz/st have been delineated by drilling. A 10-to 25-pct Sn gravity concentrate was produced by treating the minus 20-mesh ore with a spiral, then regrinding to minus 65 mesh and tabling. Sulfide contamination in the gravity concentrate was as high as 60 pet. Sulfide flotation of this concentrate produced tailings containing 40 to 50 pet Sn. Overall recovery was 76 pct for tin but only 5 to 10 pct for silver because of losses during sulfide flotation. Other methods tested to clean the concentrate included cassiterite flotation, gangue flotation, nitric acid leaching, and wet and dry magnetic separation. Tin beneficiation tests on the minus 325-mesh fraction included cassiterite flotation, vanning, sulfide flotation, and fuming. The bench-scale and locked-cycle tests were used to estimate the mass flows for a 1,000-st/d plant.

Jan 1, 2010

Objective To develop a passive, inexpensive technique for monitoring explosion overpressures within sealed areas in underground coalmines. Background From 1994 to 2000, seven explosions of methane and/or coal dust occurred within the worked-out, sealed areas (gobs) of underground U.S. coal mines. These explosions, believed to have been started by lightning, destroyed many seals and caused much damage external to the sealed area. One gob explosion went undetected until the mine operator reopened the sealed area and discovered the damage. Fortunately, these gob explosions did not cause any fatalities or injuries. Because lightning occurs in just about all mining areas, several questions arise. Could gob gas explosions be occurring in other sealed areas and going undetected? If so, what is the magnitude of the resulting explosion overpressures? The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) undertook a study to identify and evaluate passive measuring devices to monitor and quantify the overpressures associated with such explosions. This work was done in parallel with full-scale explosion experiments for evaluating the strength characteristics of seals used for isolating areas in underground coal mines. Approach Evaluation studies were done in PRL's 20-liter explosion test chamber and in the full-scale Experimental Mine at Lake Lynn Laboratory to evaluate the response and accuracy of various commercially available automobile tire pressure gauges to overpressures generated from gas and dust explosions. The first series of tests was done in the 20-liter chamber, which is used to study the explosibility and inerting of fuel dusts and gases. Data from the tire pressure gauge tests were compared to the pressure-time data obtained from the 20-liter chamber 's traditional electronic strain gauge pressure transducer recorded on a high-speed data acquisition system. To evaluate the tire pressure gauges, the valved inlet (tip) of the candidate pressure gauge was removed and the body of the gauge was cemented with epoxy into a 0.25-in pipe elbow and attached to the outside of the test chamber. A second series of tire gauge evaluation tests was done at Lake Lynn during explosion-resistance testing of seals used in underground coal mines. Full-scale seals (20 ft wide by 8 ft high)were constructed as one wall of a 2,000-ft3 chamber and exposed to a series of methane explosions. Average overpressures ranged from20 to 80 psi. The seals were built with various strength materials ranging from 7 to 48 in thick. The modified tire gauges are attached on the outside of the chamber to a 0.25-in NPT pipe that extends into the chamber (figure 1). The axis of the gauge is mounted at a right angle to the plane of the seal to minimize the coupling of any seal movement to the stem of the gauge that may cause inaccurate readings. The internal explosion pressure history is recorded with a strain gauge pressure transducer mounted inside the chamber. Methane is injected into the chamber, mixed with air, and ignited with an electric spark located at the geometric center of the chamber. Maximum explosion overpressures are recorded and compared with the tire gauge pressure.

Jun 1, 2001

By J. E. Chilton

Interim performance specifications are presented for carbon monoxide, methane, and air velocity transducers used in the Bureau of Mines intrinsically safe mine monitoring system. These specifications give quantitative values or qualitative descriptions of the transducers, including environmental parameters and monitoring system measurement and maintenance requirements as recommended by the Bureau of Mines. Commercially available transducer modules and prototype modules are listed together with selected characteristics.

Jan 1, 1983

Unfortunate occurrences resulting in injuries, loss of life, and destruction of property by explosion, fire, and other mishaps during shaft sinking in the past few years have focused the attention of the Bureau of Mines on the need for safety standards for such operations. Several States have some rules and regulations applicable to local conditions, and several Bureau publications (including some now out of print) cover the hazards that may be encountered in shaft sinking. Certain requirements of the Federal Mine Safety Code and Federal Coal Mine Safety Act may be applied, but there are no definite, uniform standards that will guide those desiring to sink a shaft safely and bring about uniform safety inspections.

Jan 1, 1957

By Stephen C. Tadolini

The U.S. Bureau of Mines conducted a laboratory investigation designed to evaluate the stress and deformation characteristics of fully grouted roof bolts subjected to various magnitudes of end loadings. The experiment and subsequent analysis were completed, utilizing axial deformation data obtained -ultrasonically from forty-one 4-ft, grade 40 roof bolts, with a total of 132 measurement locations along the lengths of the bolts. The ultrasonic measurement instrumentation used in this investigation allowed for elongation measurements without requiring extensive bolt modifications. The results indicate that approximately 39 pct o{ the applied end load dissipated within the first 3.4 in of the bolts. However, only 3 pct of the applied load was realized beyond 28 in of the grout column. Data are presented individually for every 6-in increment of bolt length, and analysis was performed using statistical, nonlinear equations developed for 5,000 and 8,000 lb loading conditions.

Jan 1, 1990

By Oliver Bowles

The use of fire as a source of heat was the first step from primitive existence toward modern civilization, and heat has performed functions of inestimable importance throughout the ensuing ages. The first commercial steam engine invented in 1698 demonstrated that heat was an important source of power, and heat has since become the motivating force for railroad trains and steamboats as well as for machines in multitudes of factories. Aside from its function of supplying power, heat is an agent of vast importance in chemical reactions and engineering processes. Because of the high temperature of steam under pressure, losses by radiation from boilers and pipes become excessive unless the radiating surfaces are covered with insulating materials. Insulation is important also for hot-water pipes and many other types of equipment from which heat may radiate. Radiation losses from heated surfaces increase rapidly

Jan 1, 1943