Search Documents

By Bakker J. de, P. A. Leest, W. L. Dalmijn, H. J. Glass

The test facility at the Delft University of Technology, in the Netherlands, was characterised. Advantages include the possibility of separating particles with high but different densities up to 9 g/cm3, the ease of adjustment to any required separation density and the absence of moving parts. Simultaneous separation of more than two types of particles is possible and the magnetic fluid is safe and convenient to use compared with other heavy liquids. Disadvantages include loss of magnetic fluid with outgoing particles (cost approx US $10/l) and degeneration of fluid due to bacterial activity, reaction with particles and with surroundings. Only non-magnetic materials can be separated, there is limited potential for scaling up and high investment is required on account of the cost of magnets. Future improvements in the design of the apparatus and the properties of the magnetic fluids can only enhance its attractiveness for commercial applications

Jun 18, 1905

By S. Kelebek, J. A. Finch, Zhenghe Xu, S. R. (Ram) Rao

To improve SO2 emission compliance, pyrrhotite from Sudbury copper-nickel ores is being depressed with DETA. To understand the mechanism of depression, the role of complexing in controlling metal-ion activation of pyrrhotite was investigated. DETA was found to remove Cu and Ni ions but leave hydrophilic ferric species on the pyrrhotite surface. The metal:DETA ratio appeared to be 1:2. Cu was more readily removed than Ni, but the combination of DETA with sulphur dioxide was equally effective for both metal ions. Certain combinations of DETA, Ni ions, xanthate and dithionite (S2O4) or dithionate (S2O6), as representative derivatives of SO2 in water, produced hydrophilic precipitates. These may enhance pyrrhotite depression

Jun 19, 1905

Two concentrates from Palabora, in South Africa, containing 0.056-0.068% undesirable Cu and 0.8 or 2.2% Ti, were chlorinated with air:chlorine ratios of 10:1, 15:1 and 20:1 at temperatures between 1 200 and 1 329 K. The resulting volatile chlorides were condensed and the solutions analysed for Cu, Fe and Ti. Recovery of Cu was less than 25% at low temperatures and short reaction times, but at 1 258 K almost all Cu was removed from the magnetite at all ratios of chlorine to air. At higher temperatures, the increased carrying over of iron as FeCl3 could be minimised by decreasing the partial pressure of chlorine. No titanium was detected in the volatile products and the percentage of Cu recovered was independent of Ti concentration in the concentrates, though as a function of Cl2 vol%, more Cu was recovered at 1 200 K from the low-Ti than from the high-Ti concentrate. In a fluidised-bed reactor, Cu recovery was 58-90% and iron carry-over less than 10 ppm

Jun 21, 1905

By H. Y. Sohn, Hang Goo Kim

Computer simulations were carried out using calcium ferrite slags containing 25 wt% CaO, and the results compared with those obtained using fayalite slags. There was little difference in overall elimination of Pb and Bi, but elimination of Sb and As was much lower with calcium ferrite slag. When calcium ferrite slag is used only in the converting stage and fayalite slag in the smelting stage, as in the Mitsubishi process, the contents of Sb and As in the blister copper can be kept to reasonable levels. This allows advantage to be taken of the considerably higher iron oxide-holding capacity of calcium ferrite slag than of fayalite slag at the high oxygen potential under converting conditions, thus preventing precipitation of magnetite. Satisfactory agreement was obtained between predicted values and observed data from a Mitsubishi converter

Jun 18, 1905

By B. Tiryaki, O. Z. Hekimoglu

Shearer drums are a critical component in the overall performance of coal shearers, with the cutting performance depending very much on the disposition of cutter tools on the drums (the tool-lacing arrangement). A series of practical and theoretical studies has been undertaken to investigate aspects of shearer drum vibration in terms of circumferential pick spacing. A number of commercially available drums were redesigned and the lacing patterns compared with those of the original drums under near-uniform conditions. Mine trials were carried out at the Middle Anatolian lignite mine in Turkey with drums fitted on Eickhoff type EDW-230 double-ranging drum shearers. It was found that the performance of drums could be improved if the concept of circumferential pick spacing was taken into account in CAD packages along with the existing design parameters such as cutting rate, reduced dust, low pick consumption and low down-time

Jun 19, 1905

By P. E. J. Pitfield, S. D. G. Campbell

The regional shear zone runs along or near the southern margin of the Chinhoyi greenstone belt. It hosts four of the seven mines in the southern part of the belt with recorded production above 100 kg Au, including the top two current producers. Displacement occurred in the late Archaean, producing a shear zone with a trend ranging from northeast at Golden Kopje to east at Muriel. The orebodies at the two mines formed synchronously with the shearing and show strong but contrasting structural controls on mineralisation. The Golden Kopje orebodies plunge to the southwest, parallel to the intersection of curved foliation with discrete shear planes and sub-perpendicular to local stretching lineations. The Muriel orebodies plunge steeply west but parallel to local stretching lineations. The greatest fluid flow during mineralisation of the shear zone was along either the intersection of fabrics (Golden Kopje) or the extension direction (Muriel). There is no unique relation between the orebodies and the extension or shear direction. Where earlier mining has not established the directions of the oreshoots it is essential to understand the possible structurally controlled geometries of orebodies before planning a drilling programme to evaluate their potential

Apr 1, 1996

By B. B. Dhar

Slope stability at the proposed mine in Rajasthan was analysed in two dimensions using a finite difference code. The properties of the rock material were determined in the laboratory and subsequently modified to approximate those of the in situ rock mass. Geotechnical mapping was undertaken to determine the critical orientation of structural discontinuities. The results of the work indicated that an open pit 148 m in depth would be stable with overall slope angles of 60 degrees

Aug 1, 1994

By H. L. Paterson, R. R. Keays, M. J. Donaldson, D. J. Boyack, M. F. Smith, J. J. Gresham

"Albite-rich sedimentary rocks that contain abundant Fe sulphides occur in the lower portion of the ultramafic sequence at Kambalda and their broadly antipathetic relationship to most of the nickel orebodies is well documented. These sediments generally contain less than 0.1% Ni, but nickeliferous equivalents with 0.3 to >6% Ni occur locally in close spatial association with more typical volcanic peridotite-associated massive, matrix and disseminated ores. Nickeliferous sediments have been mined at several locations at Kambalda but, collectively, they constitute less than 2% of the total Kambalda nickel reserve. The nickeliferous sediments occur both on the ultramafic-footwall basalt contact and within the lower part of the ultramafic sequence, and are usually less than 5 m thick. They are commonly finely laminated rocks with a cherty appearance, composed essentially of layers of albite+quartz±amphibole, alternating with pyrrhotite+pentlandite±pyrite layers. Some contain a minor amount of carbon. The sediments are only of ore grade (> 1% Ni) immediately adjacent to massive Fe-Ni-Cu sulphides, which are interpreted as normal magmatic ores on the basis of geochemistry and the presence of distinctive ferrochromites. The nickel content of the sediments decreases to background levels (<0.1%) within about 20 m of the massive sulphides. In most locations the massive sulphides clearly have been emplaced tectonically within or adjacent to the sediments, which are commonly highly deformed. Typical nickeliferous sediments contain about 1% Ni, 0.1% Cu, 0.1% Zn, 400 ppb Pd, <0.2 ppb Ir and 10-200 ppb Au. They have lower Ni/Cu (average 10), higher S/Ni (average 6) and higher S/Se (average 11 200) than associated massive sulphides (average 40, 4.8 and 7400, respectively). The Pd/Ir ratio of the nickeliferous sediments (typically > 1000) contrasts markedly with that of associated massive sulphides (average ca 16).The high Pd/Ir values are similar to those which have been reported for hydrothermal Fe-Ni sulphides and barren sulphidic sediments of probable volcanic exhalative origin. They preclude a direct magmatic origin for the sulphides in the nickeliferous sediments, though S/Se and S isotope data indicate a magmatic source for the sulphur. The restriction of nickeliferous sediments to within about 20 m of normal magmatic sulphides and the lack of a widespread Ni dispersion halo suggest local redistribution of originally magmatic Ni. This probably occurred by diffusion and hydrothermal mobilization during deformation and amphibolite-facies metamorphism. Although not totally ruled out, a volcanic exhalative origin for the Ni seems unlikely."

Jan 1, 1984

By R. L. F. Kay, T. A. Fletcher, A. J. Boyce, C. M. Rice

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The synorogenic, mafic Ordovician intrusion comprises orthopyroxene-rich xenoliths and mafic-ultramafic cumulates with low-grade pyrrhotite, chalcopyrite and pentlandite mineralisation. Despite abundant textural, mineralogical and O isotope evidence for significant assimilation of country rocks, S isotopes indicate only a modest uptake and suggest that mineralisation is dominated by magmatic sulphur. The preferred explanantion is that the magma was close to S saturation on emplacement. Uptake of elements such as Si and O led to early crystallisation of orthopyroxene, resorption of olivine and early segregation of a sulphide liquid. Post-magmatic interaction with a high-temperature, surface-derived fluid, whose movement may have been controlled by regional shear zones, reset biotite and whole-rock O isotope values but not those of orthopyroxene. This model identifies the presence of olivine-rich rocks and evidence of extensive assimilation as guides to prospectivity

Jun 19, 1905

By K. C. Dunham, M. Solomon, T. A. Rafter

Sulphur isotope ratios have been determined for 81 sulphides and S and O isotope ratios for 26 barites from the Alston Block in the northern Pennine ore field. In addition, both isotope ratios have been determined for 29 evaporitic anhydrites of various ages from European and Australian localities. The consistency of the sulphate isotope ratios over a wide area of the northern Pennines, and their similarity to values for Lower Carboniferous evaporites, suggests that the sulphate originated from Lower Carboniferous connate waters. It is suggested that these mingled with warm brines rising through granitic plutons beneath Tynehead and Upper Weardale, the aqueous sulphide ion in these brines having a delta34S value of approximately +10 per mille. The delta34S values for the sulphides range from +15.0 to -5.9 per mille and show an outward zoning with higher values in the central fluorite zones and mainly negative values in the outer barite zones. The wide range of delta34S values for the sulphide S is not characteristic of magmatic S and there is no adequate local source in the Carboniferous sediments. It is suggested that formation waters, probably mainly of connate origin, sank down sufficiently deep to become heated above 200°C before rising through Caledonian granite plutons into the Carboniferous sediments, where they spread laterally to mingle with cooler sulphatic connate water. The rising fluids were hypersaline brines carrying F, Ba, Pb, Zn, Cu and S. Temperatures of deposition calculated from galena-sphalerite isotope fractionation are similar to temperatures previously determined from fluid inclusion studies.

Dec 1, 1971

By W. R. Paterson, W. Morton, D. B. Cameron

The Massbal II computer simulation program has been used to develop a general framework for the building of thermochemical models of metallurgical processes. The framework allows the rapid, simple construction of complex models of process equipment for use in flowsheet design, planning and plant operation. Application of the program to model the iron-making blast furnace and a flash smelting process is described

Apr 1, 1991

By A. F. Neil, A. S. Bahaj, P. Watkins, P. M. Hyslop, C. E. Kirby, P. A. B. James

The results of initial work indicate that for 3 of the 5 quarry sands bioleaching reduces the iron oxide content to a commercially acceptable 0.035 wt% Fe20 3, although the time taken to achieve this is 14-22 days against a target leach time of 7 day. Subsequent work has identified strains of Aspergillus niger that are more efficient at producing the array of complexing agents for iron and is yielding excellent and rapid reductions in Fe levels. Potentially, bioleaching offers a more environmentally friendly and energy-efficient process for the removal of Fe from glass-making sands than conventional routes but the production of organic acids by fermentation must be achievable with low-cost substrates such as sugar-beet molasses and lactose permeates for bioleaching to offer a commercially viable alternative to treatment with hot mineral acids. Silica sands usually contain three groups of Fe minerals: iron oxyhydroxides, which comprise crystalline types such as goethite and limonite tending to occur as thin, discontinuous coatings and in cracks and crevices on the surface of the quartz; the assemblage of heavy trace minerals, which include ilmenite, rutile, leucoxene, chromite and haematite, commonly present at levels of 0.1 wt% or less as discrete grains or sometimes cemented to the quartz; and clay minerals cemented in pits on the surface of the quartz and in association with weathered, discrete feldspars. The response of the assemblage of iron minerals to short periods of exposure to hot inorganic acids is broadly related to which group they belong to, those that form coatings being accessible to acid and tending to react rapidly whereas the trace minerals are usually resistant and react very slowly, if at all, and the clays are probably digested. The note reports on a preliminary study of the use of microorganisms to develop an alternative clean technology that will give results comparable to those achievable with hot inorganic mineral acids but with more environmentally acceptable procedures. Various fungi and bacteria produce organic acids when grown in certain media. When these acids come into contact with Fe-stained sand grains the iron is removed as soluble complexes. Several strains of Aspergillus niger have been found to produce organic acids from sugar, predominantly citric, gluconic and oxalic acids, their relative yields depending on cultivation medium and conditions. Sand samples were prepared from five quarries in the UK: Levenseat, Lothian; Redhill, Surrey; King's Lynn, Norfolk; Chelford, Cheshire; and Oakamoor, Staffordshire; ranging in iron oxide content from 0.035 to 0.153 wt% Fe203

Jun 18, 1905

By T R. Meng, C Wu

After carrying out a brief review of the existing safety assessment criteria for the spontaneous detonation of explosives in the mining of sulphide ore deposits in China, and giving a detailed description of the dynamic process and mechanism of the spontaneous detonation of explosives and the relative factors, the latest research results of three kinds of explosives reacting with a group of sulphide ores are presented, based on a reliable experimental method. Afterwards, a complete safety criterion for spontaneous detonation assessment, which depends on the hole temperature, the water solution Fe2+ and Fe3+ and the pH value, is established to determine (he safe charging time of explosives in variable conditions. The criterion is verified as correct by a large-scale field test.

Jan 10, 1996

By D. W. Holliday

The major deposits of anhydrite and secondary gypsum in Jamaica occur discontinuously at a single horizon within the Lower Eocene succession of southeast Jamaica. They are not intruded from other horizons of different age, as has previously been supposed. The gypsum and anhydrite occur in a regressive sequence at the junction between marine (Richmond Formation, Halberstadt Volcanics, Halberstadt Limestone) and overlying non-marine (Wagwater Formation) sediments. They are thought to have been formed in an arid supratidal (sabkha) environment. A variety of 'nodular' structures occurs in the gypsum and anhydrite which can be related to early diagenetic processes and compaction effects. All gradations exist between single isolated anhydrite nodules and structureless anhydrite due to closer packing and coalescence of nodules. The structures and textures in the anhydrite are thought to be consistent with penecontemporaneous formation from gypsum crystals rarely more than 2 cm in diameter. Single anhydrite nodules are not usually larger than 2 cm; nodules of greater size are compound, due to the coalescence of several smaller nodules. Some large compound nodules may have developed from single sand crystals or rosettes. Compaction of anhydrite appears to have been largely mechanical, but some rocks have an aligned fabric, suggesting later flowage

Dec 1, 1971

By G Williams

Discussing equipment, systems of work, the need for updated programmes of local seismic exploration, and developments within the South Wales coalfield.

Jan 1, 1993

By H. Forster, F. H. Koenemann, U. Knittel

The greenstone belt developed along the Sandawana line, an anastomosing, transcrustal shear zone. The lode gold is concentrated in veins and along brittle-ductile shear zones and other faults. Gold contents of 200 rock samples were found to be well below economically significant levels, excluding purely syngenetic deposit formation. Average gold content of unmineralised banded iron formation decreases from 7.3 ppb in the east (Manica) to 1.6 ppb in the west (Odzi), where depletion reflects hydrothermal leaching. The mineralising fluids may have been generated during deep crustal deformation, metamorphism and magmatism. Gold was hydrothermally deposited during carbonatisation and sericitisation of ultramafic and mafic rocks and during hydrothermal overprinting of banded iron formation and felsic rocks. It is present in native form and as microscopic to submicroscopic inclusions in pyrite, arsenopyrite and pyrrhotite. Argentiferous galena and other sulphides are commonly observed. Rezende, which produced over 38 t Au, is hosted by a granodiorite stock. By-product gold was produced from Cu-Ni sulphides at Mundonguara. The deposits are related to the older, but not the younger, of the granitoids intruding the belt's supracrustal sequences; the estimated age of mineralisation is 2700-2600 Ma. Odzi district, with 61 mines, has produced only 3.5 t Au as its higher-level host rocks have apparently been eroded. Mutare (formerly Umtali) district, with 133 mines and 9 placers, has produced 68 t Au (65 t from Rezende and adjacent deposits), and Manica district, with 23 mines and 8 placers, 12 t Au. Estimated reserves for the Rezende area are 20 t Au and for Manica district 4 t lode Au and 19 t placer Au

Apr 1, 1996

By L. J. Cabri, J. M. D. Wilson, R Lastra

An image analysis program can search for gold minerals in polished sections by scanning about 100 x 100 back-scattered electron images at a magnification of x400, allowing gold grains as small as 1 micrometre in diameter to be detected. Typically, a c.15 h overnight search of a product smaller than 45 micrometres will scan c.1 500 000 particles, providing data that are not easily obtained through manual operation of an optical microscope. The program locates grains of the correct brightness, acquires gold X-rays from them by wavelength-dispersive spectrometry, filters the data to remove artefacts and record the images and stage locations for subsequent retrieval. At the end of the run, the program allows the operator to verify and identify the grains found. Industrial studies at Canmet have included determining the nature of gold in cyanidation tailings, checking the mineralogy and size of gold grains in samples from an Indonesian Cu-Au concentrator and locating and measuring gold liberation and grain sizes in an ore

Jun 21, 1905

By A. L. W. Lips, B. P. J. Stevens, T. J. R. Barclay, E. Rothery, S. H. White

Discussion by B.P.J. Stevens of the paper, published in Trans. IMMA, vol.104, 1995, p.B1-B17, is presented together with the authors' response. Stevens questions the authors' radically different interpretation of the structural geology of the Broken Hill Block, considering that the descriptive part of the paper is a useful addition but that the conclusions are unwarranted on the basis of the data presented. A number of major points of disagreement are outlined and half a dozen additional minor points listed. In response, the authors admire Stevens's contribution to unravelling the geology of the area but defend their attempts to take the regional studies a step further, pointing out that he has misquoted what they wrote and arguing that because of the assumptions underpinning the derivation of the present stratigraphy it cannot be used to constrain structural models. With regard to shear zones, they cite the extensive earlier literature and refer to horizontal displacements shown on maps produced by Stevens et al. Detailed discussion follows of the stratigraphy and of the stratigraphic correlation problems resulting from failure to recognise the presence and significance of shears, particularly those parallel to stratigraphy. The remobilised position of the Pb mineralisation in the North Mine open cut is reiterated. It is concluded that there is an urgent need for systematic isotopic dating in the area to constrain the stratigraphy

Apr 1, 1996

By Stainier X.

The connexion between the Kent and the Continental coalfields on the one hand and the western British coalfields on the other has been for many years a controversial subject between geologists. These coalfields were once considered as detached portions of a former extensive sheet of Carboniferous deposits, but some geologists seem now to incline to the view that they were never connected. The writer hopes to show that the problem is one of the most difficult of geological investigations; that we are still far from a perfect solution; and that both of the extreme theories must be set aside. The physiography of NW Europe during the Carboniferous, with its various generations of earlier folds, is outlined and the features of the Lower and Upper Carboniferous anticlines and synclines discussed, followed by consideration of the denudation of the coalfields and local descriptions of the Malvernian range and Usk anticline, the Pennine chain, the Shropshire coalfield and the Kent coalfield. An attempt is made to trace the transverse Midland anticlines southwards and to deal with the intervening syncline: for example, if the dissymmetrical profile of the Pennine Chain holds good at its southern end then the syncline west of the chain must be deeper than the syncline east of it (the Kent syncline), and in this syncline the deepest part must be at its south-eastern corner, and therefore south of the diagonal ridge. T here is some actual evidence of the existence of Coal-Measures in this syncline, as the results of the Batsford and Burford borings prove. The hypothetical character of most of the conclusions will prove, beyond any doubt, how fa r geologists still are from a perfect settlement of this problem, and how much this settlement is dependent on the more or less advanced state of knowledge regarding all the geological features of these coalfields and of the surrounding country

Dec 1, 1916

By M. J. Howes

The high degree of mechanisation, which is mainly diesel-powered, has a significant effect on heat loads; heat output from this source often exceeds the heat flow from the surrounding rock. The extensive use of diesel-powered equipment also influences ventilation rates and minimum values are necessary to ensure that emissions of diesel exhaust are adequately diluted. Many Australian mines are in subtropical or tropical areas with high ambient wet- and dry-bulb temperatures on surface. This, coupled with the large amount of heat from mechanisation, usually means that refrigeration is required at much shallower depths. A secondary problem is associated with the definition of acceptable thermal environment conditions, which are sometimes based on the assumption of no air movement. This gives rise to very stringent thermal environment acceptance criteria, which, in some areas, would prohibit work on surface, let alone underground

Jun 12, 1905