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By B. Birol, M. N. Saridede

"Slag density is a significant factor in determining the process efficiency of the electroslag remelting (ESR) process, where calcium fluoride (CaF2)-based slag is formed synthetically to refine metal ingots. Although there are some former studies investigating the density of CaF2-containing slags, the prediction models focusing on them are applicable only to some specific systems. The present study aims to build a model to predict density for a wide range of CaF2-containing ESR slags. To investigate density for various slag compositions, CaF2-Al2O3-based and CaF2-Al2O3-CaO-based slag compositions were prepared. Additionally, some minor constituents like FeO, MgO and MnO were added to a 5:3:2 CaF2-Al2O3-CaO slag in order to investigate the effects of these constituents on the slag. The volumes of the prepared slags were measured in a tube furnace at 1450-1550 °C using the sessile drop technique, and their densities were calculated. The results showed that for the slags, density is related to optical basicity, and therefore a prediction model based on an Arrhenius equation was built. The model was tested with data from literature, and its limitations and validity are discussed.IntroductionThe electroslag remelting (ESR) process is a refining method in which a metal ingot is remelted under a synthetic slag. These synthetic ESR slags are mainly composed of calcium fluoride (CaF2), calcium oxide (CaO) and aluminum oxide (Al2O3). Other constituents like iron oxide (FeO), magnesium oxide (MgO), manganese oxide (MnO) and chromium oxide (Cr2O3) are added to this system in relatively low amounts, according to the type of steel ingot to be refined. The prediction of slag properties, such as electrical conductivity, viscosity and density, is crucial for the selection of the synthetic slag in order to obtain the required process parameters, like temperature, the passing time of the molten metal droplet through the slag, and metal-slag separation (Akbari, Reitz and Friedrich, 2009; Hara and Ogino, 1981; Mattar, El-Faramawy and Fathy, 2002; Mehrabi, Rahimipour and Shokuhfar, 2005; Presoly, Korp and Schneider, 2008).As slag density affects metal-slag separation in the ESR process, predicting the density of an ESR slag is important for appropriate refining and improved product quality. Although there are many studies investigating the density of slags (Akbari, Reitz and Friedrich, 2009; Aune, Hayashi and Sridhar, 2005; Hara and Ogino, 1981; Matsushita, 2011; Mills and Keene, 1987, 1981; Seetharaman et al., 2013; Shu, 2007; Shu and Chou, 2013; Sikora and Zielinski, 1974; Xu et al., 2012; Zhang and Chou, 2010), the prediction models built are generally valid for oxide-containing slags (Aune, Hayashi and Sridhar, 2005; Bottinga and Weill, 1970; Mills and Keene, 1987; Seetharaman et al., 2013; Shu, 2007; Xu et al., 2012; Zhang and Chou, 2010). These models were built on either the molar volumes of the constituents (Bottinga and Weill, 1970; Mills and Keene, 1987) or the thermodynamically calculated enthalpy or free energy of mixing, which can be applied to a system containing constituents sharing an ion, such as an O- ion for oxide systems (Aune, Hayashi and Sridhar, 2005; Hillert, 1980; Persson et al., 2007). Some recent studies modeled the density of some oxide slags on their optical basicity (Shu, 2007; Shu and Chou, 2013; Xu et al., 2012; Zhang and Chou, 2010)."

Jan 1, 2016

By Tianzu Yang, Weifeng Liu, Lin Chen, BOYI XIE, DUCHAO ZHANG, HUI XIAO

In this study, the oxygen-rich bath smelting process of copper dross was simulated using Factsage software. It was found that the two-step simulation results agreed better with the industrial data, especially in the speiss. Bismuth (Bi), lead (Pb), antimony (Sb), arsenic (As) and copper (Cu) contents in the speiss by two-step simulation differed from the industrial data by 0.6, 0.8, 2.6, 7.2 and 8.6 weight percent, respectively. The two-step simulation results indicate that the speiss partitioning of Sb, As and Cu increased from 60.1, 32.3 and 27.5 percent to 81.6, 67.8 and 47.2 percent, respectively, with the smelting temperature increasing from 1,050 to 1,250 °C, while the metal partitioning of Sb and Cu increased from 0 and 2.7 percent to 15.2 and 13.3 percent, respectively, with the separation temperature increasing from 400 to 700 °C.

By R. Jin

Fine coal flotation using gaseous carbon dioxide has demonstrated the potential for producing superclean coal. The success of this new flotation .procedure is attributed to the coal's high adsorption potential for CO2. To understand the nature of gas-phase CO2 adsorption at the coal surface, in-situ FTIR spectroscopy in a controlled-environment chamber with an ultravacuum sys-tem has been used and the results are discussed in view of other experimental results from differential scanning calorimetry. It has been found that specifically adsorbed CO2 molecules at the coal surface are polarized and have a characteristic doublet at 2336 and 2361 cm-1. Two adsorption states have been proposed to account for the doublet observed from in-situ FTIR spectroscopy measurements. It is believed that the band at 2336 cm-1 originates from the activated site adsorption of CO2 and that the band at 2361 cm-1 arises due to the molecular aggregation of CO2 within the coal pores.

Jan 1, 1988

By G. M. Wilemon, Swanton. R. G.

The Bureau of Mines is investigating the leaching of phosphate values from Florida phosphatic clay wastes using sulfuric acid (H2SO4) as the leaching agent and methanol as the solvent. Acid-alcohol leaching studies were done using research-grade apatite to investigate potential causes of flow extractions. It was found that a barrier layer formed on the surface of the apatite. Initial discovery of the barrier layer was made by analyzing pure apatite samples before and after leaching using an optical microscope. Subsequent Fourier Transform Infrared (FT-IR) analyses proved the coating was calcium sulfate hemihydrate (CaSO4•1/2H2O) and that unreacted apatite existed beneath the coating. Scanning electron microscope (SEM) photographs depict the CaSO4• 1 /2H20 morphology as long slender crystals adhering to the apatite surface. It was also shown that grinding the leached tailings and leaching again in the H2SO4-methanol system resulted in additional phosphate extraction.

Jan 1, 1992

By P. V. R. Bhaskar Sarma, P. K. Sahoo, G. Roy Chaudhury

A process was developed to treat an ammoniacal leach liquor containing zinc using Di (2-ethyl hexyl) phosphoric acid (D2EHPA) as the extractant. The objective of this work was to develop a process package for the treatment of complex sulfide leach liquors. Zinc extraction could not be carried out directly from the ammoniacal solution in mixer-settler units because of crud formation and low extraction efficiency. After neutralizing the free ammonia with H2SO4, the extraction efficiency was only about 40%, due to the high concentration of (NH4)2SO4. To decrease the (NH4)2SO4 concentration, the free NH3 was steam stripped, and the resultant liquor was subjected to zinc solvent extraction. An extraction efficiency of 98% could be achieved by controlling the equilibrium pH. Stripping studies were also optimized after removing ammonia from the zinc-loaded organic. A continuous 100-hr operation that included extraction, scrubbing and stripping, was carried out successfully.

Jan 1, 1995

By M. Prasad, G. M. Rao, A. K. Majumder, T. C. Rao

Froth flotation was employed to beneficiate a lean-grade siliceous rock-phosphate ore containing fluorapatite, the phosphate-bearing mineral. The main gangue minerals were quartz, iron oxides and aluminum oxides. After the rougher stage, four cleaning stages were required to upgrade the ore. The liberation size of the phosphate mineral was below 200 mesh, The reagent scheme consisted of commercial-grade sodium silicate and sodium oleate. The effect of reagent dosages, number of cleaning stages and pulp density on the efficiences of separation were studied systematically. A flowsheet was proposed for the processing of low-grade siliceous phosphate ore containing 12.1% P2O5, 55.36% SiO2 and 15.45% CaO. The flowsheet provided a useable phosphate concentrate containing 34.18% P2O5 and 14.20% SiO2 with a P2O5 recovery of 70.4% (the weight yield was 25.0%).

Jan 1, 1999

By David Belknap, Clay Haynes, David Egger

Rehabilitation challenges were met nearly two months ahead of contract schedule for the Design-Build, Fast Track Scituate Aqueduct & Tunnel project in Cranston, Rhode Island. The aqueduct and tunnel were built in the 1920s and consisted of three sections—a 2.3 m diameter reinforced concrete section that extends approximately305 m before it transitions to a horseshoe-shaped 2.3 m wide by 2.1 m high cast-in-place concrete tunnel that continues for approximately 5.3 km until it transitions back to a 2.3 m circular section that extends approximately 1.9 km to the end of this project. Major repairs were required to assure sustained operation of this water supply tunnel.

Jan 1, 2005

By R. D. Sharpe

Gypsum wallboard manufacturers in the United States shipped 3.18 billion m2 (34.2 billion sq ft) of wall-board products during 2004 versus 2.93 billion m2 (31.5billion sq ft) in 2003. Following a historic high production of gypsum wallboard products in 1999, production decreased in 2000. But it has steadily increased during2001 through 2004. Wallboard production in the United States increased about 8.6 percent in 2004 from 2003. Following several years of a “building boom” of new wallboard plants and the expansion of the manufacturing capacity of several existing plants, 2004 was a relatively quiet year. However, several new plants and capacity expansions were announced or are in progress during 2004.

Jan 1, 2005

By R. W. Amstutz

Abstract. The shaft was drilled on U.S. Government land in the Piceance Creek Basin and was funded by the U.S. Bureau of Mines. It was drilled to 723 meters (2 371') to provide access to rich deposits of oil shale, nahcolite and dawsonite for geotechnical test work and environmental mining research. Rotary drilling and dual string, reverse-air, jet-assist circulation methods were used. Drilling required 8 months. Site preparation, running and cementing the casing required another 4 months. A 2.44-meter (96-inch) ID steel welded casing, 5.1 cm (2 inches) thick was installed and 2 700 tonnes (63 000 sacks) of cement were slurried and pumped into the annulus.

Jan 1, 1980

By Larry L. Snyder

A compact 4.87 m (16 ft) diameter tunnel boring machine (TBM) is capable of boring a 12.2 m (40 ft) radius curve while gripping horizontally, or vertically, as may be required for the excavation of turnouts. The machine's 5.0 m (16.5 ft) length and a patented machine structure allows steering while boring without causing harmful eccentric loads. An extremely stiff thrust system, rigid front and rear grippers, and the torsional stiffness of a front end electric cutterhead drive combine to create superior machine stability and boring efficiency. A 2.2 m (7.2 ft) diameter prototype, complete with a soft ground shield attachment, was used successfully on a tunnel project in Scotland.

Jan 1, 1989

By G. S. Austin

New Mexico produced 83% of domestic potash and 27% of domestic consumption in 1992. The potash industry of New Mexico produces sylvite (KCI), langbeinite (K2SO4-2Mg(SO4)2), and artificial K2SO4. Average sylvite grade in New Mexico today is about 14%. The average grade of langbeinite is 8-10% Kp. Commercial potash occurs in the middle or McNutt Member of the Salado Formation (Upper Permian Ochoan Series). The 120-m-thick McNutt Member dips about 1° east and contains 11 of 12 potential ore zones in the Salado. The mineralogy and proportion of clay minerals, up to 7% of the ore, influence optimum milling procedures and ore grade cutoff.

Jan 1, 1994

By M. A. Chandler, G. T. Adel, J. N. Richardson, E. C. Gutierrez

A rapid, bench-top analyzer has been developed to determine P2O5 content and CaO/P2O5 ratio in phosphate ores. The analyzer utilizes a portable computer equipped with a frame grabber to measure the reflective intensity (gray level) of phosphate samples placed in front of a television camera. P2O5 content is related to the average gray level of the sample, while CaO/P2O5 ratio is determined from the amount of bright material present. The sensor is currently being used to analyze flotation concentrate samples at Texasgulf's phosphate operation near Aurora, North Carolina. Sensor development along with results from laboratory and in-plant testing are discussed.

Jan 1, 1993

By Milton E. Wadsworth, Ximeng Zhu

Impurity metals can markedly influence the anodic dissolution of gold in the presence of cyanide. Several important findings related to the influence of lead are reviewed and some new observations presented. Based on the effect of pH, the scan direction, and voltage, it may be shown there are three separate voltage regimes where lead influences the anodic dissolution of gold. These are related to Pb°/ HPbO2, Au-Pb /HPbO2, and HPbO2/PbC2; oxidation-reduction reactions which provide low resistance paths for electron exchange. The gold dissolution rate was determined by direct solution analysis and is compared to the rate implied by electrochemical measurements.

Jan 1, 2005

By Yaxiong Wang, Yong Li, Yuedong Wu, Haigang Dong, Jiachun Zhao

A roasting-leaching process has been developed for concentrating platinum group metals (PGM) from a PGM-containing ferroalloy. The optimized roasting conditions used a NaOH-to-ferroalloy mass ratio of 1.2 at 600 °C for 2 h. The roasted product mainly comprised Na4SiO4, NaFeO2 and Fe2O3. The iron oxide and sodium silicate associated with the roasted product were leached in water and dilute sulfuric acid solution, while the PGM was concentrated in the acid-leached residue. A PGM concentration of 23.4% was obtained with assaying, and the concentration factor of PGM from the ferroalloy to PGM concentration was greater than 9.

Jun 14, 2021

By Bekta? Uz

The study area is located between Orhangazi and Sapanca geographically known as Armutlu Peninsula (Figure 1). It is steep broken and mountainous with an area of 4000 km2. [ ] Economic marbles are investigated in regionally such as Orhangazi, Elmali, Menek?eyayla, Sapanca, Pamukova and they are seperated approximately 800 km2 (Figure 2). These marbles are massive, thick and dispersed as small sized outcrops in Armutlu Peninsula.

Jan 1, 2005

By Joao B. Cardoso

This paper describes a two-stage reverse flotation method developed at the Mineral Resources Institute (MRII, University of Alabama, for Kerr-McGee Corporation (KMC), to separate the trona (Na2CO3 ? NaHCO3 ? 2H2O) from a saline deposit containing halite, borax, minor salts, and water insoluble materials. In the first stage, trona is depressed with Quebracho, and the insoluble gangue is floated with fatty acid. In the second stage, trona is floated with cresylic acid. The flotation concentrates contained better than 90% trona with insolubles ranging between 1 and 2%. Although the trona recoveries were low, optimization and middlings recycled in a continuous circuit could substantially increase the value.

Jan 1, 1989

By N. Sheikh

In galena flotation, lead ethyl xanthate, Pb(EtX)2, is precipitated and is physically adsorbed in the form of multilayers on the chemically adsorbed first layer of Pb(EtX). 1,2) The solid particles are coated with layers of Pb(EtX)2 in heterogeneous manner over surface areas possessing both anodic and cathodic character (3,4) It is anticipated that the mode of formation of Pb(EtX)2 and the number of ions present, together with stable or unstable by-product species, have great influence on the surface characteristics of galena. The information obtained from a study of these parameters may have important practical applications in flotation. Lead ethyl xanthate is sparingly soluble in water. The metal and xanthate ions released to the aqueous solution during its dissolution undergo various types of reactions depending upon the pH values of the system. Extensive work (5,6) has been carried out to elucidate the mechanism involved in acid decomposition of xanthate ions. Different decomposition paths (7,8) have been proposed for the hydrolytic decomposition of xanthate in neutral and alkaline solutions, The concentrations of lead ions vary due to a number of chemical reactions, regulated by the pH and the temperature of the bulk phase. The hydrophobic character of Pb(EtX)2 may change with the nature of chemical reactions. Some of the numerous by-product species in solution may adsorb on the solid and change the properties of surface film either favourably or adversely. The flotation performance of galena, therefore, may depend to a considerable extent on the physical and chemical stabil¬ity of Pb(EtX)2 layers. Since little work has been reported in literature dealing with the stability of Pb(EtX)2 and its correlation with the flotation of galena, attempts have been made In this study to evaluate the behaviour of freshly formed Pb(EtX)2 in aqueous systems at various pH values.

Jan 1, 1971

By M. Hancer, J. D. Miller

It is known from soluble salt flotation practice that the K, Mg double salts of kainite (KClMgSO43H2O), and carnallite (KClMgCl26H2O) are difficult to float and must be converted to other salts such as schoenite (K2SO4MgSO46H2O) and sylvite (KCl) in order to recover potash values. The flotation characteristics of these double salts have now been confirmed in some detail by carefully controlled laboratory experiments with both cationic and anionic collectors. The experimental results are discussed in view of recent experimental findings regarding the flotation characteristics of simple salts, in which the flotation response was shown to be determined by the interfacial water structure and whether the salt could be considered to be a water structure maker or a water structure breaker. The same approach can be use to explain the flotation response of the potassium double salts ; schoenite, kainite, and carnallite. In addition, the sign of the surface charge of schoenite (K2SO4MgSO46H2O), was determined as a function of pH from nonequilibrium electrophoretic mobility measurements. Schoenite appears to exhibit three charge reversals (CR) which can be explained based on surface hydrolysis reactions. The flotation behavior of schoenite is further considered based on solution chemistry calculations, electrophoretic mobility measurements, and microflotation results.

Jan 1, 2001

By Nicholas T. Esposito

An advanced coal preparation plant has been built at Homer City, Pennsylvania, by Pennsylvania Electric Company, a subsidiary of General Public Utilities Corporation, and New York State Electric and Gas Corporation, as an alternative to utilizing flue gas desulfurization technology to meet the Federal Environmental Protection Agency and the Pennsylvania Department of Environmental Resources air quality emission regulations of 4.0 lb S02/106BTU for the two (2) existing coal-fired generating station Units No. 1 and No. 2, and a 1.2 lb S02/106BTU for the new Unit No. 3. The coal preparation plant is designed to process 5,200,000 tons of run of the mine coal annually and has a design capability to process 1,200 tons per hour via two (2) equal capacity 600 tons per hour preparation circuits.- The plant is designed to produce multi-product coal streams consisting of a middling product of medium ash and medium sulphur content, which is environmentally compatible to support operation of the two (2) existing generating Units I and 2, and a deep cleaned, low ash, low sulphur coal product capable of environmentally supporting the ambient air quality requirements of the new Unit 3 generating facility. The waste product from the process consists of high ash, high sulphur reject material. The process has the acronym MCCS (Multi-Stream Coal Cleaning System).

Jan 1, 1982

By David A. Lee

It was estimated in Chemical Week1 that the uranium fuel requirements for the U.S. Electric Utility Industry by the mid 1980's would be about four times that-of what it is today. This corresponds to approximately 45,000 tons per year of 'yellow cake' - of which a good portion is represented by ammonium diuranate - vs. the 11,700 ton total estimated for 1975. Perhaps just as significant is the 40-fold increase in thirty years projected for the entire world since 1970. Thus by the year 2000. 'yellow cake' production could be in the order of [3]50.000 short tons annually.2 'Yellow cake', so named because of its inherently bright yellow color, is a finely divided precipitate that can be formed after the leaching step when refining uranium ores. Feed solids enhancement then occurs to at least 50% by weight using filters or centrifuges This is followed normally by drying and then calcining with the conversion of ammonium diuranate to triuranium octoxide represented by the following equation: [9 (NH4)2 U2 07 heat 14 NH3 7 + 15 H2O7 + 2N2/ + 6 U308 4] Theoretically, assuming 100% conversion every 100 kgs. or 100 lbs. of ammonium diuranate will result in 90 kgs. or 90 lbs. of triuranium octoxide.

Jan 1, 1976