Search Documents

By J. T. McCartney

Thin sections of coal have been prepared for many years either by cutting on a microtome (1,2)5 or by grinding and polishing (2,1). Specimens of most coals had to be demineralized in hydrofluoric acid and softened in caustic solutions before they could be successfully cut with a conventional microtome. Some lignites could be cut without pretreatment. Jeffrey (1) obtained sections from coals of all ranks, although long and tedious pretreatment was required for anthracite. His sections were less than 1 cm.2 in area (probably much less for high rank coals) and about 5 microns thick. Thiessen (2) also cut sections of softened coals, mostly of low rank. His sections were a few square millimeters in area and about 3 microns thick. However, Thiessen preferred ground and polished sections for detailed studies because they were larger and had not been chemically attacked by softening media. He prepared ground sections as large as 4 cm.2 in area and usually 5 to 10 microns thick. Thousands of such sections, covering complete column samples of many coal beds, were studied for a number of years (4). With the development of the electron microscope and increased interest in quantitative optical studies of coals, a need for much thinner sections arose. However, no suitable technique for preparing such sections was known until Fernández-Morán developed a diamond knife for cutting ultrathin sections of hard materials (5). Workers at the Centre d'Etudes et Recherches de Charbonnages de France applied this new tool to the cutting of coal sections and have recently described their technique to the Burg, of Mines. Using their methods, with some modifications, researchers of the Bureau of Mines have succeeded in cutting ultrathin sections of coals ranging in rank from lignite to

Jan 1, 1961

By P. L. Weston

The Bureau of Mines used high-temperature reduction roasting, magnetic separation, acid-leaching, and autoclave precipitation processes to recover iron and manganese from brown Cuyana range ores of Minnesota. Wet magnetic separation concentrated over 90 percent of the iron in 3 of 4 ores as high grade products analyzing 74 to 85 percent iron, 2.5 to 6 percent manganese, and 3 to 10 percent SiO2. The nonmagnetic fractions were leached with dilute sulfuric acid extracting 83 to 93 percent of the contained manganese and small amounts of iron. The leach solutions contained Mn-to-Fe and Mn-to-SiO2 ratios favorable enough for possible consumption in metallurgical mane operations. Exceptionally pure Mn solutions were achieved by pressure precipitation of the remaining iron in an autoclave followed by lime precipitation of silica and alumina.

Jan 1, 1966

By Frank D. Lamb

"INTRODUCTION The use of beryllium and its alloys has come into prominence in the last 15 years and increased considerably during the war. In contrast to other light metals, such as aluminum and magnesium, beryllium is relatively hard, has a high melting point (1,285° C.), and other properties that make it resemble steel in many respects. It has a specific gravity of 1.85, is only slightly heavier than magnesium (specific gravity 1.74), and is appreciably lighter than aluminum (specific gravity 2.7). Its lack of ductility prevents its use as a structural material, but this difficulty may be overcome in the future by the use of various alloy forms. The only important commercial alloy in which beryllium is used today is with copper. The addition of small percentages (1/2 to 2 percent) of beryllium to copper imparts properties to the alloy that make it desirable for use in springs carrying electrical current, particularly at high temperature. Many other uses of berylliam are known, and new uses are being found constantly that make the metal of increasing interest.Possibly the main factor preventing the use of more beryllium is the lack of a large source of beryllium ore. Many beryllium minerals are found as minor constituents of natural deposits, some of the more common ones being beryl (Be3Al2(Si03)6), chrysoheryl (Be A1204), helvite (3(Mn, Fe) Be Si04. MnS), and phenacite (Be2Si04). Of the known beryllium minerals, beryl is by far the most common and has been found distributed rather widely throughout the world. It usually occurs associated with granitic rocks and is commonly found as a constituent of granitic pegmatite."

Mar 1, 1947

By T. G. Carnahan

The Federal Bureau of Mines investigated, on a laboratory scale, a technique for recovery of silver from pregnant solutions generated in the hydro-metallurgical treatment of complex base-metal sulfide concentrates with oxidizing chloride media. This technique provides a means for recovery and simplified reduction of accessory silver to metal from chloride solutions. The method consists of adding NaI or KI to the solution to precipitate AgI, which is then contacted with Na2S to produce Ag2S and to regenerate the iodide salt solution. Silver recoveries range from 99 pct with 20 pct excess iodide precipitant, to 92 pct when the theoretical stoichiometric amount of precipitant is employed. The Ag2S product can be reduced to silver metal by contact with aluminum chips in NaOH solution followed by purification with conventional fire refining techniques.

Jan 1, 1980

By Jack E. Fraley

The Bureau of Mines has successfully developed and tested a machine for spraying sealant onto coal mine roof and ribs. Dry material is transported pneumatically to a water-adding nozzle designed to provide dust-free spraying while being nonplugging and self-cleaning. The machine is self-cleaning, 35 inches in height, and capable of applying l/2-inch-thick coatings at over 1,000 ft2/hr.

Jan 1, 1978

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX E EQUIPMENT USED FOR FIELD TESTING OF MINE SEALING SYSTEM I. Drilling Operation - Equipment supplied by local drilling contractor 1. Mobile drill rig. 2. Flat bed truck, containing 20 lengths of drill pipe. 3. Auxiliary compressor. 4. Pickup truck for small parts and supply of diesel fuel. 5. Bulldozer. 6. Water supply, in this case the nearby stream. 7. Supply of casing, positioned next to the drill rig. 8. Ready mixed cement grout. 9. Drill bits, stabilizer units, cutting and welding equipment, other miscellaneous tools and supplies. II. Sonar Probing Operation 1. 25 foot tower with pulley mounted atop. - FMA 2. Electric winch with 100 feet of 1/4-inch cable, Model No. 100A, City Engineering Co. , Indianapolis, Indiana. 3. 400 feet of 1-1/2-inch-diameter aluminum pipe with alignment holes and coupling grooves. - FMA*

Jan 1, 1973

By C. E. Wood

[Because of the renewed i~,ortanc of the strate ic netal ~ngane8e the Bureau of Mines is conductin further ro~aarch on pyrometallurgica1 ~ethods of boneficiating 0 ngani.foro'l iron ores nnn lo\,f-~~r de oanganesc ores. Published data on .the l2~roI'let llurgica.l treatnent of tl::1.nganse8 ores have been revi .. \-'en by Jose-ph ? .2]

Jan 1, 1940

By Robert L. de Beauchamp

The Bureau of Mines designed a chlorination apparatus to prepare CrCl2 free of CrCl3 by the direct reaction of chlorine and chromium. Equipment and procedures were developed for routine preparation of 25-pound batch quantities of anhydrous CrCl2. Calcium, iron, nickel, and silicon impurities were in the 0.01 to 0.05 percent range, and all other impurities were below 0.01 percent.

Jan 1, 1968

By Alla D. Mah

The heats of combustion of three chromium carbides, Cr23C6, Cr7C3, and Cr3C2, were determined by combustion calorimetry. Heats of formation calculated from the results follow: ?Hf°298 (Cr23C6) = -94.7 ± 5.0 kcal/mole, ?Hf°298 (Cr7C3) = -43.3 ± 1.7 kcal/mole, and ?Hf°298 (Cr3C2) = -22.5 ± 0.8 kcal/mole.

Jan 1, 1969

By W. W. Weller

Heat-capacity measurements of sodium dimolybdate (Na2Mo207) and sodium ditungstate (Na2W207) were conducted over the temperature range from 51° to 298° K. The entropies of the two compounds at 298.15° K were calculated from the heat-capacity values and were used, in conjunction with other entropy data, to evaluate the entropies of formation of the compounds from their constituent elements and oxides.

Jan 1, 1963

By W. S. Sanner

Grinding experiments were conducted to determine the finest anthracite particles that could be produced in a ball mill. Continuous and batch tests were run in a dry-grinding ball mill. Batch grinding produced the finest coal particles. They averaged 2.2 microns in diameter and were 99.0 percent smaller than 37 microns. Continuous grinding yielded a product 6.1 microns in diameter, with 96 percent smaller than 37 microns.

Jan 1, 1968

By William M. McKewan

The U.S. Bureau of Mines has established a wire rope research laboratory to examine the factors that affect the life of wire rope. Ropes of sizes ranging from 3/4 to 2 in. in diameter and from 2 to 35 ft in length were tested to determine their breaking strength, elongation, and torque. This was done to characterize the test equipment on ropes used in mine hoisting systems.

Jan 1, 1990

By I. L. Nichols

The Bureau of Mines is investigating vanadium recovery from various domestic resources. A low-grade carnotite ore sample containing 0.34 pct V20S and 0.04 pct U30S was leached, and the results were compared with those of similar leach tests using a mill-grade sample containing 1.26 pct V205 and 0.19 pct U308. Experiments on the two ore samples included agitation leaching, pugging, salt-roast leaching, and autoclave leaching. None of the leaching methods investigated showed any significant advantage over another except autoclaving, which reduced the leach time but at the expense of greater acid consumption. Typical of the experimental results attained are the data gathered from the agitation leaching tests. Agitation leaching of the mill-grade ore with 100 lb/ton H2S04 resulted in extractions of 94 pct U308 and 33 pct V205. To increase the vanadium extraction from 33 to 91 pct required concentrations of 300 lb/ton H2S04 and 10 lb/ton NaC103. Complementary agitation leach tests on the low-grade ore required 200 lb/ton H2S04 to extract 94 pct U308, and 300 lb/ton H2S04 and 10 lb/ton NaC103 to extract 90 pct V205.

Jan 1, 1983

By Jesse J. Brown

Over 60 simple; were prepared and forwarded to Dr, S. Z. Toma, TPO, PMSRC as a result of this project. Included among these samples were various low temperature forms of silica. Samples of quartz, cristobalite, and tridymite with iron, manganese, and titanium impurities present were prepared. In addition, a long series of samples both wet ground and dry ground for times from 1/2 to 8 hours were prepared. Numerous miscellaneous samples were submitted which included kaolinite, calcite, muscovite, illite, montmorillonite, Ba3(P04)2, and YPO4 among others, in response to special requests from the TPO. The silica rich portion of selected binary (CA 203-Si02, In 203-Si02, Li20-Si02) Na20-Si02, PbO-Si02, SnO2-Si02, Sn02-Si02 BaGa204-SiO2 and SrGa204-Si02) and ternary systems (Na20-Ga203-Si02 and Li20-Ga203-Si02) was investigated to determine the effects of solid solubility on the stabilization of the high temperature forms of tridymite. In addition to the determination of the extent of these crystalline solubilities, observations were made. on the mechanism of the transformation of silicic acid to tridymite and the rate of the reaction in the presence of foreign ions,

Jan 1, 1973

This work presents: 1.) the results obtained from measurements of temperature profiles in pillars and at working faces of three coal mines located in Colorado and New Mexico, 2) a comparison of the experimental results with theoretical predictors based on linear heat flow models, and 3) temperature profile predictions based on a two dimensional coal mine model with an inclined crack located in the roof or wall of the opening. The thermal properties of the coal and shale samples taken from the mines were used as input data for the computer model. Good agreement was found between the measured profiles and the theoretical values obtained with the one dimensional model. The two dimensional model results show that a visible crack (0.01-0.07-ft thick) in a coal roof causes a surface temperature difference from 0.2 to 1°F at the edge of the crack for rock exposed to air from 1 hr to 288 hrs and with the air to rock temperature differences from 2°-6°F. A temperature difference of 0.3 °F was found between solid and broken rock in a shale roof with a 0.03-ft thick crack inclined 45° to the horizontal after a ventilating time of 48 hrs and the air to rock temperature difference of 2.1°F.

Jan 1, 1972

By W. H. Oppelt

The continuous gasification of lignite in an externally heated alloy-steel re-tort was investigated by the Bureau of Mines, Grand Forks, N. Dak., from 1945 to 1951. The main objective of the long-term experimental program was to obtain data on the mechanical performance of this type of gasification retort, particularly the alloy-steel heat-transfer surface of the retort, when operated on large pilot-plant scale. At the same time, extensive experimental data were obtained concerning the effect of process variables and the effect of a limited number of design modifications on gasifier performance. In the period covered by this progress report 4 pilot-plant runs totaling 2,879 hours of operation were completed with the rolled-plate, 310-alloy reaction tube. Over 30 million cubic feet of gas, having H2-CO ratios from 2.1 to 4.4, was made by the partial gasification of 636 tons of 1-1/2-by 3/8-inch natural lignite. Rates of gas generation were from 8,200 to 14,300 cubic feet per hour. Three of the four runs were carried out with the lowered gas offtake or continuous-annulus design modification of the gasification retort. In the final run of the series, gasification of lignite from seven different mines in North Dakota and Saskatchewan, Canada, was investigated at similar combustion-space temperatures and lignite and steam feed rates.

Jan 1, 1955

By James F. Neill, O&apos

Brown iron ore resources in Barbour, Butler, Crenshaw, and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama. The aggregate footage drilled was 18,010 linear feet. When developed, reserves of 12,664,000 long tons of crude ore were indicated, containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet. Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons. Beneficiation of samples by simulated log washing and use of a 118-inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese. Screen-test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size. While an indicated 2,198,000 dry long tons of usable iron ore can be recovered, sink-and-float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing. However, applicable commercial processes have not been demonstrated.

Jan 1, 1965

By John R. Duda

The Bureau of Mines is developing estimates of capital investment, operating cost, and selling price for underground mines producing bituminous coal by various mining methods. This study estimates the required capital investment, operating costs, and selling prices for two hypothetical mines designed to produce 1.3 and 2.6 million tons per year (MM tpy)3 by using a longwall system in conjunction with a continuous-mining system. The coal properties being mined are assumed capable of sustaining a 20-year production period. Wages and union welfare payments used in this study are those in effect as of December 6, 1975, as set forth under the National Bituminous Coal Wage Agreement of 1974. Costs of materials and equipment are based on January 1976 indexes. Initial capital investment is $34.6 million for the 1.3-MM-tpy mine and $63.5 million for the 2.6-MM-tpy mine. Capital requirements, including deferred investments, were estimated to be $50.8 and $92.2 million, respectively. These figures translate into total capital investments of $38.51 and $34.91 per ton of annual production. Assuming a desired 15-percent discounted cash flow (DCF) rate of return, with Federal income taxes at 50 percent, the required selling prices would be $13.41 and $12.27 per ton for the 1.3- and 2.6 -MM- tpy mines.

Jan 1, 1976

By Thomas Brunsing

The program was carried out to develop deep kerfing and core breaking techniques to be incorporated into the design of a field prototype hard rock mining machine. The field machine is designed to mine non-abrasive bedded deposits up to 20,000 psi in uniaxial compressive strength. The mining technique involves cutting approximately 2 ft deep parallel kerfs spaced 2 ft apart in either a horizontal or vertical direction and subsequently breaking out the cores so defined. The prototype machine is intended for demonstration of the technique in a quarry or equivalent field environment. The program was aimed at minimizing the required kerf width, obtaining reliable breaking within that kerf width and determining cutter blade requirements necessary to achieve a mining rate of 20 ft3/min. Full scale breaking experiments and 1/2 scale kerfing experiments were employed to evaluate the system. High strength concrete test specimens were used to simulate the rock being cut and broken. The test results indicate the kerf/break technique can achieve the desired mining rate by utilizing two 7 ft diam blades to cut 2 in. wide by 24 in. deep kerfs. A lateral load applied at the base of the kerf (base shear) was selected at the core breaking technique to be employed by the full-scale prototype machine.

Jan 1, 1983

By James F. Neill, O&apos

Brown iron ore resources in Barbour, Butler, Crenshaw, and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama. The aggregate footage drilled was 18,010 linear feet. When developed, reserves of 12,664,000 long tons of crude ore were indicated, containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet. Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons. Beneficiation of samples by simulated log washing and use of a 1/8-inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese. Screen-test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size. While an indicated 2,198,000 dry long tons of usable iron ore can be recovered, sink-and-float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing. However, applicable commercial processes have not been demonstrated.

Jan 1, 1965