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By K. O. Bennington

The thermodynamic properties of hedenbergite, of composition [(Ca0,9516) (Mg0,0583Fe2+0.7134 Fe3+0.0934 Mn0,1366) (Si206)], were experimentally determined at the Bureau of Mines. The standard enthalpy of formation determined by hydrofluoric acid solution calorimetry is AHf298 = -680.96±0.855 kcal/mol. The standard enthalpy of formation from the oxides is AR-96 = -24.55±0.485 kcal/mol. Low-temperature heat capacities were determined by adiabatic calorimetry from 12.3 to 300.1 K. The derived standard entropy is S-98 - 41.218±0.148 cal/mol-K. High-temperature heat capacities were measured with a differential scanning calorim¬eter from 397 to 1,147 K. These experimentally determined data were combined with data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of measurements. Standard enthalpies of formation are given as a function of temperature. The standard Gibbs energy of formation at 298.15 K is AGf298 = -641.90±0.86 kcal/mol.

Jan 1, 1984

By Louis H. Berkelhamer

"INTRODUCTION The method of differential thermal analysis suggested by Le Chatelier (1)1 in 1887 has recently emerged as an outstanding means of studying the constitution of various substances, particularly clays, soils, and miscellaneous hydrous materials (2). The literature ably discusses the applications and results obtained but has paid too little attention to specific details of construction of the apparatus. Knowledge of the apparatus is of importance to the experienced research man as is extremely useful to the novice v ho ventures into this field of analysis. Further, it is generally acknowledged that the variations in design and conditions of operation are one of the essential causes for differences in characteristic temperatures as reported by various investigators. A step forward in the elimination of such differences is the publication of the details of construction and operation of a simple and inexpensive apparatus that has proved useful at the southern Experiment station of the Bureau of Mines, where it was used in cooperation with the University of Alabama, Tuscaloosa, Ala."

Jul 1, 1944

By J. Pasini

The Bureau of Mines has investigated novel methods of stimulating petroleum production from reservoirs in the Appalachian Region. An important consideration in applying stimulative production methods is the control and removal of solid precipitates from the boreholes of production wells. Where paraffin-base crude oils are produced, as in the Appalachian Region, the accumulation of paraffin may be particularly troublesome. Paraffin deposition is a major production problem that has confronted the petroleum industry for many years. Although considerable effort has been expended by industry and government, a suitable solution has not been found because of the individuality and complex nature of the deposits. Remedial methods used to prevent or remove paraffin fall generally into four classes: (1) Chemical, (2) physical, (3) operative, and (4) combination. Each class has many subclasses that apply to particular problems in different oil- producing areas. Recently, chemical inhibitors and the sonic pump have assisted operators in preventing and removing paraffin deposits. Because these methods are relatively new, their degree of application has not been completely evaluated.

Jan 1, 1963

By Thomas K. Matson

The coal reserve base in the Western United States is presented for coalbeds amenable to extraction by underground mining methods. The Federal Bureau of Mines has abstracted data on the quality and quantity of coal resources/reserves from numerous State and Federal publications and modified such data as necessary to allow computer storage and retrieval. Tonnages are compiled by State, county, coalbed, and rank, and allotted to sulfur categories by statistical apportionment. The coal reserve base in those States west of the Mississippi River, amenable to underground mining, is estimated to be approximately 131 billion tons. Of this total, about 30.8 billion tons are bituminous coal, 100.2 billion tons are subbituminous coal, and 126.4 million tons are anthracite. Lignite is not considered for underground mining in this report. Included in this report is a glossary of terms applicable to a classification system for coal resources and reserves as jointly defined by the Bureau of Mines and U.S. Geological Survey. The purpose of this system is to provide for direct comparison or compilation of various resource/reserve data.

Jan 1, 1975

By M. J. Sapko

The pressure and flame development of the methane-air-nitrogen system was investigated in the Bureau's l2-foot-diameter sphere to define buoyancy effects and to develop relationships for predicting venting requirements. Pressure rise (?P) is defined as a function of time (t) and nitrogen dilution and is shown to deviate noticeably from the cubic law (?P = kt3), depending upon the period of combustion and the mixture composition. Corresponding flame speed (Sf) and burning velocity (Su) data are given which show that Sf is time dependent and that Na dilution has a greater effect than air dilution in inhibiting the flame propagation. The Su data agree with "accepted" values and are unique in that they are based on much larger flames than those used in other investigations. Downward propagation limits are shown to depend mainly upon buoyant forces, which can affect the burning of even stoichiometric CH4-air systems. Theoretical expressions, based on the mixture burning velocity and expansion ratio, are given for predicting the venting requirements for ignitions of hydrocarbon-air-nitrogen mixtures in spherical or cubical enclosures.

Jan 1, 1976

By David Schlain

The galvanic corrosion properties of titanium in contact with commercially pure aluminum, copper, or type 302 stainless steel in some of the common organic acids were investigated. Acids used in these experiments were 10 percent formic, acetic, lactic, citric; 1 percent oxalic and tartaric; and 9 percent oxalic. Electrode-potential measurements and several types of galvanic couple experiments were carried out. Solutions were aerated by three methods: Flow of air, flow of helium, and natural aeration. Work was done at 35° C. with couples consisting of equal areas of the 2 metals. Titanium was resistant to corrosion in most of the organic acids studied, whether alone or in contact with a dissimilar metal. However, titanium coupled with aluminum did corrode in 1- and 9-percent oxalic acid solutions. Contact with titanium usually caused aluminum to corrode by galvanic action. Copper was subject to galvanic attack in 10-percent acetic acid with a flow of air. Contact with aluminum to some solutions in which titanium is ordinarily inert and noble with respect to aluminum caused titanium to corrode

Jan 1, 1956

By John J. Mulligan

The Bureau of Mines investigated reports of mineral deposits within 10 miles of the route of the proposed pipeline from Prudhoe Bay to Valdez. No producing lode deposits or lode prospects of possible national economic significance were found. Measured placer deposits in the route are or slight value except possibly some deeply buried gold placer deposits in the Fairbanks and Livengood Quadrangles. The pipeline corridor crosses five belts of minerals having potential economic value: (1) The north slope of the Brooks Range (oil, gas, oil shale, coal, phosphate); (2) the south slope 01 the Brooks Range (copper, gold); (3) the Livengood area (gold); (4) the Fairbanks area lead-silver, antimony); and (5) the Wrangell Mountains-Denali copper belt (copper-gold). The Jarvis Creek coalfield, an eastern extension of the Nenana coalfield, is on the north side of this belt. Scattered along the corridor across the Chugach Mountain and in the vicinity of Valdez are a wide variety of metallic deposits that make up the eastern margin of the Chugach gold belt but do not seem to constitute a well-defined zone.

Jan 1, 1974

By Robert J. Timko

Because of leakage through and around permanent stoppings in underground mines, more air must be forced into a mine than would otherwise be required for ventilation. As power costs increase, costs resulting from air leakage add increasingly to the operating costs of mining. The Bureau of Mines evaluated four different stopping construction techniques based on the ideas that (1) airtightness could be enhanced by brushing rather than troweling on mortar sealant and that (2) modified mortars (mortars containing glass fibers and other additives for increased strength and adhesion) would improve sealing performance. Air leakage tests comparing conventional to modified stoppings were done when the stoppings were built, after 6 months, after 1 yr, and following simple maintenance. It was found that stoppings can be built and maintained better if-- The area where a stopping is to be built is properly prepared. Stoppings are constructed using the techniques devised by the Bureau. Stoppings are periodically examined for leaks. Stoppings found to be leaking, especially at the perimeters, are resealed.

Jan 1, 1983

By Thomas C. Atchison, Joseph M. Pugliese

Six explosives were compared by measuring their strain- producing abilities in limestone . Peak strain , e , varied with scaled distance , R/Ro , according to the following equation : € = Kc (R /R 。)- ". The distance exponent , n , was a constant of the rock and did not depend upon explosive . The strain intercept , Ke , increased with increasing detonation pressure of the explosive . The strain intercept also depended upon the explosive- to - rock impedance ratio . For impedance ratios from 0.53 to 1.38 , the strain intercept was approximately proportional to the medium stress , Pn , as calculated from the explosive detonation pressure , P , and the explosive - torock impedence ratio , Z , by the simple elastic theory relation : P = 2P / ( 1 + Z ) . PD However , the data indicated that , at lower values of impedance ratio , the strain intercept is relatively larger than would be expected from the simple elastic theory . The results presented provide a simple method for predicting the relative effectiveness of different explosives in breaking limestone from the detonation pressures and characteristic impedances of the explosives .

Jan 1, 1964

By M. P. Ristenbatt

A new automated post-disaster signaling system, intended to use through-the-earth EM propagation, was demonstrated in the laboratory at an input SNR of -34 dB. The system presently available requires an input SNR of +6 dB, and uses a human-ear detector. The work here demonstrated coherent integration, for the automated system, in multiples of 17 s, up to 1088 s (18 minutes). A repeating pseudorandom (or pseudonoise) signal is used, which offers an ideal auto-correlation at the receiver matched-filter output. A novel decision-variable algorithm achieves the estimate of noise level by using those matched-filter output samples that occur between the signal auto-correlation peaks. This work included corraboration that the received signal power decreases as distance to the tenth power, for through-the-earth propagation. Thus, the above 40 dB reduction in required input SNR permits an automated system to have a range 2.5 times that of the present system. In addition, an automated system permits the possibility of operating receivers around-the-clock; this would reduce the initial-detection-time from a few hours (present system deployment time) to a few minutes (signal processing time).

Jan 1, 1981

By A. C. Smith

The U.S. Bureau of Mines constructed a large-scaJe facility to study the self-heating of a large coal mass under conditions that simulate a gob area of a mine. The insulated coal chamber can hold up to 13 short tons (st) of coal and is provided with a forced ventilation system and computer-controlled temperature and gas measurement systems to monitor the heat and mass transfer phenomena that occur in the coalbed. Three experiments were completed with high-volatile C bituminous coals that exhibited high spontaneous combustion potentials in laboratory-scale tests. In the first two tests, a sustained heating was not achieved. In the third test, temperatures throughout the coalbed increased steadily from the start, with thermal runaway occurring near the center of the coalbed after 23 days. The thermal reaction wne then moved toward the front of the coalbed. The results of these tests showed that the self-heating of a large coal mass depends not just on the reactivity of the coal, but also on the particle size of the coal, the freshness of the coal surfaces, the heat-of-wetting effect, and the availability of O2 at optimum ventilation rates.

Jan 1, 1991

By L. D. Patts, J. D. Noll, S. E. Mischler, G. H. Schnakenberg

In this study, we evaluated the ambient diesel particulate matter (DPM) concentrations (at the intakes and exhausts of the mine) as the entire vehicle fleet of a stone mine switched from using 35% biodiesel to using a water emulsified fuel (PuriNOx). Elemental carbon (EC) was reduced by 45% when a PuriNOx blend containing 10% water replaced 35% biodiesel and by 57% when a PuriNOx blend containing 20% water was used. Other factors such as engine duty cycle and production changes could potentially cause some day-to-day EC fluctuations, and no direct comparison to commonly used dieselfuels (No. 1 or No. 2) was achieved. Therefore, a second study was performed in a controlled “isolatedzone” environment to fametal mine, comparing PuriNOxto No.1 diesel fuel in a load haul dump vehicle. The EC fraction of the DPM was reduced by about 71% when the PuriNOx blend containing 10% water was used and by about 85% when the PuriNOx blend containing 20% water was employed. This study did not determine how the water emulsified fuel would affect the engine or power.

By Mandius C. Lundal

This report describes the work done to develop a coal mining machine to increase productivity and recovery from thin seams beyond the highwall, in addition to decreasing the miner's susceptibility to to highwall hazards. First, radar transducers were adapted to measure coal thinkness and detect rock and coal interfaces; Then, the radar was incorporated into a cutterhead with steering controls. Next, visual displays were designed to show cutter position in the coal seam, and anticipated change In coal seam inclination. Finally, development of a telemetry system made remote control of the cutterhead possible. Simultaneously, a high-performance extended depth (HPxD) auger machine was designed with an automatic system to handle 600 ft of 36-in. diameter dual spiral flight conveyor sections. A two man crew controls all operations from a weather conditioned cab outside the VDZ, either at night or day time. As a primary mining tool, working 4000 hr/yr (2 shifts/day) recovering 60% of the coal 600 ft beyond the highwall, production to 500,000 ton/yr can be achieved. Volume II contains technical discussion of subsystems and machine drawings.

Jan 1, 1977

By Duvall Wilbur I.

This is the second report to be presented on th application of stress analysis to underground Mining problems. In part I2/ of this investigation the stress distribution around single openings in unidirectional and hydrostatic stress fields was analyzed. Relationships between maximum stress concentration and size and shape of openings were determined by the photoelastic method. In most cases the results were verified by mathematical methods This report considers the stress distribution in pillars formed by two or more openings in a. unidirectional stress field. Relationships between stress concentrations and size and shape of pillars are developed. Applied to mining, results snow how estimates may be made of the stress distribution in pillars, what factors cause high local stresses, and how local stress concentrations may be reduced by proper design of mine openings. The photoelastic method was used, as in Part I, to study the stress distributions, and, whenever possible, the results were verified mathematically. A description of the photoelastic method and equipment is .given in Part I.

Jan 1, 1948

By A. D. Garman

This paper presents one of a series of digests of foreign mining legislation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the laws of Bolivia has been prepared from the best available information in Washington, but is released subject to correction and amplification, if necessary, by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State. SYNOPSIS OF LAW All useful substances of the mineral Kingdom belong originally to the State. The soil and subsoil are regarded as two distinct parts, the latter extending indefinitely in depth (Art. 2). The subsoil is under the dominion of the State, which may either abandon it to common use, grant it gratuitously to the owner of the soil, or alienate it, in return for an annual fee, to any individual or association that applies for it. (Art. 1-3.)

Jan 1, 1929

By Mandius C. Lundal

This report describes the work done to develop a coal mining machine to increase productivity and recovery from thin seams beyond the highwall, in addition to decreasing the miner's susceptibility to to highwall hazards First, radar transducers were adapted to measure coal thinkness and detect rock and coal interfaces; Then, the radar was incorporated into a cutterhead with steering controls. Next, visual displays were designed to show cutter position in the coal seam, and anticipated change in coal seam inclination, Finally, development of a telemetry system made remote control of the cutterhead possible. Simultaneously, a high-performance extended depth (HPxD) auger machine was designed with an automatic system to handle 600 ft of 36-in, diameter dual spiral flight conveyor sections. A two man crew controls all operations from a weather conditioned cab outside the VDZ, either at night or day time. As a primary mining tool, working 4000 hr/yr (2 shifts/day) recovering 60% of the coal 600 ft beyond the highwall, productlon to 500,000 ton/yr can be achieved. Volume I provides an overview of machine, systems and productivity.

Jan 1, 1977

By Donald F. Reed

In the latter half of 1948 the Bureau of Mines investigated the Magnet Cove Rutile Co.'s prerty in northern Hot Spring County, Ark. This work was supplemental to the work done by the Bureau on the same property in 1945.2/ It was undertaken for the purpose of investigating the extent of the ore body toward the south and west and at depth and to obtain representative samples of the ore for metallurgical tests. For the latter purpose, the samples were so taken as to minimize alteration of the physical characteristics of the ore, these characteristics being determining factors in working out processes of bencficiation. During the investigation, 27 holes were drilled, 10 with a diamond-coro drill end 17 with churn-drill rigs using a Baker standard cable-tool core barrel. Drilling developed an extension of the ore deposit westward from the previously mined area but did not disclose the full depth of mineralization. Metallurgical tests to determine methods of beneficiating the ore and utilizing the resultant products are now in progress.

Dec 1, 1949

By J. T. McCartney

"INTRODUCTION The surface areas of the finest fractions of a pulverized material are disproportionately larger than their weights. For instance, Pesrott and Kinney 3/ showed that, in a sample of minus 200-mesh coal, particles that are about 2 microns in diameter represent 15 percent of the entire surface area but only 1.5 percent of the total weight. Because the sur- face area is the dominating factor in the behavior of finely divided materials in many practical processes, the role of the finest particles is of great importance. The oxidation and combustion of pulverized coal, both in the dry form and in suspension in oils, and the hydrogenation to fluid hydrocarbons of mixtures of pulverized coal and heavy oil are reactions in which the surface area of the coal particles has considerable influence. This investigation of the size distribution of fine coal particles was conducted with the hope that such processes would thereby be better understood. The results should also be of value in the study of the crushing and fracture of coal."

Sep 1, 1945

By Farrel W. Lytle

An X-ray emission spectrographic method of analysis is presented for determining rare-earth elements in fractions obtained from bastnaesite ore. The method includes determination of yttrium, thorium, lanthanum, and the rare-earth elements in various complex mixtures. The analysis technique is based upon comparing the samples with synthetic standards approximating the composition of the samples. Working curves are plotted on an absolute-intensity basis, with no correction for back-ground. Examples of working curves and the analyses of typical rare-earth concentrates are included. The selection of spectral lines for the various sample matrices is discussed. A special technique is used for samples in which rapid hydration and carbonation occurred. By analyzing synthetic samples of known composition, the accuracy of the method was determined. The average error of analysis was about 3 percent of the amount present in the range from 5 to 100 percent and about 7 percent in the 0.2-to 5-percent range. A maximum of about 40 samples per day may be analyzed for 7 elements each.

Jan 1, 1957

By P. A. Wasson

The investigation described in this publication was conducted by the Bureau of Mines to determine the effectiveness of the anionic silica flotation method on goethitic iron-bearing materials from the Cuyuna Range, Minn. Samples used in this investigation were a composite of drill core from 13 holes, and 3 samples from lean ore stockpiles. These samples are believed to be typical of the mineralization occurring in an area with a potential reserve of several million tans of submarginal iron ore. Results from batch tests showed that the iron-bearing minerals could be effectively concentrated by flotation removal of the siliceous gangue. The drill hole composite yielded laboratory flotation concentrates from locked tests containing 56.8 percent Fe and 6.1 percent silica, with an accompanying iron unit recovery of 94.2 percent. Concentrates containing 52.4 to 53.7 percent Fe also were produced from the lean ore stockpile materials; corresponging iron recoveries ranged from 71 to 79 percent in the batch tests, with the possibility remaining for additional recovery of iron from the middlings.

Jan 1, 1963