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By S. Illendula, B. Q. Li, R. A. Mirshams

"An integrated mathematical model is developed to represent the thermomechanical behavior of the materials and microstructure evolution during metal forging. The model development is based on the finite element solution of the thermoviscoplastic deformation of metals coupled with the internal state variable model describing the microstructure evolution involving work hardening, recovery, recrystallization and grain size distribution. The procedures for the integration of the microstructure model into the macro finite element model are described. Computed results for both macro and micro phenomena during metal forging, such thermomechanical deformation such as velocity field and effective strain rate and materials characteristics such as distribution of grain size and recrystallization volume fraction, are presented.1. IntroductionThermomechanical behavior and material microstructural evolution are two critical, interrelated aspects associated with metal workpiece undergoing large plastic deformations such as encountered in forging processes. In much of the modeling work up to date, these two aspects have been addressed separately. Die designs and forging processes are investigated using finite element based thermomechanical models while material dynamics during forging is studied, more often than not, as a separate subject. For many industrial applications, especially those involving novel, light and high strength materials, it is critical to combine these two aspects into a single, integrated model so that materials dynamics and thermomechanical deformation during forging processes can be considered simultaneously [1], thereby providing required information for intelligent process design and optimal process control."

Jan 1, 1998

By Fuxing Yin, Akira Sato, Yoshiaki Ohsawa, Kohji Kawaharai

"INCRAMUTE alloy (nominally 45Mn-53Cu-2Al wt. %) has a specific damping capacity as high as 0.4, through a solid-solution and aging treatment. The damping behavior of the alloy is highly temperature-dependent and shows a peak near room temperature. The inadequate strength in the high damping condition restrains the practical application of the alloy, as structural components. Ferromagnetic MnB particles are dispersed in the alloy during induction remelting the matrix alloy in an argon atmosphere. Surface modification of the MnB particles by mechanical alloying (MA) and suitable control of the addition process cause a homogeneous distribution of MnB particles in the alloy. In the composite containing 2 wt. % MnB particles, temperature dependence of damping capacity is improved, and higher damping capacity is still retained in the temperatures over 60 °C. Meanwhile, the Young's modulus and tensile strength were also increased by about 20%. The roles of the MnB particles in improving both damping behavior and mechanical properties were also discussed.IntroductionMany viscoelastic materials, such as rubbers, polymers and plastics, have the superior ability to damp vibration and noise. However, in the applications as structural materials the high damping capacities of materials are pursued upon the satisfactory mechanical properties, especially those at elevated temperatures. Damping alloys are finding more and more applications in structures where noise and vibration ·should be ·eliminated. Specific damping capacity (SDC), defined as the ratio of the energy dissipated to the maximum vibration energy stored per cycle, is usually used to evaluate the damping capacity of alloys. INCRAMUTE damping alloy, developed by the International Copper Research Association, Inc., has a nominal composition of 45Mn-53Cu-2Al in weight percent. The high damping· microstructure of this alloy is obtained through the solution treatment at 820 °C followed by a water quench and aging at 400°C for 10 hours followed by cooling to room temperature [1]. With the heat treatment, a SDC peak ·vs. temperature of as high as 0.4 was observed in the alloy at the strain amplitude of about 10-3 while a tensile strength of about 500MPa was sustained."

Jan 1, 2000

By N. L. Piret

In copper smelting minimization of solid waste generation is receiving increased attention with more stringent environmental legislation and lower disposal space availability. Copper smelting slags generally being valorizable, solid waste generation is attributed to the presence in the feed of unvalorizable impurities which do not report to the slag and to the unavoidable formation of contaminated dilute acid solutions which need neutralization. As to unvalorizable impurities, solid waste minimization is achieved by rejecting them in the highest possible concentration. Dilute acid is mainly due to the formation of SO3 in the smelter gases and to the discard of decopperized bleed-off electrolyte. Its generation is substantially lowered by preventing SO3 formation, by converting the dilute acid to a valorizable product, e.g., by thermal decomposition for H2S04 recovery or by precipitation as chemical gypsum, and by suitable treatment of the bleed-off electrolyte for impurity removal. Industrial processes are evaluated and alternatives are discussed.

Jan 1, 1994

By Zhaohui Xie, Bin Xu, Qian Li, Yongbin Yang, Tao Jiang

A high carbon low-grade gold ore, in which gold mainly occurs in carbonaceous matters, is a typical refractory gold ore whose conventional cyanide leaching extraction is only 12.9 %. In this paper, by the process of flotation-roasting-leaching, gold was effectively enriched and extracted. The flotation results showed that the enrichment ratio of gold was relevant to that of carbon, indicating that gold occurred in close association with carbon. A concentrate containing gold 7.26 g/t and carbon 12.37 % was obtained, with gold recovery 83.10 % and carbon recovery 90.24 %. Subsequently, the roasting of flotation concentrate favorably made the removal rates of carbon and sulfur reach 99.81% and 98.79%, respectively. After roasting, the gold in the roasted product was further enriched to 29.70 g/t and the optimal gold cyanide leaching extraction reached 93.66%.

Jan 1, 2015

By Mikiya Tanaka

This paper outlines our attempt to establish a recycle process of nickel in the spent baths and waste rinse water of electroless nickel plating plants using solvent extraction and solvent-impregnated support, Solvent extraction studies of nickel from actual spent baths revealed that (i) nickel is efficiently extracted by a hydroxyoxime extractant such as LIX84I at a pH greater than 6 and is readily stripped with sulfuric acid, and (ii) the mixtures of LIX63 and acidic organophosphorus extractants (D2ERP A, PC88A, and Cyanex 272) enhanee the nickel extraction efficiency to a sufficient degree without pH adjustment, but at the same time, reduce the stripping efficiency. The application of acidic organophosphorus extractants to selectively remove impurity metal ions (iron and zinc) from a real spent bath before extracting nickel lead to the finding that PC88A and Cyanex 272 effectively remove iron and zinc without pH adjustment leaving nickel in the raffinate. The removal of nickel from the waste rinse water was also studied. Solvent-impregnated supports with a macroporous resin and oil sorbents made of natural kapok fiber and synthetic fiber as supports were applied using D2EHPA and LIX860 as the extractants. During the batch operation, nickel is removed with a high efficiency without pH adjustment. During the column operation, however, the effective removal is hindered by (i) the dissolution of the nickel-D2EHPA complex into the aqueous phase in the high loading region, and (ii) the slow removal rate of the LIX860-impregnated support.

Jan 1, 2003

By Fujio Ishii

The deoxidation of liquid nickel and nickel binary alloys with silicon has been determined at temperatures between 1500°C and 1650°C using quartz crucibles in order to investigate the deoxidation of nickel based alloys. The equilibrium constant of the deoxidation reaction in liquid nickel and the effects of the different alloying elements such as chromium, molybdenum, tungsten, iron, cobalt and coppcr on the activity coefficient of oxygen in liquid nickel have been established.

Jan 1, 1993

By Jun Lu, Min Chen, Wei-jian Su, Jian-zhong Luo, Yu-tao Lei

"In the case of treating phosphatizing wastewater containing zinc, zinc had an impact on the solution chemistry, especially on pH. Fe2(SO4)3 and CaCl2 were used as precipitators to remove phosphate from zincic phosphatizing wastewater and the optimum pH was investigated. Zinc ion had a significant effect on the optimum pH. The optimum pH ranges were 12.10(inlet concentration of 15.67mg/L, outlet concentration of 9.53mg/L), 3.04-5.50(inlet concentration of 11.97mg/L, outlet concentration of 0.44-0.26mg/L), and more than 10.72(inlet concentration of 12.24mg/L, outlet concentration of less than 0.47mg/L) under the conditions without precipitator, with Fe2(SO4)3 and with CaCl2 respectively.Introduction Phosphate coating is commonly used for protective coating of machine elements. Including oil removal by caustic washing, rust removal by acid washing, phosphatization and inactivation, the phosphatization process produces wastewater containing inorganic salt of high concentration, especially the phosphate, beyond the environmental standards and polluting environment seriously. What’s more, the wastewater from zincic phosphatizing technology also contains another pollutant, zinc. At present, Chemical Precipitation (CP) and Biological Nutrient Removal (BNR) are two of most common technologies of phosphate removal. BNR, such as A/O, A2/O and UCT technology, is suited for wastewater containing organ phosphorus of low concentration and CP for wastewater with phosphate of high concentration [1]. Researches on CP treating wastewater containing phosphate of high concentration, mainly focus on adding quantity of precipitators[2-5] and coagulants[2-4] and the choice of technologies[3-9]."

Jan 1, 2008

By Jonkion M. Font

An expression for the distribution ratio of arsenic between slag and copper matte or liquid copper was developed by both, an extension of the Reddy-Blander model for deriving a priori the arsenic capacity, and by a relationship between the arsenic capacity and the arsenic distribution ratio. In this study, the a priori arsenic capacities in the FeO-SiO2, CaO-SiO2, MgO-SiO2, FeO-CaO-SiO2, FeO-FeO1.5-CuOo.5-MgO-SiO2, FeO-FeO1.5-CuO0.5-CaO-MgO and FeO-FeO1.5-CuO0.5-CaO-MgO-SiO2 slags were calculated at 1573 K. The a priori arsenic distribution ratio between the FeO-FeO1.5-CuO0.5-CaO-MgO-SiO2 slag and copper matte (L s/m as), and between the FeO-FeO1.5-SiO2 or FeO-FeO1.5-CuO0.5-CaO-MgO slag and liquid copper (L s/Cu as) were calculated. The model calculated data are found to be in good agreement with the reported experimental data. The availability of reliable thermodynamic data for slag components and impurities in the slag-matte-metal system is essential for the accurate prediction of impurity capacities and distribution ratio data. The arsenic distribution ratio model developed here, can be extended for prediction in multi-component slags and mattes or liquid metal, and thereby may lead to the development of new slag systems for the efficient removal of arsenic in the copper smelting, converting and refining processes.

Jan 1, 2003

By Satu Strömberg

A single-particle laminar-flow technique was used to study oxidation of two nickel concentrates and a granulated nickel matte (43 wt% of Ni). Experimental conditions were: reaction gas from N2 to N2 + 75 vol% O2; gas preheating temperatures ranging from 500 to 1100°C. The major nickel-bearing minerals in the two concentrates were pentlandite and violarite, respectively. Chemical analysis of the particles was used to determine the oxidation degree of the materials, and optical and scanning electron microscopy were used to detect their morphology and mineralogy. Total desulfurization of the nickel concentrates was achieved under the most oxidizing conditions, while the sulfur removal from the nickel matte was not as efficient, especially with the coarse size fraction. Pentlandite-based concentrate was found to be less reactive than the violarite-based.

Jan 1, 1995

By Ragnhild E. Aune, Mark William Kennedy, Shahid Akhtar, Jon Arne Bakken

"To determine the heating rate of billets using ‘short coils’, an appropriate correction factor must be applied to the theoretical relationship. In 1945, Vaughan and Williamson published a semi-empirically modified Nagaoka coefficient applicable for moderate frequency induction heating processes (10 kHz). Recently it was demonstrated that the method of Vaughan and Williamson gives <10% error in the estimated power when heating aluminum billets at 50 Hz.In the present study, experiments have been conducted on aluminum billets in order to verify an empirical frequency corrected ‘short coil’ equation. Measurements of electrical conductivity (<± 0.5%), current (± 1%), heat (± 1-3%), and magnetic flux density (± 1-2%) have been performed. The results are compared with 1D analytical calculations, and 2D axial symmetric FEM modeling using COMSOL 4.2®. The frequency corrected equation has proven to provide accurate predictions of power (<4% error) within the frequency range 50 Hz to 500 kHz.IntroductionInduction heating is commonly applied to the re-heating of billets before forging or extrusion processes. The resistive heating produced by eddy currents in the solid or semi-solid work piece during this procedure, is driven by the time varying magnetic flux density in the air-gap between the work piece and the coil. The flux in the air-gap is created by the current flowing in the induction coil, i.e. the magneto-motive force. In Figure 1 it can be seen that the currents present in the work piece are concentrated in the outer ‘shell’, or the first electromagnetic penetration depth (dw), and flow in a direction which opposes the magnetic field produced by the induction coil."

Jan 1, 2012

By B. Mishra

The application of various bydrometallurgical, pyrometallurgical and electrochemical processes in the extraction, purification and production of radioactive metals as well as the use of various materials, eg. metals and alloys, ceramics, polymers, etc. in the process, construction and handling equipment in the nuclear industry has generated a large stockpile of radioactively contaminated waste material and scrap metal which can not be directly discarded, recycled or considered for long-term storage due to its volume and potential hazards, without the separation of radionuclides. This paper reviews the emerging methods that have been &apos;investigated and suggested for dealing with some of these wastes&apos; and scrap material. The separation technologies studied for the recovery of radioactive components from the pyrometallurgical and electrochemical processing wastes have been discussed in details with results from some of the recent theoretical and physical modeling work as well as the data obtained? from the actual waste treatment. Specific processes shall be described in terms of its advantages and limitations. These emerging separation technologies are being considered by the US Department of Energy as alternatives for dealing with the issues of environmental management [EMI&apos; and decontamination and decommissioning [D&D].

Jan 1, 1996

By Mingming Zhang, Marcelo W. Andrade

The evolution of microstructure and mineral phases in iron ore sinters have been investigated by scanning electron microscope and QEMSCAN (Quantitative Evaluation of Minerals by Scanning Electron Microscopy). It was found that MgO, basicity and Al2O3 content play an important role in the formation of mineral phases and microstructure in sinter. The low Al2O3 (<2.0 wt%), medium MgO (2.0–2.5 wt%) and high basicity (>3.0) sinter showed higher low temperature degradation index (LTD) due to the presence of silico ferrites of calcium and aluminium (SFCA), and magnetite phase, and lower pore phase as compared to low basicity iron ore sinter.

Mar 1, 2017

By Peter G. Mason

Over the last 15 years numerous Pressure Oxidation and Pressure Leach plants have been installed throughout the world. The technology is no longer regarded with awe and trepidation as plants designed to treat a wide range of feedstocks continue to be successfully brought on line. Important aspects of the design of such plants include feed preparation, slurry pumping, heating and heat recovery, pressure control and let-down, vessel design, safety and provision of associated services.

Jan 1, 1999

By Jerry D. St. Clair

A multidisciplinary team of scientists and engineers at Wont has been working to understand heavy metal contamination of DuPont process waste streams and technologies for abatement of these metals. As part of this effort, an extensive study was made of a specific waste stream of importance in DuPont&apos;s environmental commitment. This 200 gpm stream contains 5-5000 ppm of nickel plus a variety of inorganic and organic constituents. The chemical complexity of the waste rendered conventional. alkaline precipitation ineffective, and only through the simultaneous application of analytical characterization, fundamental chemical understanding, and process engineering did effective technical approaches emerge. In this instance, ion exchange, sulfide precipitation, and caustic digestion ultimately proved successful in reducing the nickel to below the 1 ppm target. The results of this study will be presented, along with key learnings about the process of solving heavy metal contamination problems.

Jan 1, 1994

By Z. R. Llanos

This paper presents a review of industrial and experimental processes for the recovery of molybdenum, vanadium, nickel, cobalt and aluminum from spent hydrotreating or hydrodesulfurization catalysts. Numerous processes have been developed in a laboratory and pilot scale. However, worldwide, there are only four well established commercial facilities currently in operation. The installed capacity of these facilities exceeds the availability of spent catalysts and may be sufficient to assimilate future increases of spent catalysts. Despite liability risks; significant quantities of spent catalysts are still being landfilled. Changing regulations that may affect the future handling and disposal of spent catalysts are also reviewed.

Jan 1, 1995

By Geoffrey S. Plumlee

The Summitville gold mine, located in southwestern Colorado, received tremendous publicity in the 1980&apos;s and 1990&apos;s for leaks of cyanide solutions from its heap leach facility. As is typical with cyanide spills, real time, geochemically rigorous assessments of the environmental effects were not performed. Past United States Geological Survey (USGS) research used simple mixing experiments to model the influx of alkaline cyanide heap leach solutions from Summitville into a nearby stream, whose waters were highly acidic due to severe acid-rock drainage (ARD) from the mine. These experiments indicated WAD cyanide rapidly degraded due to formation of Fe-Cu-CN solids and lesser HCN volatilization. The alkaline heap leach solutions also precipitated hydrous iron-and aluminum, oxides and hydroxysulfates (iron and aluminum &apos;supplied by the acid. rock drainage (ARD]), which then sorbed copper and other heavy metals from the ARD. These results indicate that mixing of cyanide heap leach solutions with ARD may be a cost-effective remedial method at mine sites where treatment of both is required. New experiments are currently in progress to further refine a potential remedial process.

Jan 1, 1998

By Katri Avarmaa

Aluminum and copper are large volume metals in electronic appliances, while tin and indium exist as common minor elements. All of these non-ferrous metals are aimed to be separated and recycled from the end-of-life electronics into non-ferrous scrap fraction(s), and further through pyrometallurgical and/or hydrometallurgical processes to pure metals. Depending on the mechanical pre-treatment processes, aluminum and copper liberation from each other varies. This study focuses on the influence of alumina on indium and tin distributions between copper alloy and iron silicate slags with 0, 9 and ∼16 wt% of Al2O3. The experiments were executed with an equilibration-quenching-EPMA technique in an oxygen pressure range of 10−10–10−5 atm at 1300 °C. The metal-slag distribution coefficient of indium remains constant as a function of alumina in slag, while that of tin increases. Therefore, aluminum in feed or alumina addition to the slag improves the recovery of tin into copper. Nevertheless, oxygen pressure has clearly more significant influence on the behavior of both the metals in the smelting conditions.

By James Vaughan

Australia is a major miner of ore that requires hydrometallurgical processing. According to the 2016 US Geological Survey Minerals Commodities Summaries, the country is 1st for aluminium (bauxite) and lithium, 2nd for gold, zinc and cobalt, 4th for nickel and silver, and 6th for copper mining, not to mention its wealth in coal and iron ore. In this paper, examples of recent Australian hydrometallurgical activities are summarised. Then, selected research projects from the University of Queensland hydrometallurgy research group are profiled. The projects profiled are related to fundamental aspects of processing bauxite with organics and reactive silica as well as the development of a synergistic hydro- and pyrometallurgical process for copper. The process context and motivation for the research is introduced, key results are highlighted with the associated relevant references.

By Mingming Zhang, Ramana G. Reddy

A 3-D mathematical model was developed for the batch reactor of low temperature aluminum electrowinning using ionic liquid electrolytes. This model describes the deposition process by incorporating the mass transport of participating ionic species, homogeneous chemical reactions within the diffusion layer, and the associated electrochemical kinetics. Processing parameters, current and potential distribution, species concentration, fluid flow distribution, and electrode spacing were evaluated for the optimal reactor performance. The results indicated that the electrode spacing significantly affects the electrolyte fluid flow and current density distribution. The parallel electrode configuration (in line with electrolyte inlet) improved the convection and resulted in uniform current density distribution and electrolyte fluid flow. However, for this electrode configuration, electroactive species distribution was most favorable between the electrodes. Perpendicular configuration of electrodes resulted in a more non-uniform fluid flow within electrolyte domain, and it has a potential to cause non-uniform deposits. Aluminum electrowinning experiments were conducted using batch reactor at 80 °C, electrolyte flow rate of 5–20 ml/min, and applied cell voltage of 3–3.5 V. Good agreement was obtained between the model and the batch aluminum electrowinning experimental results.

Mar 1, 2017

By Rajesh S. Ransing

An intelligent tool has been developed to analyse the quality of diecast components. The influence of both design and process parameters has been studied in great detail. The tool, based on expert systems related technologies, can identify the causes for the defective castings manufactured. Design related causes such as gate position; gate area, runner design etc. as well as process related causes such as cycle time, cavity filling time and melt temperature are suggested by analysing the data on defective castings for a manufacturing campaign. This intelligent analysis is useful for both design as well as production engineers in the decision making process. All the causes for the occurrence of defects are classified into two categories. The firs category is the &apos;rootcauses&apos; i.e. the causes which are related to the actual process, material and design parameters and which can be directly monitored. The second category is more abstract in nature and is classified as `metacauses&apos;. These capture the scientific rationale implicit in the cause and defect relationships. This knowledge on causes and defects is represented in the form of a structured graph rather than by a set of rules, which, coupled with forward reasoning and heuristic search techniques results in an elegant and efficient approach. Uncertainties and the degree of relationship among causes and defects are represented by a fuzzy probabilistic model.

Jan 1, 1994