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By Y. Rao, Y. Huang, G. Wang, W. Liu

The properties and deterioration in strength of cemented tailings backfill (CTB )in the underground acidic environment under oxidizing conditions were studied. X-ray diffraction analysis and scanning electron microscopy of the surface of the CTB was carried out, and the sulphuric acid corrosion mechanism elucidated. The properties tested included compressive strength, elastic modulus, cohesion, internal friction angle, variation in the hydrogen ion concentration, and stress-strain relationship in different corrosion periods. The damage model of the CTB was established considering the effects of parameters such as corrosion time and strain on the damage evolution. It was found that the compressive strength, elastic modulus, cohesion (binder effect), and internal friction angle increased at first and then decreased with exposure time. In the long term, the peak stress decreased with corrosion time while the peak strain increased; elastic modulus, and deformation modulus also decreased. The damage caused by corrosion and by load were related by means of a mathematical model, which revealed the relationships between sulphuric attack, load, and damage to backfill in complex underground environments. During corrosion, the expansion of gypsum and ettringite caused microfractures in the CTB. With increasing corrosion time, micro-cracks developed and proliferated. The mechanism of corrosion damage was found to be the dissolution of hydrogen ions and a sulphate ion reaction that produces an expansive substance, resulting in deterioration of the strength of CTB.

Jun 1, 2021

By R. P. H. Willis, A. G. du Plessis, R. B. Wilson

This paper reviews issues to be considered in choosing primary access and transportation options for platinum and other mines. It proposes appropriate criteria and a methodology for deciding on the optimum primary access option for any particular orebody. Also included are generic parameters that can be used to facilitate the process of choosing the optimal access option.

Jan 1, 2004

By W. K. Ting, A. Hasan

Mine stope is typically backfilled with cemented paste backfill, which provides a regional underground stability and also a reduction of aboveground tailings accumulation. During backfilling, a phenomenon known as arching occurs and affects the stress distribution of the cemented paste backfill. The change in temperature due to uncontrolled heat transfer from the surrounding rock mass and/or generation from hydration process complicates the stress distribution development of cemented paste backfill. This paper presents results of the investigation on the effects of hydration to cemented paste backfill behaviour when backfilled into a narrow wall model using uncemented paste backfill as controlled sample. The parameters considered include backfill type (cemented paste backfill vs uncemented paste backfill), curing temperature (30°C–60°C), and stress evolution during pouring, consolidation, and curing stages. Results show that uncemented paste backfill re-establishes arching effects more readily, with lower peak stresses and greater stress relaxation than cemented paste backfill, of which its behaviour is significantly influenced by hydration under elevated temperatures. The main outcome of this work is that hydration critically controls the stress-temperature response of cemented paste backfill, and the balance between hydration-driven strength gain and stress relaxation can be leveraged to optimise backfill mix design for safer and more efficient stope filling.

Jan 30, 2026

By A. J. Jager, D. P. Roberts

The stoping of platinum orebodies in the Bushveld has in the past been accomplished by using in-stope pillars to ensure stability of the workings. In the future, the use of continuous mining machines to mine the platinum orebodies is probable. It is not envisaged that such machines will cut in-stope pillars. This paper describes the alternative support systems that will replace the pillars and the stope geometries that will be required for this type of mining. The paper describes how the support resistance provided by in-stope pillars in current mining was determined and then evaluates support systems that can substitute for these pillars. Conceptual layouts based on existing breast mining layouts are presented. The layouts consist of panels of up to 100 m face length between rigid strike stabilizing pillars. A number of design charts are then proposed that allow for the design of appropriate support systems.

Jan 1, 2004

Careful monitoring of the position of the cave front is essential for well-managed block cave mining. Seismic monitoring systems yield 3-D information about the location of fracturing ahead of the cave. However, because the a seismic gap between cave surface and seismogenic zone is of unknown extent, the cluster of micro-seismicity can only yield an upper bound for the cave height. The large velocity contrast between the fractured rock in the aseismic gap and the broken loose material within the cave can be used by an inversion procedure to find a few simple geometric parameters (such as height of the top of the cave) if a simple 3-D shape?for example a paraboloid?is assumed for the cave. Ray-tracing must be used as the large velocity contrasts cause seismic waves to bend around the cave, but the inversion takes the form of a minimization problem in only a few dimensions and so the computational time is feasible. This technique has been successfully tested on realistic synthetic data.

Jan 1, 2007

By A. Chiappone, M. Barla, U. Rabagliati, L. Repetto

ABSTRACT: The paper describes the application of both continuum and discontinuum modelling to the study of the stability conditions of the Alpetto mine, a high rock cut located in Cesana Brianza (Italy). The main objective is to provide valuable information for future mine planning and for the assessment of the stability conditions of the abandoned high rock cuts. Continuum modelling involved the applications of the finite difference method, whereas the distinct element method was used for discontinuum modelling. RESUME: L'article décrit l'application des méthodes de modélisation continue/discontinue pour l'étude des conditions de stabilité de la mine d' Alpetto, située à Cesana Brianza (Italie). Le but du travail consiste à determiner des paramètres utiles vis-à-vis du projet et d'estimer les conditions de stabilité de l'amas rocheux au terme de l'exploitation de la mine susmentionnée. La modélisation continue a impliqué l'application de la méthode des différences finis alors que la méthode des éléments distincts a été utilisée pour la modélisation discontinue. KURZFASSUNG: Der Artikel beschreibt die Verwendung der Modellierung von continuum und discontinuum zur Untersuchung/Studium der Stabilitätsbedingungen von der Alpetto Mine, hohe Aushubsfront in einer Felsmasse die sich in der Gemeinde von Cesana Brianza befindet. Das Hauptziel dieser Arbeit ist die Festlegung von Parametern die zur Planung nützlich/behilflich sein können sowie auch die Möglichkeit zur Analyse/Auswertung der Stabilität der Felsmasse-Front nach Aufhebung der Nutzung derselben. Die continuum Methode/Analyse wurde verwendet durch Unterstützung der Finite Differenz Methode da man für die Analyse der discontinuum (Fels als discontinuum beschrieben) der Distinct Elemente Methode verwendet hat.

Jan 1, 2003

The captions to Figs. 1 and 2 of the paper by B. J. Parry entitled 'High-strength cold-rolled steels' should read as follows:

Jan 1, 1984

By T. J. Otto, G. C. Lindeque

Productivity is improved by increasing the ratio of output to input. In an operating open-pit mine, improving the productivity of heavy mining equipment (HME) enables the unit cost of production to be reduced. To optimize HME productivity, the Kolomela open-pit iron ore mine transitioned to an enhanced short-term mine planning (STMP) process that supports the application of a manufacturing-type operating model. At the core of the enhanced STMP process is a focus on integration across the open-pit mining value chain. The interdependencies between mining activities are highlighted and emphasized, thus ensuring that mining activities are synchronized. The improvements related to HME productivity were monitored from 2019 to 2020. The utilization of mining area in the Leeuwfontein pit improved from 71% to 90%, and the blasting frequency reduced by 14% while the average blast size increased by 17%. The distance travelled during shovel relocations between mining phases reduced by 16%, and the lost time associated with drills relocating reduced by 53%. These productivity improvements resulted in an 11% increase in the loading rate of the main waste shovel at Kolomela from 0.9 Mt/month in 2019 to 1.0 Mt/month in 2020. The enhanced STMP process can be adapted to other open-pit mining operations.

Nov 1, 2021

By I. M. Wolf, S. A. Usmar, L. A. Cornish

The limiting criterion in the use of stainless steel for certain forming operations such as coining is its hardness, which determines parameters such as required striking pressure, wear on dies, and integrity of pattern detail. Attention is given here to the development of ultra-soft ferritic stainless steels for coinage. In the first instance, the influence of carbon content on the striking properties of a series of commercial and experimental 17%Cr alloys was evaluated. It was found that a lower carbon content permitted the striking of relatively highly profiled and intricate patterns, provided that the hardness did not exceed 125 HV. Hardnesses as low as 115 HV were achieved in the fully annealed condition, but these alloys required high striking pressures. In a further study, three grades of experimental 14%Cr ferritic stainless steels were produced with a view to optimizing the ductility. When the residual impurities were minimized, hardness values of about 100 HV and lower were achieved. Micro-alloying additions allowed the heat-treatment response and grain size to be controlled. Excellent tensile properties, with elongations of up to 42 per cent, were achieved in the fuly annealed condition, and highly profiled patterns were produced in coining trials.

Jan 1, 1993

By S. Banisi, S. Zare, M. Mahmoudi, M. Maleki-Moghaddam, M. Yahyaei

As the orebodies become more complex and lower grade, there is an increasing demand from crushing circuits for a finer product. When the product from a crushing circuit does not satisfy the requirements of the downstream processes, the cost of production increases. Thus, enhancing the performance of cone crushers through optimisation of their operating factors becomes important. One of the key factors affecting performance of cone crushers is the filling of the crushing chamber during the operation. The effect of varying the filling of the crushing chamber of a cone crusher was investigated. To assess the crusher performance, parameters such as crusher capacity, power utilisation, and reduction ratio were used. Extensive plant trials were conducted to obtain samples and operational data when the crusher chamber was 50% full (half-full) and 100% full, which is 300 mm above the top of the crusher chamber (super-choked condition). The results indicated a 62% difference in the crushing capacity when the crusher was operated in a super-choked condition compared to the half-full chamber level. In the super-choked condition, the size-specific energy at 12.7 mm was 20 % lower than that of the half-full condition. The Bond ball mill work index (BBWI) of crusher product indicated that the BBWI of the product of the super choked condition is 5.6% less than that of the product of half-full condition. This can be attributed to the generation of micro cracks in particles due to increase in the interparticle breakage when the crusher was operated in the super-choked mode. Keywords: Cone crushers, crushing efficiency, crushing chamber filling

Jan 1, 2020

By M. Lange

The postulation that primary platinum group metal (PGM) matte will chemically react with magnesia-chrome bricks when temperatures exceed 1500°C was tested. Magnesia-chrome brick samples were heated in contact with matte at 1300°C to 1750°C for 30 minutes, after which the refractory samples were analysed using reflected light microscopy and scanning electron microscopy. The samples were all completely penetrated by matte. As the temperature increased the matte also penetrated the fused aggregate grains and disintegrated them. The chromium concentration of the matte inside the refractory samples was found to be slightly higher than that of the bulk matte. At temperatures of 1500°C and higher, MgO, FeO, and magnesium-rich silicate crystals could be identified in the matte directly adjacent to the refractorymatte interface. Phase relations clearly indicated that chemical reactions take place between primary PGM matte and the magnesiachrome refractory material at temperatures above 1500°C, but that these reactions are more complex than expected from FactSAGE® calculations.

Jan 1, 2014

By J. P. Gouvea, T. R. Stacey

A research project was carried out on a gold mine in the Vaal River region of South Africa (Witwatersrand Basin) to evaluate the effect of two particular aspects of rockbolt installation – the angle of inclination of the bolt relative to the orientation of the rock surface, and the protruding length of the bolt – on the mine’s gully support system. A keyblock analysis approach indicated that these factors do not have an adverse impact on the stability of the strike gullies. This was confirmed by extensive empirical data collected from the case study mine. While safety is the primary concern, cost saving opportunities can be realized through reconsidering historically inherited support standards that are perceived to be correct and appropriate. The research described in this paper sets forth a practical approach, that is easy to implement and repeatable, to evaluate the role of rockbolts in stoping gullies.

Feb 12, 2024

By M. Gomo, L. S. Mokhahlane

"Underground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for electricity generation. Residue products from UCG have the potential to leach into surrounding groundwaters. The geochemistry and leaching dynamics of these products are explored in this study. The products include char, ash, and the heat-affected zone in the surrounding rocks. Core samples from the pilot plant at Majuba are the first ever to be recovered from a UCG cavity in Africa, and they give key insights into the geochemistry of the gasification zone. Mineralogical and chemical analyses were performed on the samples, and acid-base accounting (ABA) was used to predict the acid-producing capacity of the gasification zone, particularly for char samples. Some of the char contained pyrite, although not all samples were acid-producing as determined by the ABA analysis. The ABA results showed that some of the unburned coal has moderate levels of sulphur, which could be the driving medium for acidic conditions. The ABA analysis indicated that water in contact with the gasification zone would eventually have a pH lower than 7, which could lead to acid rock drainage. These results form part of a preliminary investigation into the geochemistry of the reaction zone, post gasification. IntroductionUnderground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for industrial purposes, including electricity generation. The gasification process leads to the formation of a cavity composed of char, rubble, and void space (Bhutto, Bazmi, and Zahedi, 2013). Residue products from UCG have the potential to leach into groundwater. These products include char (devolatilized coal), which can generate acid rock drainage (ARD). ARD is caused by the oxidation of sulphide minerals, which acidifies the leachate, thus increasing the solubility of some environmentally toxic metals (As, Cd, Hg, Pb, Zn, etc.) (Bouzahzah et al., 2015).The main source of ARD is oxidation of sulphide-bearing minerals due to interactions with oxygen, water, and microorganisms (Simate and Ndlovu, 2014; Kefeni, Msagati, and Mamba, 2017; Bouzahzah et al., 2015). Although ARD occurs naturally, it can be enhanced by mining activities that escalate exposure of sulphide minerals to water, air, and bacteria (Simate and Ndlovu, 2014). At the Majuba pilot plant, the unburned coal remaining in the cavity has been in contact with groundwater since the gasifier was shut down in 2013. It is possible that in a commercial UCG plant, most of the coal will be consumed and no unburnt coal will be left in the cavity. Most of the sulphur will be converted to H2S during the gasification process and transported with the syngas to surface, where it can be removed and captured as elemental sulphur."

Oct 1, 2018

By M. B. Díaz Aguado, I. Á. Fernández, C. González Nicieza, B. S. Menéndez

This paper summarizes the works that the Research “Group of Ground Engineering”, belonging to the Mining Department of the University of Oviedo, Spain, has been developing in close cooperation with the Regional Mining Department, since 2001, in order to control and monitor an experimental underground limestone exploitation by the room and pillars method. The aim of the current research is not only the geotechnical characterization of the rock mass (by means of laboratory and site tests) or the instrumentation of its displacements and stress changes (using convergence meters, INCREX probe, extensometers and rigid inclusion cells), but, moreover, to undertake intensive monitoring and control of such pilot mine, which is mined exclusively in order to accomplish this research. The data transmission was made on line via Internet, to achieve a full understanding of the behaviour of the experimental mine, to access data from remote locations and to visualize results from a website. All the collected information becomes input data for several numerical models using finite differences under a program developed in the research Group, ALMEC. The simulation and a final economical analysis lead to a design of an underground exploitation, at production scale, for a resource that is traditionally mined by means of open-pit process methods that could be worked underground with less environmental impact. The main purpose achieved by this exhaustive analysis is the technical and economic viability of such mine, for their optimisation for a future productive exploitation.

Jan 1, 2003

By W. Lin, H. Endo, M. Kwasniewski, A. Kamei, M. Takahashi

Uniaxial tension tests were conducted on specimens of eleven granitic rocks which came from eastern Japan, and included a granite, four granodiorites, four tonalites and two gabbros. The axial and transversal deformability of these rocks was determined based on strain measurements using wire strain gauges. The experimental test results revealed that deformational properties of the rocks investigated varied depending on their petrographic features. However, the axial strain and the lateral strain characteristics showed a similar trend for all the rocks, i.e. the stress-strain curves were non-linear throughout the whole stress range from the initial point of loading to the point of ultimate failure. Moreover, the tangent Young's modulus and the ratio of the lateral strain to the axial strain decreased monotonously with the increasing of the axial stress. Still, the deformational properties were different for individual rocks in a quantitative sense. In particular, the difference in the lateral strains among different rocks was more distinct than that in the axial strains. For example, the Poisson's ratio at a stress level equal to 50% of the ultimate strength of a granodiorite was very low, close to zero. Furthermore, the Poisson's ratio of a tonalite was lower than that of a granodiorite, and assumed a negative value. This effect occurred because the lateral strain became positive as it changed from contraction at the initial stage of loading to extension at higher stress levels. There is no ready explanation for this phenomenon; it is believed, however, that it occurs due to microcracks pre-existing in rock materials and/or weak bonds between the adjacent mineral grains. Les essais de traction directe ont été conduits sur les échantillons de onze roches granitiques provenant de la région Est du Japon: un granit, quatre granodiorites, quatre tonalites et deux gabbros. Déformabilité axiale et transversale de ces roches s’était déterminée en utilisant des jauges extensométriques à fil. Les résultats obtenus à partir des essais montrent que la déformabilité des roches examinées varie selon leurs propriétés pétrographiques. Cependant, à partir des essais, une tendance semblable était observée dans les paramètres de la déformation axiale et la déformation latérale de toutes les roches; c'est-à-dire chaque courbe de contrainte-déformation était non-linéaire dans tout l'intervalle de contraintes à partir de l’état initial jusqu’à l’état d’une rupture finale au cours du chargement. De plus, le module tangent de Young et le rapport de la déformation latérale sur la déformation axiale a diminué de manière monotone avec l'augmentation de la contrainte axiale. Cependant, les différences quantitatives de propriétés de déformation sous traction étaient observées entre des roches individuelles. Particulièrement, la différence de déformations latérales était plus notable que celle-là de déformations axiales entre des roches différentes. Par exemple, le coéfficient de Poisson à un niveau de contrainte égal à 50 % de la résistance d'un granodiorite était très bas, près du zéro. En outre, le coéfficient de Poisson de la tonalite était inférieur que celui du granodiorite et a assumé une valeur négative. Cet effet est apporté parce que la déformation latérale est devenue positive en passant de la contraction dans l'étape de chargement initiale à l'extension sous les contraines plus hautes. Il n'y a aucune explication prête de ce phénomène; on prétend, cependant, qu'il est induit par des microfissures préexistantes dans des matériaux rocheux et/ou des joints faibles entre les grains minéraux adjacents. Einaxiale Zugversuche wurden auf Probestuecke von elf frischen, in Ostjapan vorkommenden, granitartigen Gesteinen durchgefuehrt, welche einen Granit, vier Granodiorite, vier Tonalite und zwei Gabbros umfassten. Die axiale und transversale Verformbarkeit von diesen Gesteinen wurde durch Verformungsmessungen mit Drahtdehnungsmessstreifen geklaert. Die experimentellen Versuchsergebnisse offenbarten, dass Verformbarkeitseigenschaften des untersuchten Gesteins in Abhaengigkeit von ihren petrographischen Eigenschaften variierten. Jedoch zeigten die axialen und die lateralen Spannungsdehnungslinien eine aehnliche Tendenz bei allen Gesteinen, d.h. die Verformungskurven waren nicht linear im ganzen Bereich vom Ausgangspunkt des Belastens bis zum Punkt des entgueltigen Bruchs. Ausserdem verringerten sich das tangentiale Elastizitaetsmodul und das Verhaeltnis der lateralen Verformung zur axialen Verformung monoton mit der Erhoehung der axialen Spannung. Dennoch waren die Verformbarkeitseigenschaften der einzelnen Gesteine in der quantitativen Wahrnehmung unterschiedlich. Insbesondere war der Unterschied bezueglich der lateralen Verformungen zwischen verschiedenen Gesteinen eindeutiger, als der in den axialen Verformungen. Z.B. war die Querkontraktionszahl auf einem Spannungsniveau, das 50% der Zugfestigkeit eines Granodiorits entspricht, sehr niedrig und nah an Null. Ausserdem war die Querkontraktionszahl eines Tonalits negativ und deshalb niedriger als die eines Granodiorits. Dieser Effekt trat auf, weil die laterale Verformung, als sie sich von der Kontraktion am Ausgangsstadium des Belastens bis hin zur Ausdehnung auf den hoeheren Spannungsniveaus aenderte, positiv wurde. Es gibt keine fertige Erklaerung fuer dieses Phaenomen; es wird jedoch angenommen, dass es wegen der Mikrorisse auftritt, die vorher im Gesteinsmaterial und/oder in den schwachen Bindungen zwischen den angrenzenden Mineralkoernern existieren.

Jan 1, 2003

By M. Pötsch, W. Schubert, A. Goricki

Geological and geotechnical data are essential for the design of tunnels. To determine the rock mass behavior and the support of a planned tunnel excavation a consistent method for rock mass characterization and excavation and support determination has been developed. Probabilistic data processing with analytical methods is used for the quantification of the procedure and allows an evaluation of the applicability and the technical risk of different excavation and support methods. The sensitivity of the procedure on selected input parameters is highlighted in a parametric study. Finally an application of the procedure illustrates the use of the described method of probabilistic excavation and support determination for tunnels. Des données géologiques et géotechniques sont décisives pour la planification d’un tunnel. Pour la détermination du comportement des strates, le choix du soutènement et de la méthode de progression une description compréhensible de la montagne a été développée. À l'aide d'un traitement de données probabiliste, la procédure proposée est transposée quantitative sur une base de méthodes analytiques. De cette manière l'évaluation des méthodes de construction et la détermination du risque technique deviennent possibles. La sensitivité de la procédure de différents paramètres d'entrée est représentée dans une étude de paramètre. Pour finir, l'application de la procédure décrite est montrée à l’aide d'un cas pratique. Geologische und geotechnische Daten sind entscheidend für die Planung von Tunnels. Für die Ermittlung des Gebirgsverhaltens und der Festlegung von Ausbruch und Stützung wurde ein nachvollziehbarer Ablauf der Gebirgsbeschreibung entwickelt. Mit Hilfe von probabilistischer Datenverarbeitung auf Grundlage analytischer Methoden wird die vorgeschlagene Prozedur quantiativ umgesetzt. Dadurch werden die Bewertung von Baumethoden und die Ermittlung des technischen Risikos ermöglicht. Die Sensitivität des Verfahrens von einzelnen Eingangsparametern wird in einer Parameterstudie dargestellt. Abschließend wird anhand eines Beispiels die Anwendung des beschriebenen Verfahrens gezeigt.

Jan 1, 2003

Report M294 A mineralogical investigation of potential gold-sorbing minerals and shales, by c.T. Logan. Dec. 1986. 12 pp. Computer software The Fifth IFAC/IFIP Symposium on Software for Computer Control (SOCOCO 88) is to be held in J ohannesburg from 26th to 28th April, 1988. Tunneling 88 The Institution of Mining and Metalurgy, with the cooperation of the British Tunneling Society, the Institution of Mining Engineers, and the Transport and Road Research Laboratory, Department of Transport, is pleased to announce the fifth international symposium, Tunneling 88, which wil be held in London, England, from 18th to 21st April, 1988. Ion-exchange processes ION-EX '87, an international conference and industrial exhibition on the industrial, analytical, and preparative applications of ion chromatography and ionexchange processes, wil be held in Wrexham (North Wales) from 13th to 16th April, 1987.

Jan 1, 1987

South Africa?s now a member of this body, tailored on the World Bank, and headquartered in Abidjan-Cote d'Ivoire. As a funding agency for capital projects within 59 member countries of the ADB it is to be expected that there are guidelines to the requirements for funding application and for project management and control.

Jan 1, 1996

By S. Adams, J. R. C. von Holdt, J. L. Broadhurst

Fugitive dust from mineral extraction and processing activities can significantly influence air quality, the environment, and the health and quality of life of workers and surrounding communities. Poor engagement and communication between experts and lay persons, disciplinary silos and polarised viewpoints have made it difficult to develop a holistic understanding of the complex health issues associated with environmental emissions of mine dusts, and consequently to design meaningful and integrated approaches to address such issues. The collaborative Global Challenges Research Fund (GCRF) Mine Dust and Health Network, hosted by Minerals to Metals at the University of Cape Town, serves as a collaborative think-tank to inform research directions within and across disciplines, government policy and regulations, health monitoring programmes at public clinics, industry best practice, community healthcare and impact prevention programmes. It focuses initially on the southern African region, but with the intention to expand to mining-intensive developing countries within the rest of Africa, South America and Asia. This paper outlines the approach and activities of this global transdisciplinary and intersectoral network and presents some of the key outputs and achievements to date. Keywords: Mine dust, Global Challenges Research Fund Mine Dust and Health Network

Jan 1, 2020

By P. Fu, Y. Ma

Residual collectors and their byproducts (e.g., CS2) in flotation effluents can cause water contamination and even result in serious health hazards to humans and animals, Therefore, residual flotation reagents should be removed properly before discharge or recirculation into flotation circuits. In this work, four thiol collectors (potassium ethyl xanthate (EX), sodium diethyl dithiocarbamate (SN- 9), O-isopropyl-N-ethyl thionocarbamate (Z-200), dianilino dithiophoshoric acid (DDA)) were chosen as model pollutants. The collector removal, mineralisation and byproduct formation were compared by sole O3 and O3/UV185+254nm. The degradation rate constants of thiol collectors by O3/UV185+254nm were 2~6 times higher than those by sole O3. The mineralisation of collectors was also remarkably enhanced by O3/UV185+254nm. The degradation efficiency by O3/UV185+254nm had the order: EX>SN-9>>Z- 200>DDA. The Z-200 and DDA were refractory flotation reagents. The degradation of thiol collectors caused the reduction of solution pH and the increase of ORP and conductivity. However, the O3/UV185+254nm achieved more evident changes of these parameters than sole O3. During the degradation of thiol collectors, less than 4% of total sulfur in collectors was emitted into air as CS2 and H2S. Compared to sole O3, the O3/UV185+254nm had additionally included UV185+254nm photolysis and O3/UV254nm, resulting in higher efficiency in removing collectors. The O3/UV185+254nm was an effective process in treating mineral flotation wastewaters containing organic reagents. Keywords: Thiol collectors; flotation effluents; ozone; vacuum-UV; degradation, mineralisation

Jan 1, 2020