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By R. H. Lien

The Bureau of Mines developed a flue gas desulfurization process as part of its goal of minimizing the undesirable environmental impacts associated with energy and mineral-processing plants. The modified citrate process involves absorption of sulfur dioxide (S02) in a buffered citric acid solution. The S02-loaded solution is regenerated by countercurrent contact with steam in a packed tower. The wet S02 product is then dried and can be liquefied or further processed to make sulfuric acid. Test data from process investigation unit studies are presented. Material balances, flowsheets, and cost estimates are given for recovering S02 from copper smelter reverberatory gas, lead smelter sintering machine tail gas, and power-plant stack gas. Operating cost estimates show the process will add $0.04 per pound of copper, $0.01 per pound of lead, and $0.015 per kwhr to the cost of the respective operations. These costs could be substantially reduced if a source of waste heat was avail-able to provide the process steam requirements.

Jan 1, 1982

By Joe L. Castagno, Kenneth H. Johnston

Several hundred membrane - filter tests were made as part of a program to develop equipment and procedures to evaluate the quality of waters and to determine the quality of water suitable to efficiently flood oil sands of known permeability . Results indicated that neither the color of the water nor that of the precipitate on a membrane filter is a criterion for determining the quality of injection water . Reasons for poor water quality include poor operation of filtering systems , dirty filtering aggregates , excessive amounts of oil in injection water , commingling of incompatible waters , and excessive use of chemicals . A good water is required to efficiently flood sands of low permeability , but fair results may be obtained in flooding more permeable sands with poorer quality water .

Jan 1, 1964

By Manuel Gomez

The mean and the standard deviation were used to describe general sulfur and ash populations as well as specific populations of these variables from one coal seam. Both the mean and the standard deviation were incorporated in the exploration process to determine the number of drill cores necessary for seam evaluation and to guide the sequential drilling plan. Probability regions were computed to establish a basis for predicting probable ranges of average sulfur and ash concentrations that may be expected upon continued or future drilling. A computerized plot program was utilized to interpolate sulfur and ash concentrations between grid points. The plot program, which is essentially a moving average technique, permits a rapid evaluation of sulfur, sulfur forms, and ash spatial distributions as a drilling program progresses sequentially. This information, in the form of contour plots, can be made available to both the mining engineer and the fuel technologist in advance of mining to outline reserves, to improve selective mining, and to anticipate preparation facilities.

Jan 1, 1972

By R. V. Higgins

A numerical method is presented to calculate the isopressure (isobar) lines and streamlines for an oilfield from the pressure distribution. A knowledge of these lines is useful in the study of the flow of fluids in underground reservoirs, especially for those containing gaseous and/or liquid hydrocarbons. This work was done primarily to enable determination of the shape factors needed in the calculation of petroleum reservoir performance. However, it has application for the flow of water in aquifers, or electricity or heat in odd-shaped geometry. Techniques previously developed were used to calculate the pressure distribution. From this pressure distribution, the isopressure lines were calculated accurately by the method presented in this paper. Then by successively projecting orthogonal lines from one isopressure line to another, the streamlines are determined. From the coordinates of the isopressures and the streamlines, the shape factors can then be determined by a published method. Computer methods are presented to calculate the streamlines and isopressures for any well-spacing pattern existing within a field with multiple wells. The method reproduces the flow net for several well configurations having extensive geometrical variations. Such information provides the petroleum engineer with data from which he can compute oil recoveries for different patterns and thereby maximize the recovery of hydrocarbons from the reservoir.

Jan 1, 1972

By John Durkin

A computer model has been generated to evaluate speech intelligibility of individuals wearing conventional and electronic hearing protectors. For speakers talking at normal levels in noise levels of 65 db(Lp) or less, it was found that conventional hearing protectors significantly reduced speech intelligibility. Under the same conditions, electronic protectors provided scores equal to those for the unprotected individuals while providing protection from high noise levels. Therefore, electronic hearing protection is valuable in areas where high noise level is intermittent.

Jan 1, 1979

By G. A. Howes

This is one of a series of circulars dealing with the cost of equipping and developing mining properties in the United States and Canada, prepared and published by the Bureau of Mines in cooperation with various mining and exploration companies. This group of circulars is designed to supplement an earlier series which covered the methods and costs of mining and milling at a large number of producing properties. ACKNOWLEDGMENTS The authors desire to thank Robert A. Bryce, president of Macassa Mines (Ltd.), for permission to use the data presented in this paper, and to acknowledge the cooperation of A. J. Keast, under whose direction as manager the plant was installed and equipped and the shaft was sunk to a depth of approximately 2,000 feet.

Jan 1, 1932

By William P. Diamond

Ventilation has long been the primary means of controlling methane emissions in underground coal mines. However, as mining has progressed into gassier areas of U.S. coal basins, supplemental means of methane control have become of interest, if not a necessity, for continued safe and productive mining operations. This paper describes the history and technology of methane drainage in the United States and other countries. The methane drainage technology developed in European countries is a valuable resource since their longer history of mining has already forced mine operators to deal with methane emission problems only now being experienced in the United States. Methods for assessing the need for methane drainage and the data required for planning and implementing an appropriate system are reviewed. The effectiveness of the various technologies for reducing methane emissions underground and/or the in-place gas content of individual coalbeds is illustrated with case studies. In addition to the safety and productivity gains to be realized from methane drainage systems, the potential for commercialization of coalbed methane is discussed.

Jan 1, 1994

By A. J. Leighton

An improved mathematical model with the attendant computer program to calculate multiphase fluid flow in petroleum reservoirs is presented. The model is used to simulate the behavior when a fluid is used to displace hydro-carbon fluids in a reservoir. The method is an expansion of a previously published method, in Bureau of Mines RI 7011, but handles constant injection rate as an alternative to constant pressure. Program documentation is provided along with thorough explanations of the added program features. Using the program, the petroleum engineer can calculate oil recoveries for different flood patterns and operating conditions and select the conditions most likely to optimize recovery. Experience with the previous model demonstrated the need for the improvements in order to simulate reservoir behavior more accurately. The improved method will result in improved oil recovery. In this paper, the significant improvements are described in detail so that anyone interested can put the program to use.

Jan 1, 1975

By R. R. Backer

The Bureau of Mines, in cooperation with Washington Irrigation and Development Co. (WIDCO), evaluated the dewatering of fine coal-refuse slurry using chemicals and various types and combinations of drains in natural earth impoundments. About 40 lb of lime and 2 lb of polymer per ton of dry solids were mixed with the underflow from the preparation-plant thickener. Clear, free water was immediately liberated from the slurry. The percent solids by weight of the slurry increased from about 17 to 30 immediately, and after 5 days increased to 45 wt-pct. This indicates a threefold reduction in total volume after 5 days from 172 cu ft/ton solids originally to 56 cu ft/ton solids.

Jan 1, 1981

By W. H. Ode

Low-temperature distillation tests at 200°, 350°, and 500° C. were made on a subbituminous coal from Boulder County, Colo., and a subbituminous coal from Weld County, Colo., in connection with a survey of carbonizing properties of American coals and investigations of their chemical and physical properties. The coal represented by the sample from Weld County was reported to give off combustible volatile matter at unusually low temperatures When placed on a fuel bed. The yields of tar and oil and the composition of the gas from this coal, as obtained in the distillation tests, did not confirm this report. These yields and the gas composition of the Weld. County coal differed but little from those obtained from the coal from Boulder County. Both coals yielded tar and gas in amounts considered to be normal for coals of their rank.

Jan 1, 1937

By A. W. Khair, L. D. Gehl

"This paper describes the mechanism of coal and rock cutting from quasi-static indentation through dynamic indentation to rotary cutting. The results indicate that during quas~static indentation, a crushed zone, and subsurface fractures develop. The crushed zone is a potential source of dust generation. Dynamic indentation produces a crushed zone due to the frictional resistance offered by the coal or rock during penetration of the bit. Confining pressure changes the mode of failure from tension to mixed tension and shear. The wider bit causes larger crushed zone and more dust generation. The rotary cutting is a combination of quasi-static and dynamic indentation which results in chip formation. 1. INTRODUCTIONThe trend from conventional mining to continuous machine-cutting of coal, using more productive machinery is inexorable. Intolerable levels of dust generated at the face is an indication of inefficient coal or rock cutting by these machines. The Federal Government of the United States paid about 11.7 billion dollars workman compensation to more than 470,000 miners with Coal Workers Pneumoconiosis (Newmeyer, 1981). Bieniawski and Zipf (1985) reported that annual benefit payments were about 2 billion dollars. The need for research m improving coal cutting 1s therefore paramount. The enactment of Health and Safety Act in 1969 in the United States triggered the initial investigation into coal cutting mechanism and cutting tool design. The European countries were also engaged in the same area of research, however, their emphasis was in the use of wedge shaped bits. In 1981, the United States Bureau of Mines commissioned the South West Research Institute to investigate the effect of operating parameters mainly on airborne respirable dust in order to provide a healthier and safer atmosphere for coal mine workers.A research program by the Department of Mining Engineering, West Virginia University, USA was initiated to study the fragmentation mechanism during coal/ rock cutting. The research program was divided into three areas of research, namely quasi-static indentation, dynamic indentation and rotary cutting."

Dec 1, 1995

By W. T. Reid

A shortage of anthracite for home heating indicates the necessity of using other fuels for this purpose; low-volatile bituminous, or "soft" coal is the most feasible supplementary fuel, either burned alone or when mixed with anthracite. Comparison of Bituminous Coal and Anthracite Whereas anthracite is clean, burns without smoke, and requires little attention, bituminous coal is dusty, tends to burn with a smoky flame, and forms coke in the fire pot that must be broken up to maintain a continuous high output of heat. When properly fired, however, bituminous coal responds more quickly than anthracite to changes in damper settings and consequently can supply more heat in a short time. It is generally less expensive and usually contains less ash than anthracite.

Jan 1, 1943

By F. Matanzo

This guide considers only nine of the many wire rope terminations used in the mining industry so use of the information presented for terminations not specifically addressed can be done, but with some risk. The nine terminations considered are: Flemish Loop with Steel Sleeve & Thimble, Flemish Loop with Steel Sleeve, Wedge Socket, Swaged Socket, Turn Back Loop with Aluminum Sleeve & Thimble, Thimble Splice with Four Tucks, V-Bolt Clip with Thimble, Zinc Poured Socket, and Epoxy Resin Poured Socket. The guide uses pull test data, axial fatigue test data, and data on sensitivity to poor workmanship, to rank the nine terminations with respect to these performance measures. A selection procedure is suggested and illustrated with an example. Failure data is used to identify the common modes of failure of each termination and so help the inspector direct his attention to the likely location for a failure and describe what he should be looking for. The data on which this guide is based is included so that as new data becomes available, the ranking order can be adjusted accordingly.

Jan 1, 1978

By E. Chin

The production of crude mineral commodities in Bangladesh was limited to natural gas, a small amount of construction materials, and clay for ceramics and bricks. No metallic minerals were mined. The only mineral commodity of economic significance was natural gas. Natural gas production has 'been climbing steadily and becoming an increasingly important source of energy for the country. Proved gas reserves were over 4.5 trillion cubic feet, but the amount has been increasing as exploration discovers large new deposits. Some sources quote reserves at over 10 trillion cubic feet.

Jan 1, 1984

By A. E. Raddatz

Previous Bureau of Mines research has shown that tungsten ores containing as little as 40 pct W032-can be processed by a high-temperature molten-salt extraction technique to produce a tungstate-bearing sodium chloride phase with 99 pct W recovery and little impurity contamination. The objective of this work was to demonstrate that the tungstate-bearing sodium chloride phase can be a suitable feed material for preparing am-monium paratungstate (APT) by a modification to the present industrial solvent extraction process. A combined crossflow-count·ercurrent flow solvent extraction technique to extract tungsten is presented. APT produced by this new technique contained 88.6 pct W032-and the following impurities, in percent: Mn02_ 0.0007, Mo02 0.017, P205 <0.010, and Si02 0.012. Implementation of this processing technique would improve tungsten recovery from concentrates and simplify processing operations.

Jan 1, 1988

By Jack O. Jones

The Furnish mine, Caharrus County, W. C., was operated intermittently until 1905 as a gold mine. Scheelite was discovered by A. L. Mash in the mine dumps of the Furniss and Phoenix mines, and he later informed the Bureau of Mines of his discovery. The Bureau of Mines, in two projects at the deposit in 1948 and in drilled 12 holes totaling 1,706.6 feet, examined and sampled the underground workings, excavated by bulldozer and hand, 3,155 linear feet of trenches and collected numerous samples for assay. The best scheelite shown; was found in the underground exposure of the Furniss mine.

Jan 1, 1950

By W. D. Riley

The Bureau of Mines is conducting research on methods for the rapid identification and sorting of mixed scrap metals and alloys so that domestic scrap resources can be fully utilized. One method, spark testing, is the examination of the pattern of sparks that results when a metal or alloy is ground on an abrasive wheel. This technique requires experienced sorters. Bureau researchers have shown that spectrophotometric methods can be used in lieu of the highly skilled sorter. The spectra of a mild steel, an HSLA steel, several stainless steels, and four nickel-base alloys have been measured. Differences in the spectra that are sufficient for identification are apparent.

Jan 1, 1985

"Human accidents are caused by production accidents, generally ones (such as derailment of cars, falling rock, etc.) that have occurred numerous times before an employee was actually involved. Prevention of human accidents is, one of the essentials in cutting operation costs, and advocates of safety are studying economics to assist them in their work of preventing accidents.Workman's compensation insurance or compensation for human accidents is a true operating cost, and is the only purely tangible measure available which gives a measurement of the cost of accidents even though, as will be pointed out later, it represents but a portion of the total cost of human accidents.In using premiums paid for compensation insurance as a measure of the cost of accidents, it must be kept in mind that most insurance laws, as pointed out in a former paper (Serial 2590 of the Bureau of Mines) provide a waiting period before compensation for the lost-time wages starts, with the compensation limited to definite percentages of the wages. The waiting period and limited compensation combined tend to limit the amount paid to an injured workman who, if he receives 1/3 of the lost-time wage, will probably have been reimbursed as high as the average injured workman.The total or complete economic cost of human accidents, must include, in addition to compensation paid for lost time, and the portion of the lost-time wage suffered by the workman for which he is not compensated, the additional cost to the company through-(a) temporary decreased production by the breaking down of the morale, etc., (b) the breaking in of a new employee which is admittedly expensive,(c) the increased liability of human and production accidents caused to or by the new employee.Another charge against accidents, which is not included in the compensation payment, is the economic loss through the killing of as workman who has no dependents. Few of the States' laws require any compensation except burial expenses to be paid for fatalities to persons having no dependents. It is estimated by the United States Bureau of Labor Statistics that the economic loss through a fatality is 6000 shifts. If each fatality was compensated for this amount of time and at half-time wages, using an average wage of $5.00 per shift, the compensation for fatality based on the economic loss would be $15,000. but the average actual compensation paid for each fatality is about $3,000."

Jul 1, 1924

By Gerald V. Gibbs

As a part of the Bureau of Mines long-range program in asbestos, synthetic asbestiform compounds and minerals were prepared and described. Fundamental structural data on two such compounds are given in this report. Crystallographic data are provided for the synthetic isotypic compounds potassium-lead silicate, K2.Pb4 -Si8021 (I), and lead-aluminum silicate, Pb2. Pb4 .Al2Si6O21 (II). The space group symmetry 14/mmm was assigned provisionally to I and II on evidence of single crystal and piezoelectric measurements. A statistical evalua¬tion of indexed powder diffraction data revealed the cell edtes of I to be a 11.816 and c 7.932A and those of II to be a 11.723 and c 8.044A. The phases are uniaxial with observed refractive indices eD 1.790, an ?D,699 and eD 1.884, cusp 1,807, respectively. The atomic structure of I and II may be based on a complex of chains of silicon-oxygen tetrahedra lying along the c cell edge similar to the type of chain structure postulated by Pauling for scapolite. K2.Pb4.Si8021 and Pb2.Pb4 Al2Si6021 were first described by Geller and Bunting (5, 6)4 as fibrous compounds similar in crystal habit to asbestos. These authors gave powder diffraction data, although no attempt was made to find the cell edges or to index the powder diffraction patterns. Later, Shell and others (9) conducted a crystallochemical study of these fibrous silicates in search of a substitute for strategic asbestos. Their single crystal data revealed K2.Pb4 -Si8021 to be tetragonal body-centered with cell edges a 11.66, c 7.95 A. Pb2.Pb4 Al2Si6021 was concluded to be isotypic with K2.Pb4 -Si8021 on the basis of similar powder diffraction patterns, chemistry, and physical properties. No attempt was made, however, to index the powder diffraction record nor to determine the appropriate space group of either compound.

Jan 1, 1962

By T. Estelle Gardner

Heat-capacity measurements were made over the range 8° to 350° K on beryllium sulfate dihydrate and beryllium sulfate tetrahydrate using an adiabatic calorimeter. No anomalies were noted in the curve for either compound. Smooth values of heat capacity, entropy, enthalpy function, and free-energy function were calculated from the heat-capacity data at 10° K intervals and at 273.15° and 298.15° K. The entropy values calculated at 298.15° K were 39.01 ± 0.12 entropy units (eu) for the dihydrate and 55.68 ± 0.17 eu for the tetrahydrate.

Jan 1, 1967