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By Robert C. Fouchard, Gordon Chalmers, David E. G. Jones, Ivana Alilovic, Phillip D. Lightfoot

There have been numerous international instances over the last several years in which pumping emulsion explosives has resulted in accidents, apparently as a result of increased thermal sensitivity under these conditions. The key questions for the explosive industry are (1) what are the parameters that influence the sensitivity of emulsion explosives and, (2) how do these various parameters interact. To address the sensitivity of emulsion explosives to various parameters, a study was undertaken using an accelerating rate calorimeter (ARC) and a heat flux calorimeter (HFC). The effects ofthe addition of ammonium nitrate (AN) prills and different grades of aluminum (Al) on the thermal behaviour of emulsion explosives were determined. Additionally, changes in pressure, atmosphere (inert or oxidizing) and sample vessel material were assessed for their impact on thermal sensitivity. Addition of AN prills, fine granular Al or atomized Al did not affect the onset temperature for exothermic decomposition, so that the maximum “safe” temperatures for emulsions containing these additives will be similar. There were differences in the rates of self heating, however: AN prills decreased the rate of self heating, whereas atomized Al increased it. The emulsion formulations containing atomized Al produced small holes in titanium vessels. This phenomenon did not occur in Hastelloy C vessels, providing a reminder that materials of construction need to be carefully considered for equipment used to manufacture or handle emulsion explosives.. Both ARC and HFC experiments gave lower onset temperatures in air than in argon. We attribute this to oxidation of the oil phase by air. This result is significant for dry-running pumping conditions, where emulsion is heated in the presence of excess air.

Jan 1, 2000

By Thomas Barkley

Mining tradition holds that a parallel round underground can not be any deeper than it’s smallest face dimension. ln other words, a mine using a 12’ (3.7 m) high by 24’ (7.3 m) wide room and pillar mine, the deepest pull that can be achieved is plus or minus 12’ (3.7 m). After experience with decking of rounds in a 12’ (3.7 m) diameter shaft to achieve more than 12’ (3.7 m) advance per round, the concept of deepening the pull on horizontal parallel rounds seemed to be a feasible concept. Tests were conducted in a conventional room and pillar metal mine with a round size of 12’ (3.7 m) high by 24’(7.3 m) wide. Standard rounds were drilled with a 16’ (4.9 m) steel as parallel rounds to an average depth of 14.5’ (4.4 m). The average depth of pull on these rounds was about 13’ (4.0 m). Using the available drilling equipment, 20’ (6.1 m) drill steel was used to drill holes to an average depth of 18’ (5.5 m). Five rounds were drilled and shot with a resulting aven$e pull of 16.2’ (4.9 m) or 90 % of drilled depth. Rounds were designed with decked bum cuts to maximize depth of pull in the cut area An innovative method of de&mining drilling accuraq was used to estimate it’s effect on depth of pull in the rounds. This method used a standard automatic 35-mm camera and scaling to determine the average drill deviation for many of the holes in the rounds.

Jan 1, 2000

By AJ Rorke

Blasting trials using Daveytronic Electronic Delay Detonator systems (EDD’s) were conducted at the Alpha Ferro Quany (Pretoria) and the Eikeboom Colliery near Witbank in November 1999. The objectives of the trials were to determine the influence of accurate hole firing on rock fragmentation, blast-induced vibration and blast throw. This paper provides an outline of the trials and an analysis of the results. The results were compared with a normal shock tube initiation system. Fragmentation was measured using video-imaging techniques at the hard rock Ferro Quarry for one conventional shock tube blast and two EDD blasts. No significant difference was measured in the fragmentation between the shock tube blast and the two electronic detonator blasts. Joint planes mostly defme the fragments at Ferro Quarry. The fragment sizing was therefore controlled mainly by the rock structure and the blast timing appeared to have no influence. Vibration measurements made at Ferro Quarry indicate that electronic detonators have a marked effect on vibration frequencies compared to shock tube systems. The more accurate detonators resulted in a narrower f+equency band at lower amplitude with similar timing. By modifying the blast timing, the dominant frequencies were changed. The electronic detonators had a significant positive influence, therefore on blast vibration and its control. The timing scatter measured from the shock tube blast was considerable, with measured inhole detonator scatter at 48 ms over a sample of 19 units. Surface delay periods less than 42 ms would therefore not be able to provide effective sequential firing. The scatter of the Daveytronic units was below the 2 ms resolution of the high-speed camera used to film the blasts. Reliable sequential firing, even at very short delay intervals was considered the main reason for notable improved throw in an overburden blast at Eikeboom Colliery. Blast throw was improved by 25% for the test blast.

Jan 1, 2000

By Piyush Rai

Proper use of fi ring pattern vis-à-vis the blast requirements can provide optimal blast performance in terms of fragmentation. Further to this, each fi ring pattern has its own characteristic, for instance, although V-type and diagonal fi ring pattern provide same Se/Be ratio, the V-type fi ring pattern increases the opportunity for in-fl ight collision amongst broken rock fragments during their movement. Similarly straight V-type and skewed V type fi ring patterns (V1,V2 etc.) have their own characteristic strengths and weaknesses. In this light the present paper highlights the application of three different types of fi ring pattern on two different type of sandstone overburden benches of a large coalmine in India. The study reveals that Firing pattern infl uences the effective spacing to burden ratio at the time of detonation. By changing the fi ring pattern, effective burden (Be) changes and the ratio of effective spacing (Se) to effective burden (Be) during the fi ring is also subject to change in comparison to drilled spacing to burden ratio (S/B) Hence, the Se/Be ratio vis-à-vis fi ring pattern must be used to design the blast rounds. The results have been derived on the digital image analysis based fragment size characterization, excavator performance and evaluation of powder factor values on blasted muck piles. Skewed V- type fi ring yielded the best results in comparison to straight v-type and normally practiced diagonal fi ring pattern on the moderately strong sandstone benches, whereas, the existing diagonal fi ring pattern appears to be satisfactory on weak (weathered and gritty) sandstone benches. The presence of geological anomalies has also been investigated.

Jan 1, 2008

By Midori Sakamoto, Nobuaki Sakuma, Tsuyoshi Murashita

Recently, tunnel blasting works near the residential area and existing building are increasing and environmental problems caused by vibration have become serious public concern. In order to solve these problems, blasting works have been conducted with segmented blasting and reduce advance per round. However, with these blasting, work efficiency is not obtained, and regrettably the cost and risk of accident tend to increase. We developed a new controlled tunnel blasting technique with electronic delay detonator. Electronic delay detonator can supply extremely large range of delay period which could not be achieved with conventional pyrotechnical delay detonators. We utilized advantages in initiating hole by hole over entire tunnel face at the same round. Much seismic data obtained from tunnel blasting with conventional detonator was statistically analyzed in order to find average duration time of vibration caused by a single hole initiation. Numerical simulation using sample waves from a single hole initiation was carried out in order to find an optimum delay time which can separate vibration in each hole initiation and without decreasing blast performance. Trial blasting was conducted to examine the correctness of optimum delay time obtained from numerical simulation. This blasting technique was applied to an actual tunnel construction. This tunnel is 2 lane automobile tunnel with a total length of 659 meters and internal cross section of 70 square meters. The purpose of the use of blasting technique on occasion, was the protection of fresh water reservoirs directly above the tunnel, and to keep the effect on local private houses to a minimum. The vibration level against this station was limited under 20 mm/see P.V.V. With this blasting, the tunnel construction was completed without exceeding the limited vibration level, with minimum cost and construction time.

Jan 1, 1998

By Mark S. Stagg, Steven V. Crum, Stephen A. Rholl

As part of its ongoing research concerning rock fragmentation by blasting, the Bureau of Mines has undertaken a series of test blasts where six cylinder-shaped pieces of granite rock were fragmented using high explosives. The tests were intended to: 1) Establish a dataset that could be used in the development and verification of theoretical models that simulate rock blasting and 2) To add to the fragmentation data currently being collected by Bureau researchers. The cylindrical geometry was chosen so that the fragmentation could be directly compared to two-dimensional computer simulations that assume an axisymmetric configuration as well as more sophisticated three-dimensional models. The granite cylinders, Carnelian granite and Charcoal granite, ranged in size from about 0.46 meters (18 inches) to 0.58 meters (23 inches) in diameter by 0.91 meters (36 inches) to 1.52 meters (60 inches) in length. Physical rock properties tests performed on the Charcoal granite cylinders indicated that the rocks did in fact have similar physical characteristics. PETN-based detonating cord and dynamite were used as the explosive charges and estimates of the values of some important physical properties are given. For the first five tests, the blasted rock was contained by a heavy rope mat suspended inside the Twin Cities Research Center's blasting shelter. The fragments from each of these shots were sorted and weighed to determine the corresponding fragment-size distributions. Even though different types of granite and cylinder sizes were used, similar fragment distributions were produced from shots that used a similar explosive, in this case the PETN-based detonating cord, and comparable burden-to-charge diameter ratios. Significantly coarser fragmentation was produced from a blast that used dynamite as the explosive charge. Fragment velocities were calculated using photographic data from the sixth test which was shot unrestrained in a quarry and filmed with high-speed cameras.

Jan 1, 1990

By Dae-Woo Kang, Sang-Wook Kim, Shin Lee

The Air-tubes blasting method is provided in which a series of aligned boreholes are charged with explosive s and air tubes in a predetermined blasting pattern. The air tube is composed of cylindrical flexible tubes which have a predetermined width and length to be fit with the site boreholes. Within a preferred formation, each borehole is charged with the explo sives and detonators with an air tube installed just above the explosives. Stemming materials are filled above the air tubes. At the limestone mine of Sung-Shin Cement Co., in South Korea, these blasting tests were performed by a diameter 102 millimeter and 15 m long boreholes with the charging length of explosives was 8m to 10 m by the total weight of explosive 40 to 50 kg with 3m to 6m air tube which has a 76 mm diameter, and 1m to 3m stemming cover. Blasting results showed the about 10% to 30% explosives savings available and especially, the about 20% to 50% reduction of ground vibration with the low noise measures around 2dB to 5dB by this new blasting method which was compared with the conventional blasting methods. The explosives and air tubes may be alternately charged along the boreholes. The use of air tubes which were charged above an explosive layer allow to form the quantitative air decking in every blast hole. Therefore, the Air-deck effect can be easily obtained through this blasting method, and also easy to increase the fragmentation rate resulting in the more suitable mucking procedures at the working site with the minimum usages of explosives for the better economic operations in mine quarries.

Jan 1, 2005

By Wood Marcum, Gary McLemore, Randall Franklin

Description of Project: Nelson Brothers/Walter Energy (Choctaw Mine) Pre-Split Wall. Walter Energy – Choctaw Mine is a multi-seam surface coal mine in Northwest Alabama.Pre-splitting is the standard procedure of the Pratt Seam, which is the top seam (186 feet deep) as shown in the photo at Choctaw Mine in Parrish, Alabama

Jan 1, 2013

By C. T. Aimone-Martin, V. L. Rosenhaim

The response of two structures to blast-induced ground vibrations were evaluated and compared in order to quantify the impact of different blasting operations, hard rock and soft rock blasting, upon the structures movements. The first instrumented structure was a residential type, located in the operational area of a coal mine, were blasting is conducted in soft rocks, such as siltstone and coal, with compressive strength ranging from 20 to 50 MPa. Blasting is characterized by low benches, with hole lengths averaging 5.5 m (18 ft) and low powder factors, 140 to 210 g/m3 (0.236 to 0.354 lb/yd3), resulting in very little horizontal movement of the rock during the blast. The second structure was a commercial building, located in a basalt quarry (compressive strength between 109 and 180 MPa), where blasting is conducted in 12 m (39.4 ft) benches with powder factors ranging from 200 to 350 g/m3 (0.337 to 0.590 lb/yd3). Velocity sensors were placed on the structure walls to measure wall displacements and calculate blast-induced strains in the walls, and these results were compared with the driving ground excitations. The calculated strains were compared with the limits of rupture of the cement grout used as mortar between bricks and as wall coating, considered to be the weakest material in the structure composition. The blast-induced response of existing cracks in the structures were also measured using displacement gages and compared to the daily influence of weather fluctuations, such as changes in temperature and humidity, on crack movement. The results show that for the same levels of ground motions the structures present different movement, resulting in distinct levels of induced strains on the walls depending on the geology. The influence of long-term temperature and humidity variations on crack movements on both structures is very similar, during the same seasons of the year. Crack response to long-term weather changes is 2.5 to 3.5 times greater than blast influences.

Jan 1, 2015

By Martin Langenderfer, Sergii Chertopalov, Catherine Johnson, Vadym Mochalin, William Fahrenholtz

The high temperature and high pressure of an explosive detonation can be used for the production of nanomaterials. The controlled detonation of explosive compositions along with the collection and characterization of reaction products encompasses a process known as detonation synthesis. The primary advantage of the method of detonation synthesis is the possibility for producing monocrystalline nanoparticles with diameters of less than 10 nm. In order to successfully synthesize nanomaterials via the detonation process, it is necessary that the explosive detonation is conducted in a sealed environment. This environment when pulled to a vacuum or purged with inert gas such as argon will reduce the oxidation of detonation reaction products. Detonation synthesis testing is currently being conducted in a 1.8 cubic meters (m3) (64.3 cubic feet (ft3)) ellipsoidal pressure vessel consisting of two interlocking half shells. The testing involves the controlled detonation of cast mixtures of Cyclotrimethylene-trinitramine (RDX) and 2,4,6-Trinitrotoluene (TNT) in conjunction with siliceous compounds to produce nanocrystalline diamond and silicon carbide. Alternative detonation environments including the presence of a cooling medium such as water or dry ice to absorb residual, post detonation, thermal energy and enhance the stability of the materials being produced have improved yield. Modifications to the explosive charge composition have an effect on the type and quantity of materials that can be produced. Doping of explosive charges with various organic and inorganic compounds has shown promise in the synthesis of materials that are difficult or uneconomical to produce through other methods. This paper outlines the process development of detonation synthesis facilities. Preparation of the pressure vessel to create a suitable detonation environment for the production of nanomaterials is examined. Formulation of explosive charge compositions and considerations involving test charge initiation are discussed in detail. Experimental results and analysis from initial testing as well as plans for future research are also evaluated.

Jan 1, 2018

By David G. Paton

"Electromagnetic surveys were conducted at the BXL Bulk Explosives Limited Mixing Plant andsurrounding area to characterize runoff from the site and possible impacts of salinity. The BXL Plant is located at the edge of a depressional area and any escape of soluble ions, such as nitrates, would have ended up in the slough to the west of the plant. Two electromagnetic (EM) instruments were used in the survey. A Geonics EM 3 1 was used in October 1997 and in June 1998, a new multifrequency instrument, a GSSI GEM 300 was also tested. Both instruments were individually mounted on a plastic sled with Teflon runners and towed with an ATV quad. Position was determined using a Trimble Pro XL global positioning system (GPS) with a real time correction mode Landstar receiver for an accuracy of about *l m. Both GPS and EM instruments were set to collect data at 1 second intervals. The quadrature maps for both instruments showed essentially the same information, namely of very high conductivity, appearing to emanate from the mixing plant. The levels of conductivity were highest where the saline water appeared to pool, at the southern end of the slough. Soil sampling locations were identified from the EM maps and navigated to using the real time GPS. Composite samples were collected by hand using a Dutch auger, from two locations, in increments of O-1 5, 15-30, 30-60 and 60- 90 cm. The analysis of the soil samples indicated a complete absence of nitrate or ammonium ions; the major anion was sulphate, indicating naturally saline subsoil conditions. The GEM 300 made the collection of data more efficient, as only one pass was required to collect the data from four depth intervals. The EM survey combined with the real time GPS allowed rapid characterization of the site with respect to soil salinity and proved to be cost-effective for Phase l/ Phase 2 site assessments and targeting sampling locations."

Jan 1, 1999

By Zheng Shuangying

The vibration effect of the buried oil pipeline caused by tunneling blasting affects the pipeline safe transportation, tunnel construction schedule and its construction cost. The dynamic response characteristic of the buried pipeline under blast loads is the foundation of designing blasting scheme as well as the prerequisite to pipeline safety. Taking the blasting engineering of Xiannvyan tunnel passing through a buried oil pipeline of the high-speed railway from Xi’an to Chengdu as the background, according to the space relation between tunnel and pipeline as well as the charge structure of V-cut blasthole, the 3D non-linear dynamic finite element model of tunnel-pipeline was established in the light of the equivalent explosive. The vibration response of the ground surface over pipeline resulting from V-cut blasting was simulated by LS-DYNA finite element program. Comparing with the measured vibration velocity waveforms in site, the accuracy and reliability of the numerical model are well verified. On the base of the simulation method, the coupling dynamic response characteristic between buried oil pipelines and soil was further studied and the Von-Mises stress distribution of pipeline wall was obtained. The safety of buried oil pipeline was quantitatively analyzed through the inside stress data of pipeline given by the simulation calculation above. The analytic results show that the maximum vertical vibration velocity of pipeline on the interface between pipeline and soil is 1.62~5.07 times as large as that of soil. When the buried pipeline is located over the tunnel and 13 m (42.6 ft) away from tunnel, the maximum vertical vibration velocity of ground surface caused by V-cut blasting with charge weight 17 kg (28.6 lb) is 3.17cm/s (1.25 in/s) and the vertical peak vibration velocity of pipeline top is about four times as the ground location directly above the pipeline. Meanwhile, the peak dynamic stress of the buried pipeline caused by blasting vibration is only 2.35% of the allowable stress of steel pipeline. The maximum superimposed stress of the blasting dynamic stress and the hoop stress produced by the pipeline internal pressure is 242.56 MPa (35 180.36), which implies that the buried oil pipeline is completely safe under the conditions of the given tunnel blasting scheme.

Jan 1, 2015

By Michael Wieland

The thrust of this report is to overcome some of the technical deficiency in the scientific methodology that correlates the work output during a charge explosion to the resulting toxic fumes. Thermodynamic work-principle models yield (undissipated) shock and heave results for shooting underwater and in rock stratum with related toxic fumes. Underwater circumstances yield reliable test data for the work process, though questionable or no fume results. Work-output measurements in rock shots remain difficult if not intractable, though some fume reports exist. Underground tests with thick-wall metal pipe bombs yield consistent toxic fumes trapped within the test chamber. The work output, rendered as fragment kinetic energy, can be inferred from the well-tested theory of R. W. Gurney, originally designed for military ordinance. Therefore a work-principle model for cylindrical pipe bombs was developed to predict fragmentation work output and reaction-zone fumes, permitting the double comparisons to reported and inferred results.

Jan 1, 2010

By Tom Treleaven

This guide presents numerous patterns that provide 8 millisecond separations between initiated charges. The guide is tabulated in seven sections to provide quick reference by number of decks or bunch blasting. The pattern is presented in the section where the highest number of decks works. It should be noted that patterns applicable to multiple deck shootings are also applicable for fewer decks.

Jan 1, 1997

By Michael Wieland

The thermodynamics work-principle was used to develop the rupture-fracture-throw (RFT) model for ranking the performance of reduced-density explosives when shot in rock or other stratum. The RFT model revises techniques used for the rock-water-jelly (RWJ) model, where the reaction-zone remains trapped within the rock/stratum. Therein, ranking of performance refers to trends for the two resolved components of the total expansion work: the reversible mechanical work taken as the heave and the residual irreversible portion, taken as the undissipated shock. For numeric tractability, the RFT and RWJ thermodynamic efficiency were taken equal, while the RWJ late-stage confinement was replaced with restrained venting through the rock, to render the RFT inefficient heave. The transfer of heat from the reaction-zone was neglected and the root-power formula was used to render the gas-covolume. Ranking trends were found for a generic charge formulation over a wide ranging density, with underwater results noted for comparison. Realistic compositions, some with natural resource materials, were treated for just typical and reduced density. Rock characteristics, ranging from hard rock to weak stratum, were represented by their density and rupture compression strength. Quantitative test results for shock or heave in rock remain difficult, so qualitative guidelines remain helpful when reviewing the graphic trends. Theoretical refinements for rock fragment size-distribution remain under development, though some relationships are touched upon to gain insight.

Jan 1, 2011

By Michael Wieland

Work-principle computations for explosions underwater or in rock reveal the way the thermodynamic characteristics of surrounding material influence the resulting shock and heave. To reach total thermodynamic equilibrium under such transitory dynamic circumstances, reactions must quickly readjust to changing circumstances, which works for molecular (military) explosives where the fuel and oxidizer type atoms are originally in close proximity. For non-molecular mixtures with their dispersed zones of oxidizer or fuel, in particle or droplet form, there are numerous unproductive collisions, increasing the wait time required to reach chemical equilibrium. Underwater test data for molecular explosives compare rather well with the shock and heave resolved from the work-principal model, while the non-molecular explosives normally used in mining tend to yield a noticeable discrepancy. Years ago, it was recognized that the underwater shock was lower than expected and the heave was higher than expected for ammonium nitrate fuel oil (ANFO), though their resultant sum for the total work was roughly what was expected. When the readjustment of thermodynamic equilibrium warrants quicker chemistry than occurs in underwater or rock shooting, the time-retarded chemistry reduces the shock and raises the heave within the surrounding material without reducing the total work, unless the reaction retardation is quite severe. This technical complication in reality is a nonequilibrium issue that is difficult to resolve with just thermodynamics, though a rational set of transformation factors is formulated herein to represent those circumstances.

Jan 1, 2008

By Michael Wieland

The work principle from thermodynamics is used to model the shock and heave for explosives shot in rock or under water, with the latter compared to reported results. The work principle utilizes restrictions and constraints to yield a representative fit to the irreversible (natural) shooting process. The reduction of the internal energy of the reaction-zone yields the total expansion work (TXW), the resultant sum of the rock/water shock and heave. The restoration technique of forming a closed thermodynamic loop yields the reversible mechanical work (RMW) or the rock/water heave. The residual work that remains when RMW is subtracted from TXW yields the irreversible disorder work (IDW) or the un-dissipated (without loss) shock in the surrounding rock or water. The work principle renders an unequivocal relationship for the shock-loss factor, rather than the traditional roundabout formula for correcting the underwater gauge-shock of un-modeled explosives. There’s a novel heave-ratio factor that unquestionably rates the fit of results under comparison. Rock-shots are more complex in nature than underwater shots due to rock fracture and stratum rupture, though numerical resolution is worthwhile. The proposed rock-water-jelly (RWJ) model yields rough estimates, with rock-type results not wholly different from their underwater counterparts. Though reported underwater shots reveal shock and heave trends with respect to charge formulation ingredients, there are no such rock-shot results for comparison, since the relevant test measurements in rock remain difficult, if not intractable.

Jan 1, 2007

By Jacob Miller, Phillip Mulligan

"Measuring the blast pressure associated with an explosion suspended above the ground (Free Air Burst)is a common research objective in Explosive Engineering. Theoretically, the shockwave from a Free Air Burst (FAB) configuration expands radially and the shockwave is assumed to have a smooth (uniform) shock front. The way in which the FAB explosive charge is suspended, packed, and the charge geometry can affect the shockwave expansion. These factors can generate a non-uniform shock front. As the scaled distance between the pressure sensor and the FAB increases, the shockwave expansion averagesnon-uniformities into a uniform shock front, at which point the FAB suspension system becomes less critical than when the scaled distance is “close-in” (Z <3)."

Jan 1, 2017

By Elliott Giles

"Measuring a blast’s performance based on the bucket fill time or “diggability” has always been achallenge due to the subjectivity generally involved. The diggability of a blast is often based onopinions and speculation without the data to properly support the claim. This paper focuses howthe blast design can impact diggability and how it can be properly measured."

Jan 1, 2016

By Scott G. Giltner, Terry Millar, Ben Bringhurst

"Kennecott Utah Copper (KUC) Smelter scheduled a rebuild of their flash smelting furnace forSeptember, 2014. KUC’s goal in this project was to reduce the rebuild time from 65 to 55 days by using explosives to break the matte and brick layers of the uptake shaft and hearth sections of the furnace. Previous rebuilds had employed the slower technique of mechanical breakers to remove the matte and brick layers which took 22 days. KUC has many years of experience in removing slag from the uptake shaft, but they had never used explosives to remove the hearth. As far as KUC was aware, no other smelter operation had attempted a hearth removal in this way."

Jan 1, 2016