Search Documents

By T. Inoue, K. Okaya

"Movement of mill charge in the centrifugal mill is essentially different from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. As proved e.g. in [11], this results in substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Back in 1983, Bradley et al. presented a model of the centrifugal mill based on the kinetics of the mill charge by regarding it as a lumped mass. On the other hand, numerical modeling by ‘discrete element method (DEM)’ enabled us to observe the movement of each ball in the centrifugal mill with an extremely minute time intervals (Inoue et al., XX IMPC in 1997). The former approach rendered simple, even though approximate, expression of the mill behavior, while the latter method was advantageous in describing the behavior of the mill in terms of individual events taking place in the mill body, even though the result did not reduce to a simple expression. The characteristics of the centrifugal mill described by both these approaches proved to be in a degree of agreement. Thus, the kinetic approach was capable of presenting the overall view of the mill, while the DEM model was informative of the details that could not be depicted well enough by the simple math expressions."

Jan 1, 2003

By A. Shibayama

Soil contamination by organic compounds is one of the most concerned issues on polluted soil. It is well known that there are limited methods to remediate the contaminated soil on site. Especially, the in-situ method for contaminated soil is too difficult to de-contaminate the organic pollutant. In this study, the fundamental ability of soil remediation, which aimed to decrease oil concentration in, in-situ process, have been researched by using a high pressure gas generated from ?crush composition? on artificially oil contaminated soil. The n-hexadecane (n-C16H34) and other organic compounds were selected as soil oil contaminators, gravimetric analysis by soxhlet extraction and GC-MS were used as qualitative and quantitative analysing methods. For the experimental examination, the influences on the difference in the concentration of n-hexadecane (and other organics), the tamping amount, position and repetition of crush composition in soil, and scale (size) of experimental model were investigated. The n-hexadecane concentration reduced by the explosive effect of crush composition showed a reasonable decrease of about 30 wt%~60 wt% compared to the initial n-hexadecane. The removed amount of n-hexadecane and distance from explosion point of the crush composition was related in scale and model of contaminated soil.

Jan 1, 2014

By K. D’Elia, L. D. Ogrel, O. A. Malyshev, T. I. Yushina, I. M. Petrov

"The purpose of this research is to develop enhancements in the mineral processing by flotation methods of nonferrous ores. Currently, 180-190 million tons of ore are processed by flotation in Russia. The annual processing volume of copper-nickel and copper-zinc ores exceeds 20 million tons. In the total volume of processed ores by flotation, non-ferrous ores account for roughly 35% and ores of precious metals for another 15%. The total demand of flotation reagents in Russia in 2016 was estimated at 170,000 tons. Sulfur-based collectors used in the flotation of non-ferrous sulfide ores (typically, xanthates) do not always offer sufficiently high recovery of valuable components.It has been found that reagents like DMIPEC and DK-80 improve the recovery of metals into concentrates. To identify the reasons of that higher recovery, quantum chemical calculations of the mechanism and interaction forces of DMIPEC with non-ferrous sulfides were undertaken by determining the stabilization energy of the resulting chemical complexes. It has been shown that, in the interaction of DMIPEC and DK-80 with the surfaces of sulfide minerals, ethylene and acetylene bonds act as the reaction centers, and the formation of molecular p-complexes is the result of metal-cation interactions with the surface and the flotation reagents.In the flotation of non-ferrous ores, DMIPEC and DK-80 act as selective supplementary collectors with foaming properties, and at a flow rate of 3-35 g/ton, they reduce the flotation time, and increase copper recovery by up to 3.5%, zinc recovery by up to 12%, gold recovery by up to 8-10%, allowing to increase the recovery of valuable components by 1.5-12.0%, basically this kind of reagents nearly double the flotation rate, improve the grade of the concentrate, improve the stability of the flotation process parameters, and reduce the environmental impact of flotation plants."

Jan 1, 2018

By Caroline Olsen

The objective of this study was to achieve Zn activation control in an industrial Cu flotation circuit treating a complex Cu-Pb-Zn-Au-Ag sulphide ore at the LaRonde Division of Agnico-Eagle Mines Limited (Québec, Canada). In order to provide process relevant results, a laboratory testing methodology was developed to duplicate plant operational parameters. The action mechanisms of ZnSO4, TETA (triethylenetetramine) and NaHSO3used as depressants in order to limit ZnS activation were examined. Laboratory flotation tests with and without Cu2+ions (the ions responsible for ZnSactivation)were performed. All depressants showed equal or better flotation performance relative to baseline tests. For example, in the presence of Cu2+, the Zn recovery reduced from 32.2% to 17.5% in the copper rougher concentrate after adding ZnSO4(with a dosage of 50 g/t). TOF-SIMS analyses confirmed the relative decrease in surface Cu in the samples treated with ZnSO4and TETA. For the case with TETA, this indirectlyindicates the formation of a copper TETA complex in solution, thereby reducing available Cu for transfer. The TOF-SIMS and XPS data indicate that the addition of ZnSO4and NaHSO3resulted in an increase in surface metal hydroxides and SO3 on ZnS grains inhibiting both Cu and collector attachment.ZnSO4 was subsequently tested with success in the LaRonde concentrator. The addition of 40 g/t ZnSO4 at the conditioning (or cleaning) stage led to a 2% reduction in Zn content in the Cu and PM concentrate. Recently, improvements towards the control of copper sulfate addition in the downstream Zn flotation circuit resulted in the reduction of Cu2+ in process water. As this ?cleaner? water is recycled for Cu and PM flotation, the addition of ZnSO4 is now used only as required.

Sep 1, 2012

By S. Banisi, A. Ghasemi, S. Zare, F. Ghorbani, E. Nematollahi

"Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Working at the maximum operating capacity of comminution equipment plays a significant role in the efficiency of the circuit. Appropriate design of cone crusher feed box could result in the choked crushing which is known as a vital factor in achieving target performance. In this research, the non-uniform cone crusher feeding at the Sarcheshmeh copper complex was studied and appropriate measures were taken to solve the problem. The problem resulted in non-uniform and high wear rate of crusher liners and high fluctuations of power draw. In recent decades, the discrete element method (DEM) has been applied successfully to study the effect of different factors on the behavior of particles flow. In this work, various designs for feed box were tested using an in-house developed DEM software called KMPCDEM©. The best feed box design obtained from the simulations was selected, constructed and installed in of the cone crushers. The new feed box design resulted in more uniform feed distribution on the distributor plate of crusher indicated by a reduction of the standard deviation of power draw measurements from 13 to 3 kWh. The better control of the crusher, 49% increase in the crusher throughput and finer and narrower product size distribution were the main outcomes of the installation of the new feed box. Furthermore, the wear rate on mantle and liners of crusher not only decreased but it also became uniform.INTRODUCTION Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Reaching the maximum operating capacity in comminution equipment is a key sign of approaching the nominal productivity of the process. Due to the effect of crusher efficiency on the downstream circuit performance, optimization of the crushing circuits has received considerable attention (Herbst, & Potapov, 2004; Quist, & Evertsson, 2010; Li, Huiqi, McDowell, Glenn R, Lowndes and Ian, 2014; Cleary, Sinnott, Morrison, Cummins, & Delaney, 2017). Improving the performance of crushing circuits not only decreases the capital and operating costs but also increases the efficiency of downstream grinding circuits (Jacobson, Janssen, & Urbinatti, 2010). In cone crushers particles can be subjected to two different modes of compressive breakage; single particle breakage (free feeding) and inter-particle breakage (choked feeding). The maximum efficiency of the cone crusher directly depends on the type of feeding arrangement (Operation Manual, 1977). An appropriate feeding must lead to choked feeding the cone crusher. If the rate and method of feeding the crushers are correctly be executed, the maximum efficiency of the crushers could be available (Jacobson et al., 2010)."

Jan 1, 2018

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

Roller presses are widely utilized in mineral industry for fine milling and compaction. Recently used models are providing only limited information about the material behavior in the roll bite. This paper introduces a 2-dimensional finite element model for analyzing those two basic processes. A pressure-dependent plasticity model with linear elasticity was used as a constitutive model for the particular material. Coulomb friction law was used to describe phenomena on the material/roller surface interface. Two basic roller geometries are considered: smooth (used for milling and compaction) and with cavities, commonly used for briquetting. Comparison of the results obtained from the model with experiment indicates that they are following the general trends of experimental values recorded with laboratory roller presses. It is shown, that the model is suitable to analyze material behavior through all stages of the rolling process: feeding zone, nip region, neutral plane and release section. It can predict pressure, shear stress, slip of the material over the roller surface, material velocity field, failure of the compact during release and the course of other important process variables. This allows the process engineer to gain an improved understanding, leading to a better process and equipment design and control.

Jan 1, 2003

By C. Y. Jia

Adsorption of Thiooxidans ferrooxidans and Mycobacterium Phlei on the surface of pyrite and galena was studied. From the experimental results, it was observed that Mycobacterium Phlei adsorbed preferentially on pyrite than on galena at neutral and alkaline pH values, while Thiooxidans ferrooxidans is not at all pH range, and the scanning electron microscopy photograph also indicated that. FTIR and XPS of two strains of bacteria indicated that there are much functional groups on surface of them, such as O?H, N?H, C-O, C?N, C?O etc, but S-O group occurred on Thioox-idans ferrooxidans cell surface and the P-O group appeared on Mycobacterium Phlei cell surface, and the content of C?O?H and C?O?C groups on Mycobacterium Phlei cell surface is higher than that on Thiooxidans ferrooxidans cell surface, this also been known from UVS investigation. The affinity of these groups to metal ions on sulfide minerals is able to explain the selective adsorption.

Jan 1, 2014

By M. M. Yahyaei

The Sarcheshmeh new concentration plant uses a 32 ft×16 ft constant speed (10.5 RPM) SAG mill with two 5500 hp motors which could rotate in two directions. The mill liners are chrome-molybdenum steel casting type with a Brinnell hardness between 325 and 375 with the lifter face angle of 14° and lifter height of 152 mm. The shell liner consists of 120 (two 60 rows) pieces with a High-High configuration in a rail design. A specially designed liner wear profile measuring device enabled fast and accurate measurements inside the mill during the mill shut-down periods. The measurements indicated that the liner wear profile along the liner length is non-uniform and the highest wear occurs between 1.25m and 2.75m of the mill length. The average weight of liners at the time of removal was 47% of the original weight indicating a significant metal loss. The modification of liner shape was undertaken with the aim of having a uniform profile at the liner removal time. The proposed liner unlike the pervious type did not have a uniform shape with a lifter height of 187mm at the section where the wear rate was high. It was believed that this new profile could arrive at a uniform profile at the liner change out time. A study was also directed to the possible change of charge motion due to the liner profile modification. The dynamic behaviour of charge was investigated through the analysis of forces acting on a single ball using mill characteristics such as mill diameter, rotational speed, lifter height and release angle. The simulation of charge motion with this method and Milltraj TM software indicated that the impact position of charge will change only one degree due to the maximum increase of 35 mm in the lifter height. This assured that the installation of the modified liner would not have any adverse effect on the mill because of ball impacting the mill shell. It was predicated that the amount of scrap metal will reduce to 30% from the current value of 47% beside 1500 h increase in the liner life time.

Jan 1, 2014

By J. Ma

Vanadium ore is widely distributed in black rock series (Fan, Zhang and Ye, 2004) in many provinces of China, which accounts for 87% (Zuo, Peng and Dugang, 2001) of vanadium reserves in China. In Cambrian black rock series in south Qinling Mountain, there are large or medium-sized sedimentary deposits such as Zhongcun vanadium deposit, Yinhua vanadium deposit, Qianjiaping vanadium deposit, Xiajiadian gold-vanadium deposit and Lengshuigou vanadium deposit. The vanadium is distributed in other minerals mainly in the form of isomorphic replacement. These types of ore are characterized by no independent vanadium mineral, low grade and vast reserves. Now in China the vanadium extraction technology is backward with low utilization rate of resources. The difficulties of vanadium extraction from black rock series are that the enrichment by means of mechanical beneficiation is difficult; the cost of direct chemical extraction is high and the emission of waste gas from pyrogenic process does not conform to environmental protection standard. Therefore the study of vanadium occurrence, the improvement & optimization of vanadium extraction technology and the realization of pollution-free and low-cost extraction of vanadium from black rock series are of great and realistic importance for environment-friendly exploitation & utilization of vanadium resource in China. The study is based on carbon content in ore of Cambrian black rock series in south Qinling Mountain. Two kinds of ore are selected. Vanadium ore with low carbon content (TC<1%) is taken as Sample 1 while vanadium ore with high carbon content (TC>10%) as Sample 2. Based on analysis of ore?s lithologic features and vanadium?s occurrence, a vanadium extraction technological process characterized by selective grinding, low cost and no pollution is proposed.

Jan 1, 2014

By T. Onnela

Metso Mining and Construction Technology is one of the world leading suppliers of equipment and knowhow for aggregate and mining industry. The processing capacity, ease of use, and reliability are featuring Metso?s state-of-the-art cone crushers. Crushing is a complicated process affected by numerous parameters. The optimized crusher kinematics is one of the key factors for high performance. To fine tune the crusher kinematics and crushing chambers one needs to know how different parameters affect. The main cone crusher parameters are head angle and diameter, gyration point, shaft speed, eccentricity, stroke length, and inclination and design of crushing cavity. Selecting the correct combination of these parameters is a multi task optimization challenge. In practical life there are more factors to achieve satisfactory performance, like crushing chamber wear and profile management keeping the performance constant over the whole wear life, control of crusher frame loads, ability to handle disturbances in feed material etc. The extensive research work has lead to a solution that enables the highest possible material density in the crushing chamber. This design provides maximum reduction of processed material and thus increased share of 0/10 mm product. High density in the cavity offers further benefits, such as high throughput capacity, less material contact with wear parts and even load on crusher frame and bearings. The challenge that an equipment supplier involved with high density crushing is how to design a robust cone crusher, which is able to cope with the high crushing forces due to high resistance from the crushed material against the gyration movement. Metso has launched a new series of cone crushers HP3, HP4 and HP5 that are all able to work in high density crushing applications The test results and evidence from over 300 installations clearly prove the effectiveness and importance of high density crushing. Keywords: cone crusher, crushing chamber, crusher kinematics

Sep 1, 2012

By Baidyanath Mandal

Technology in the solid-liquid separation industry has evolved rapidly during the last fifty years and from the beginning, DIEMME Filtration has played a very important role in this evolutionary process by developing innovative solutions, which are used for a diverse range of industrial applications. Since the last decade, we find more and more examples of filter presses employed in the mining & mineral processing field, where high performances in terms of productivity, dewatering capacity and mechanical strength even in extreme working conditions are required. Mainly the requirement of such high quality equipment comes from the Process, however in few cases the reason could be linked with the environment. For stringent process applications like Mineral Concentrates dewatering & leached Slurry Filtration, it requires a high quality & extremely reliable equipment. In these applications, since many years industries are achieving the desired result by using Diemme Filter Presses. Also, recently, due to stringent environment practices are been applied globally, industries needs equipments which could dewater a high amount of residues / tailings with minimal moisture content in the filtered cake. In comparison to all the conventional dewatering equipments, Diemme Filter Presses are most efficient for these kind of product & applications. Diemme Filtration is a highly professional & technological company with several decades of experience in designing equipment for mineral processing. We take up each project as separate & design and manufacture equipment based on individual process or project requirement. This presentation will be focused on the Solid-Liquid separation technologies & equipment Diemme Filtration offers to the mineral processing Industries. It consists of Diemme?s History, Global Network, Technologies & Expertise, R & D Capabilities, Manufacturing Range, Some Applications & results on different mineral processing. Keywords: solid-liquid separation, filtration, dewatering, filter press

Sep 1, 2012

By S. K. Chaudhuri

With a growing emphasis on maximizing the value by rapidly deploying it across their assets, mining firms are eager to identify any issues that may hinder such efforts and to refine their approaches to overcome them. As such a CDE vision can be considered realized when the following components are addressed and functioning as intended - People: the right resources working together and efficiently to achieve shared goals, Process: well-defined workflows mapped out for key value processes, Technology: availability of the correct tools and applications to increase efficiency in work execution and Locations: regional locations/ sites that need to be linked for collaboration and information exchange. For the above vision, an approach that considers the degree of interaction between the roles in metallurgy operations, mineral resource planning, mine engineering, plant operations, logistics and infrastructure, and which accounts for the current technology states across these groups to determine sub-processes where the impact of a CDE will be the most is critical. In effect, CDE is more about transforming an organization?s operational philosophy than a technology driven project. This paper examines the definition and components of a CDE in a mining context. Real-time operations co-ordination, maintenance interventions, production analysis and optimization processes are examined along with current state technologies and manual processes as candidates which are likely to result in most benefits from collaborative work processes. Finally, the paper examines technologies that can be used to further enable a collaborative working environment.

Sep 1, 2012

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, A. Abazarpoor

The research aimed to compare the chemical analysis (K, Na, Cl) of Iranian concentrate plants, which are the main source of materials corrosion in the pelletizing plants. Cl alongside alkaline elements (especially K) may cause corrosion and plug in the grate plates and other involved equipment. Therefore, it is tried in the processing plants to remove impurities from the concentrate to prevent potential problems in pelletizing and iron/steel making processes. Part of these impurities are existed in the nature of ores and others are sourced in the processing water. Various samples from the largest Iranian concentrate plants including Chadormalu, Gol-e-Gohar, Jalal-Abad and Sechahun were prepared to investigate the possibility of alkaline problems for each samples. The amount of Cl, K and Na of Chadormalu sample was obviously low and therefore no alkaline problem is expected. The Cl content of Gol-e-Gohar sample was high (980 ppm) while amount of K was less (0.008 Wt. %). Due to low content of K, most of Cl will release as Cl2 or HCl and so problems caused by KCl plugging would not be a problem. The amount of Cl in Sechahun case was nearly same as Jalal-Abad (400-600 ppm), higher than Chadormalu and less than Gol-e-Gohar samples. However, the K content was higher than all samples (0.04 Wt. %). Therefore, the amount of evaporated K would be 2-4 times more than other samples. Since the amount of Cl and K is simultaneously higher than usual iron ores, therefore alkaline problems may be a serious prevention factor for the continuous operation of this plant. In order to solve this problem some counter-measures is suggested and discussed including cleaning system, partial dust enriched with KCl removal and variation in the materials type of involved equipment.

Jan 1, 2018

By Walter W. Focke, Zola Kwela, Willem van der Merwe, Arao Manhique

"The advantages of the de Wet zirconium process for the manufacture of AZST from zircon sand include: Fewer processing steps; removal of radioactivity by leaching rather than by precipitation; alkali reagent recovery in the form of a sodium silicate solution that is essentially free of radioactivity; fewer waste streams and less waste to discard.Here we report on our efforts at maximizing the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since they do not hydrolyse in water they limit the recovery of alkali. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed. Optimum process conditions, with respect to NaOH recovery, correspond to a 2:1 stoichiometry and fusing for 2-hour at 850°C. At these conditions the alkali recovery is ca. 78% and the zirconia yield is ca. 57%."

Jan 1, 2003

By Ajay K. Jha1

Drilling and Blasting are two important unit operations in the production cycle of a mine and a strong link exists between these two and other unit operations/subsystems like loading, transportation, and crushing. Under the present concept of ? Mine to Mill?, it is important to optimize the drilling and blasting operations by applying scientific approach to drilling and blasting using sophisticated instruments and new technologies, which depends heavily on Information technology (IT) to meet this imperative. Development of innovative models and software has lead to blast optimization process. Till date, the blast results are evaluated in terms of available empirical approaches like powder factor, which are too simple to exclude some key parameters or lack in providing reliability because of non-availability of user friendly IT enabled techniques. Although with the help of developed approaches, formulation of user-friendly software to assist the site engineers in effective post blast assessment has started but there is a dearth of holistic approach to design an optimum blast considering the techno-economic feasibility of the subsystems and the geo-mining conditions to achieve blast optimization. The science of IT enablement in drilling and blasting is capable to build innovative models for achieving blast performances which will be doped with productivity, economy and safety with due regard to environment. The present paper discusses the use of existing IT enablement in various mines of India citing the Indian scenario and the future requirements for achieving the techno-economics in overall mining operations.

Sep 1, 2012

By Jacob Masliyah, Zhenghe Xu, Lujie Yan

"Understanding adsorption mechanism of polymeric organic process modifierssuch as carboxymethyl cellulose (CMC) on talc hasbeen a major challenge due to anisotropic nature of talc basal planes and edge surfaces. The main objective of this study is to investigate the adsorption of CMC on the basal planes and edge surfaces of talc.Smooth basal plane and edge surfaces of talc were prepared successfully by simple cleavage and sophisticated ultramicrotome cutting method, respectively. The prepared surfaces were characterized by atomic force microscope (AFM) imaging to be sufficiently smooth for colloidal probe force measurements using AFM. Anisotropic surface charge characteristics were determined,with the basal planes to carry a permanent negative surface charge and edge surfaces featuring a pH-dependent charge characteristic. The adsorption of CMC on talc basal plane and edge surfaces at pH 9 in KClaqueous solutions of various ionic strengths wasinvestigated by in situ AFM imaging technique. Themorphology of adsorbed CMC on talc basal planes and edge surfaces was found to be significantly different, due to different binding mechanisms involved. Interaction of CMC with the talc basal plane was found to bedominated by hydrophobic interactions while its binding with the talc edge surface was mainly through chemical complexation and hydrogen bond. The amount of CMC adsorbed on both talc basal planes and edge surfaces increased with increasing ionic strengthof solutions. The methodology developed in our study opens the door to probe polymer adsorption on anisotropic phyllosilicate surfaces, which can help us better understand the mechanism of polymer adsorption on specific mineral faces."

Jan 1, 2014

Anglo American Platinum practices fine grinding in its processing plants to enhance the liberation of valuable minerals. If the fine particles of valuable minerals generated during fine grinding are not recovered during the flotation process, this could significantly contribute to the overall losses. This study examines the flotability of fine moncheite (PGE mineral) particles in a controlled environment (moncheite size distribution, concentration and liberation). A barren Norite ore ground to 40% and 80% passing 53µm was spiked, with four different size fractions of moncheite (-5, -10+5, -25+10 and -53+25µm) in order to evaluate the effect of particle size on flotation. The investigation also included the effect of energy input and collector dosage on the flotation of two moncheite size fractions, namely -5µm and -10+5µm. The results showed that the moncheite particle size has a significant impact on flotation. Coarse particles (-53+25µm) showed the highest Pt flotation kinetics and overall recoveries. The -5µm size fraction of moncheite could also be recovered by flotation, however, at a lower rate compared to the other size classes investigated. The increased collector dosage of 300g/t at the finer Norite grind of 80% passing 53µm enhanced the flotation rate of the -5µm size fraction of moncheite when compared to the lower collector dosage of 150g/t. The higher energy input during laboratory flotation, at an impeller speed of 1000rpm also increased the flotation rate of the -5µm size range, however, at a lower concentrate grade, when compared to the lower impeller speed of 700rpm. More favourable Pt flotation kinetics data was obtained for the -53 +25µm size fraction of moncheite at the fine Norite grind when compared to the coarse Norite grind. Keywords: flotation, moncheite, particle size, energy input and SIBX

Sep 1, 2012

By K. Saberyan

In this study, solvent extraction of zirconium by using triphenylphosphine oxide as extractant has been investigated. The results showed that extraction of zirconium by triphenylphosphine oxides in nitric acid and hydrochloric acid media were negligible. Extraction of zirconium in acetic acid media with concentration of 0.01~0.2 M has been studied and the results showed that the maximum percent of zirconium extraction was 40% in acid acetic with concentration of 0.01 M. By addition complexing agents such as potassium thiocyanate with the concentration of 0.01~0.2 M zirconium extraction increased up to 86% in 0.2 M potassium thiocyanate. By addition of sodium salicylate with concentration of 0.01 M and in pH=2.5, the maximum extraction of 96% was achieved. The striping of zirconium from organic phase can be carried out by 0.5 M solution of sulfuric acid.

Jan 1, 2014

Due to complex mineralogical and chemical interactions of the value and gangue mineral phases present in uranium-containing lateritic ores, deleterious pulp gelation which impacts on value metal recovery sometimes occur during atmospheric leaching. In this study, the leaching behavior and particle interactions of selected oxide (hematite, quartz) and clay minerals (muscovite, chlorite), which constitute predominant host gangue phases of typical lateritic uranium ores are investigated to provide basic, mechanistic understanding of temporal pulp gelation phenomenon. Isothermal, batch leaching with H2SO4 was carried out on concentrated dispersions (30 ? 57 wt.%) of single minerals at pH 1 and 25 or 70 °C and their concomitant solution, speciation and rheology (shear yield stress, viscosity) were characterized. It is clearly shown that despite the high oxide content of lateritic ores, the pulp chemistry and rheology is largely affected by the incongruent leaching behavior of more reactive, acid-consuming aluminosilicate clays. Furthermore, time- and temperature-dependent alumino-silicate species polycondensation interfacial reactions are shown to be responsible for the enhanced particle interactions, reflecting strong pulp rheology in agitation and pumping. If not properly mitigated, high pulp shear yield stress and viscosity have a striking impact on processability and hence, value metal recovery.

Sep 1, 2012

By M. Guo

Coal-based Direct Reduction in Interior-combustion Shaft Kiln (CDR/ISK) is a brand-new technique. Compared with the traditional Coal-based Direct Reduction (CDR) technique, its main character is to use Interior-combustion Shaft Kiln (ISK) as the reactor of direct reduction. After being crushed and grinded, iron ore is made into green pellet, which will be surface-coated by coal fines. Then, the surface-coated green pellet can be directly reduced in ISK. The pellet should not be too dry and should be charged from the top of ISK. Oxygen-contained air should be blasted into ISK to keep the temperature in it higher than 1000 degrees centigrade, at which iron oxide will start direct reduction. The reduced pellet will be discharged from the bottom of ISK and after de-surface-coated, spherical Direct Reduced Iron (DRI) can be gained. The volume of carbon monoxide in the off-gas discharged from ISK is less than one per cent. By using this technique to get one tonne DRI, the consumption of coal is about 300kg of fixed carbon, which is much lower than the energy consumption by using other CDR techniques. There is a lot of complex refractory iron ore in China, which remains unexploited. The iron-bearing minerals in this kind of the iron ore can not be beneficiated economically by present technique of gravity, magnetic, flotation or magnetic roasting because the iron minerals are too very finely disseminated to be liberated, or, the iron minerals are too similar to gangue to be separated each other. By using CDR/ISK, complex refractory iron ore can be directly reduced in lower temperature and all kinds of iron mineral can be turned into iron metal. As the grains of iron metal growing larger during direct reduction, magnetic separation can be used to separate iron metal from gangue mineral, thus high-grade iron metal fines can be gained. According to the experiments, the grade of iron metal fines is above 90 percent and the recovery of iron is higher than 90 percent. The consumption of coal to process one tonne of complex refractory iron ore is only about 90kg of fixed carbon.

Jan 1, 2014