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By R. Lodha, C. Oprea, G. Oprea, H. Zargar, T. Troczynski

"The basic refractories used in non-ferrous industry contain chrome ore for improving the thermal shock resistance, thus reducing the penetration of molten metal and fayalite-type slags into the lining. The current study aims to replace chrome ore with Me4+ ions along with Fe3+ ions in order to form MgO-Al2O3- FeOx-Me4+O2 based complex spinel systems that could perform similar to the complex chromia-bearing spinel in the magnesia-chrome refractories. This system allows for lower temperatures of synthesis and sintering. In our study, compositions with 60% MgO were fired below 1500°C and resulted in complete formation of complex spinel, and open porosity less than 5%. The in-situ formation of the complex spinel from the fine mix of oxides in the MgO-Al2O3-FeOx-Me4+O2 system offers a suitable alternative of binding system to produce basic refractories at lower temperatures and of similar physical and mechanical properties with magnesia-chrome bricks fired above 1750ºC. INTRODUCTIONThe synthesis of magnesium aluminate spinel (MgAl2O4) (Maschio, Fabbri, & Fiori, 1988) or magnesium chromate spinel (MgCr2O4) from their respective oxides is diffusion controlled resulting in a sluggish reaction even at high temperatures. For instance, the diffusion of Mg2+ and Al3+ ions in the intermediate spinel layer during reaction is slower than the diffusion of Mg2+ in corundum and Al3+ in periclase. The interfacial layer of spinel formed during the reaction increases the diffusion path for the spinel forming cations. This accompanied by ~8% volume expansion retards further reaction resulting in incomplete spinel forming reaction during sintering and hence densification during the reaction cannot be achieved. In order to assess sintering studies with fine particulate oxides that would result in a lower diffusion path, a mechanical mixture of the hydroxides of aluminium and magnesium calcined at 1400ºC to 1600ºC for 1 hour does not result in complete spinel formation (Sarkar, Das, & Banerjee, 2003), which indicates that reaction sintering of stoichiometric magnesium aluminate spinel is retarded by initial reaction forming the interfacial spinel layer. The basic bricks used as linings in non-ferrous pyro-metallurgical convertors are manufactured using magnesia and chrome ore, the sintering of which produce spinel solid solution. This solid solution is a mix of both normal and inverse spinel structures that sinters at temperatures in excess of 1800ºC in air."

Jan 1, 2012

By Yuki Koshino, Kenji Kaneko, Yasuhiro Aruga, Takuya Maeda

"In general, there is a strong correlation between dislocation characteristics and mechanical properties of aluminum alloys. In this study, dislocation characteristics of tensile deformed Al-Mg alloys were examined by transmission electron microscopy. An Increase in the solute concentration, ranging between 0.3 and 1.1%, Mg leads to increase in strength and decrease in uniform elongation. The accumulation of dislocations during the tensile deformation is observed in lower strain as the concentration of solute Mg in the alloy is higher. It is believed that the solute Mg in Al-Mg alloy promotes the accumulation of dislocation during the tensile deformation resulting in the decrease in elongation.INTRODUCTION The influences of the amount of Mg concentration on the tensile properties of Al-Mg alloys has been investigated by many researchers. It has been understood that the tensile ductility of Al-Mg alloy is higher for the Al-Mg alloys with higher Mg concentration beyond 2 mass% (Mukai, Higashi, Hirano & Tanimura, 1993). Uchida and Yoshida (1995) reported the formation of microbands during the tensile deformation due to the localization of dislocations, and the amount of microbands were reduced when the Mg concentration of the Al-Mg alloy was increased from 3 to 9 mass%. Their study suggested that the dynamic recovery of dislocation was retarded due to the increase of the Mg concentration during the tensile deformation, which resulted the increase in ductility. On the other hand, in the case of Al-Mg alloys with the Mg concentration less than 3 mass%, the reason why the ductility of Al-Mg alloys decreases with increasing Mg concentration has not been sufficiently investigated. In general, the Mg concentration used for automotive usage is less than 1 mass%, in the case of Al-Mg-Si alloys (Aoki, 2013). Therefore, to clarify the roles of Mg in the low concentration range on ductility of aluminum alloys and to elucidate its mechanism contribute to alloy design of Al-Mg-Si alloys having good formability."

Jan 1, 2018

By A. B. Rossetti

"THE MISSION TO Offshore Scotland was in my opinion a very worthwhile venture, as it indicated the scope of the offshore oil and gas business and how we might exploit it to the fullest here in Nova Scotia - if our offshore fields eventually become producing fields. The writer was able to attend a considerable number of lectures and as a result gained some valuable know-how on the engineering design, financing and operation of the North Sea oil industry. There are many new fields of technology that had to be developed to overcome the North Sea's hostile environment and a great deal of the same technology will have to be developed to win oil and gas from our continental shelf. The visit left me with several impressions, which in the main are:(1) The high order of investment required to develop offshore oil. The investment ranges from 10 to 20 times that required for a similar output on land. Each barrel of oil costs on the average of about $2,- 500 per barrel per day.(2) Because of the high investments required, before the first oil is produced the field must be brought into production at the earliest possible date and initial lead time from decision to production is less than four years. In the British Petroleum field, working at a depth of 450 feet will require an investment of $900,000,000 to develop a production of 400,000 bbl per day. (3) The size and complexity of equipment required is beyond anything ever imagined. Problems which must be overcome are such factors as water depth, wind velocities, wave height, wave period, long periods of darkness, low temperatures, distance from land, and fog."

Jan 1, 1973

By T. Haubold, K. Ortner, T. Jung, D. Roth-Fagaraseanu, C. Mattern

Application of integrally bladed disks (blisks) is of increasing interest in compressors of aero engines. Blisks are preferred due to their potential for size and weight reduction, for increased performance and for reduced manufacturing costs compared to conventionally bladed disks. Erosion of the blisk aerofoils in service reduces engine performance, and can result in short shop visit cycles. This significantly increases the life cycle cost of these components, particular when considering that eroded aerofoils can't be exchanged easily for blisks during refurbishment. Shop visit cycle times can be extended and maintenance costs can be reduced through the application of an effective protective coating. The ongoing development of an erosion resistant coating and deposition process suitable for coating complex blisk geometries is described here. The coating is a multilayered W /TiB2 system exhibiting superior erosion resistance compared to known single- and other multilayer concepts. A modified sputter process is used to enable coating even of blisk geometries with shadowed surface to competitive recurring cost.

Jan 1, 2006

By L. T. Munn

"IT IS NOT necessary here to dwell on the fact that sulphur is currently in short supply. It may be well, however, to •point out that this •storage is not merely a temporary condition, but that, judging by trends in world consumption of sulphur, it may •be anticipated that requirements will double in the next ten years.Even with improved techniques for mining elemental sulphur in the United States and the new finds in Louisiana, there is much concern as to how these future sulphur requirements can be met. It appears necessary to .turn more and more to other sources than elemental sulphur for •additional production. The three major alternative sources were:(1) By-product sulphuric acid •from smelter gases.(2) Sulphur and sulphuric acid from iron sulphides.(3) Sulphur from hydrogen sulphide contained in natural gas. The Jumping Pound sulphur plant of the Shell Oil Company of Canada, Limited, is designed to produce sulphur by the •third of these methods.Jumping Pound is a natural gas field about 20 miles west of Calgary where Shell has a number of producing wells."

Jan 1, 1952

By A. Lawson

"Continued and expanded use of underground diesel-powered equipment is considered desirable in order to achieve necessary production capability, particularly when coal becomes increasingly in demand as an energy source. Although diesel engines are derated for underground use, concern has been expressed in many quarters regarding the health effects of worker exposure to diesel-generated particulate and NOx emissions. This concern will increase as Canadian diesel fuel quality becomes heavier and with higher sulphur content. This could result in a requirement to increase ventilation rates by 50%.This paper describes the results of studies of various approaches designed to reduce diesel emissions. Two major approaches have been followed: fuel modification, and emission control hardware development. The results of progress in the development of these approaches will be described.Fuel modification includes the application of water/diesel and methanol/diesel fuel emulsions to the engine. Details of the techniques employed in this approach will be described, together with the effects on diesel emissions. (The paper is concerned with the emission aspects only, not the possible major engine modifications and/ or substitute materials of construction for 100070 methanol.) Use of methanol has the added advantage of acting as a diesel fuel substitute and extender, and there are expectations that underground diesel engines could eventually operate on close to 100% methanol fuel, thereby eliminating particulate emissions. The results of emission control hardware development will also be presented and will include the effects of catalysts, water scrubbers, exhaust filters and exhaust gas recirculation techniques on emissions. A combined systems approach employing a number of these components appears to be the most viable method of controlling the complete array of diesel emissions.This work should culminate in a better understanding of the costs involved in employing fuel modification or emission control hardware relative to the costs of increased ventilation which mpy be necessary to maintain a safe working environment for the underground worker."

Jan 1, 1981

By J. O. G. Posada

Magnesium derived foams were prepared by using the so-called baking of powder blended precursor material method. This method comprises mixing magnesium powder with a small fraction of blowing agent (ZrH2, Cs2CO3 and CaH2) and Ni like catalyst, compacting this mix and creating a foam by heat treatment above the magnesium melting temperature. The resulting samples were characterised by microscopy, gas adsorption (BET method) and by small angle neutron scattering. Several mathematical models were used in order to determine particle size distribution, fractal dimension and total pore volume fractions.

Jan 1, 2005

By M. Oliazadeh

The bioleaching of fine low grade copper sulfide ore is described. A sample of ground (> 1 mm) copper ore from Sarcheshmeh, Iran, was subjected to a series of agglomeration procedures and subsequently leached. The best agglomerate was obtained by using lime and sulfuric acid as binders. A column bioleaching test of agglomerated ore was then run for 105 days along with a non-inoculated control column having thymol as bactericide. The results show that about 77.5% of copper was extracted in the bioleaching, whereas the control column achieved only 57% copper leaching.

Jan 1, 2007

By J. Kang

There is increasing demand to utilize aluminium alloy sheets and their spot welds by the automotive industry. While traditional uniaxial tensile tests only determine mechanical properties to small strain, direct measurement of the constitutive behaviour of aluminium alloy spot welds at large strain remains a challenge. A technique was successfully developed using digital image correlation coupled with shear tests to directly measure the constitutive behaviour of an AA6022-T4 spot weld to large strains. The results show that the spot welding process not only decreases the yield strength but also lowers the work hardening rate of the nugget versus the base material. Details of sample preparation, experimental approach and results will be discussed.

Jan 1, 2011

By J. Keith Haddock

"Introduction The Boundary Dam Mine is located 5 km south of the City of Estevan, Saskatchewan and is operated by Manitoba and Saskatchewan Coal Company Ltd., one of the Luscar companies. The entire production of 1.7 million tonnes per year is delivered to the Boundary Dam Generating Station of Saskatchewan Power Corporation. Geology There are basically two seams mined on the property, the main Estevan seam ranging in thickness from 3.0 m to 4.5 m with partings and the upper Roche Percee seam (roughly 15 m to 23 m above the Estevan) which ranges from 0.6 m to 2.0 m in thickness. Most of the reserves are concentrated in the Estevan seam, the Roche Percee only being mined whenever its thickness makes it economic to recover. The coal measures belong to the Ravenscrag Formation of Tertiary (Paleocene) Age. This formation is widespread in North Dakota and Montana and contains the lignite fields of North Dakota and subbituminous coals of Montana. The formation is gently tilted to the southeast at Boundary (0.5 degrees) and consists of weak sandstones, siltstones and silty mudstones. Reserves and Coal Quality The present minesite encompasses a coal reserve of approximately 50 million tonnes calculated to a maximum stripping depth of 37 metres or 20:1 mining ratio. The reserves form only a part of the total reserves in the Estevan area which are owned by the Saskatchewan Power Corporation. The coal being mined is classed as Lignite ""A"" and has the following specifications:"

Jan 1, 1985

By T. Newton, G. A. Bezuidenhout, P. J. Tauetsile, F. Trask

The technology to selectively leach gold, silver and base metals from ores, concentrates, and wastes, using an alkaline glycine solution, has initiated significant interest in using the new technology in various environments such as in-situ, in-place, dump, heap, and vat and agitated tank leaching. It has been shown that glycine acts synergistically with a number of other lixiviants to lower the net consumption of the other lixiviants while allowing low cost glycine solution recovery. Glycine is a non-toxic, stable, environmentally benign reagent that is available in bulk industrial quantities. It has the ability to dissolve most copper oxide and sulfide minerals, as well as native copper, whilst not interacting with acid consuming gangue nor dissolving iron and various or ubiquitous gangue elements. It acts synergistically with small amounts of cyanide to leach gold-copper ores at leach rates higher than either glycine or cyanide on their own, while significantly reducing cyanide consumption and eliminating detoxification requirements. The leaching behaviour of various glycine based systems will be reviewed, followed by the evaluation of the adsorption of gold onto activated carbon. Where the economics merit it, copper can be easily recovered using solvent extraction or sulfide precipitation.

Jan 1, 2017

By K. Waters, A. Navarra, T. Grammatikopoulos

Strategic decisions to develop a mineral deposit are subject to geological uncertainty, due to the sparsity of drill core samples. The selection of metallurgical equipment is especially critical, since it restricts the processing options that are available to different ore blocks, even as the nature of the deposit is still highly uncertain. Current approaches for long-term mine planning are successful at addressing geological uncertainty, but do not adequately represent alternate modes of operation for the mineral processing plant, nor do they provide sufficient guidance for developing processing options. Nonetheless, recent developments in stochastic optimization and computer data structures have resulted in a framework that can integrate operational modes into strategic mine planning algorithms. A logical next step is to incorporate geometallurgical models that relate mineralogical features to plant performance, as described in this paper.

Jan 1, 2017

By M. M. C Jiménez, J. A. S Ténorio

For the recovery of valuable materials and for the protection of environment, recycling process of printed circuit board is an important subject of study. Moreover, the popularization of the computers and its technological evolution has generated a large number of waste electrical and electronic equipment. This paper presents a study of synergistic solvent extraction of copper, nickel and zinc from a sulfuric leaching liquor of printed circuit boards (PCB’s). The percent extraction of copper, nickel and zinc from dilute aqueous sulfate media besides synergistic effect of mixture of the .extractants Cyanex 272 and D2EHPA have been studied. Furthermore, different conditions such as temperature, pH of the feed solution have been examined. The results suggest that the synergistic effect of the .extractants mixture enhance the extraction efficiency of nickel.

Jan 1, 2014

By A. M. L. Cushing, S. Kelebek, A. Ghahreman

Iron sulfides are part of many ore deposits affecting flotation separation of non-ferrous base metals from them. Open-circuit potential (OCP), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) measurements were carried out with pyrite and pyrrhotite electrodes to investigate their reactivity under various flotation conditions, which involved the use of TETA, SMBS, and their combination. TETA was found to adsorb on the electrode surfaces causing a significant increase in charge transfer resistance of the product formed, which was most significant at OCP. This effect is much less with SMBS, indicating its greater surface reactivity compared to TETA. The combined use of these reagents decreases charge transfer resistance to a greater degree than that experienced with their individual uses. Addition of Cu2+ as a potential activator to this system nearly eliminates the action of TETA on the electrode surface, which can be attributed to sequestration/chelate formation in liquid phase. The relative effects of these reagents on pyrrhotite electrode are similar to that of pyrite. The main difference between the pyrite and pyrrhotite electrodes is that the observed charge transfer resistance on the pyrrhotite surface with each reagent case is significantly lower by 3 to 4 fold. This is compatible with its anodic nature and ease of oxidation since the OCP value of pyrrhotite is lower than that of pyrite. Results are discussed in relation to flotation/depression behavior of these iron sulfide minerals in mineral separation processes.

Jan 1, 2017

By Z. D. Hora

Traditionally, industrial minerals in British Columbia comprise about 10 per cent of the combined value of mineral, coal, petroleum and natural gas production. Over the years a wide variety of industrial minerals have been produced in British Columbia, often with a different level of marketing success. For some products such as building stone, common brick or expanded shale, once strong demand gradually disappeared; for others such as asbestos and barite, new discoveries or new industrial activities created demand and new markets. For yet other minerals such as fluorite, talc and perlite, wider use has been prevented by the small size, poor quality or remote locations of the deposits. Bentonite (1926 to 1944-as a by-product from coal mines) Building stone (intermittently since the mid-1800s) Chromite (1918 and 1929) Over the past years, the list of industrial minerals produced has been expanded to include several new commodities: glassgrade silica sand, magnesite, pumice and silica for ferrosilicon and silicon carbide manufacture.

Jan 1, 1984

By J. E. Gill

"The Wasa Lake property is a block of about 1,640 acres in Beauchastel township, Quebec. Gold was discovered there first in 1936 in what is now known as the 'Southern area ( Fig. 1). Stripping and trenching were followed by 9,218 feet of diamond drilling in twenty holes. A number of good intersections were obtained, but their interpretation in terms of ore was difficult. A shaft was then sunk to 220 feet vertical depth. Thirteen hundred feet of lateral work and 543 feet of diamond drilling were completed at the 200-foot level before work was discontinued in 1938. Results up to this point had been just fair.Early in 1944, surface diamond drilling was resumed. The first hole cut material of ore grade in a strong shear zone 1,000 feet north of the old workings, and holes to the east and west showed this to be an extensive gold-bearing zone.In August 1945, a main working shaft was started. This has been sunk to 550 feet slope depth. A cross-cut at 390 feet vertical depth was driven to the ore zone and, by drifting and drilling at regular intervals, a length of 725 feet had been tested to December 31st, 1946 ( Figs. 1 and 2). The results check those from surface drilling quite closely.In the main zone, scoping widths from 8 to 40 feet and averaging about 25 feet are indicated. The grade after dilution should be about 0.15 oz. gold a ton and operation will probably start at 1,000 tons a day."

Jan 1, 1954

By D. B. Dreisinger, A. A. Gunaratnam

A pressure oxidation (POX)-hot cure (HC)-lime boil (LB) process is used in industry to recover silver from refractory gold sulfide ores containing minerals such as pyrite and arsenopyrite. Pressure oxidation is used to oxidize minerals and liberate occluded gold particles. As such, iron goes into solution and under acidic and high temperature conditions often precipitates as basic iron sulfate (BFS). BFS consumes excess lime during neutralization prior to cyanidation. Therefore, a hot cure stage is required to re-dissolve BFS back into solution. BFS re-dissolution consumes acid and produces ferric sulfate. In the presence of silver, these conditions favor the slow formation of silver jarosite. Silver jarosite is refractory to cyanidation, and must be broken down prior to cyanidation. This is done in the lime boil to produce a cyanide-soluble silver hydroxide. A study was conducted to investigate parameters that affect the precipitates that form in each stage of the POX-HC-LB process.

Jan 1, 2017

By P. R. A. Andrews

"Talc ore from Bakertalc, High water, Quebec analyzing about 60% talc, previously dry ground to about 95% minus 53 µm was beneficiated in an 11.4 kg/ h pilot-plant flotation circuit. A concentrate of 95.9% talc (necessary for paper-grade) was obtained at a recovery at 75.3% by employing 53 g/t of Dowfroth 250 collector at pH 9.2; further cleaning increased the grade to 97.2% talc at a recovery of 57.5%.Flotation of fresh ground 60% minus 44 µm ore at a feed rate of 18.6 kg/ h produced a grade of 96.4% talc with a recovery of 78.2%, using Aerofroth 70 collector a six carbon-branch chain alcohol, at pH 9.2.The similarity in the concentrate grade and recovery between pre-ground and fresh-ground ore indicated that it was not neces¬sary to grind to 95% minus 53/2m to achieve comparable selectivity. A grind of 60% minus 44 pm corresponds to 100% minus 300 µm.Flotation retention times obtained with fresh ground ore indicate 33 min. for combined rougher/scavenger, and 15 min. each for the first and second cleaners.Talc-magnesite flotation separation is explained in terms of physico-chemical forces, with reference to surface charge and adsorption mechanisms."

Jan 1, 1989

By Eugene Sun, Qiang Xu

This presentation will review current applications of composite materials in aircraft design and discuss the challenges involved in maximizing the potential of the composites in aircraft applications.

Jan 1, 2010

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012