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By K. Enns, J. J. Byerley

"While thiocyanate (SCN-) is used in a number of industrial processes (production of polyacrylonitrile filaments, synthesis of agricultural chemicals and certain metallurgical solvent extraction and flotation circuits) it is recognized more as an undesirable by-product associated with ' the metallurgical industry. Thiocyanate is present at low concentrations in some waste streams from the iron and steel industry. Of particular significance is the formation of thiocyanate during cyanidation of gold and silver ores, concentrates, tailing s and residues. The thiocyanate levels present in the resulting effluents may range from a few mg/I to several thousand mg/I.At present, thiocyanate does not appear to be as hazardous in the environment as cyanide (CN-) at the same concentration although its interaction with other species and resulting decomposition of products may be unacceptable. Of course the presence of thiocyanate in the leaching circuit and ultimately in the effluent streams may add considerably to the oxidative requirments of any non-selective treatment process for cyanidation wastes.With respect to the thiocyanate as it relates to the cyanidation process, two aspects are evident. Thiocyanate forms and persists in the cyanidation circuit resulting in a ""fouling"" condition with subsequent loss of leaching activity. In order to reduce or control this problem, it is common practice for some mills to discharge daily as much as 20% of the barren leach liquor. Besides contributing to fouling of the leach liquor the formation of thiocyanate represents an irreversible loss of reagent cyanide. It is noteworthy that in some present or proposed mill practice reagent cyanide loss through thiocyanate formation may reach 50%(1). The purpose of this paper is to discus s the application of controlled electrooxidation of thiocyanate with the view of suggesting a process for regenerating cyanide from waste thiocyanate(2). The paper describes the important theoretical aspects and presents experimental data obtained for thiocyanate electrooxidation using both small and large scale electrochemical reactors. Some economic conclusions are presented."

Jan 1, 1984

By B. J. Morash

"The six mineable coal seams at Quintette Coal Limited (QCL) vary in thickness from 0.75 m to 9.5 m and include waste partings varying from 0.2 m to 4 m thick. They are highly faulted and folded in some areas and dip angles range from horizontal to 90 degrees. Due to this variation in thickness and orientation of the seams, several different mining methods are used to economically recover the coal. The key to QCL's success depends on the timely collection of detailed geology data and on mine planning which allows selection of the best method of mining to achieve maximum coal recovery with minimum dilution and cost. This paper will describe the various methods of mining employed and the criteria used to select them. IntroductionThe unique challenge in mining at Quintette Coal Limited (QCL) is to extract large quantities of coal and waste, from a complex orebody, with constricted areas for mining and waste disposal. This challenge dictates the mining of as many as four 10 m benches per year, through complicated coal structures, from three separate open pits with a total of 19coal seams. This total is made up of 5 seams at Mesa, 8 seams at Wolverine and 6 seams at Shikano (Fig. 1).Computer-aided mine planning and scheduling is carried out on a routine basis to ensure the prudent selection of methods of mining, to produce plans which ensure delivery of appropriately blended raw coals to the plant, and to coordinate disposal of large quantities of waste.Several methods of mining are applied simultaneously, and as a result coal and waste are released at different rates from twelve to fifteen mining faces. In order to ensure uninterrupted flow of material from excavators and to utilize the truck fleet effectively, a computerized dispatch system is employed.GeologyGenerally, geological conditions can be related to structural (faults and dip angle) and/or stratigraphic (coal seam and interseam waste thickness) sources"

Jan 1, 1988

By D. Laguitton, D. Cimon

"BILMAT is one of the most powerful algorithms in existence for material balance computation in mineral processing flowsheets. It is based on a hierarchical decomposition coupled with the Lagrange multipliers method widely reported in the literature. Flowrates can be calculated optionally for pulp, solid or water. Assays are adjusted for a variety of subnetworks, such as assays of the solid as well as assays of fractions of the solid called level 4 data (l: pulp, 2:solid and water, 3:assays of solid, 4:assays of classes of solid).BILMAT4 is a new implementation of BIU1AT that operates in a new microcomputer environment and makes the method more accessible than ever. Its main features are a full-screen colour editor allowing graphic flowsheet drawing and data entry with automatic error checking. Mass balance equations are automatically generated by analysis of the graphics and corresponding data, thus relieving users from the error-prone definition of networks. Sensitivity analysis is performed to assess confidence intervals of computed flowrates and adjusted assays.BILMAT4 incorporates an option for gold leaching circuits where the element to be balanced appears in both the solid and liquid phases with negligible effect on the mass flows of solids. Recoveries are computed in all streams. This program is currently released by CANMET as part of the CAMP collection for Computer Aided Mineral Processing. A complete sample run of the program is discussed."

Jan 1, 1989

By Y. Prevost, D. Verhelst

"A computer-assisted process control system for the Noranda Process Reactor Wa5 installed at the Home smelter in 1991. Operating as an advisory tool for the furnace operators, and using a flexible oxygen balance as the basic building block of the computer program, the new control system has helped to reduce the variability in the grade of the matte produced by 50% . The smelter is currently operating at a 72% copper matte, with a standard deviation of between 1.0 and 1.3, while treating a wide range of concentrates, secondary materials and scrap. Enhanced process control has allowed for longer reactor campaigns, and improved stability of the converting operation.This paper reviews the feed classification and blending practice used at the smelter, outlines the strategy of the new computer control system, and summarizes the benefits realized since the implementation of the system in early 1990.IntroductionUntil 1989 the Noranda Home smelter operated as a multi furnace smelter, at one time having three hot-charge reverberatory furnaces, and finally operating with one wet-charge reverberatory furnace and one Noranda Process Reactor. In 1989 the final reverberatory furnace was closed and the Reactor became the sole smelting vessel, treating around 750 000 tonnes of concentrate, secondary materials, and scrap per year. At the time of the start-up of theNoranda Reactor in 1973, the vessel was capable of treating 750tonnes per day of a heterogeneous mixture of copper concentrates, fluxes and secondary materials to produce copper in one operation. Through process improvements, and the introduction of additional oxygen in 1982(pannell and Mackey, 1988), the daily tonnage increased to 1800 tonnes by 1988. The operation had also been changed to produce a high-grade matte instead of copper. Figure1 illustrates the main features of the reactor, a cylindrical vessel which is charged at one end and tapped at the other. The matteis subsequently processed through Peirce-Smith converters and anode furnaces before being cast into copper anodes. Figure 2 outlines the progressive increase in the furnace smelting capacity. Over this period the percentage of secondary materials, and scrap feeds also increased to approximately 110 000 tonnes per year, or 15% of the total new feed input (Bedard et al., 1991). Now operating wholly as a custom feed operation, the Home smelter can treat over 2200tonnes per day of new metal-bearing material."

Jan 1, 1993

By O. Moselhi

This paper describes a method for selection of most suitable project delivery systems for capital projects. It expands upon the method advanced by the Construction Industry Institute (CII) in 2003, and incorporates additional decision criteria and project delivery systems in a multi-tier decision computational platform. The paper integrates the analytical hierarchy process to alleviate the inherent subjectivity associated with the assignments of relative weights to selection criteria used in the CII method. It also expands the range of project delivery options to include Public Private Partnership (PPP) and Integrated Project Delivery (IDP). The range of selection criteria was expanded by 60, beyond the 20 criteria of the CII method. Relative effectiveness values are proposed for the added project delivery systems making use of recent project cases in Canada and the USA. The method was implemented in a spreadsheet application. Multiple scenarios were considered for one of the cases presented in the CII study and a sensitivity analysis performed based on the developments made in this paper. The differences in outputs between the CII method and the proposed method are discussed. This is the first decision framework that incorporates both the presently used PPP and the recently introduced IDP, along with the widely used project delivery systems. The developed method allows users to filter out the factors and alternatives that do not apply to the case at hand, based on key inputs at the upper tier. The method is flexible and can easily be expanded upon and customized by the user.

Aug 1, 2013

By Raymond D. Potts

"Minntac is a taconite mining, concentrating and pelletizing operation located near the town of Mountain Iron, Minnesota, U.S.A. It is totally owned and operated by USX Corporation and represents its largest source of domestic iron units. Minntac began producing fluxed pellets in 1988 and has produced both acid and fluxed pellets since then. This paper compares the acid and fluxed pellets produced at Minntac. It reviews modifications that have been made to the plant flowsheet and discusses areas recognized for improvement since the beginning of fluxed pellet production. It also comments briefly on the performance of Minntac fluxed pellets in USX blast furnaces and the future of fluxed pellets at Minntac.IntroductionMinntac was built in three steps with each step designed to produce 6 million long tons of acid pellets per year. The actual production has varied though. Figure I shows the production by year at Mirmtac. Step I began production in 1967, Step 2 in 1972 and Step 3 in 1978. Mirmtac produced 16.5 million tons in 1979 but only 3.5 million tons in 1982 when the facility was shut down for six months because of the lack of demand for pellets. Since the initial start up, Mirmtac has produced over 200 million long tons of pellets. Until 1987, all the pellets produced were ""acid"" pellets. In 1987, equipment to produce ""fluxed"" pellets was installed and tested. In 1988, full scale production of fluxed pellets began."

Jan 1, 1991

By C. J. Li, J. L. Feng

In the present study we focuses on developing the poroelasticity model that deals with adsorptioninduced permeability change mostly occurred in porous media constituted several phases such as coal. The underlying pressure induced by adsorption is obtained by Virial expansion form, which is substantially founded on statistical physics. The corresponding thermodynamic pressure applying on the pore surface is then used to detail the pore pressure and further to evaluate the macroscopic volumetric strain and the porosity. In the process of physical adsorption, the adsorbed phase is in thermodynamic equilibrium with the gas phase regardless of pore size, and the corresponding chemical potentials are all equal. The relationship between surface strain and volumetric strain is derived under infinitesimal deformation conditions to gain an explicit formulation of pore surface area with respect to volumetric strain and porosity. After the formulation of surface stress modified by the Langmuir isothermal adsorption is derived, the differential micromechanical constitutive equations of porous media are obtained. By supposing that the ratio of current permeability to initial is equal to the cubic ratio of current porosity to initial porosity, the differential equations for permeability change is consequently derived. The numerical simulations by the present model for permeability change of coal induced by adsorption of CO2 and CH4, respectively, are presented under confined stress conditions. The predictions from the model are good in agreement with the experimental data of sorption-induced permeability change of coals in the literature.

Jan 1, 2015

By Robert B. Parsons

"Finance Minister Paul Martin's first budget disappointed almost everyone. The business sector was disappointed at the some what feeble attempt to grapple with the country's deficit. The mining industry was disappointed by tax proposals regarding mine reclamation that fall short of the industry's needs. Has anybody been happy with a federal budget? Federal Budget DisappointsThe federal government's budget papers that were tabled on February 22, 1994, contained a rather bizarre mixture of unrelated tax proposals. The budget signals an unexpected attack on the tax treatment of debt settlements, on certain types of corporate reorgani2ations, and on income earned by foreign affiliates. This is an old style budget, which proposes a pot pourri of technical changes and policy initiatives. Mine ReclamationEffective February 23, 1994, a taxpayer's contributions to a prescribed mine reclamation trust fund will be deductible as a current expense. The budget papers do not provide a definition of what will constitute a ""prescribed"" trust: this definition will surface in due course. However, the budget papers indicate that:• income earned in such trusts will be subject to tax each year;• all withdrawals from the trust (including income already taxed) will be included in computing the income for tax purposes of the recipient;• reclamation costs will continue to be fully deductible at the time incurred; and • contributions, trust earnings, and withdrawals will not be taken into account for the purposes of determining a taxpayer's resource allowance."

Jan 1, 1994

By A. B. Szwilski

The paper outlines the factors taken into account for the selection of steel arch supports. The results are based on experience using the long wall system of coal mining where roadway closure can be extreme. Results of tests on scale-model steel arches and full-scale yield elements are also presented.

Jan 1, 1979

By Janice Zinck, Ian London

In recent years, the secure supply of critical and technology metals has become increasingly important tomajor industrialized economies that seek to sustain their industrial base and develop advanced technologies, such as clean energy. Canada, with its significant reserves of rare earth element (REE) and other metals, has an opportunity to supply some of the global demand for these materials. However, to transition from promising mineral deposits to marketable products, investment in strategic research and development (R&D) and expertise is needed to address the complex technological challenges around the production, separation and processing of these metals, and to better understand the global market for these key commodities. To this end, in its April 2015 budget, the Government of Canada committed to invest $23M over 5 years to accelerate production of REE and chromite/ferrochrome. The goal of this program, developed in close association with industry, is that Canada contributes a sustainable supply of REE to the global market. The research and development program will provide the technological capacity to establish a Canadian REE industry. This paper will discuss REE R&D advances achieved in the first year of the program in areas of mineral characterization, beneficiation, leaching, separation and environmental management and will highlight the Canadian model of collaboration where industry (e.g. prospective producers, technology companies), government, academia and other stakeholders work closely to ensure that the R&D is targeted, innovative and effectively deployed and commercialized.

Jan 1, 2016

By A. K. Debnath

Coal is the mainstay of Indian energy supplies. The many-fold increase in demand for coal puts a huge pressure on augmenting production, primarily from opencast mines. The increase in production necessitates heavy blasting in overburden and coal benches of opencast mines, which poses numerous challenges in carrying out blasting operations techno-economically. Presently, the consumption of industrial explosives and accessories in Coal India Limited (CIL) has touched a whopping figure of $350 million USD per annum and CIL will be spending approximately $1 billion USD between 2012?2013 to 2014?2015 for procuring explosives and accessories. This paper discusses some of key challenges faced in various mines of CIL during blasting, where blast instrumentation at the mine level will prove to a harbinger for practicing blasting engineers. Presently, the problem of scattering in surface detonators and down-the-hole detonators affects the blast performance significantly by increased blast induced ground vibration and reduced fragmentation. The paper discusses a case study carried out at Umrer opencast project of CIL to investigate the effect of scattering by using blast simulation techniques (i.e., JKSimblast) and observing the actual blast results with the help of a high-speed camera and multi-channel high frequency data acquisition systems. The fragmentation assessment was carried out by adopting Digital Image Analysis techniques and using the granularity software viz. Wipfrag. The blast instrumentation in the case study mine resulted in improvement in fragmentation of 12.76% and a direct savings in explosives cost of 28%. Geophysical techniques such as the seismic survey method have been used at Umrer Project, CIL to characterize the rock mass using the Multi Channel Analysis of Surface Waves system for selecting the explosives technoeconomically. The minimum deck thickness for mines of CIL using drill cuttings as decking materials should be 10 D, where D is the drill diameter. The estimation of blast performance on the basis of prescribed Powder Factor (i.e., kg of explosives per m3 of rock) is technically unscientific as the criterion of a good blast depends on many factors (i.e., good heave, loose muck, muck profile angle, ease of digging, uniform fragmentation). The present paper proposes a new methodology for techno-economic evaluation of blast performance. The new methodology involves four significant factors viz. specific energy consumed by the loading equipment, charge factor, productive yield and diggability index for assessing blast performance. The use of user-friendly, accurate, reliable, rugged and handy instruments in blasting will significantly improve mine productivity, equipment efficiency and economics. The improvement in blast performance, even by 1%, will provide a significant savings of $3.5 million USD per annum to CIL. It may be concluded with high degree of confidence that blast instrumentation at the mine level will influence the mine productivity and economics.

Aug 1, 2013

By Robert B. Parsons

"It is quite likely that more than a handful of junior exploration companies will receive some startling news from their accountants this spring when 1989s tax returns are being prepared. These companies could find that, for the first time ever, they will have to write a cheque to the federal government on account of a new federal capital tax which became effective July I, 1989IntroductionMany mining companies which have never had to pay a federal income tax are finding that they indeed have a tax liability for 1989. Non-producing companies, such as junior exploration companies, almost automatically assume that they don't have to pay any income tax. But, a new tax imposed under the Income Tax Act catches especially the company that has no income.Effective July 1, 1989, a federal capital tax (some call it a corporation minimum tax) is payable by any corporate carrying on business in Canada where the corporation has ""taxable capital"" exceeding $10 million. As a result of the popular use of flow-through shares in recent years, many junior exploration companies are finding that their balance sheets show capital stock over $10 million, and that they are consequently caught by the new tax. Further, some of these companies are finding, to their chagrin, that the tax for 1989 was due on February 28, 1990, and that non-deductible interest is ticking away on unpaid taxes."

Jan 1, 1990

By S. Bantubani, I. Mc Dougall, S. Arjun, H. Joubert, R. Hansraj

The requirements determining the design of the Söderberg electrode columns used in base metal applications are different to those of other industries. There is a strong trend to position the contact shoes above the furnace roof in order to reduce the risk of water leakages directly onto the furnace bath. Tenova Pyromet has adapted its proven electrode column design for application on base metal electric furnaces based on these requirements. The design modifications implemented as well as considerations regarding the overall electrode-roof-furnace arrangement are discussed. Equally important is the management of the Söderberg electrodes to prevent over or under baking. Tenova Pyromet has developed the AutoFurn™ furnace controller to not only optimise furnace operations, but to improve electrode management. An overview of the electrode management control philosophy implemented by AutoFurn™ is provided, focusing on intelligent electrode regulation, slipping and baking. INTRODUCTION Tenova Pyromet has developed an electrode system for use in base metal furnaces, which builds on the experience that Tenova has gained during the past 30 years with electrodes in the ferroalloy and base metals industries. In base metals applications, an important safety consideration is the minimization of water within the furnace and on the furnace roof. In addition, direct contact between copper equipment such as contact shoes and pressure rings and the contents of the furnace is discouraged. In a 3 phase AC furnace, three electrode columns transfer the electrical energy to the furnace bath. Both Söderberg and prebaked carbon or UHP graphite electrodes are in use in base metal furnaces. In each column, the electrode is held in position by a hydraulic slipping and regulating device, a pressure ring and contact shoes. The electrodes can operate in a submerged-arc or brush-arc configuration, where the electrode is immersed in the slag or a short distance above the slag (Mc Dougall 2013). The electrode equipment is divided into an upper and a lower electrode assembly. The self-baking Söderberg electrode is made from lengths of steel casings that are added to the top of the electrode column and welded into place. Carbon electrode paste is added to the inside of these casings and is baked to form a solid tip in the region of the contact shoes. The working platform that surrounds the area where new electrode casings are added, is electrically isolated from the building and each electrode is isolated from the others to ensure the safety of the personnel who perform the electrode casing additions.

Jan 1, 2019

By J. H. Reiss, D. F. Bruhn, Idaho National Laboratory, Y. Jiao, D. W. Reed, Y. Fujita, D. L. Daubaras

"Bioleaching offers a potential approach for recovery of rare earth elements (REE) from recyclable materials, such as fluorescent lamp phosphors or degraded industrial catalysts. Microorganisms were enriched from REE-containing ores and recyclable materials with the goal of identifying strains capable of extracting REE from solid materials. Over 100 heterotrophic microorganisms were isolated and screened for their ability to produce organic acids capable of leaching REE. The ten most promising isolates were most closely related to Pseudomonas, Acinetobacter and Talaromyces. Of the acids produced, gluconic acid appeared to be the most effective at leaching REE (yttrium, lanthanum, cerium, europium, and terbium) from retorted phosphor powders (RPP), fluidized cracking catalyst (FCC), and europium-doped yttrium oxide (YOEu). The Acinetobacter isolate, BH1, was the most capable strain and able to leach 33% of the total REE content from the FCC material. These results support the continuing evaluation of gluconic acid-producing microbes for large-scale REE recovery from recyclable materials.INTRODUCTIONAn enhanced recovery, substitute, reuse or recycle paradigm is important for balancing the supply and demand of critical materials (DOE, 2011). The recovery of rare earth elements (REE) from recyclable materials is an important component in this model. REE are used in a variety of modern products. For example, neodymium, europium, terbium, dysprosium, and yttrium are important for applications such as permanent magnets, lamp phosphors, rechargeable batteries, etc. (Binnemans, Jones, Blanpain, Van Gerven, Yang, Walton, & Buchert, 2013; DOE, 2011; Graedel, Harper, Nassar, & Reck, 2013). Cerium and lanthanum are used in glass polishers and additives in fluidized cracking catalysts (FCC)."

Jan 1, 2016

By Fathi Habashi

A new era in pressure hydrometallurgy is marked when the roasting - leaching - electrowinning process in the zinc industry was replaced by direct pressure leaching of zinc concentrate. Since then, the technology has received recognition as the technology of the future. Large autoclaves of unprecedented size have been manufactured and installed in a number of metallurgical plants for recovering copper and nickel from their concentrates or liberating gold from its refractory ores. An attempt to recover alumina from clay using pressure technology is underway. Autoclaves lined with acid resisting bricks or with titanium clad may weigh as much as 800 tonnes were transported successfully from the manufacturing workshop to the mine site over long distances.

Jan 1, 2014

By A. C. Bonnier

"INTRODUCTIONI have been asked to make available our method of determining the ""Live Inventory"" within a gravity type thickener. The ""Live Inventory"" being that tonnage compatible with the optimum underflow density that satisfies the process requirements.One prerequisite of the calculations is the proper determination of the final pumpable underflow density. A further requirement is that, prior to shutdown, the thickener has been operated properly, particularly that it has not been operated for storage capacity.Until recently I had few chances to check the method. However, I was most fortunate to have had a recent opportunity covering several months on a 300 ft diameter thickener at a plant in the U.S.A., wherein the method was tested and verified many times. The method proved accurate in that our calculated tonnage checked with the actual dried physical inventory of the drying facility.At the precise moment that the feed to the thickener was shut down, a per cent solid determination was made at the critical place and the tonnage in ""Live Inventory"" determined. Let us say that at the moment the thickener U' Flow solids was 20%. The thickener then was allowed to cperate until the U' Flow solids dropped below 20%, at which time the thickener was deemed to be relieved. Anything much less than 20% was not suitable to the subsequent centrifuge operation.Most large metallurgical thickeners have a configuration of three slopes at the thickener ""bed"". These slopes are dictated by the raking blades and are shown on the manufacturers' erection drawings. The first slope is from the outer periphery and generally takes up a distance of about 60% of the radius, the second slope generally taking up the remaining 40%. Within this 40% area, there is usually another slope taken up by the cone on ""B"" type thickeners or an actual steeper inner slope on ""C"" type thickeners."

Jan 1, 1989

By Janice Zinck

?Past? Images of Mining ?Historic practices have been poor ?Mining still widely perceived as environmental ?spoiler? ?Public only hears the bad news stories. Lessons Learned from the Past ?Sustainability matters ?Recognition of social and environmental responsibilities ?Recognition of importance of public concerns and perceptions ?Community engagement

May 1, 2009

By A. Bauer

The correct application of large crater blasts in unfrozen tar sand is an effective means of resisting frost penetration during winter. This results in much higher productivity and considerably less down time with excavators during winter operations. The resulting flatter angle of repose of the highwall has readily been accommodated with slight modification to bucket-wheel excavator operating procedure. Other mining schemes call for large draglines to be located on top of the highwall, which can be as high as J80 feet. The question now arises as to the effect that blasting might have on the stability of such a situation in which the highwall includes potential planes of weakness. This paper applies blast vibration data from large-scale blasting in tar sand to the stability analysis for typical production situations likely to be encountered and indicates safe scaled distances to be employed between dragline and blast.

Jan 1, 1979

By T. R. Yu, D. B. Counter

"Kidd Creek Mines primarily employs sublevel blasthole stoping for underground mining operations. During pillar recovery in No.1 Mine and panel mining in No.2 Mine, the free standing fill exposures may reach a height of 100 m or more. Consequently, a competent consolidated rockfill has been required to fill the mined openings.Since 1976, a total of more than fifty stopes and pillars have been filled with over four million tonnes of backfill. Fill exposures, up to heights of 100 m, have stood up well after blasting adjacent to the backfill.The fill material consists of a graded aggregate, Portland cement and ground slag. Sand has been occasionally mixed in the fill material to serve as avoid filler. The aggregate is prepared in a fill crushing plant, transported underground through raises, and hauled to the filling stopes by conveyors in No. 1 Mine and by trucks in No.2 Mine.Two mixing methods are currently in use. No. I Mine utilizes the free fall of gravity; the fill materials are sprayed with cement slurry as the aggregate departs from the conveyor into a mixing culvert. The other is the use of a rotary mixer on a batch basis in No. 2 Mine.This paper describes the fill systems, filling operation s, and the backfill quality control practice, together with various testing results related to improving fill quality as well as reducing fill costs.IntroductionThe Kidd Creek minesite, located 27 km north o f the city centre of Timmins, Ontario, produces 4.5 million tonnes of copper, zinc, lead, and silver ores annually from its No. 1 and No.2 underground mining operations. Both mines employ a sublevel blasthole stoping method."

Jan 1, 1983

By S. Usui, Y. Shinohara, C. Tokoro, K. Horiuchi, S. Owada

Process optimization of heating and physical separation for Cobalt (Co) recycling from spent lithium ion battery (LIB) was investigated. LiCoO2 in spent LIB was transformed to LixCoO2 which was more easily decomposed than LiCoO2 by heating. Coexisting materials of aluminum and carbon, and sealed atmosphere of the LIB promoted LixCoO2 decomposition. In an atmosphere of Argon, 95 % of LixCoO2 in the spent LIB was decomposed to 76 % of Co oxide and 19 % of Co metal in 10 min at 823 K; a lower temperature than the theoretical value for LiCoO2. The Co oxide and Co metal exhibited magnetic properties and could be recovered by wet magnetic separation. Furthermore, slow heating was effective for grain growth of Co oxide and Co metal. At 2 K/min rate of heating, average grain size of Co oxide and Co metal were 239 µm and 28 µm respectively, whereas at 30 K/min they were 190 µm and 15 µm respectively. Therefore, separation efficiency for Co recovery by wet magnetic separation was increased when spent LIB was slowly heated at 2 K/min.

Jan 1, 2015