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By V. I. Lakshmanan

Recycling helps to save energy and is good for the environment. It is also important for preserving the limited natural resources. In addition, recycling creates economic benefits and frees up space at the landfill sites. Process Research Ortech Inc. (PRO) has conducted extensive testwork in the area of waste processing and recycling. A process was developed for the recovery of Zinc from galvanized steel by alkaline leaching followed by solvent extraction and electrowinning. Extensive testwork has been conducted at PRO to obtain a useful by-product from rice husk. Rice husk was combusted in a gas/solid reactor to obtain an environmentally acceptable amorphous silica ash suitable for use in high strength concrete. In another development, vanadium was recovered from fly ash by separating carbon first, followed by alkaline pressure leaching, solvent extraction and precipitation. PRO has also developed an environment friendly process for treatment of industrial wastewater for its reuse to obtain zero or minimal effluent discharge. In this paper, four case studies related to recycling of zinc scrap, controlled combustion of rice husk, processing of fly ash, and reuse of waste water will be discussed.

Jan 1, 2011

By G. Harper

"AbstractThe Suetut. Copper deposit, 230 miles northwest of Prince George, B.C., was discovered in August of 1971. Subsequent exploration has included 56,417 feet of surface diamond drilling in 139 holes. The deposit occur in gently dipping volcanic rocks of the Upper Triassic Takla Group, which out crops as rugged mountains.The general Mesozoic sequence comprises some 20,000 feet of green and red basaltic to andesitic rocks. The Lower Formation is characterized by subaqueous basalt, andesite and augite porphyry flows with interbedded breccias. They were rapidly deposited in tectonic depressions of limited extent and steep gradients. Facies changes are abundant. The Middle Formation. consists of volcaniclastic rocks made up of fragments from the underlying formation. Two cycles are discernible , both with basal turbiditic, tuffaceous sandstone and shale units overlain by massive, volcanic conglomerates exhibiting graded and cross bedding. A broader, shallower-water basin is indicated. The top of the uppermost unit was subaerially deposited. The Upper Formation is a variable sequence of volcanic sedimentary rocks. Detritus was supplied from a wide source area and included multiple reworked fragments of the lower formations and material from other rock groups known in the region. Zeolite facies metamorphism is recognized throughout: the entire sequence. Epidote is particularly abundant in the Middle Formation, demonstrating the results of metasomatism.The mineralized zone is approximately concordant with the strata over 100-200 feet of the Middle Formation succession . It lies just below the zone of transition from subaqueous to subaerial deposition in the top unit. Hematite, chalcocite, pyrite, bornite, chalcopyrite and native copper are disseminated throughout all sizes of lithic fragments and matrix. Concentration into the specific zone is believed to be due to upward leaching of copper during lowgrade metamorphic and metasomatic reaction. Precipitation occurred in the zone of hydration characterized by prehnite-pumpellyite below the oxidized subaerial rocks."

Jan 1, 1977

By R. J. T. Charles

Introduction An apparatus that will measure the surface area of a few of the simple minerals with a high degree of accuracy has been described by J. W. Bell (1). His apparatus consisted essentially of a photometric device that would measure the turbidity of fine particle suspensions. Turbidity, in this case, was considered as a function of surface area. Bell's method of surface area determination seemed to offer possibilities of extension and improvement to the point where it might approach a general method of particle size measurement. Theoretical and Practical Considerations of the Photometric Method In order to illustrate how turbidity may be considered as a function of average particle size, and to indicate the type of results expected from a photometric method of particle size measurement involving turbidity, the following theory may be hypothecated. If a number of particles, considered as spheres of uniform diameter, are placed at random in the path of a beam of light, the following expression, which will give the change in light intensity as a function of the diameter of the particles, the specific gravity of the material, and the weight involved, can be formulated from the Beer-Lambert Law:

Jan 1, 1951

By E. B. Wilson

"Although the Operations Research technique of Reliability Theory has been applied with marked success in many fields, including the Apollo spaceship programs, the concept of reliability has not been generally adopted in mining and other heavy industries. Of course, reliability, or the probability that a system will be able to operate without a failure for a given interval of time, does not require the same emphasis in mining as in the aerospace industries. Nevertheless, certain aspects of Reliability Theory can be followed advantageously. For example, reliability calculations can determine the best time to overhaul and whether to retain stand-by units.The usefulness of the pseudo-operations research technique known as Replacement Theory is more readily re-cognized by the maintenance engineers in mining and other heavy industries. One of the least complex models enables the optimum Lifetime of an asset to be determined."

Jan 1, 1970

By B. Burke

Magnesium and its alloys are attractive materials for use in automotive and aerospace applications because of the low density and good mechanical properties. However, difficulty in forming magnesium and the limited number of available commercial alloys limit their use. The present paper reviews the efforts to improve the attractiveness of magnesium through non-traditional processing, and presents preliminary results of current work on producing magnesium alloys via powder metallurgy P/M. P/M can be used to alleviate the formability problem through near-net-shape processing, and also allows unique chemical compositions that can lead to new alloys with novel properties. The feasibility of producing magnesium powder metallurgy products utilizing the industrially dominant process of mixed powder blending, uniaxial die compaction and controlled atmosphere sintering was investigated. An alloy composition based on the commercial Mg alloy AZ31 (3% Al, 1% Zn) was used to facilitate comparison to similar wrought products. The optimal processing conditions (compaction pressure, sintering time and temperature, and quenching temperature) were found to maximize sintered density and mechanical properties.

Jan 1, 2007

By Ray Mason, Damien Label, Howard Bernier, Kevin McDermott, Kevin Coombs

"GeneralWabush Mines is an unincorporated joint venture of seven steel companies and Pickands Mather & Co. The mining and concentrating facilities are located in southwestern Labrador and the pelletizing and shiploading facilities are at Pointe Noire, 200 miles south, near the town of Sept-lies.The operation is based on a 5 ½ sq. mi. specular hematite deposit with a reserve of 375 million tons of concentrate. Annual production capacity is rated at 6 million tons of pellets per year. The final upgrading process utilizes high-tension separation of silica following wet autogenous grinding, spiral gravity separation and fluo-solids drying. The concentrate is railed in closed cars to Pointe Noire. The concentrate is reground dry and pelletized on Dravo Lurgi travelling grate machines to produce an oxide pellet with 65.5% Fe, 3.0% Si02, 1.95% Mn and 93.5% Tumble Index.HistoryPlant operations commenced in 1965 with a concentrator capacity of 5.3 million tons per year and a pelletizing capacity of 4.8 million tons per year. The original facilities for classifying the crude ore into fine and coarse fractions for storage purposes before reblending as autogenous mill feed were found to be unnecessary and were by-passed after plant startup. Capacity of the operation was increased to 6.0 million tons of pellets per year in 1968. This increased capacity required the installation of an additional160 cleaner spirals in the ore dressing plant, a new 5000 hp ball mill, three balling circuits and increased cooling air capacity in the pellet plant.In 1970, the regrind circuit in the pellet plant was converted to dry grinding and a significant reduction in grinding media consumption and maintenance costs was realized. A ninth grinding mill of 5000 hp capacity was installed to compensate for the reduced capacity in going from wet to dry grinding."

Jan 1, 2000

By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By Charles Kingsley

THE PRESIDENT (DR. C. B. KINGSTON, member C.l.M.M.) expressed regret that neither of the authors of the paper was able to be present to submit the paper in person. In their absence, it would be introduced formally from the Chair. It was a clear, straightforward account of a fine piece of shaft sinking, cleverly conceived and boldly executed. He referred briefly to the distribution and nature of the Dome ore-bodies and stated that, for both the miner and the metallurgist, the mine had provided a wide range of problems of unusual interest. Discussion on the paper was then invited. MR. THOMAS PRYOR said the paper was most opportune, because the subject of internal shafts did not appear to be fully treated in current mining literature. Many members were not familiar with Canadian gold deposits and it would be of interest if the authors could give a brief description of the location of the ere deposits of the Dome mine. This information would doubtless explain why a new internal shaft was needed in a position which required such an exceptionally long cross-cut to connect it to the main hoisting shaft to surface. It would also add to the value of the paper if the authors would give some idea of the duty expected of the new shaft in terms of tons of rock hoisted and of trips engaged in the transport of men and materials, and it would be helpful if figures could be given of the total capital cost of the hoists and subsidiary excavations at the shaft top, and of the cost per foot for sinking and lining the shaft below the collar. Turning to details of the paper, one was favourably impressed by the care given to the provision of a good travelling way for men in the main cross-cut, as shown in Figure 1. It was by no means always that one could walk in comfort and safety in a working where there was a 20-in. ventilating pipe in the roof.

Jan 1, 1939

By M. E. Charles

The use of water flowing as a lower layer to reduce pressure gradients in petroleum pipelines was investigated using 17.5 deg. A.P.I. Lloydminster crude oil in a 1-inch laboratory pipe-line and a 21h-inch field pipeline. The method was found to be very effective in reducing the pressure gradient below that for the oil flowing alone. The factor by which the pres-sure gradient was reduced varied with the percentage of water added, and in general exceeded 10 for water contents ranging from 40 to 60 per cent. Within this range of water content the pressure gradient reduction factor was independent of the oil flow rate.

Jan 1, 1960

By J. -F. Blais, M. -O. Simonnot, P. Charbonnier, J. Mocellin, Université de Lorraine INRA, G. Mercier

"Huge amounts of air pollution scrubber sludge have been generated during ferromanganese production using blast furnace. These residues have been historically deposited in ponds near steel making plants. They are very rich in zinc, manganese and lead (5 to 40 %) and also contain aluminum and iron. Considering the market value of these metals, brownfield sites can now be used as secondary resources. These ponds also have to be cleaned up to meet the environmental regulations.We have developed a hydrometallurgical process to recover Zn, Mn and Pb in order to produce valuable compounds of Mn and Zn and recover the final Pb residue by pyrometallurgy. The Zn and Mn compounds need to be pure enough to be economically valuable. Batch laboratory tests were carried out to determine suitable selective leaching conditions. The investigated operating conditions were acid concentration, pulp density and temperature. Optimal conditions to maximize zinc extraction (100 %) and manganese extraction (95.9 %) were found using sulfuric acid and sodium metabisulfide. The final residue contained 14.8 to 23.8 % of Pb. Then, Zn was recovered in the form of ZnO or ZnS by precipitation and Zn metal by electrowinning, while Mn was recovered as MnCO3 with a fairly acceptable concentration of impurities.INTRODUCTIONFerromanganese has been produced by pyrometallurgy in much of Western Europe for centuries. Use of wet scrubber to remove pollutant and dust particles from gas stream was common for most of these operations. Those residues contain high concentration of Zn, Mn and Pb. They have been left to decant in settling ponds installed close to the steel production plants. They now constitute heavily contaminated artificial soils. Those sludges are so contaminated with Zn, Mn and Pb that they can be used for metal production. Currently, no method is available to decontaminate these residues and recover Zn, Mn and Pb. Therefore, an approach considering these brownfield sites as secondary resource is in development. Doing so would achieve two goals, decontaminate the site and produce metals.. (Huot, Faure, Biache, Lorgeoux, Simonnot, & Morel, 2014a; Huot, Simonnot, Marion, Yvon, De Donato, & Morel, 2012; Huot, Simonnot, Watteau, Marion, Yvon, De Donato, & Morel, 2014b)."

Jan 1, 2016

By Marc C. Bétournay

A number of successful proof-of-concept projects have been carried out to replace conventional power application, such as diesel and rechargeable batteries, in underground mine vehicles. This has led to the development of the world?s first fuelcell production vehicle, a mine locomotive. A mine loader project has also started and several other projects are planned. These projects are providing the mining industry with the required information to make this technology shift possible. The application of fuelcell power will yield several important benefits such as the elimination of underground diesel emissions, significant reduction in the primary extraction?s sector greenhouse gas emissions and support for a more productive scenario. This article reviews these successes, discusses ongoing and potential projects and presents the technology application benefits that could be possible for mining operations.

May 1, 2003

By Courtney E. Cleveland

THE gold deposits of the Pioneer and Bralorne mines, in the Bridge River district of British Columbia, are closely associated with a long, narrow intrusive body of extremely variable composition, outcropping on the northeast side of Cadwallader creek and lying almost entirely within the property boundaries of the two companies. Other masses of the same type of intrusive rock are found in the district, more or less along the line of the main axis of the Pioneer-Bralorne in trusive, and have associated with them variable amounts of gold-quartz mineralization (Figure 1). The ore deposits of the district have been the subject of investigation by officers of the Geological Survey of Canada at various times during the past 25 years, and articles on the geology and mines of the district have been published by various individuals in technical journals. A list of the more important re-ports follows: SELECTED BIBLIOGRAPHY

Jan 1, 1938

By A. Zarei-Hanzaki, S. M. Fatemi-Varzaneh, M. Haghshenas

The microstructure in modified semi-solid ALTHIX (A356) alloy consists of aAl phase with Al/Si eutectic structure. Silicon phase in eutectic structure is coral like with fine fibers. The lack of good ductility in this alloy is related to the presence of silicon fibers. Accordingly many investigations have been recently conducted to modify the Si morphology through Thermomechanical processing on this alloy. In the present work an ALTHIX (A356) alloy was deformed at 450°C, 500°C and 540°C through different strain rates. Consequently the silicon fibers were broken into small particles. The results indicated that the Si particles may coarsen according to Ostwald ripening mechanism at 540°C deformed by rate of0.0005 sec-1 & 0.0001 sec-1-

Jan 1, 2006

By G. Kolosay, J. Rajala, G. Deschênes, A. Romanov

ABSTRACT: The Kupol project, located in Far East Russia, treats a high-grade, free-milling ore containing 25.5 g/t Au, 298.3 g/t Ag, and 0.5% pyrite,with a P70of 53 microns. Most of the gold occurs as elec-trum and the silver is predominantly present in the forms of acanthite, stephanite, pyrargyrite, andproustite. The mill reached the design throughput of 3,000 tpd six months after start-up. AKnelson con-centratorrecovers10.4% gold and 0.5% silver. Leaching (14.5 hours pre-treatment and 116 hours cyanidation)of gravity tailings is performed with the CANMET Enhanced Leach Process (CELP),using only 490 ppm NaCN (cyanide consumption of 1.1 kg/t). The precious metals are recovered by counter-current decantation and the Merrill-Crowe process. Calcium hypochlorite destroyscyanide and thiocyanate. Overall, gold and silver recoveries for 2008 were 95.4% and 85.6%,respectively (2.8% and7.5% higher than targets). In the first eight months of 2009, gold and silver recoveries were 95.0% and82.6%, respectively. By August 2009, the mill processed 1.42 million tons of ore with production of 1.1 million ounces of gold and 11.3 million ounces of silver. CELP performance was not affected by changes in feed grade and ore mineralogy. Additional modifications to the leaching strategy allowed further reduction in cyanide consumption and effluent treatment costs.

Jan 1, 2011

By M. R. Coffin

Since the plant startup in 1972, the leaching and jarosite precipitation circuits at the zinc plant of the Kidd Metallurgical Division have been reconfigured several times to improve overall performance, and/or to respond to market conditions. For the most part, the circuit changes have been driven by two market factors: the price of zinc and the price of silver. Until recently, circuit modifications undertaken to improve zinc extraction and recovery came at the expense of silver recovery, and vice versa. In 2004, the plant was modified once again to produce a precious metals-bearing residue, but additional leaching circuits were added to ensure that zinc extraction and recovery did not suffer as a consequence. The development of the zinc plant of the Kidd Metallurgical Division is updated in this paper, with a focus on the recent circuit modifications and associated control strategies that were implemented to maximize zinc and precious metals recoveries, and control the quality of the jarosite residue.

Jan 1, 2006

By J. D. Christian

WHEN mining development began in the Kirkland Lake camp, twenty-five years ago, there was very little information obtainable from surface showings as to the nature of the ore deposits. A length of almost a mile of the main 'break' lay under the south arm of the lake, and elsewhere most of the outcrops were covered with glacial drift. Shafts were sunk on ore-bodies of uncertain value, either on the outcrop of the veins or-because of the lake to the north-in the south or hanging-wall. In the second year of the camp's development, the Great War broke out and retarded progress for its duration. He would have been a real optimist who, in those early years, could have foreseen mining at depths of more than a mile.

Jan 1, 1939

By J. C. Gilbert

"IntroductionTHE PURPOSE of this paper is to discuss in a general way the heavy oil situation in Western Canada, and particularly to acquaint those in the oil industry who have not participated in the heavy oil end of the business with past and current developments. The author has covered •briefly the location of the heavy •and asphalt-base oil fields, their geology, current drilling and production practice, the location of the •refineries capable of handling heavy crude, their products and markets, and the problems and future prospects of the industry.Location and Description of FieldsThe term heavy oil is generally used to denote crude of 20.9° gravity and under. Since the products from heavy oil are also to a lesser extent obtained from asphalt-base crudes of higher gravity, some mention will be made here of the latter; but in general the emphasis of the paper is on heavy oil as such.In the order of their production to date, the heavy oil fields and those light oil fields which produce asphalt-base crudes are : Lloydminster, Taber, Vermilion, Conrad, Princess, and Wainwright.The Lloydminster oil field has not only produced most of the heavy oil, but also is currently the largest producer, supplying at the present time about 80 per cent of the heavy and asphalt-base crudes produced in Western Canada."

Jan 1, 1952

By Jesus Garcia Iglesias, Jorge Loredo

"Abstract -The Asturian fluorspar district consists of vein and stratiform deposits where mineralization is controlled by a combination of lithological and tectonic factors.It is postulated that these fluorspar deposits have been formed under disequilibrium conditions created during circulation of ascending hydrothermal solutions along faults and other high permeability conduits. Mixing of solutions is inferred from fluid inclusion studies. Cavity filling and replacement processes are very important in localizing the ore deposits and in determining their morphology.Permian volcanic rocks in the area yield a regional positive geochemical anomaly in fluorine implying that Permian vulcanism may be a possible primary source of fluorine.On a regional scale a relationship can be established between some of the ore deposits and important tectonic lineaments. The stratiform deposits preferentially occur within a calcareous-detrital facies located at the margins of basins. These basin margins are related to important synsedimentary faults.Fluorite is the only economic mineral in these deposits. Quartz, carbonates, barite and pyrite are common minerals accompanying fluorite. Other minerals that may occasionally be present as minor components are: marcasite, chalcopyrite, fahlore, sphalerite, galena and related supergene minerals."

Jan 1, 1994

By S. Esfahani, M. Barati

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, slags with different basicities were studied during non-isothermal cooling. Their continuous cooling transformation (CCT) diagram were plotted and compared with each other. Then, a mathematical model was developed that predicts the amount of crystallization during cooling. The results were validated by experiments performed by Single Hot Thermocouple Technique and image analysis. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow optimizing the slag/air ratio for both heat recovery and slag glass content.

Jan 1, 2015

By J. Y. Liu

In Comparison to the application of HPGR (high-pressure grinding rolls) in the cement industry and in iron ore processing, the introduction of this energy-efficient comminution technology to processing of nonferrous base-metal ores has progressed slowly as yet. In the field of minerals industry, challenges lies not only in the large variety of the feed material with respect to particle size, density, hardness, moisture and mineralogy of the material but also in complexity of the processing flowsheet, which need to be addressed from case to case based on result of HPGR comminution test work. Whereas conventional comminution test with HPGR in lab-scale or pilot scale needs quite a large amount of feed material, a compressive stressing test of particle-bed in piston-die device provides an effective way to study interparticle breakage behavior of ore material with much less feed. In the present study the effects of interparticle breakage on comminution of a copper ore has been investigated by compressive stressing of particle bed in a piston-die device. The feeds to the particle-bed stressing tests were four narrow size fractions in the size range of 0.3~3.35 mm and a broad size fraction of 0/3.35 mm. The pressures applied were in the range between 30 and 180 MPa. The results showed that the specific energy consumption increases linearly with the pressure; the product fineness increases also with the pressure, but the magnitude of this increase declines as the pressure goes up. Under the same stressing intensity, the product size distribution curve becomes steeper as the particle size decreases, so there is no self-similarity between product size distributions of different feed sizes. The suitability of a material-characterization model for interparticle breakage was verified for this ore. In addition, the effect of interparticle breakage on comminution of this ore with respect to its influence on the downstream flotation were analyzed in terms of size-metal distribution and mineral liberation.

Jan 1, 2016