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By Craig Faulkner

Discharge cones for large Semi Autogenous Grinding (SAG) and Autogenous Grinding (AG) mills are subjected to high wear as significant volumes of ground ore and slurry exit the mill. With the larger diameter mills of 32ft to 40ft in size becoming the norm, very high, concentrated wear is highlighting the limitations of conventional discharge cones and frequent changes are subsequently required. This paper outlines the advances made in the design of the Bullnose discharge cone. Superior wear materials to increase wear life over conventional rubber or chrome-moly steel discharge cones and the introduction of key design features to reduce reline times and improve fit and safety during installation, offer significant opportunities for the mill operator. Collated from multiple case studies, the wear data and reline history from 2004 to present clearly illustrate the way in which superior component longevity has reduced the frequency of relines over the life of the product to increase mill availability and effectively increase the tonnes milled in a period.

Jan 1, 2012

By M. E. Holter

"Five main lignite seams occur in the Tertiary Ravenscrag Formation in the Eastevan area, at depths of 100 feet or less. They are named, in ascending order: the Boundary, Estevan, Souris, Roche Percee and Short Creek seams. A total sequence of approximately 250 feet is represented by the coal beds and interstratified clays, silts and sands. Strata dip to the southeast at 25 feet per mile or less and trike northeast. Large areas underlain by coal seams at shallow depths are delineated. Reserve calculations are dependent on detailed information on seam thicknesses and feasible stripmining depths. The stratigraphically higher seams are thinner on the average than lower seams and this, together with the increase in elastic size fractions in higher strata, suggests a retreat of a Tertiary marine margin to the south during the closing depositional history of coal seams and associated strata."

Jan 1, 1972

By A. A. Iranzadeh

The performance of a tunnel boring machine (TBM) depends on the efficiency of the cutters, which can be influenced by geological conditions and rock mass properties. In this study, a three-dimensional numerical model, based on a discrete element method, was used to evaluate the effects of joint orientation and its spacing on the fragmentation process by a TBM cutter. Several models were constructed to study the effects of variable orientation; these models incorporated different spacing, variable spacing, different orientations on the fragmentation process, and different sections of the block model. Three parameters, consisting of induced tensile stress, induced shear stress and maximum displacement, were calculated. The stress in each section that forms chips was considered as critical stress; critical joint spacing and orientation in each section were determined. Results show that the critical orientation was in the range of 45 to 60º, where there was a possibility to achieve the maximum penetration rate. The critical joint spacing was 200 mm and, by increasing joint spacing, the value of critical stress decreased significantly. Furthermore, joint orientation could influence more than joint spacing in the rock cutting process.

Jan 1, 2009

By J. F. Boux

"The study of the total utilization of fly ash has involved all of the known technology in the processing of this waste material into useful products. In addition, a complete knowledge of all the possible uses of fly ash and its products in the market area was probably the most important factor in evaluating the theory and practical feasibility of the total utilization of fly ash from a single large supplyLaboratory tests carried out on the separation of fly ash into different fractions were shown to improve its value and utilization. Four main fractions were studied: a fine pozzolanic low-carbon fraction; a coarse fraction for light-weight aggregate production by pelletizing and sintering; a high-iron fraction; and a carbon-rich fraction. The term ""beneficiation"" here refers to a process of separating fly ash into more useful components.Laboratory and pilot sinter strand tests were employed to optimize the sintering capability and the quality of the heat-hardened pellets through a study of the agglomeration cycle in four principal heat zones, under controlled conditions of air flow, temperature and atmosphere, and including the controlled sizing of pellets.The suitability of the heat-hardened pellets as light-weight aggregate was evaluated in test batches of concrete, which were compared with concrete containing commercial lightweight aggregate of established quality.A study of beneficiated fly ash pozzolan as a partial cementitious binder component in normal and high-temperature cured concrete was reported in a paper at the re-cent Second International Fly Ash Symposium.Samples of raw and beneficiated Lakeview ash were compared with samples of other established high-quality fly ash pozzolans. The evaluation indicated the usefulness of beneficiated Lakeview ash as a pozzolan. Economic studies indicated that to accomplish the primary objective of total utilization of any single source of fly ash (in this case. fly ash from the Lakeview Generating Station, producing approximately 400,000 tons per year), a broad knowledge of the technology of various mineral processes was essential.The design of the fly ash processing plant had to be based on the disposal of all the raw fly ash produced by the generating station. This is contrary to the normal design of a processing plant in which raw materials are supplied and produced according to product demand. The design, therefore, had to be of such flexibility as to pro-duce as wide a variety of products as possible, and the ability to market them had to be well researched and understood."

Jan 1, 1970

By Q. Han

A modified cast-on method has been developed to reinforce aluminum castings with steel insert. Defect-free bond between the steel insert and the aluminum casting has been consistently obtained. Data obtained from a push-out experiment indicated that the bond strength was much higher than that obtained using the Al-Fin approach. This paper introduces this modified method in four sections: the coating of the steel pins, the cast-in method, microstructure characterization, and the bond strength. The section on the coating of the steel pins contains coating material selection, electro-plating technique for plating Cu and Ni on steel, and diffusion bonding of the coatings to the steel. The section on cast-in method deals with factors that affecting the quality of the metallurgical bond between the coated steel and the aluminum castings. The results of microstructure characteristics of the bonding are presented in the microstructure characterization section. A push-out experiment and the results obtained using this method is described in the section of bond strength/mechanical property.

Jan 1, 2015

By J. L. Feng, F. Zhang, S. K. Hu

"Cracking is one of the most serious damages in tunnel linings, which is often observed by in-situ inspection to tunnel engineering. It is difficult to better characterise for the deformations from continua to discontinua by the traditional continuum mechanics due to emerging of crack initiation, crack propagation, and coalescence, at several scales. In this paper, the process of failure that was from micro damage to macro crack in concrete tunnel linings under experimental load conditions, was quantitatively simulated by the combined finite-discrete element method (FDEM). Comparison of the simulating results with that obtained by the full-scale test of concrete lining under different loading conditions in the literature was respectively good agreed and shows that such FDEM technique is appropriate to model the continuousdiscontinuous problems. The present study indicates that the FDEM technique could be benefit to quantitatively evaluate the stability and damage level of tunnel lining system. INTRODUCTIONMost damage to tunnel linings is caused during the construction phase, which can emerge in a form of single macro cracks or even large-scale spalling. The cause of such damage is mostly the occurrence of, either impermissibly large contact stresses resulting from high thrust loads combined with production and installation tolerances in the segments resulting in a geometrical lack of fit (Maidl et al., 2012; Transportation Research Board, Basic Research and Emerging Technologies Related to Concrete Committee, 2006), or unallowable tensile/shear stresses appearing in the tunnel linings under complicated loading conditions (Ansell, 2010). Such a macro failure phenomenon may also be regarded to as a result of growth, coalescence, initiation of microcracks in tunnel linings due to the complicated loading action, and even potentially lead to an instability or collapse of the local or entire tunnel system. Much work has been devoted to investigate for the characters of micro and macro cracks, the influence factors of damage patterns, the settlement of a tunnel, the width, length and density of lining cracks, especially from classifiedly and qualitatively (Wang, 2010; Huang et al., 2013). However, the safety evaluation of tunnel is definitely required to not only inspect in situ, but further also quantify computing and analyzing for tunnel lining systems, so as to provide a global viewpoint of process of the tunnel deformation, which aims to help for subsequent decisions, e.g. controlling traffic flow or immediately repairing task. Additionally, the design of lining thickness and its structural analysis that is mostly determined by previous experience and similar construction examples is also needed to be improved."

Jan 1, 2015

By A. S. Baillie

THE subject of taxes appears to engage our attention altogether too lightly. At least it would seem that, notwithstanding the increase in the cost of government, and its concomitant increased taxation, little constructive work is being done with a view to solving the problem of increased taxes. I believe that the inattention of the public generally to the subject of increased taxation is due largely to the fact that shareholders are not advised of the amount of taxes paid by industry. Were companies to advise their shareholders the amount of monies paid or payable out of each year's earnings for taxes in one form or another, and were such amounts compared with the amounts available for distribution to shareholders, the effect would be a general demand for more equitable taxation methods. While I am not unmindful of the burdens and inequities in taxation confronting industry generally, I believe that the mining industry in this Province does not fully appreciate the burden represented by the costs of taxation. My reason for this belief is based partly upon1the fact that no serious effort has so far been made to devise some means By which the mining industry in British Columbia might protect itself against the ever-increasing burden of taxation. In addition to this fact the widely diverse nature of mining in British Columbia makes the accumulation of comparable data a problem which, so far as I can ascertain, has never been attempted in a manner which would be authoritative. It should not be necessary to cite the effects of this burden upon any one mining company or upon any branch of the mining industry, such as coal mining, placer mining, base-metal mining, or the precious-metal mines. In my opinion, the operation of our mines by large corporations is conducive to the payment of taxes with much less protest than would be the case were the taxes being taken out of the earnings of just a few partners or a very few shareholders. We appear to be too unmindful of the taxes, paid by mining companies, of a kind that are not so prominently brought to our attention as are the taxes which are calculated upon the taxable income of the company at the end of its fiscal year. British Columbian mining companies pay many other taxes besides those which are calculated upon taxable income. Among these are school taxes, property taxes, gasoline taxes, mineral taxes, coal royalty, to say nothing of fuel-oil tax, sales tax, and excise taxes.

Jan 1, 1935

By T. Prietl

Metallurgical vessel linings are multilayered, consisting of refractory bodies, insulation materials, joints, and additional space to control for thermal expansion. A unique biaxial hot testing press (BHTP) was installed at the RHI Refractories Technology Center Leoben, Austria to enable the three-dimensional behaviour of complex vessel lining segments to be investigated under simulated service conditions. Using the BHTP, the heat up and thermo-mechanical behaviour of magnesia chromite brick lining segments with and without mortar filled joints were examined. The results obtained during the initial heat up provided validation of CFD modelling of the lining system. In addition, after the heat up and under steady state conditions, the lining behaviour during deformation-controlled compression and relaxation was examined. These analyses generated important data regarding the stiffness, joint compressibility, and brick damage of the lining segments after cyclic loading and unloading as well as the benefits of using mortar joints in the lining. These investigations were performed in collaboration with the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals, University of Leoben, Austria. The BHTP has been operational since November 2004 and is providing information regarding the thermo-mechanical behaviour of different lining segments.

Jan 1, 2007

By F. Ajersch, M. Rigaud, M. Jallouli

"Le gonflement des boulettes d'hématite à été étudié à l'aide d'une méthode de mesure standard ISO ainsi qu'à l'aide d 'une méthode de mesure dilatométrique.La première méthode a servi à l'étude des boulettes haute silice (5% SiO2) dont l'indice de basicité (IB = CaO + MgO -i- SiO2 + Al2O3) a été ajustée soit à l'aide d'une addition de dolomie, soit à l'aide d'une addition de pierre à chaux, soit à l'aide d'une addition de ces deux composes. L'indice de basicité variait de 0.05 à 0.12. Les résultats de gonfle ment obtenus à 1000?C dans une atmosphère de 40 CO - 60 N2 ont permis de montrer qu’indépendamment de l'indice de basicité c'est la dolomie qui contribue le plus à diminuer le gonflement par rapport à la pierre à chaux. L'utilisation de l'indice de basicité comme critère de sélection des boulettes est discutée.La méthode dilatométrique a servi à l'étude du gonfle ment de deux types de boulettes préparées à partir de deux concentrés de fer et dont la teneur en silice a été fixée à 2.5% et 0 5%. Ces deux types de boulettes ont reçues les mêmes additions de liant en quantité et en nature. La détermination en continue du gonflement, à 950?C dans 40 CO - 60 N2, a permis d'une part de mieux cerner le niveau de réduction auquel correspond le maximum de gonflement et d'autre part de montrer que l’allure des courbes de gonflement est étroitement liée à la nature du liant. Une augmentation de la teneur en silice des concentres contribue à diminuer le gonflement des boulettes.Des essais de réduction de gonflement non isothermes ont été réalisés à des montées de température à 10 et 20?C/min. Les résultats indiquent que le gonflement déterminé dans les conditions non iso thermes est inferieur à celui obtenu lors des essais isothermes. On discute alors de la validité des essais standards de gonflement qui sont utilisés pour prédire le comportement des boulettes lors de leur réduction dans un haut fourneau."

Jan 1, 1983

By Peter A. Hacquebard

"The early history of the Geological Survey of Canada is closely connected with coal geology investigations in the Atlantic Provinces. In 1843, Sir William Logan, the first director of the Geological Survey, measured the 4441m thick shore section at Joggins in Nova Scotia. Detailed mapping of the coalfields were subsequently carried out by H. Fletcher during the latter part of the nineteenth and first part of the present century. During the 1920-1940 period, the stratigraphy of the carboniferous WIZS' established by WA. Bell, who later also became a diretor of the Survey. Bell's work WIZS' followed by coal geology investigations of A.A. Hayes, W.S. Dyer, EA. Goranson, G. W.H. Norman, J.E. Muller, T.B. Haites and P.A. Hacquebord.The activities and accomplishments of the Survey geologists during the past 150 years are presented in this paper.General Outline of Survey Activities in Coal Geology During the Past 150 YearsIn 1842, when the Geological Survey of Canada (GSC) was established, the industrialization of the major countries of Western Europe and North America was actively persued. The energy required for this industrialization was obtained from the only fossil fuel then available, namely coal. The measure of a country's major mineral wealth at that time was the availability of mineable resources of coal. Eastern Canada, where mining had been carried out since 1720, was known to be well endowed with valuable coal deposits. In the major fields of Nova Scotia (Fig. I) several large-scale operations had been started during the middle and latter part of the nineteenth century.The significance of coal, therefore, was well understood, and exploration surveys specifically oriented toward coal were carried out by the Geological Survey from its earliest beginning. The first report of a detailed geological description of the coal measures of eastern Canada was prepared in 1843 by Sir William Logan (1845), the founder and first director of the Geological Survey of Canada. This early work was continued and complemented in 1896 by H. fletcher (1906), who during the latter part of the nineteenth century and first part of the present century systematically mapped the coal-bearing regions of Nova Scotia, which he considered all to be of approximately the same age."

Jan 1, 1992

By Euler De Souza

"Underground operation ventilation energy requirements constitute a significant portion of mine energy consumption (40–50%) and total energy costs (25–40%). In general, mine ventilation systems are energy inefficient; the author has found several systems that operate at efficiencies below 65%. This paper presents how engineering design principles can improve the performance and efficiency of ventilation appliances, resulting in reduced power consumption and operating costs. Case studies demonstrate that, by retrofitting ventilation appliances using proper engineering concepts, systems will operate at efficiencies well above common operating efficiencies, resulting in a drastic reduction in costs and base electrical and energy loads.RÉSUMÉ Les besoins énergétiques nécessaires à l’aérage d’une exploitation souterraine représentent une part considérable de la consommation d’énergie d’une mine (de 40 à 50 %) ainsi que des coûts totaux liés à l’énergie (de 25 à 40 %). De manière générale, les systèmes d’aérage d’une mine sont loin d’être écoénergétiques ; l’auteur a trouvé plusieurs systèmes fonctionnant à des rendements inférieurs à 65 %. Cet article présente les principes de conception technique qui peuvent améliorer la performance et l’efficacité des systèmes d’aérage, entraînant une réduction de la consommation d’électricité et des coûts d’exploitation. Des études de cas montrent qu’en les rénovant à l’aide de concepts techniques adéquats, les systèmes d’aérage fonctionneront à des rendements bien supérieurs aux rendements habituels d’une exploitation. Ces rénovations donneront lieu à une réduction considérable des coûts ainsi que des charges électriques et énergétiques de base.INTRODUCTIONIncreasing electricity supply problems in North America have encouraged an industry-wide evaluation of energy consumption, resulting in a more urgent emphasis on energy-efficient design and operation for all energy-consuming systems. Electricity is the main mode of energy supply and the mining industry is affected by the increasing cost of this commodity (Natural Resources Canada, 2017). Ventilation systems normally operate 24 hours per day, 365 days per year, and account for 25–40% of the total energy costs and 40–50% of the electrical consumption of a mine operation (De Souza, 2013). Ventilation engineers are under ever-increasing pressure to reduce ventilation energy consumption and be cost effective."

Jan 1, 2018

By L. Li

Backfill is increasingly used in underground mines, as it can help reduce the environmental impact from mining operations. However, the primary objective of backfilling is to provide safe working space for miners, by improving ground stability conditions. As cement is often added to the backfill, a critical issue is the determination of the required backfill strength (cohesion) due to the binder. This value is usually obtained from a solution proposed by Mitchell and co-workers, in the early 1980?s, for stopes with an exposed backfill face. This paper presents a brief review of the Mitchell et al. solution, with some of its main limitations. Some of the recently developed solutions for backfill design are then summarized and discussed.

Aug 1, 2013

By A. van As, J. McGaughey, M. J. Mol, R. Tosen

Geotechnical monitoring is a key element of the successful management of a block cave mine. The interrelationships between production and various monitoring datasets are often not realized due to a lack of data integration and appropriate 3D visualization. Timely delivery of information to ensure best cave management practices is only possible with an integrated cave management system. At Rio Tinto, a state-of-the-art cave management system (CaveCAD) has been designed and developed in cooperation with Mira Geoscience to integrate and analyze vast datasets and report this as instructive information regarding the current \u201cstatus\u201d of the cave.

Jan 1, 2014

By B. D. Sparks, I. E. Puddington, F. W. Meadus

The continuous separation of bitumen from Athabasca tar sands, with a high clay content, has been demonstrated. Recoveries of 95 per cent or higher have been obtained. Further processing of this product, to produce an accept-able type of crude oil, would require less heat than currently used in the hot-water process. Also, by comparison, substantial savings in equipment and operating costs are indicated.

Jan 1, 1971

Train on Different Equipment - * Immersive?s interchangeable cabin controls technology - ?clip on & off? * Change Simulator from one machine to another in minutes * No technical expertise required to swap * Real, functioning, controls and displays are used to aid rapid learning Immersive has produced a range of Conversion Kits to suit most equipment. Modular design - Easy to convert from one machine model to another with a Conversion Kit. Caterpillar Models Trucks - 769D, 773D, 777D Trucks - 785B, 789B, 793B Trucks - 785C, 789C, 793C, 797 Excavator/Shovel - 5130, 5230 Front end loader ? 992, 994 Dozer ? D10, D11 Komatsu Models Trucks - HD325, 785-5, 985-5 Trucks - 730E, 830E, 930E Dozers - D375A-3, D475A-3 Shovel - PC8000 P&H Shovels - 4100A, 4100XPB, 4100BOSS Hitachi Shovels - EX2500, EX5500 O&K Shovel - RH200 Bell Articulated Truck - B40C

May 1, 2003

By N. Gharib, F. Hassani, P. Nekoovaght

"Novel rock breakage techniques are becoming more viable and attractive to industry. Microwave energy, as a thermal energy capable of inducing micro cracks through differential heating (therefore expansion) is a technology gaining considerable attention in mineral processing and ore comminution applications. Recently, the use of microwave radiation has been evaluated as a possible avenue for terrestrial and extra-terrestrial drilling applications as well as full face tunneling or rock breaking machines. As part of an overall research on use of microwave in rock breaking systems, the influence of microwave energy on the mechanical properties of common hard rock types as basalt has been investigated. The results revealed that microwave energy irradiation imposes micro and macro cracks to the surface of the rock being irradiated. In explosive free tunneling applications using TBM, jointed and cracked surface of rock eases the cutting process and increases penetration rate. The experimental setups have been simulated with the help of a multi-physics numerical modeling and the results have been compared with practical experiment. The wave propagation of microwave has been simulated and the distances where the power intensity is higher are identified. Experimental and simulation results underlined the potential impact of the use of microwave energy in underground or surface excavation applications such as mining and tunneling. This will also contribute economically when mine-to-mill operation is fully considered to improve the efficiency of rock crusher stages. INTRODUCTIONDuring hard rock breakage (i.e., separation of a piece of a rock from its parent deposit) in mining and civil applications, the performance of mechanical equipment such as tunnel boring machines (TBMs) is limited by high levels of bit wear and maintenance. Preweakening natural rock prior to breaking it by machine is one approach to lower bit wear and maintenance costs. Some preweakening methods apply heat directly or indirectly. For example, flame torch-assisted TBMs (Lauriello et al., 1974; Resource Technology, 1984) have been deemed economical in terms of equipment, but their feasibility is limited by high fuel consumption. Microwave energy could offer several advantages over the flame torch method: it does not produce emissions or increase fuel consumption (electricity source is available on the machine), and is easy to control (quick power on and off)."

Jan 1, 2015

By Nick Vayenas

This paper discusses the application of a commercially available state-of-the-art PC discrete-event simulation modeling software, called Promodel, for simulating a typical underground mine hoist system in the Sudbury mining region, in the province of Ontario in Canada. The reasons for using Promodel as a two-dimensional simulation development tool is its simplicity in use and its capabilities to provide enough flexibility to meet the modeling requirements of a mine hoist system. General information of a mine hoist system was collected for building the model. Example of the model?s output is also presented. The application of Promodel in underground mining offers a powerful, two-dimensional simulation environment in an affordable price for mining engineers to analyze and study operational problems. This hoist simulation model is an intuitive demonstration of the mine hoisting elements and the operational logic of the hoist, based on which optimization of the entire mine system materials flow can be considered as part of a mine cycle management feasibility study.

Oct 1, 2009

By Joanna LaForte

"IntroductionIn respect to The Human Dimension by M. Phyllis Bray, this author's impression is that research on long distance commuting (LDC) is long overdue. This type of mining is not new to many workers, especially those from areas such as the Maritimes, who have had to look for work away from their families for at least a decade. Perhaps to the industry the over-all set-up is new, but to workers who have faced mine shut-downs in their areas finding a job was the main objective and if the security of long-term employment was evident, then the families might join them later. This was the situation with which the writer' s family was faced.LDC LifestyleBeing the wife of an underground miner, the author has personally experienced this lifestyle for almost 10 years, and has never experienced accommodation in a company town. The first five years of marriage were spent in a small rural municipality within 50 miles of the worksite, but the town had industry separate from mining and was not affected by the mine shut-down.Since her LDC lifestyle began her family has been pretty much city-based, out-of-province commuters with two children and a third to arrive some years later. She therefore lived a fairly normal married life with a husband home daily. The author has experienced life with a husband who worked away for five-day stretches and then drove long distances to be home weekends or the portion of time left over from driving and fatigue. She has done the 3D-days in/l4-days out routine, and for approximately the past four years has been existing on a two-weeks in/two-weeks out ritual .The author does not agree that the ""bottom line is that mining families go where the jobs are"" . The miners go where the jobs are and the families fend for themselves with the assistance of the pay cheque making it home each pay period.Perhaps because there are many personal frustrations with this type of lifestyle, perceptions may be inaccurate. Having only dealt with underground operations, there may be gross differences between the pressures and demands of other forms of mining."

Jan 1, 1991

By Y. Héroux, A. Chagnon, M. M. Savard

"Résumé- Le gîte de Pb-Zn de Gays River s'accompagne d'anomalies des propriétés de la matière organique (MO) et des assemblages de minéraux d'argile (AMA). L'association entre la minéralisation, la distribution de la réflectance de la MO et des AMA suggère que ces traceurs peuvent servir à l'exploration des sulfures de métaux de base dans cette région.A l'emplacement du gîte, la réflectance varie considérablement (0,80% à 1,88%), pouvant même afficher une baisse avec l'enfouissement, ce qui est interprété comme une altération chimique de la MO. Les valeurs les plus élevées s'accompagnent localement de quelques textures en mosaïque et délimitent une anomalie thermique au centre sud de la région. Parmi les minéraux des argiles identifiés, l'illite et la chlorite sont terrigènes alors que la smectite, la kaolinite et la corrensite sont authigènes et, à l'instar de l'altération de la MO, résultent des nouveaux équilibres chimiques créés suite à la précipitation des sulfures.Abstract- The Gays River Pb-Zn ore deposit is associated with anomalies defined from the characters of the organic matter (OM) and from the clay minerals assemblages. The relationships be­ tween these anomalies and the mineralization at the mine suggest that these parameters can be used as new guides for the exploration for base-metal sulfides in this area.The vitrinite reflectance (RJ shows a wide range of values (0.8% to 1.88%) and exhibits an anomalous suppressive effect with depth of burial at the mine site, suggesting a chemical alteration of the OM. The highest R, values are associated with mosaic textures and outline a thermal anomaly at the south-center of the studied area. Among the identified clay minerals, illite and chlorite are terrigenous, whereas smectite, kaolinite and corrensite are authigenous and, like the alteration of the OM, are due to the new chemical equilibria resulting from the precipitation of the sulfides."

Jan 1, 1994

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012