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By G. B. Harris, C. W. White

Cyanide has been used for the recovery of gold since the mid 1800s, but several jurisdictions have already banned its use, and environmental pressures are increasing to finding an alternative. Gold also forms chloride complexes similar to those of cyanide, but the use of chloride has never achieved widespread acceptance. This paper describes a chloride-based flowsheet, wherein the key unit process is the recovery and recycle of chloride ion. It is shown that the chloride-based flowsheet is competitive economically with the conventional cyanide-based flowsheets, and that it has a number of other advantages, particularly environmentally.

Jan 1, 2011

By J. Mrozowski, R. Kurowski, A. Chmielarz, Z. Szolomicki

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.

Jan 1, 2014

By A. J. Monhemius

"This paper reviews the history of modern iron-control processes in hydrometallurgy. Attention is paid to processes developed in the electrolytic zinc industry for removal of iron from zinc sulfate leach liquors and the problems faced by the industry in the safe disposal of the iron residues produced by these processes. Past lessons learned are projected onto current efforts to develop hydrometallurgical processes for treatment of copper sulfide concentrates. It is argued that any attempt to create a “hydrometallurgical copper smelter” will fail, unless methods are developed that can recover iron in a form that can be directly used by the steel or pigment industries.RÉSUMÉ Cet article passe en revue l’histoire des procédés modernes de contrôle du fer en hydrométallurgie. Il accordera une attention particulière aux procédés développés dans l’industrie du zinc électrolytique pour l’élimination du fer dans les liqueurs lixiviantes de sulfate de zinc anhydre, ainsi qu’aux problèmes rencontrés par l’industrie en termes d’élimination sans danger des résidus ferreux générés par ces procédés. En projetant les leçons tirées du passé sur les efforts actuels, on pourra développer des procédés hydrométallurgiques pour le traitement de concentrés de sulfure de cuivre. Beaucoup prétendent que toute tentative de créer une « fonderie de cuivre hydrométallurgique » échouera à moins de développer des méthodes permettant de récupérer le fer sous une forme pouvant directement être utilisée par les industries sidérurgique ou des pigmentsINTRODUCTIONThis paper resulted from an invitation to the author from the CIM’s Historical Metallurgy Committee to give a presentation on the early developments of iron control in hydrometallurgy. This was to take the form of a plenary lecture at the 4th Symposium on Iron Control in Hydrometallurgy, which formed part of the 28th International Mineral Processing Congress, held in Quebec City in September 2016.I was naturally flattered that the invitation was to give the lecture at an IMPC, the prestigious conference series that has been held since the 1950s. That this particular IMPC was to include the 4th Symposium on Iron Control in Hydrometallurgy, a conference series held only every 10 years, made the invitation even more appealing and appropriate. This was because I had been co-chairman of the First Symposium on Iron Control, together with my erstwhile colleague, John Dutrizac, which was held 30 years ago in Toronto."

Jan 1, 2017

By J. C. Bothan

A program to provide technical in-formation on the use of fuels in pyro-metallurgical processes, from the Canadian fuel viewpoint, was initiated about five years ago by a Canadian Institute of Mining and Metallurgy liaison grou1> composed of members from the Coal Research Committee of the Coal Division and the Iron and Steel Committee of the Metallurgy Division. This paper is another of a series prepared for this program. Previous papers included a review of pyrometallurgical processes of Canadian interest, a survey of ferrous processes relevant to the development of an integrated steel industry in western Canada and a survey of the fuel requirements of the non-ferrous metals industry in Canada. It is widely recognized among per-sons familiar with the Canadian coal industry that, because of the large resources of coking coal in western Canada, the

Jan 1, 1963

By Jean Scott, G. A. Collins, G. W. Hodgson

WHILE it is well known that trace metals in crude •oils and distillates have been a matter of deep concern to refining engineers because of the damage done .by the metals to cracking catalysts and refractories (8, 5), the trace metals in crude oils may be of great benefit in correlation studies and in origin studies. During the geological processes in which the oil is formed from •animal and vegetable life, the hydrocarbons are subjected to a host of inter-related reactions, both physical and chemical. It has been well demonstrated that the lighter materials, certainly the short-chain paraffin hydrocarbons, are degradation products of the heavier molecules, and it might be concluded that for correlation studies it would be advisable to direct attention as much as possible not to the degradation products of the large molecules but to the large molecules themselves. Be this as it may, the methods at •hand to conduct the study are not particularly precise and, in the past, attention has centred on the simpler small molecules, as evidenced by the great mass of work involving distillation and chromatography with painstaking separation of the simpler 'front-end' hydrocarbons.

Jan 1, 1954

By C K. Bell, L. S. Collett

An AFMAG survey was flown in 1968 over the Upper Nelson River area, Manitoba. The flight direction was northwest-southeast and flight spacing was 2 miles. In the Cross Lake Subprovince, AFMAG showed that an isolated peridotite outcrop was part of a dike that extended over 80 miles. Diabase dikes are not always marked by an anomaly, but isolated cross-overs, when used in conjunction with geological and magnetic data, permit their extrapolation. Anomalies coincide with areas of sulphide mineralization. In the Flin Fion Subprovince, known and unknown northeast-trending faults are detected. The Berry Creek fault was extended south through Tramping lake, then under the Paleozoic cover. Conductors were detected at, or near, the axes of major synclines within Amisk and Snow Group sediments. Granitic terranes have low conductivity and, because they are characterized by smooth AFMAG profiles, they can be delimited. AF.MAG is being recognized as a geophysical method that can aid geological mapping and interpretation. Its most important contribution to the geologist will be in regions where out-crops are sparse.

Jan 1, 1971

By Vard H. Johnson

"In contrast with the well-publicized Pittsburgh coal, and the Everglades of Florida, most coal-forming swamps of Cretaceous time in western North America occupied relatively limited areas. They formed in areas of irregular subsidence, bounded by the changing levee systems of meandering streams. Coke quality is determined by the physical and chemical behaviour of the vitrain during thermal decomposition. Vitrain is at least in part a colloidal substance, originally containing large proportions of water; its formation and survival depend on maintaining a shallow cover of stagnant water up to the time of burial. Heat from swamp fires or subaerial dyhydration could destroy it or impair its quality. Observed patterns suggest that the metamorphism is almost entirely thermal, and that there is little relation to tectonic stresses, or loading. These coals had probably achieved essentially their present rank prior to deformation. Evidence of frictional heating along the thrust planes is minimal or absent. Normally, coal beds are aquifers. Oxygen carried into the subsurface becomes available and reacts with the vitrain to destroy its natural thermoplastic properties. The tolerance of oxygen without loss of thermoplasticity is inversely related to the volatile content. Significant lateral variations of coal thickness are common and sometimes occur in short distances. In deformed areas these thickness changes are more commonly due to differential tectonic stress rather than to original thicknesses of coal. Locally, coal is known to have flowed into cavities, or fractures. These principals are discussed in relation to coal deposits of western Alberta and eastern British Columbia."

Jan 1, 1972

By K. C. Grogan

"GeneralGIANT ORE is complex, with the gold values for the most part occurring in extremely close association with arsenopyrite, stibnite, jamesonite, and a wide group of antimonial minerals locally termed 'the grey minerals'. Pyrite is the most abundant of the sulphide minerals• and minor quantities of chalcopyrite, galena, and sphalerite also occur. Pyrrhotite has been found in some sections of the mine, but to date none of it has been nickeliferous. Native gold occurs in varying amounts throughout the ore bodies.In 1944, ore dressing investigations were commenced on diamond-drill core rejects and samples of surface outcrop ore. Results soon indicated that treatment to produce satisfactory recovery of the gold values would involve fine grinding to 80-85 per cent minus 200 mesh, recovery of free gold by jigs, followed by flotation, roasting of the flotation concentrate, and subsequent cyanidation of the calcine. Proceeding from this information, the flow-sheet was prepared, plant design worked out, equipment purchased, and construction of the treatment plant commenced in May, 1947.The crushing, grinding, and flotation units of the plant were rushed to completion and commenced operation on May 12th, l.948, at 225 tons of ore per day. This rate was maintained until January 27th, 1949, when the Allis-Chalmers roaster and cyanide plants were completed and commenced operation. During the period May 12th, 1948, to January 27th, 1949, gold recovered by amalgamation was the sole source of revenue. Flotation concentrate was stockpiled pending the completion of the Allis~Chalmers roaster and cyanide plants."

Jan 1, 1953

By P. H. Tolcher

Canada, as the Free World's largest mine producer of zinc and the third largest mine producer of lead, has a vital interest in the future growth in demand for these metals. This paper traces the development of lead and zinc consumption in the last two decades, both on a total-Free-World basis and by major market areas. How Canada, as a major mine producer, has shared in this growth is also indicated. In addition, future consumption for both metals in the current decade of the 1970's is fore-cast. The demand these projections will make on Free World mines, particularly on Canadian mines, is examined. Some of the opportunities and challenges the Canadian mining industry will likely face during this period are also dealt with.

Jan 1, 1971

By Dwayne D. Tannant

The Adra tunnel near Naramata BC experienced a fire in 2010 that burned timber sets within the tunnel and caused severe spalling of rock from the roof and tunnel walls. The nature of the damage is documented and efforts completed to rehabilitate and open a portion of this tunnel to the public are described. The use of shortcrete and rock bolts is a technically and economically superior support system to timber sets as well as being far more fire resistant.

Jun 1, 2012

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is con-?ned by tectonic shear zones between marble and metapelites, extending laterally into the marble astabular, pod or lenticular oreshoots (up to 50 m x 20 m x 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical pro?les across mineralized zones con?rm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the in-situ supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly in?uenced by seasonal ?uctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent ?ooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2~10-3.8 to 10-1.4) and oxygenated (fO2~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sul?des and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+was transportedinto karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Abstract-Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is confined by tectonic shear zones between marble and metapelites, extending laterally into the marble as tabular, pod or lenticular oreshoots (up to 50 m ?? 20 m ?? 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical profiles across mineralized zones confirm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the insitu supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly influenced by seasonal fluctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent flooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2 ~10-3.8 to 10-1.4) and oxygenated (fO2 ~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sulfides and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+ was transported into karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2 in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2 increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997

By J. K. Weglo, M. U. Savich

"The measurement and evaluation of the noise emanating from an ST4A scooptram in an underground stope under a simulated work cycle, and under three conditions of after-treatment systems is covered.These include scooptram without muffler or filler (bare engine), an in-line small filter, compared to a larger-filter, and the larger filter with an in-line muffler in series with fume diluter, which were tested under three engine operating conditions-IDLE, wide open throttle (W. 0. T.), and working condition. This is load, short haul and dump operation.The results showed an attenuation of the scooptram at work of 8 to 15 dBA, 16 cm from the exhaust pipe of the machine, to 4.8 dBA at the operator's ear. Recommendations are made to increase the attenuation at the operator 's ear by additional improvement in design of the fume diluter.IntroductionIn current mining operations, the diesel engine provides a safe, efficient and highly mobile source of power. In the major underground mine s in Canada the most common types of diesel equipment are load-haul-dump (LHD) machines and ore trucks. In general, there is a tendency to use high horsepower, diesel LHD machines in mines to achieve maximum productivity. The increased use of diesel-powered equipment in underground mines has shown no cause pressure levels were measured at the exhaust and outlet pipe. Also, while measuring the octave band and A-weighted sound pressure levels, the operator's position was also measured."

Jan 1, 1986

By Stefan Boshkov

THE ADVENT of mining at great depth has brought to the fore the question of stresses around mine openings. The many-pronged attack on this problem is certified by the accelerated appearance, in the mining literature, of articles on various topics related to this subject (1). Whereas it may be agreed that we, of the mining profession, have fallen woefully behind in research and the development of an understanding of this important facet of the general problem of mining, it must also be accepted that the analysis of the stresses in a mine structure is usually more complex than is the case in the majority of structures encountered and dealt with in civil engineering. Whereas homogeneity and isotropy are readily acceptable for most metals, such properties are but crudely approximated in rocks. Whereas the external loads on a structure in civil engineering may be readily determined, those on a mining structure are subject to ?conjecture. Whereas the limits of the structure may readily be defined in civil engineering, the boundaries of the mining structure are, in most cases, indeterminate, and subject to intelligent guesswork, at best.

Jan 1, 1956

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By Isabel C. B Rodrigues, Flávia D. Reis, Versiane A. Leão, Rosa M. F. Lima

Attention has been focused in recent decades upon the precipitation of metal sulphides from acid mine drainage (AMD) and pregnant leach solutions, due to the advantages of the sulphide precipitation process over traditional methods employing hydroxides. The aim of this work was thus to explore technologies for copper precipitation using either Na2S or biogenic sulphide. The recovery of copper sulphide was improved when the initial pH of the solution containing each metal was 4 or excess sulphide was employed. In such, a condition the removal efficiency was 99.9%, corresponding to a residual level of 0.1mg/L for copper in solution. Kinetic parameters for precipitation were determined from the particle size distributions using the method of moments, where the growth and nucleation rates, as well the agglomeration kernel, were calculated. The biogenic sulphide was a suitable alternative to sodium sulphide for copper removal as either sodium sulphide and biogenic sulphide can be utilized to precipitate such a metal allowing the effluent to be compliant with environmental legislation.

Jan 1, 2014

By F. R. Nogas

"Because of the elements of uncertainty and instabilitp associated with single-enterprise communities, there is increasing interest in the alternatives to developing additional new communities of this nature. Gulf Minerals Canada Limited has chosen a unique alternative means to accommodate employees at a new uranium mine/mill complex at Rabbit Lake in Northern Saskatchewan. Gulf has adopted a fly-in program which moves their staff from a 450-mile radius, in and out of the on-site facilities, on a 7-day rotation."

Jan 1, 1976

By G. M. Brownell

THE Falcon Lake stock is a small igneous mass, 2.6 square miles in area, which has intruded a belt of older lavas and metamorphosed sediments. It is well exposed and the entire area of its outcrop is taken up with surveyed mining claims, the claim lines forming a grid which makes ideal conditions for a detailed petrographical study of the unusual variations which are found in the composition of this unit (see Figure 1). The study of this mass, which has revealed features of both scientific and economic significance, began in the summer of 1939 when trainees in a Prospectors' Training Camp, a Do-minion-Provincial youth-training project under the writer's supervision, were, detailed to map rock outcrops on various mining claims. Microscopic study of rock specimens taken on a line across this stock were made during the following winter and proved to be of such interest that a special trip was made the following summer for the purpose of gathering more data, the results of which are presented here. Location The stock is close to the southeast corner of the province of Manitoba, about three miles from the Ontario boundary. It lies between Falcon and West Hawk lakes and less than a mile south of the Trans-Canada highway. It is easily accessible by motor car, as a branch road from the highway leads to the Sunbeam Kirkland gold mine, which is within the inner core of the stock. Previous Work This area was the first in the Province to receive attention from prospectors, who entered it from the adjacent Lake of the Woods district during the days of the mining boom in the 1890's. Small occurrences of gold, copper, molybdenum, and tungsten ores were found, but to date there has been no production from the district, except for small shipments of gold ore. The regional geology has been mapped by the Manitoba Department of Mines and Natural Resources, the Falcon Lake stock being shown and recorded as of "varying composition". The more detailed work involved in preparing the accompanying map has necessitated only minor changes in the outline as previously mapped.

Jan 1, 1941

By A. H. Ransom, M. E. Robb

The Salmita Gold Mine is located 240 air kilometres northea t of Yellowknife on the east shore of Matthews Lake. Salmita is one of several gold showings which are regionally associated with the steep easterly dipping contact zone between mafic, intermediate and fe lsic volcanics to the west and overlying finely laminated argillaceous sediments to the east. The volcanic assemblage forms a narrow 2 m to 7 m wide north to northwesterly trend ing Belt of Yellowknife Supergroup Archaen greenstone rocks. The contact zone exhibits exhalite character and the increased sulphide content provides a di stinct VLF-EM , IP/Resisti vi ty and/or magnetic signature. Gold occurs at or near this contact in three main settings: associated with si liceous vein-like structures; with finely disseminated sulphides within ericitic altered upper fe lsic tuffaceous unit ; or with quartz in narrow shear zones within the overlying sediment . The B-Vein is of the former type with free mi ll ing gold occurring within a highly sil iceous zone having an average widtn of 1.69 m. Alteration is intense within the immediately su rrounding host lithologies and includes the development of si lica, carbonate, sulphide, sericite and chlorite with minor graphite, epidote. tourmaline and scheelite. The mineable zone above the 4th level (-200 m) ha an average strike of 160 m and is divided into three south plunging ore shoots separated by the regional Salmita Shear Zone in the south and by a low-grade structural hiatus in the north. Production from the B-Vein commenced in August 1983 based on a diluted in situ ore reserve of 140,000 t grading 26.6 git Au . As of December 31, 1985, a total of 131 ,537 t grading 27.8 git Au have been mined at a ra.te of 160 t per day and a 96.4 percent recovery, to produce 3,522 ,000 g (113,227 ounces) of gold . Current (January I, 1986) reserves total 45,500 t grading 37 g/t Au down to the 10th level (-500 m) .

Jan 1, 1986

By J. R. Andrews, R. P. Young, J. M. Reyes-Montes

"Microseismic monitoring provides insight into the location and extent of rock-mass fracturing induced by cave mining, enabling interpretation of the cave profile and validation of predictive numerical models. Source location uncertainties can lead to misinterpretation of the inferred characteristics of the fracture network. One principal source of uncertainty is the velocity model used to invert the location algorithm. Large-scale 3D numerical models of modulus changes across a caved mass can represent such complexities in the location algorithms, allowing more accurate interpretation of the microseismic activity. A Northparkes mine case study applies this advanced approach to microseismic data interpretation.RÉSUMÉ Le suivi microsismique fournit des renseignements sur la localisation et l’étendue des fractures de la masse rocheuse induites par l’exploitation par blocs foudroyés; cela permet d’interpréter le profil de la chambre foudroyée et de valider les modèles prédictifs numériques. Les incertitudes quant à la localisation de la source peuvent conduire à des mésinterprétations des caractéristiques inférés du réseau de fractures. Une des principales sources d’incertitudes est le modèle de vitesse utilisé pour inverser l’algorithme de localisation. Des modèles numériques tridimensionnels à grande échelle des changements du module d’élasticité à travers une masse foudroyée peuvent représenter de telles complexités dans les algorithmes de localisation, permettant ainsi une interprétation plus juste de l’activité microsismique. Une étude de cas à la mine Northparkes applique cette approche avancée à l’interprétation des données de microsismicité."

Jan 1, 2016