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By Daniel Hodouin, Claude Bazin

"This paper examines the economic advantages of adapting the production grade and recovery targets of a flotation circuit as a function of metal prices. The study is periormed using a steady state simulator for a Cu-Zn differential flotation circuit operating under the following strategies of 1) Maintaining constant operating targets, 2) Maximizing individual circuit Net Smelter Return and 3) Maximizing the global Cu-Zn circuit efficiency. Results are compared to assess whether or not one of the strategies produces benefits significantly higher than the others. A discussion of the tools required to achieve such a kind of control completes the paper.Paper not Available at Time of Publication"

Jan 1, 1997

By J. Sadaki, G. Dodbiba, S. Murakami, T. Fujita, S. Matsuo, H. Ono, K. Okaya

Printed circuit boards (PCBs) from discarded personal computer (PC) and household appliances were crushed by mechanical crushing or water explosion to remove mounted parts. More parts were stripped from PCB for PC composed of epoxy resin than from PCB for household appliance composed of phenol resin. In an attempt to raise the copper grade of PCB by removing other components, a carbonization treatment was investigated. The crushed PCB without surface-mounted parts was carbonized under a nitrogen atmosphere at 1073K. After screening, the char was classified by size into oversized pieces, undersized pieces and powder. The copper foil and glass fiber pieces were liberated and collected in undersized fraction. The copper foil was liberated easily from glass fiber by stamping treatment. On the other hand, tantalum capacitors were collected from mounted parts. The tantalum-sintered bodies were separated from molded resins by heat treatment at 723 to 773K in air atmosphere and screening of 0.5mm. Silica was removed and 70% of tantalum grade was obtained after more than 823K heating and separation.

Jan 1, 2011

By Helge B. Wurst, Michael P. Cipold, Jan F. Bachmann, Claus C. Bachmann

"In washability, the objective is to establish the set of maximum possible separation performance criteria for a given mineral feed. The method of choice for this has been the conventional sink-float analysis. Time, cost and safety aspects of the sink-float method have prompted the search for a new approach for establishing separation performance criteria, especially as performance levels of separator plants can be maximized if reliable information based on an analysis of washability in conjunction with particle size distribution, elemental constituency becomes readily available. The new method to establish washability and associated performance information utilizes at least two measurement technologies concurrently: single energy x-ray transmission and image processing. For porous or very inhomogeneous materials the results can be refined further by using dual energy x-ray transmission and image processing. The value of the collected data increases considerably if the washability data were additionally available in time to be considered in the control of the process plant. The incorporation of an automated washability monitor gives near real-time data that would impinge positively on the profitability of the plant operation. The method was extensively tested with a range of sample with different densities, varying from 1 g/cm³ (coal) to 5 g/cm³ (iron ore).INTRODUCTIONWashability of minerals like coal and iron ore is expressed by a curve or graph showing the results of a series of float-and-sink tests. Several of these curves are drawn to illustrate different conditions or variables, usually on the same axes, thus presenting the information on one sheet of paper. Washability curves are essential not only for the design but also for the operation of preparation plants.In determining the washability analysis, particle density is the underlying feature of all washability curves. Conventionally, the particles are separated into density fractions by immersing them in fluids of a predetermined density followed by skimming of those particles that stay afloat. The particles remaining afloat thus have a density lower than that of the fluid they were subjected to. The particles that remained at the bottom of the fluid container thus had a higher density higher than that of the fluid. By progressively increasing, for example, the density of the fluid and immersing the remaining particles so as to be able to skim the next density fraction, the particles would be fractionated into density groups. The liquids used range from aqueous solutions to organic liquids to suspensions. Unfortunately the liquids used for this separation process are often toxic and expensive. It stands to reason that a new method of determining washability is sought."

Jan 1, 2016

By A. Taylor, E. Thorn Corthay, R. Storey

In response to requests from its stakeholders, the International Standards Organisation is engaged in development of an international standard for Energy Management Systems (EnMS) which will become "ISO 50001". This new standard will build on the successes of both the EN16001 EnMS standard that has been used by dozens of European companies, as well as the ANSI/MSE 2000:2008 EnMS standard that is currently being used in several pilot projects in the USA and Ontario. This paper provides an overview of the key points of the EnMS standards, and describes how they can be used to drive sustainable energy reductions in the metallurgy industry.

Jan 1, 2010

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016

By Donald V. Currie

"The Alberta and Northwest Chamber of Mines was founded in Edmonton, Alberta in 1935. The organization represented private sector mining explorers and developers in the province and north west Canada. The Chamber aided and abetted the establishment of the two territorial mining associations. Because of corporate human resource department creation by north of sixty mine operators, the Chamber refocused on Alberta and broadened its perspective to include activities beyond mining. In 1977 the name changed to the Alberta Chamber of resources. The slogan (in more modern terms vision, mandate, goal, etc) remains as Orderly Development of Canada's Resources.The sixty-three year reputation of the Chamber, built on volunteer rather than staff contribution, is the principal reason for any success. The key has truly been the reputation, not an image, as all activities have been solution oriented.This presentation provides insight into the structure and methodology applied by the organization, and reviews some of the successes and failures during the period 1985 to present. Examples discussed include:• Canada-Alberta Partnership on Minerals 1992-1995• Regional Upgrader Business Plan• National Oil Sands Task Force• Lakeland and Waterways Railway"

Jan 1, 1998

By S. k. Kim, H. B. Trinh, R. R. Srivastava

"Spent auto-catalyst is a promising secondary resource of platinum group metals (PGMs), which are being extensively used in automobiles catalytic converters to control the hazardous gaseous emissions (CO, NOx and hydrocarbons). Several pyro or hydrometallurgical routes has been employed to recover PGMs from such spent materials but there is no proper process for recovering the other constituents metals. Therefore, it causes the loss of other major constituents like, Al and Mg along with rare earth metal Ce. In the present study, we investigate the dissolution of Al and Mg using sodium hydroxide (NaOH) roasting followed by a sulfuric acid (H2SO4) leaching; thereby concentrating the PGMs and Ce in leached residues. The effect of roasting temperature, time and amount of NaOH were varied. Subsequently, the dissolution behavior of metals in H2SO4 as a function of acid concentration was investigated from the roasted samples. At an optimal condition for roasting at 600°C with 1:1 NaOH-to-catalyst ratio and 60 min duration, the maximum of Al and Mg were dissolved in 1 M H2SO4 solution at ambient temperature (~25°C). Thus obtained leached residues containing enriched PGMs and Ce content can be treated separately for the recovery of these high-value metals.INTRODUCTION Spent auto-catalyst has been considered as a potential resource for recovering the platinum group metals (PGMs) (Jha et al., 2013). The commonly used auto-catalyst is made of cordierite (2MgO.2Al2O3.5SiO2) in which the chloro complexes of PGMs are impregnated onto the surfaces of porous washcoat of alumina substrate (Aberasturi et al., 2011). The average concentration of PGMs in ore are 2-4 g/ton for Pt, 7-2 g/ton for Pd and 0.2-0.5 g/ton for Rh, whereas, an individual catalytic converter weighing about 1 - 2 kg contains on average 1.56 g Pt, 0.62 g Pd and 0.156 g Rh (Upadhyay et al., 2013). Moreover, recovery of PGMs from spent auto-catalyst offers other advantages like, simple process, low cost and less pollution, as compared to recovery from primary resources (Dong et al., 2015).Therefore, technologies to recover PGMs from spent auto-catalyst has become attractive in the recent past and their recycling contribution has been accounted for 35% Pt, 26% Pd and 36% Rh of the quantity consumed in the production of auto-catalysts (Johnson Matthey, 2016)."

Jan 1, 2017

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By Ernest A. Hodgson

A SERIOUS hazard which must be faced in some mines, though quite absent in others, is that of rockbursts. Bursts cannot be wholly avoided in such mines, but the hazard would largely disappear if they could be predicted. The problem of prediction resolves itself into that of measuring pressure in the mine and determining when that pressure nears a critical value. The geophysical approach to the problem lies in discovering some physical property of the rock, which varies with pressure, which can be measured for rock in place, and for which the indication of critical conditions is sufficiently definite and open scale. A physical property, suggested first in connection with earthquake pre-diction, is that of sub-audible snapping. It was argued that, as the pressure grows, the rock probably yields microscopically and that minute snapping occurs which is so faint as to be inaudible to the unaided ear. Experience has proved this to be the case. Following other earlier work begun early in 1939, experiments with this method were initiated at Lake Shore Mines in 1941, and equipment was slowly being developed in practice when, fortunately, it was found possible to by-pass this tedious development programme. Experiments with sub-audible snapping in mine rocks had been carried out by Dr. L. A. Obert of the U.S. Bureau of Mines and his associates over a period of about four years. An amplifier and a recorder were developed, each reasonably satisfactory in practice. Lake Shore Mines offers a tempting field for rockburst research. Dr. Obert was invited to test his equipment in this and other mines in Ontario and did so. As a result, he and the administrative personnel of the Bureau became interested in the Lake Shore experiments co the extent of most generously arranging for the manufacture of sets of their own designed equipment for use in this programme. The first three sets of recorders were ordered at once and were delivered in May, 1942. A second group of three sets, incorporating various improvements indicated by experience both in the United States and in Canada, reached Kirkland Lake in April, 1943. The pick-up devices, known as geophones, were made in the electronics laboratory at Lake Shore by Mr. Zack Gibbs, who has had charge of all the instrument development in this re-search.

Jan 1, 1943

The Beginning ! The status quo simply isn?t sustainable ! Our social license is at risk ! The bar keeps rising ? We must improve our performance, both operational and social ? We must improve stakeholder judgement of our industry by taking action collectively Implementing TSM " TSM Guiding Principles " Performance Indicators " Crisis communications " External Outreach " Tailings management " Energy management " Performance manuals, guides " Reporting " Communities of Interest Advisory Panel

May 1, 2004

By G. E. Norman, J. F. Jackson, A. L. Mckague

"The treatment of nickel-copper concentrate in the new smelter at Falconbridge Nickel Mines Limited, Falconbridge, Ontario, is described. The concentrate in a slurry form is partially roasted in a fluid-bed roaster and the calcine is smelted in an electric furnace. The roaster gases are treated in an acid plant. IntroductionSmelting began at Falconbridge in 1930 with the first blast furnace treating high-grade ore containing 2-3% nickel. In 1933, the Falconbridge concentrator was built and started producing a bulk sulphide concentrate containing 4% nickel. A sinter plant was built to agglomerate and partially roast this concentrate. The sinter was smelted in blast furnaces along with high. grade magnetic ore. Matte from the furnaces was treated in Pierce-Smith converters to produce shipping matte which was refined at the company's plant in Norway."

Jan 1, 1980

By D. Tao

Froth flotation is widely used in the coal industry to clean -28 mesh or -100 mesh fine coal. A successful recovery of particles by flotation depends on efficient particle-bubble collision and attachment with minimal subsequent particle detachment from bubble. Flotation is effective in a narrow size range outside which the flotation efficiency drops sharply. A fundamental analysis has shown that use of picobubbles can significantly improve the flotation recovery of particles by increasing the probability of collision and attachment and reducing the probability of detachment. A specially designed column with a picobubble generator has been developed for enhanced recovery of fine coal particles. Picobubbles were produced based on the hydrodynamic cavitation principle. Experimental results with one metallurgical coal and one steam coal have shown that the use of picobubbles in a 2" column flotation increased fine coal recovery by 10-30%, depending on the feed rate, collector dosage, and other flotation conditions. Picobubbles also acted as a secondary collector and reduced the collector dosage by one third to one half.

Jan 1, 2006

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009

By N. W. Bliss

"Bauxite has been the almost universal ore of aluminum for about 100 years, with most of the world's reserves oc¬curring in the developing countries. As a result of fiscal and political activities prompted in part by the energy crisis, the formation of the IBA combined with increasing freight and labour costs, these reserves are no longer as competitive or as secure as they once were. This has given fresh impetus to the development of processes for alumina production that utilize raw material other than bauxite. Canada has no bauxite and it is prudent to look for alter¬native raw materials within our own boundaries suitable for one of these processes.Of the three igneous rocks that have been used as a source of alumina, only anorthosite is considered as a potential source in Canada. The Al content would be extracted by a sinter process, which currently requires a raw material with a. minimum of 28% Al2O2. Thus, about 4 tons of anorthosite and 10 to 12 tons of limestone are needed to produce one ton of alumina. There are two petrologically distinct types of anorthosite, one containing the plagioclase andesine-labradorite and around 26% Al2O3, and the other containing upwards of 30% Al2O3, in by¬townite-anorthite; for our purposes they may be con¬sidered as low- and high-alumina anorthosite respectively. The high-alumina anorthosites are somewhat rare; the low-alumina anorthosites are much more common, partic¬ularly in Eastern Canada. Geologically speaking, there is no shortage of anorthosite in Canada. The reserves are im¬mense, although their low Al2O3 content coupled with con¬siderations of location, access and proximity to limestone could be constraints to their development. Fly ash from coal-fired thermal power stations and nepheline syenite can also be used in a sinter process, but neither is likely to be utilized in Canada in the immediate future.The H+ process utilizes an acid attack to leach Al from a raw material with at least 20% Al2O3. One of the best raw materials is kaolinite-bearing clay; not only is it high in Al, but most of it can be extracted. With the possible exception of the Whitemud clay in Saskatchewan, Canada is apparently deficient in clays with sufficient reserves to support an alumina plant utilizing the H+ process. Low-alumina clays with illite and montmorillonite may also prove to be a suitable raw material if advantageously sited with respect to industrial centers. The average shale con¬tains only 15% Al2O33, much of which may be contained in minerals, such as feldspar, not amenable to acid leaching. If shale is used as a source of alumina, it will be because it contains some other valuable commodity, such as oil or uranium, the extraction of which leaves the spent shale upgraded in extractable Al2O3 and lowers the over-all costs to a point where it is economic, Thus, rejects from coal washing plants are most commonly considered as a source of alumina; they are already mined, are available in large and ever increasing amounts, and may contain significant amounts of combustible material which upgrades the Al2O3, content of the resulting ash. Coal rejects from existing and developing coalfields in Alberta and British Columbia are a possible source of raw material, but present data indicate they may contain insufficient Al2O3."

Jan 1, 1976

By Erik C. Westman

Knowledge of the orientation and relative magnitude of in-situ stresses at the mine scale is important for safe and efficient production from an underground mine. With this knowledge, stope location and scheduling can be optimized. Passive seismic tomography was used for imaging horizontal stress distribution at the mine scale. Microseismic measurements from the Creighton mine were used as input for the tomography calculations. The double-difference tomography algorithm was used, which provides the most precise results. The results clearly show a low velocity zone in the previously mined areas bounded by two high-velocity lobes located adjacent to the mined openings at locations consistent with those expected due to the horizontal stresses at the mine. The overarching goal of the research is to provide a tool that can augment both numerical modeling results and underground geotechnical measurements to allow the mine operator to produce in the safest and most efficient manner possible.

Jun 1, 2012

By A. Haldar

The major problem encountered in the casting of hypereutectic Al-Si alloys is the stoppage of flow below the rigidity level of solid fraction. In this study, the flow stoppage mechanism was studied using three Al-Si alloys with 14%, 18% and 22% silicon. The horizontal foam patterns used were 12.50 mm (0.50 inch) wide with two section thicknesses 12.50 mm (0.50 inch) and 6.25 mm (0.25 inch) with a common sprue. The primary silicon distribution along the length of the casting was studied to determine the mechanism of flow stoppage. It was found that the surface of the flow tip of Al-14%Si alloy was smooth with a few undulations. As the silicon level increased, undulations at the flow tip increased. The number and size of undulations were maximum for the Al-22%Si alloy. Microstructural analysis using optical image analyzer revealed that the flow tip consisted mainly of eutectic silicon in the aluminum matrix and a few primary silicon crystals (PSC). The PSC were in the interlocked condition few centimeters behind the flow tip. It was also found that the gap between the flow tip and the PSC concentrated area increased with an increase in silicon level. Phase characterization was done with SEM-EDX to identify the precipitating phases.

Jan 1, 2007

By Shengwu Song, Xuemin Feng

Jinping I hydropower station is located in Sichuan Province in Southwest China. It is built on the Yalong River as a controlling cascade hydropower station in the middle and lower reaches, with power generation as its major function. Jinping I arch dam concerns many engineering issues and has attracted worldwide attentions due to its huge scale and unique settings. It is one of the most challenging projects in China with its 305 meters high arch dam and complex geological conditions for construction, including large-scale tectonic faults, intensively unloaded rock masses and geological asymmetry in its foundation. At present, the concrete arch dam construction has been completed and preliminarily impounded, most of the foundation treatments have been implemented, and four of six generator units had been put into operation in July 2014. In this paper, the analytical methods, design concepts, treatment measures and technical features of strengthening the geological defects in the dam foundation will be presented. Upon geological investigation into the dam foundation, a few large-scale weak discontinuities are observed. The rock masses in the left dam foundation are intensively unloaded, approximately to the horizontal depth of 150–300 m. These serious geological defects lead to a geological asymmetry on the left and right banks, and thus some major difficulties of dam construction are encountered. The influences of geological defects on the dam construction and safety are analyzed comprehensively, followed by the concepts and methods of treatment design. Based on this, the treatment methods of the weak rock masses and discontinuities are carefully determined by numerical analysis and scheme optimization, including the concrete cushion, concrete replacement grids, drainage system, anti-seepage curtains and consolidation grouting, which work together to enhance the strength and integrity of the dam foundation. Evaluations and calibrations through geo-mechanical model tests in combination with field monitoring results in early impoundment period show that the arch dam and its foundation are generally stable and function normally, which suggests that the research methods and treatment design schemes are reasonable and effective. The proposed treatment methods and concepts in the context are helpful for similar complex rock projects.

Jan 1, 2015

By O. Lashkari

Manipulation of pouring temperature is an efficient way to produce different microstructural features. In order to characterize the microstructure of rheocast billets due to different superheats of 615-695 °C, the parallel plate compression method was employed. Foundry 356 Al-Si alloy with different morphologies of primary a-Al particles were tested at different initial pressures of 4,8, 11,2 KPa, The resulted strain-time graphs were further treated mathematically to calculate viscosity of SSM billets. The interrelationships of viscosity, the microstructure and primary phase flow during compression are discussed, It is shown that the dendritic primary a-Al structure has the highest viscosity number which is almost three orders of magnitude greater than those for globular morphology, The current research have, for the first time, shown the validity and reliability of "parallel plate compression viscometry" method in characterizing microstructural evolution of Rheocast SSM billets.

Jan 1, 2005

By Alfred C. Lane

WE recently received from Professor A. C. Lane, Emeritus Professor of Geology and Mineralogy, Tufts College, Mass., and a Corresponding Member of this Institute, a very interesting account of some recent developments in radioactive methods of determining the age of minerals and, therefore, of the rocks in which they occur. It deals in particular with studies of the minerals of certain pegmatite dykes on the Huron claims and Bear claims in southeastern Manitoba, which, the results indicate, are among the oldest rocks of the earth's crust. The following article presents a non-mathematical summary of Professor Lane's paper . . It will be noted that he is anxious to obtain suitable samples of certain minerals and rocks for further age studies. We hope some o our members may be able to supply him with the material he needs. It may be well to explain briefly how the age determinations are made. Uranium is continually breaking down, or disintegrating in successive steps through radium, etc., to a final product which is lead (uranium-lead), and the rate at which this change takes place is known. Minerals containing uranium will therefore contain lead also, and the lead-uranium ratio mul-tiplied by a certain factor (approximately 7 ,600) will give the age of the mineral in millions of years. Thorium also disintegrates at a known rate to give lead (thorium-lead) as a final product, and the age of a mineral containing thorium can thus be calculated from the lead-thorium ratio. Thorium breaks down more slowly than uranium. In unit time, one gram of thorium produces about as much lead as 0.36 grams of uranium.-ED.

Jan 1, 1938

By W. Dietzel

Fracture mechanics based techniques are used to gain insight into the phenomenon of stress corrosion cracking (SCC) and to develop guidance for avoiding or controlling SCC. From constant extension rate experiments under rising load or rising displacement conditions the susceptibility of high strength steels, aluminum, magnesium and titanium alloys to SCC and hydrogen embrittlement can be assessed. Such tests on pre-cracked specimens are also well suited for studying the mechanisms leading to SCC by employing appropriate models for the degradation of metallic materials which take into account the uptake of atomic hydrogen from the corrosive environment. Measurements of crack growth resistance curves using the crack tip opening displacement as fracture parameter can be compared with simulated R-curves obtained from modeling of the mechanism of hydrogen embrittlement. The materials investigated are a high strength steel and a magnesium alloy both exposed to environmental conditions which fostered the uptake of hydrogen.

Jan 1, 2010