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By T Mahlangu

The leaching of gold in alkaline aqueous cyanide solutions may be reduced significantly by the passivation of the gold by a surface layer of polymeric aurocyanide. This passivation of the gold is typically countered by the presence of Pb(+2) species in solution, which may be present as an impurity in the solution, or specifically added for this purpose. The speciation and availability of Pb(+2) in typical cyanide leach solutions is illustrated as a function of pH, and the presence of S(-2), S(+6), Cu(+1) and Ag(+1) species. The probable role of the Pb(+2) species in efficient gold leaching is discussed.

Jan 1, 2007

By Restarick C. J & Stewart P S B, Kelsall D. P

Over a four-hour period of steady plant operation samples were taken at regular intervals from points within the grinding and flotation circuits. Size fractions of each composite sample were analysed for lead and zinc values and a comparison made of the behaviour of the lead, zinc and gangue minerals, size by size throughout the whole circuit. Analysis of the breakage behaviour using dynamic mathematical models gave the rates of breakage of each size fraction of each main component. Simulated grinding experiments showed that the main grinding circuit had sane reserve capacity. In the lead flotation circuit all lead values between 150 mesh (Tyler) and 5 microns had excellent flotation characteristics, and a major proportion had a high rate of flotation which was practically the same for all sizes. Increase in overall lead recovery would require improvement of the flotation behaviour of ultra-fine lead minerals. These were slow floating and were responsible for approximately half the lead losses in the final zinc concentrate and one third of the lead losses in the final tails.

Jan 1, 1980

The nickel refinery at Yabulu consumes an average of 118,000 kg/h of low pressure steam in stripping operations to-recover ammonia and carbon dioxide from product liquor and ore tailings streams. The steam used in the stripping operations is produced from the 25 MW power generation plant at the refinery. The back pressure on the non condensing steam turbines is maintained at 60 kPa.Studies have been carried out to determine the optimum amount of steam required to be generated for stripping operations. When steam production is increased, the product liquor flow from thewashing thickeners can be increased. This results in improved washing efficiency of the thickeners and therefore improves the plant nickel recovery. A computer thickener wash model was used to predict nickel recoveries at varying steam consumption rates.The studies have shown that in most plant situations, it is not economical to-generate more steam than that already available from existing power production.The studies also highlighted the necessity to use all steam generated from power production at all times to maintain maximum nickel recovery.

Jan 1, 1985

By Nolan D. P, Balales M

Over the last two years work has been undertaken within the Pasminco Metals - BHAS Zinc Plant to improve the efficiency and maintain the production capacity of the operation. The work has centred upon the installation of suitable process instrumentation to improve process control and the development of new unit operations to maintain control of the circuit water and sulphate balance. A key aspect of the new process instrumentation has been the development of an on-line analyser to monitor the total antimony concentration during zinc dust purification. As a result of changes made to the Zinc Plant in order to contain all effluent within the circuit, a problem developed with control of both the water and sulphate balance of the circuit. A new neutralisation plant to treat all cell house waste water so that it can be contained within the circuit has been developed and installed. In addition changes have been made to the existing circuit to control deliberately the circuit sulphate concentration by precipitation of sodium and potassium jarosite.

Jan 1, 1993

This paper explains why the valuation of mining assets is often a very different exercise from the valuation of the shares in the mining company which owns those assets. The fundamental reason for this is that mining assets, and the shares of the company which owns those assets have different risks. In order to properly value mining securities it is essential to: ò ensure all the different risks and other factors which impact on the value of the mining assets and the value of the shares are taken into account; and determine the extent to which the different risks and other factors are addressed in the value of the mining assets and the value of the shares so as to avoid double counting or not counting at all. If the alternative, but far from consensus, view is accepted that the correct valuation methodology to apply to shares in mining companies should be based on option pricing theory then conventional valuation practice of both mining assets and shares in mining companies will need to be fundamentally reassessed.

Jan 1, 1994

Production of refined zinc (99.95 per cent) at the minesite without increasing greenhouse gas emissions is considered. As an example, exploitation of the full reserve of the McArthur River orebody is proposed, using the existing concentrator, whilst introducing radically innovative smelting technology. Bulk flotation of all the sulphide minerals is followed by smelting in a melt circulation reactor with tonnage oxygen. By smelting the high-energy pyritic concentrate and reacting the evolved sulphur dioxide with near-mine dolomite, a large amount of electricity can be generated. This is enough to supply all the requirements for the smelter itself, an air separation plant and a facility for compressing and liquefying carbon dioxide. Carbon dioxide is disposed of off-shore for enhanced oil recovery or by other means. The reacted dolomite fixes sulphur as an inert and environmentally acceptable solid residue. Treatment by these means leads to virtually zero gas emission smelting. The paper concludes with a vision for the future in which expansion of zinc smelting capacity is seen to be definitely needed.

Jan 1, 1998

I wish that in addition to being a Pro- fessional Engineer I was also a communications expert. My principal task this morning, and yours after this meeting, is to convince a wide variety of individuals that steel industry slags are a high quality material that can be used for many purposes; and that their use can significantly alleviate some of the problems facing engineers, public officials, and the general public in our countries. By actual in- place performance over a long period of time steel industry blast furnace slags have proven that they are as good as the best natural aggregates, and better than some, for any type of construction or purpose for which natural aggregates are used. Steel furnace slags have many unique favorable characteristics and prop- erties when compared to other types of aggre- gate even though they cannot be used for all types of construction. We have the facts, all we have to do is present them to the right people in the proper manner.

Jan 1, 1979

Having successfully applied computer techniques to open pit mining applications, many software developers are now using their skills to tackle the much harder areas of underground mine design, planning and production.Dramatic improvements in the performance to price ratio of hardware (including high resolution graphics screens), a better understanding of the techniques of surface and solids modelling (and their subsequent display), moves towards standard user interfaces and advanced concepts of representing grade distribution in the ore body have all contributed to the recent increase in underground mining software activity.This paper details the general requirements of a workable underground mining software system, providing a minimum checklist of desirable features and emphasises the importance of ease of use, flexibility and intuitive feel. Some relevant trends in hardware, software and application techniques are highlighted and comments made on areas which require further development or are only available in a small number of packages.Finally, a comment is made on the role of computer models to provide a unifying medium for tying together all aspects of underground design, planning and production.

Jan 1, 1992

The most critical step in the development of any mining project is the completion of a feasibility study. The feasibility study has one primary goal; to demonstrate that the project is economically viable if it is designed, constructed and operated in accordance with the concepts set forth in the study. Starting from a mineral resource data base, the feasibility study will define the ore reserves, the mining methods, the mineral processing concepts and the scale of the project. The disciplined activity of developing a feasibility study leads the proponent to examine every aspect of the project, many of which might otherwise be ignored. All technical concepts will be established and the corporate philosophy with respect to organisational structure, social and environmental responsibility, infrastructure contributions and financing will be determined. All the major decisions about how the project will be developed are made during the feasibility study. The success of the project will then depend upon the assumptions and decisions in the feasibility study and the ability and empowerment of the development team.

Jan 1, 1997

Information obtained from a reconciliation system provides fundamental indicators to an operations performance and is often neglected as a key performance indicator when developing a business plan or mining schedule. The cycle of exploration, ore definition, mining and processing within a company is constantly scrutinised both internally and externally as to the safety, environmental and financial performance of these activities with the operators judged on their performance on a periodic basis. However, it is not unusual for the reconciliation process to be given scant attention until a serious issue (usually a shortfall) occurs, at which point short-term solutions may be implemented which only serve to compound the original problem. A robust reconciliation system takes time to develop and implement initially and must continue to evolve with time. The best systems are those where all the stakeholders in the ultimate outcome are involved in the design and accept responsibility for the validity of their component inputs. Output from the reconciliation process can be utilised to fine-tune all aspects of an operation once the underlying issues leading to a particular result are understood.

Jan 1, 2002

During 1979 the writer had the privilege of interviewing about 50 people with varying degrees of involvement in the industrial arena and all of them in one way and another, had a part to play in the huge and intricate saga of Australian employee relations. They fell into the following' categories Industrial Relations Officers/Managers Academics Politicians Union Officials Representatives of Employer Associations Senior Industrialists Commission Members (State and Federal) Sundry (Journalists, Government Officials). This paper seeks to give an account of their views on various aspects of industrial relations. The interviews conducted were all on a personal and confidential basis so it can be expected that sources will not be identified. Suffice it to say that this account represents, albeit in "potted" form, the opinions of some of the most experienced individuals in the country. It will be seen that in most of the vital areas there is a remarkable lack of consensus. It should be noted that this lack of consensus existed within each of the groups mentioned.

Jan 1, 1980

By B Tadesse, L G. Dyer, B Albijanic, M Jung

The presence of high concentrations of dissolved ions in groundwater, sea water or recycled water may alter the water structure, particle surface wettability and colloidal interactions between bubbles and particles and can have a significant effect on mineral flotation. While the impact of water quality on the flotation of precious and base metal minerals is well established, no relevant published study exists currently regarding the effect of water salinity on the flotation of rare earth bearing minerals. This paper attempts to quantify the effect of water quality variation on flotation recovery and grade of rare earth minerals and gain an understanding on which ions existing in saline water affect flotation behaviour. Specifically, it is aimed at investigating the effects of water quality on the flotation of monazite in the presence of cations such as Ca2+, Mg2+, K+, and Na+. Flotation tests, zeta potential measurements, and adsorption tests were performed to explain the flotation behaviour. It was found that monovalent ions such as Na+ and K+ have negative impact on rare earth minerals recovery and grade. The result of single mineral flotation tests showed that the floatability of monazite was significantly depressed in the presence of Ca2+ and Mg2+. The result of single mineral flotation test showed varying depression levels in the presence ions in the order of Ca2+ > Mg2+ > Na ~ K.

Aug 24, 2022

The effect of temperature, time and SO2 concentration in the atmosphate have been studied for a complex Pb-Zn concentrate, which contained four sulphides and some organic material, in order to determine optimum roasting conditions. Under static roasting conditions virtually complete sulphation was achieved after roasting at 650¦C.2 hours in 10% SO2 in air. Both zinc ferrite and zinc silicate were observed to form early in the roasting, but continued exposure to SO2 -containing gases caused decomposition of these as the roasting time increased. Water and acid solubilities of iron, silica, calcium, magnesium and aluminium in the calcine were determined, as a function of roasting time, temperature and atmosphere composition.

Jan 1, 1970

The adoption of new technologies is accompanied by risks that the stakeholders will wish to understand and minimise. The process of developing a dynamic simulation and the plant it will be used in provides a discipline and attention to detail that highlights and provides an opportunity to mitigate risks that will exist in a production environment. The simulations will enable investigation of what the outcome of process failures will be and the impact maintenance. Enumerating this information will enable designs to be optimised and operating and control strategies to be tested.The success of new technology is dependent on the operators and their understanding of it and the machines that use it. In this context dynamic simulations can provide training and experience without risk to personnel, equipment or production. This experience will include situations that would not be induced in a production plant for training purposes. This paper outlines a generic template for a dynamic simulation that can be used to evaluate the introduction of an emerging technology into an operating environment. It includes process flows and surge capacity, breakdown and maintenance, operator interactions and availability, push and pull production scheduling and system control.

Sep 26, 2011

The South Comet mine is an underground silver-lead-zinc mine located on the West Coast of Tasmania with an annual production in the order of 35 000 tonne per year. All ore mined is shipped to the Rosebery mill by road, a distance of 17 km.

Jan 1, 1993

The major coalfields of Australia are almost unique in the occurrence in some areas of CO partly or almost completely replacing CH4,t1e normal seam gas from metamorphism of coal due to time and depth of burial. This CO2 situation has some benefits but mostly it introduces particular safety problems result- ing from the high density of CO2 relative to air, magnifying problems of gas dilution in ventilation, and the greater affinity which coal has for CO2 than for CH4 increasing proneness to gas-dynamic phenomena. The occurrence of most CO2 seam gas can be directly related to igneous intrusion and to its associated pneumatolytic injections. Whilst intrusions locally increase the rank of coal by their contact metamorphic effect, normal coal metamorphism due to time and depth of burial continues after intrusion and injection together with the ongoing metamorph- ic production of CH . This new CH slowly displaces any CO to leave some present-day intruded coals with seam gas with reduced CO2 or even without any significant CO2 associat- ions. The seam gas maps of the Bowen and Sydney Basins and more detailed maps of specific areas exemplify these situations. Mining progress, plus more searching studies of igneous-coal relationships provide improved understanding of the factors involved.

Jan 1, 1986

By OÆNeil G. R

The gold adsorption capacity of ash-char and ion exchange resin Zerolit F.F. (I.P.) was evaluated by obtaining Freundlich isotherms in the presence of selected variables. It was found that the presence of Na , 2+, Ca 2+ cations and SO4 , CN , S Z, 0 2- Zn anions prompted adsorption of gold onto the char and reduced gold adsorption capacity of the resin. Temperature, particle size of adsorbent and pH of solution were found to influence the gold adsorption capacity of char and the resin. The most efficient desorbent for gold adsorbed on the ash char was S2 ions. Optimum sulphide concentrations were found in the region of 1% Na2S. Investigation into the concentration of gold from actual carbon contaminated gold residue dumps in Kalgoorlie area onto ion ex- change resin showed limited success in one case and not so in another. Maximum gold adsorption by the resin appeared when cyanidation and sulphidization treatments were carried out simultaneously in the presence of the resin.

Jan 1, 1979

By Ricketts N. J, Smith G. D J

A hydrometallurgical process was developed for recovery of copper from copper-lead matte formed as an intermediate product at the BHAS lead smelter at Port Pirie. A plant utilizing this process was commissioned in 1984. The leach step involves oxidation of the copper-lead matte in an oxygenated acidic chloride-sulphate leachant. The results of laboratory scale testwork from which the chemistry of leaching was deduced, are presented in this paper. The rate of recovery of copper to solution from copper-lead matte depends largely_on the availability of oxygen to the sulphide surface. The optimum leach temperature is approximately 85¦C. Free acid must be supplied according to the stoichiometry of the leach reaction: Cu1.91 S + PbS + 2.91 H2SO4 + 1.455 02 = 1.91 Cu2+ + 1.91 SOj- + PbSO4(s) + 2.91 H2O + S¦ The grind size of the matte is of minor significance. Chloride concentration in leachant should be at or above a minimum of 10.0 g/l. Chloride acts to complex cuprous ions formed during leaching.

Jan 1, 1987

By Onal G, Celik MS, Dogan MZ

Chromite tailings assaying 21.2 per cent Cr2O3 was upgraded to 48.7 per cent Cr2O3 at a recovery of 72.0 per cent using column flotation with a mixture of anionic collectors at pH 11. Electrokinetic methods were used to elucidate the mechanism of collector adsorption and correlate the findings with the optimum flotation conditions. Multivalent constituent ions such as Cr3+, A13+, Fe2+ and Mg2+ were found to adsorb on chromite surface and shift the zpc of chromite in the direction of oxide form of the mineral. The anionic collectors also imparted a negative charge to chromite in the entire pH region. The higher zeta potentials obtained upon adding the anionic collectors is ascribed to the adsorption of anionic surfactant onto the positively charged chromite surface. The positive sites are generated through formation of significant amount of hydroxy complexes of magnesium at pH 11. Complementary infrared data reveal the absence of a shift in the spectra indicating the possibility of physical adsorption in the system.

Jan 1, 1993

On the basis of investigations carried out, the author offered new technology, which allows utilising all titanium-contained waste with receiving of finished products: catalysts for utilisation of hydrogen sulfide gases, accompanying oil-extraction. This technology is presented in the paper. It is economically effective and ecologically clean.

Jan 1, 2003