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Computational models are very useful for studying many of the physical mechanisms which can cause sample bias. Within such models we can predict the trajectories of all individual particles and thereby make observations which are not possible for physical systems. Physical mechanisms highlighted include congestion at the cutter aperture, particles bouncing over the cutter aperture, air drag on fine particles, waves of material being bulldozed off the belt by the upstream side of the body of square cutters, and particles being thrown by the leading edges of cross-belt cutter blades. Having identified relevant physical mechanisms for an existing cutter, we can estimate the extent to which they are likely to result in unequal representation of portions of a stream of material and thereby estimate the maximum likely sample bias.

Mar 1, 2010

By A Woodley, G Keir

The mining industry faces concurrent pressures of reducing water use, energy consumption and greenhouse gas (GHG) emissions in coming years. However, the interactions between water and energy use, as well as GHG emissions have largely been neglected in modelling studies to date. In addition, investigations tend to focus on the unit operation scale, with little consideration of whole-of-site or regional scale effects.This paper presents an application of a hierarchical systems model (HSM) developed to represent water, energy and GHG emissions fluxes at scales ranging from the unit operation, to the site level, to the regional level. The model allows for the linkages between water use, energy use and GHG emissions to be examined in a flexible and intuitive way, so that mine sites can predict energy and emissions impacts of water use reduction schemes and vice versa. This paper examines whether this approach can also be applied to the regional scale with multiple mine sites.The model is used to conduct a case study of several coal mines in the Bowen Basin, Australia, to compare the utility of centralised and decentralised mine water treatment schemes. The case study takes into account geographical factors (such as water pumping distances and elevations), economic factors (such as capital and operating cost curves for desalination treatment plants) and regional factors (such as regionally varying climates and associated variance in mine water volumes and quality).The case study results indicate that treatment of saline mine water incurs a trade-off between water and energy use in all cases. However, significant cost differences between centralised and decentralised schemes can be observed in a simple economic analysis. Further research will examine the possibility for deriving model up-scaling algorithms to reduce computational requirements.CITATION:Keir, G and Woodley, A, 2013. Regional trade-offs between mine water and energy use - a water treatment case study, in Proceedings Water in Mining 2013 , pp 21-28 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

Investigations of the Mineragraphic Section; Commonwealth Scientific and Industrial Research Organisation, have included most of the known stannite-bearing ores in Australia, and have revealed several new occurrences of this relatively uncommon mineral. They provide information about its paragenesis, and its possible effect on tin recovery, that may be of general interest.Several of the investigations used in the preparation of this paper, were made in the first instance by pr. F. L. Stillwell or in collaboration with him.CASSITERITE-SULPHIDE ORES IN NORTH-WEST- TASMANIA Stannite is a minor component of most of the cassiterite sulphide ores of north-western Tasmania. These include the orebodies of Mount Bischoff, the Cleveland mine, Moina, the Stanley River district, Renison Bell, and the Heemskirk-Zeehan district, and form a well defined metallogenetic provence which is related to the Devonian granites of this part of Tasmania.In these ores mineralisation began. with deposition of cassiterite, a little wolfram, and quartz, topaz and tourmaline. With falling temperature, deposition of cassiterite ceased and arsenopy-rite, pyrite, and especially pyrrhotite, formed in abundance, tending to give massive sulphide ore. A little chalcopyrite; stannite, sphalerite and native bismuth accompanied the pyrrhotite. Deposition of quartz ceased after the pyrrhotite, was formed, and the later-formed nonsulphide gangue consists chiefly of carbonates and fluorite. With, the advent of the carbonates the pyrrhotite was altered to fine-gained intergrowths of marcasite and pyrite. Excess iron from the pyrrhotite entered the intergrown carbonate, or was precipitated as magnetite. Some solution of the cassiterite occurred at this stage, the tin being redeposited chiefly as stimnite replacement rims around the residual cassitellrite grains. Varying, but small, amounts of sphalerite, galena, tetrahedrite and silver minerals were depoSited at this stage, bringing the mineralisation to a...

Jan 1, 1951

By Coates D. F, Neil T. J, O&apos

A proper economic analysis of pit slope design must reflect the trade-off between the benefits and the increased risks of slope fail- ure inherent in steeper slope angles. However, no formal framework for a proper analysis existed to date. This paper describes the results of the past four years' effort in which a formal eco- nomic analysis framework was developed and tested through a case study. This framework, in essence, consists of the availability of tested procedures and com- puter programs. The procedures as well as the programs are divided into two broad functional categories; (1) the first category related to assessing the economic benefits and costs associated with various pit slope angles and (2) the second category that determines the overall financial impact which the assessed benefits and costs exert to the mine operator's overall economic stature.

Jan 1, 1977

The Mineragraphic Section of the Council for Scientific and Industrial Research has had occasion from time to time to examine rocks, ores and concentrates from the Yatukoula goldfield, Fiji. The results of the examinations have been supplied as Mineragraphic Reports and have been supplementary to various investigations carried out by the mining companies on ore treatment, or by visiting geologists on the nature of the rocks and lodes. The presence of tellurides was determined in 1935, though incorrectly as nagyagite. The general absence of lead, except in traces, was soon afterwards discovered, and it came to be recognised as the mines were opened up that the chief telluride minerals on the field were sylvanite and native tellurium. Specimens of the tellurides have been provided from time to time by E. G. Theodore, Managing Director of the Emperor Mines Ltd., and of the Loloma (Fiji) Gold Mines N.L., and further material was recently obtained, as the result of a visit to the field at the invitation of Mr. Theodore.The aim of this paper is to describe the occurrence of the tellurides in these specimens. The work has been carried out as part of the programme of research of the Mineragraphic Section.THE VATUKOULA GOLDFIELDThe Emperor, Loloma and Dolphin mines are situated at Vatukoula, six miles, south of Tavua, on the north coast...

Jan 1, 1949

By F Saloojee, F K. Crundwell

Refractory ores need to be pretreated prior to cyanide leaching for acceptable gold recovery. Pressure oxidation is one method of rendering the ores more suitable for cyanidation. The focus of this work is optimisation of autoclave configuration for pressure oxidation. An autoclave for the pressure oxidation of a feed containing pyrite and arsenopyrite was modelled, using the population balance framework. The autoclave model takes into account feed particle size, reaction kinetics and retention time. Mass balance calculations were incorporated into Cycad Process« software. This allowed for the investigation of different circuit configurations. The base case model consists of a single autoclave. The feed was then doubled and additional autoclaves were added to provide the same residence time as the base case. Four different configurations for the additional equipment were simulated. These were parallel, series, series with inter-stage thickening and parallel-series circuits. The options are compared in terms of extraction and productivity. The parallel circuit behaves similarly to the base case. The series and series-parallel circuits have higher recoveries and productivities than the base case. The series circuit with inter-stage thickening provides the highest extraction and productivity. This is because the thickening reduces the slurry volume and increases the residence time of the solids in the downstream autoclave.CITATION:Saloojee, F and Crundwell, F K, 2013. Optimisation of circuits for gold pressure oxidation, in Proceedings World Gold 2013 , pp 181-188 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By E K. Chiw, S-M Jung, S M. Masuka, ika

The world reserves of high-grade iron ore have depleted necessitating the need to utilise any existing natural iron ore deposits to meet the demands of the world’s expanding economy using hydrogen in the reduction process to curb CO2 emission. These low-grade ores include iron ores with high phosphorus content. The thermodynamic conditions in the blast furnace allow for the reduction of phosphorus that readily dissolves into the molten iron. Phosphorus in the gaseous state readily dissolves into the molten iron and therefore must be removed due to its negative influence on the mechanical properties of steel. The removal of phosphorus from molten iron is difficult causing the phosphorus to concentrate in metallic iron. The aim of this study is to provide basic knowledge on the phosphorus distribution after reduction using the CO-H2 and possibly provide the optimum conditions for phosphorus partitioning into slag, increasing the probability of its removal by magnetic separation. Total porosity, pore size distribution and surface area of the pellets used were measured using a mercury pressure porosimeter. The reduction was carried out using thermogravimetric analyses (TGA). The reduction rate increased with increasing H2 and was highest when 100 per cent H2 was used. Metal elements distribution in the reduced pellet was clarified using electron probe microanalysis (EPMA) and showed that phosphorus was distributed in the same areas as Ca. More phosphorus was concentrated in slag when 50 per cent CO–50 per cent H2 was used, increasing the probability of dephosphorization using magnetic separation. The concentration of phosphorus into slag was related to the rate of reduction. Further investigations into the reduction kinetics of this ore by CO-H2 is suggested to validate these findings. Nevertheless, a comprehensive thermodynamic analysis of the reduction of phosphorus containing phases found in iron ore with carbon, CO and H2 was provided to assist in selecting the optimal reduction experimental conditions.

Sep 18, 2023

Mineral exploration is the business of finding and defining ore deposits. Ore bodies are developed into mines and mines supply every mineral and metal upon which our society is built. Whether it be steel for our bridges, cement and aggregate for our concrete, coal for our power stations, copper for our wire, phosphate for our fertiliser or gold for our jewellery it first must he found, then mined and processed before we can use it. There is no other way.

Jan 1, 1993

By D S. Clarke, W M. Prebble

Potential waste rock products from the mining of epithermal deposits in the Hauraki Goldfield are characterised to facilitate their management. Hydrothermally altered andesites and their weathered near surface equivalents have been examined from the Golden Cross, Karangahake and Monawai gold deposits. These materials vary in both their clay content (smectite, illite, kaolinite and chlorite) and the degree of silicification resulting from alteration and weathering. The simulated degradation (slaking tests) of waste materials cannot be explained purely by consideration of clay content, siliciflcation, or the resultant variations in porosity.   Microstructure is considered to be essential in predicting the physical degradation of waste rock. The scanning electron microscope is an effective tool in such an investigation. Increasing alteration results in clay particles becoming more randomly orientated (matrix microstructure); this causes a reduction in the surface area of contacts between components resulting in increased potential for degradation. The extent of skeletal microstructure (commonly characteristic of weathering) is an important control on effective porosity and the long term potential for degradation. Management requirements for these materials include the minimisation of moisture content variations (with the prevention of initial drying being of primary importance) and the containment of sediments produced.

Jan 1, 1991

By Morley C

The Mount Charlotte gold mine is located 0.75 km east of the General Post Office in Hannan Street, Kalgoorlie WA and about 3.5 km north of the Fimiston Operations on the famous Golden Mile.Mechanised underground bulk-mining at Mount Charlotte has been in continuous operation since 1963. For the 30-year period ending December 1992, the mine produced 22 million tonnes (Mt) of ore for a recovery of 2.73 million ounces. During 1991/92, the mine produced 1.53 Mt of ore at a head grade of 3.15 gramshonne (g/t) for a recovery of 135 822 ounces.The principal ore source at Mount Charlotte has been the Charlotte Orebody which is now largely mined out. Since 1990, approximately 75 per cent of production has been sourced from the Reward Orebodies. The Charlotte Orebody was a relatively homogeneous quartz stockwork with simple geometry and average bulked grades in the range of 4.0 to 5.5 g/t. This is in contrast to the Reward Orebodies and the more recently defined Charlotte Deeps and Maritana Stockworks, which have complex grade distribution and geometry with lower average bulked grades (2 to 4 g/t). The lower grades are principally due to the decreased density and volume of stockwork venation and related vein halo alteration. Typically, these stockworks comprise a patchy mosaic of quartz veins and vein swarms, with irregular distribution and geometry within the quartz gabbro host rock.

Jan 1, 1993

By T Y. Dube

In this paper current net present value (NPV) based mine valuation techniques that take into account market and private risk are discussed and analysed. Potential pitfalls that arise from the application of a portfolio, market or commodity based risk metric to a mining project are identified. An alternative non-simulative framework for quantifying and factoring market and private risk in NPV calculations is proposed and then applied to a hypothetical case study in an attempt to overcome identified pitfalls. Mathematical proof that a static discounted cash flow (DCF) calculation can underestimate or overestimate mine NPV is presented, the conditions for each are outlined and the degree of underestimation defined.CITATION:Dube, T Y, 2012. How the use of market-based risk metrics can undervalue good mining projects and overvalue poor ones, in Proceedings Project Evaluation 2012 , pp 29-34 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 24, 2012

By U JSger

The Westerschelde tunnel will be the first permanent road link between the Dutch regions of South Beveland and South Flanders. Two tunnel tubes, each 6.6 km long, will be driven using the shield tunnelling method. The difficult ground conditions and a water pressure of up to 6.5 bar make great demands on the design. This paper describes the problems and their solutions.

Jan 1, 1999

By G Love, S Maher

In Victoria’s onshore Gippsland Basin, geology is driving brown coal developments, and geologists are key decision-makers. Prompted by volatile energy prices and the likelihood of a carbon constrained future, significant work has been carried out on the next generation of technologies to be applied to this giant resource. These include new-generation gasification technologies, coal conversion processes yielding products as diverse as diesel and fertiliser, drying technologies producing thermal and metallurgical coals and in situ conversion processes. However, coals aren’t coals, and brown coal available for new projects will have different quality parameters and mining economics from that currently mined.New projects are likely to be developed on coals with moisture contents averaging 60 per cent and corresponding low energy values. Whilst ash values will be low, averaging just 5 per cent (dry basis), this will at times approach 10 per cent, which is a level that would challenge the installed-generation technologies. Sulfur values will average 0.4 per cent (dry basis), but at times exceed 0.6 per cent, requiring technologies that address the potential for sulfur dioxide emissions. Whilst localised high levels of the fluxes iron (>1 per cent dry basis) and sodium (>0.3 per cent dry basis) would increase fouling of installed technologies, they may be suitable for selected next-generation technologies.Project viability for this next generation of technologies will be strongly influenced by mining cost, and geologists are playing a role in identifying higher-value coal. At its simplest, this is being achieved for open cut mines through regional, vertical strip ratio assessments, which are considered a first-order proxy for mining cost. Follow up assessments are incorporating mining and processing cost, coal quality penalties and product revenues. At a regional scale, it is informing the likely location and relative timing of future mine developments, as well as thinking around rehabilitation strategies, infrastructure and land-use planning.For deeper coal, factors like macro permeability, the ability to isolate seams from aquifers, groundwater chemistry, pressure temperature conditions, connection with groundwater recharge and in situ biota are being used as vectors to in situ coal conversion opportunities.Matching coal to the next generation of technologies has benefited from regional-scale geological studies of coal quality and mining economics, and has benefited from early engagement between geologists, technology developers and project proponents.CITATION:Maher, S and Love, G, 2014. Matching brown coal to the next generation of Latrobe Valley projects, in Proceedings Ninth International Mining Geology Conference 2014 , pp 77–84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

From the mid-1970s ZC Mines at Broken Hill had a policy to increase ore production rates at progressively lower head grades. In the mid-1980s the mine suffered crippling losses at a time of low metal prices. An important contributory factor was the inherent geological distribution of metal grades in the seven defined ore lenses. Grades are bimodal, and perhaps, trimodal, in each ore lens. There is a tonnage deficiency in the critical cut-off grade zone of 7-10% Pb+Zn. Lowering the cut-off grade introduced siliceous and pyrrhotitic material which resulted in significantly poorer metallurgical performance. This example shows that the mine geologist needs to know the grade distribution of the orebody and to convey clearly the downstream implications of changes in the head grade.

Jan 1, 1990

By G K. Robinson, M D. Sinnott

Three-dimensional granular flow models have been run to simulate three types of sample cutters: a cross-stream cutter, a vezin, and a cross-belt cutter. This type of modelling involves solving the equations of motion for large numbers of individual particles as they travel along a conveyor belt and interact with a sample cutter. It allows flows of bulk materials to be visualised and understood. Here we have used spherical particles. These results illustrate some advantages that modelling has compared to physical bias testing: By taking reference samples which are very close to the actual samples, the estimation of bias can be achieve quite precisely with very few runs. (Many Standards about bias testing recommend a minimum of 20 runs, but we have found that five runs generally provide adequate precision.) Potential bias can be divided into two components: the particles which are missed but should have been sampled and the particles which are extra but which should not have been sampled. This more detailed information can provide useful insight. Exactly the same material can be sampled using different sample cutters, thereby avoiding a source of variation that complicates physical testing. Much more detailed visualisation is possible, allowing better understanding of the bulk material flow in various circumstances.

Jan 1, 2005

By R Bunduwongse

The oil crisis had repercussions throughout the world and most importantly on mining, where the drive to reduce the use of liquid fossil fuel led directly to the appearance and subsequent growth in the design of mobile crushers in late 1970s early 1980s, which heralded a new era in both quarrying and mining. Even though mobile crushing has now become common, even preferred in the quarrying industry, this has not been the case in mining. This paper looks at why, in spite of the initial optimism, this technology has yet to gain full acceptance in the mining industry. The paper examines some of the problems that have been encountered in the past and offers suggestions as to how they can be avoided by applying the appropriate technology. It then takes a look at the successful application of the semi-mobile in-pit crushing system used by Italian Thai Development Company (ITD), on the Mae Moh Phase 5 contract and examines how the techniques used successfully there could be applied to the industry at large.

Jan 1, 2007

The Tom, East and West zone, stratiform Zn-Pb-Ag deposits at Macmillan Pass, Yukon, Canada were discovered by Hudson Bay Mining and Smelting Co Ltd prospectors in 1951. Further exploration, including two phases of underground exploration produced an HBM&S calculated reserve of 9.28 Mt of 7.5 per cent Pb, 6.2 per cent Zn and 69.4 g/T Ag for these zones. Cominco Ltd optioned the property in 1988. Deep, surface drilling extended the West and Southeast zones downward 200 - 300 m, indicating an additional potential resource of several million tonnes of good grade. The magnitude of the controlling syndepositional setting suggests that mineralisation continues to greater depth but with increased drilling and possibly mining costs. The 30 x 60 km Macmillan Fold belt trends WNW across the NW Selwyn Basin and Cordilleran trend. Within the fold belt, the Central Block - a complex, rift controlled basin of Devonian siliciclastics, hosts seven zones of Pb-Zn-Ag mineralisation clustered about four hydrothermal centres. The centres, distributed over 24 km, are coincident with small syndepositionally active structural sub-basins. The Tom deposits, in one such sub-basin, are localised by a third order structure consisting of two palaeobathymetric troughs flanking a syndepositional horst. This structure caused drastic facies and thickness changes over 600 metres of strata and focussed the venting of hydrothermal fluids through permeable conglomerates in the horst and its flanking growth faults. Mineral facies are zoned, with Pb-Ag contents rapidly diminishing outward from the vent resulting in restricted areas of high grade Pb-Zn-Ag-Ba ore within more extensive, sub-economic, Ba-Zn mineralisation. Widespread iron carbonate alteration of the footwall and high Si, B and Zn values in the hangingwall 'fingerprint' the deposit and along with the distinct facies variations provide aids to exploring the Tom and like deposits.

Jan 1, 1993

By F Clark, B Catto

The Mako domain comprises the Mako lodes at Sunrise Dam Gold Mine, Western Australia. This domain was initially bulk or æbucketÆ domained for the open pit resource in 2000, due to complexity in defining the lodes as a result of low drill density. Negative ore tonnage and positive grade and ounce reconciliations were experienced during mining of the domain in the mega-pit, though only small volumes of the domain were mined. Significant amounts of exploration and underground grade control drilling has been completed since the initial bulk domain interpretation and greater geological understanding of the mineralisation controls and geology of the lodes now exists. Mako provides approximately 50 per cent of the ore tonnes and ounces for the North Wall Cut-back, the latest open pit phase of mining at Sunrise Dam. The importance of Mako to mill supply and life-of-mine planning, as well as past reconciliation performance necessitated a reinterpretation of the domain to increase confidence for mining. Historic exploration drilling, underground grade control drilling and detailed pit-wall mapping were used to build mineralised subdomains within the confines of the original domain. These reflect more closely the spatial extents and geological controls on the mineralisation. A new resource model using the multiple indicator kriging (MIK) technique was generated using the new domains. It resulted in a decrease in tonnes and ounces but increase in grade for the sum total of the new domains compared to the old æbucketÆ domain. This is attributed to the increased selectivity and structural constraints imposed by the new domains. A retrospective comparison of the Mako grade control from the mega-pit versus the new resource model was conducted, which æreconciledÆ 103 per cent tonnes, 106 per cent grade and 110 per cent ounces. This has provided confidence that the new model is a better estimate of the lodes. Qualitatively, the new model is a better representation of the geology and extent of the mineralised structures with significant areas of change identifiable. Grade-tonnage plots comparing the 2006 and 2008 models show that most tonnes have been shed from the low-grade û subeconomic grade cut-offs. This is mostly attributable to the volume reduction of æoreÆ in the 2008 model compared to the 2006 model, where the true mineralised zones are captured by the new domains. The reinterpretation and remodelling of Mako is an example of an evolved domain model and shows that mineralised zones need to be differentiated adhering to the geology and geological controls on mineralisation, which are understood largely due to increased drilling density coupled with mapping.

Jan 1, 2009

By E L. Kotova

Completeness of extraction of a mineral from ore depends on many reasons. First of all it is a function of quality of disintegration of ore. It is supposed that two basic factors: character of structure and texture of the ore aggregate and a disintegration technique influence the quality of the mineral aggregate destruction, æopeningÆ of its internal boundaries. In this paper, the problem of technological mineralogy from the point of view of genesis of the mineral aggregate, its typomorphical features and methods of their quantitative description are discussed. The purpose of this research is to provide information for technologists. It should enable the development of a rational flexible scheme of disintegration of ore with full extraction of a useful component, without its losses and without unnecessary expenses of energy. For achievement of this purpose the mineralogical information should have ½number and a measure+. By the authors, the technique of the quantitative analysis of fabric of the mineral aggregate based on several models û thermodynamic, crystallographic and geometrical is offered and discussed. The leading role in the quantitative analysis of a fabric of ore belongs to internal bounders. But internal bounders of the mineral aggregate by bounders or faces of the mineral individuals or mineral grains are formed. Their geometry, orientation concerning own (mineral grain) crystallographic lattices, orientation and distribution in space of the ore aggregate are proportional to the energy accumulated at origin and the further growth. These characteristics of mineral individuals are consequences of conditions of their formation. That is why the named triad of models is used. From crystallography it is known that faces of different stability and mobility form borders of crystals. They also contain different quantity of energy. Mineral grains also are faceted by different energy borders. They form intergrowths with each other according to a principle of balance or unbalance. That is why in addition to traditional parameters of the description of a fabric of the mineral aggregate (mode and grainmetrical composition) it is necessary to add new. For example, length and the square of intergrowthing bounders of mineral individuals differentiated (in couples), crystallographic symbols of borders, their roughness and so forth. Consequently, solving a problem of the geometrical characteristic of borders, we define also its power characteristic. In this paper experience of application of our technology in studying ores of one of deposits of Urals Mountains is presented. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices, which are carrying out the analysis in a semi-automatic mode, are possessed. Structure and texture of rock or ore aggregate reflect its formation and transformation conditions. It is important to understand that disintegration energy cannot be more than aggregation energy, the energy of intergrowths formation. The square and orientation of mineral individuals borders vary at pressures or stresses of mineral aggregate evolution. These phenomena often cause selective increase in the square of borders at constant average grain size, ie the granulation. Granulation presents the increase in quantity of mineral individuals while their modal share remains constant. At the same time their average mineral grains size. Some mineral individuals increase in size at increased pressure. When lithostatic or lateral pressure drops the majority of mineral grains increases in volume at the cost of intersticial or film solutions or fine grains. These are only special examples of the ontogenesis of the mineral aggregate. They illustrate our statement that all changes in fabric of the mineral aggregate are a reaction on varying external (ie geological) conditions. It is possible to consider that structurisation of totality of mineral individuals as a whole is a process of adaptation of the mineral aggregate, which forms and exists in varying force and energy fields. Differential and integrated geometry of total internal boundaries of the mineral aggregate serves as adaptation mechanism of the mineral grains system. Boundaries form intergrowths of the mineral aggregate. Thus, it is possible to consider that the most informative parameters of the stereometric analysis for restoration of the ontogenesis of the mineral aggregate are the following. First of all, it is a quantitative estimation of the volumetric shape of the ore mineral in crystallographic coordinates, a total area of borders of all mineral grains in the aggregate, the specific square of their boundaries, the specific square of intergrowth boundaries of the ore mineral separately with grains of each minerals of the matrix of the mineral aggregate as well as traditional grainsmetric and modal composition. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices that are carrying out the analysis in a semi-automatic mode are possessed.

Jan 1, 2008

By A Gerson, S Miller, R Smart, J Thomas

Environmental Geochemistry International (EGi) and the Ian Wark Research Institute (IWRI) collaborated in a three-year Australian Minerals Industry Research Association (AMIRA) research project (Project Number P387A) focussed on the prediction and kinetic control of acid mine drainage. As part of this project, single addition, and sequential net acid generation (NAG) testing was carried out on sulfide mineral samples. The test samples comprised a range of synthetic waste materials prepared using a quartz bulk and controlled quantities of the commonly occurring sulfide minerals; pyrite (FeS2), pyrrhotite (Fe7S8), arsenopyrite (AsFeS), chalcopyrite (CuFeS2), chalcocite (Cu2S), covellite (CuS), bornite (Cu5FeS4), galena (PbS) and sphalerite (ZnS). NAG test results clearly show that there are significant differences between the acid forming potential of sulfide minerals. The NAG test results for each mineral were compared with theoretical acidity values (NAPP*). The NAPP* calculation was based on stoichiometric oxidation reactions assumed for each of the sulfide minerals. Sequential NAG values for pyrite corresponds closely to predicted NAPP* values, confirming the assumption that pyrite oxidation occurs according to the stoichiometry assumed. For the pyrite sample with 5 wt per cent S, two NAG stages were sufficient for all of the sulfur to be released to solution. Since sulfides in waste materials will generally be dominated by pyrite, results also confirm the validity of including NAG testing for ARD evaluation of most waste rock. NAG testing confirms that of the sulfide minerals examined, only pyrite, pyrrhotite, arsenopyrite and chalcopyrite are acid producing, ie able to produce leachate with a pH less than 4.5. In the case of sphalerite, galena, bornite, chalcocite and covellite the pH of the final NAG solution was greater than 4.5. The significant differences between the acid forming potential of different sulfide minerals could lead to overestimation of acid producing potentials based on NAPP values calculated from total per cent S alone, ie assuming all S is present as pyrite. The oxidation of galena during the NAG test resulted in the consumption of acid. The examination of the galena surface by X-ray photoelectron spectroscopy (XPS) after oxidation in peroxide solution indicated the presence of polysulfide. The reaction of sulfide to polysulfide is acid consuming, thus explaining the net acid consuming behaviour of galena in the NAG test. This reaction pathway may provide a possible explanation for the lower than expected acid production observed for some of the other sulfide minerals examined.

Jan 1, 2003