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By Waleska Campos Guaglianoni

With the growth of nanoscience and nanotechnology, the synthesis of nanostructured oxides has received a special attention. Metal oxides are widely used in the manufacture of microelectronic circuits, piezoelectric devices, fuel cells, catalysts, filters and bactericides systems. These metal oxides represent a large class of semiconductor materials suitable for photocatalytic processes. In recent years, new materials of this class such as TiO2 and ZnO have been developed due to their photo-catalytic abilities to degrade various environmental pollutants. This work aimed to evaluate the photocatalytic activity of zinc oxide previously synthesized by combustion synthesis in solution using citric acid as fuel and different reasons fuel/oxidant. After synthesis, the powders were subjected to heat treatments at different temperatures and photo-catalysis. The photocatalytic activity was evaluated by the degradation of a solution of methyl orange in a photochemical reactor of UV illumination, after which the transmittance of the samples measured with the assistance of a spectrophotometer. To analyze the results, a commercial zinc oxide was used as standard. The products of combustion synthesis in solution showed that photocatalytic activity varied according to the ratio fuel/oxidant and as a function of heat treatment. The results showed a higher photocatalytic activity for the products obtained with disabilities fuel in the reaction and heat treated.

Aug 8, 2018

By Nelson SOUTO, Nicolas LEGRAND, Sami ABDELKHALEK, Zafer KOONT

A work roll thermal crown model has been developed for a wide range of hot and cold rolling mill applications. The model is extremely fast, robust and accurate to determine the evolution of thermal crown all along the rolling campaigns. It has also ability to consider work roll shifting, multiple segmented cooling zones along the length and circumference of the roll as well as composite rolls properties (e.g. different thermal properties between mandrel and core of the roll). Moreover, the model includes simultaneously fast and slow temperature evolution calculations, respectively near roll surface (skin area) and at a certain distance below the roll surface (bulk area). This gives to thermal crown predictions a higher accuracy than conventional thermal crown models from literature that consider only the slow temperature evolution regime. An optimization procedure together with roll surface temperature and roll thermal profile measurements have been used to tune the model. The tuned model applied to hot rolling conditions has shown a significant influence of roll shifting and composite rolls properties on the prediction of roll temperature distribution and thermal crown during rolling. The tuned model applied to cold rolling conditions highlights the importance of mill operators practices to modify cooling distribution across roll barrel length with the segmented cooling zones to adjust the thermal crown and to get better strip shape control.

Oct 1, 2019

By Breno Totti Maia

Due to operational conditions and locations, BOF suffers variations in important parameters whose effects on the liquid bath are usually neglected. The present paper investigated two aspects: inner BOF pressure and oxygen temperature in the stagnant reservoir. The results have shown that oxygen temperature changes properties like density and velocity but has small influence on jet penetration. The BOF inner pressure has significant influence on jet penetration and creates a new challenge regarding nozzles dimensions considering overexpanding and underexpading jets.

Oct 30, 2017

By Giulio Rodrigues Altoé

The environmental concern is creating pressure for the substitution of high energy consumption materials for natural and sustainable ones. Compared to synthetic fibers, natural fibers have shown advantages in technical aspects such as flexibility and toughness. So there is a growing worldwide interest in the use of these fibers. PALF extracted from pineapple leaves, presents some significant characteristic, but until now only few studies on PALF were performed. This work aims to make the analysis of the tensile strength of polyester composites reinforced with PALF. The fibers were incorporated into the polyester matrix with volume fraction from 0 to 30%. After fracture the specimens were analyzed by a SEM (scanning electron microscope).

Aug 16, 2017

By Li Shanqing, Xu Jianghua, Li Hongmei, Huang Peijie

Cold rolled high strength steel are playing a very important role in reducing automobile weight for energy saving and environment protection. In recent year, more and more high strength steel were manufacturing in steel company. But there are some problems in the cold rolling process for high strength steel products. Periodic thickness deviation especially in strip head or tail is an important one in these problems. In this paper, the reason of periodic thickness deviation was analysed and a new AGC algorithm called Property FFC for high strength steel in tandem cold rolling was developed. The application of this new algorithm shows that it can reduce the thickness deviation.

Oct 1, 2019

By Márcia Maria da Silva Monteiro Pereira

Durante o lingotamento contínuo de aço, partículas de ZrO2 adicionadas na escória de molde facilitam a nucleação heterogênea de cristais devido à sua limitada solubilidade. A adição de ZrO2 promove a cristalização da fase cuspidina, o que auxilia na redução da transferência horizontal de calor no molde, amenizando desta forma o problema das trincas longitudinais. Outro benefício da adição de ZrO2 em pós fluxantes é reduzir a taxa de desgaste da válvula submersa (SEN) na interface metal/escória; a erosão da SEN é um problema sério. Através de testes de laboratório e de testes industriais concluiu-se que a adição de ZrO2 em pós fluxantes reduz a taxa de transferência de calor horizontal no molde durante o lingotamento contínuo de aço, considerando os dois tipos de pós fluxantes que foram analisados no presente trabalho. Além disso, observou-se que a adição de ZrO2 reduz a taxa de desgaste da válvula submersa na interface metal/escória.

Aug 16, 2017

By José Adilson de Castro

In this paper a new technology for a compact iron ore sintering machine is analyzed. The compact sintering process is based on the massive injection of gaseous fuels and the solid fuel is only agglomerated fine charcoal obtained by biomass. The solid fuel used in this study is obtained by agglomeration of fine charcoal produced from elephant glass which has very short period for production and CO2 capture(less than 6 months in tropical climate). To overcome the lower heat supply into the combustion front of the sintering process the simultaneous injection of oxygen and gaseous fuel is proposed. The proposed methodology is to combine the solid fuel (agglomerated fines charcoal) and steelworks gases in a compact machine to enhance heat and mass transfer with high productivity (about 5 times the conventional large machine). A multiphase mathematical model based on transport equations of momentum, energy and chemical species coupled with chemical reaction rates and phase transformations is used to analyze the inner process parameters. A base case representing a possible actual industrial operation of the sintering machine is used in order to compare different scenarios of practicable operations which represents advanced operations techniques. The model was used to predict six cases of combined operation with biomass and fuel gas utilization with oxygen support.

Aug 2, 2018

By Foluke Salgado de Assis

Natural fibers are attracting the interest of engineering sectors owing to specific advantages such as lightweight and lower cost as well as for their inherent condition of being renewable, biodegradable, recyclable and environmental correct material with respect to CO2 emission. The banana fiber is nowadays recognized by its mechanical properties. It is known that with the increase of fibers volume fraction the composite significant increases its tensile strength. This was obtained with amounts up to 30% in volume of banana fiber. However no higher volume of fibers was able to be molded in a composite plate until now. Thus the present work aims to study higher volumes of fiber in terms of the influence on the tensile strength of specimens prepared under 5 tons of pressure. The fibers were previously washed and dried in an oven at 60ºC, after that poured together with the epoxy resin and catalyst mixture in the metal molds bone-shaped, and pressured to ensure specimens quality. The tensile strength increased significantly with higher amounts of banana fiber incorporated in the epoxy matrix. This better performance can be directly related to the fracture obstacle imposed by the fibers as well as the type of cracks resulting from the fiber/matrix interaction.

Aug 16, 2017

By Carolina Gomes Dias Ribeiro

The modern composite materials, especially those reinforced with synthetic fibers such as glass and carbon, have been used since last century to attend the demands required by most technological fields, from home appliances to aerospace. Natural fibers composites with biodegradable polymer matrices are considered environmentally friendly materials and currently accepted as possible substitutes for synthetic composites. These green composites can be safely discarded or composted at the end of their life without harm to the environment. Another alternative for synthetic composites is to apply natural lignocellulosic fibers as reinforcement of conventional polymer matrices and already used in the automobile industry. In addition to the environmental and societal advantages of the green composites, the lignocellulosic fiber reinforced conventional polymer composite also has economical and technical advantages. In the case of a fiber collected as a waste, the price of the composite can be considerably lower than “fiberglass”. Furthermore, with high strength lignocellulosic fibers such as sisal, ramie and malva the specific strength of a composite may approach that of “fiberglass”. Therefore the objective of the present work is to investigate the mechanical behavior of polymer matrix composites reinforced with high volumes of natural malva fibers subjected to tensile stresses.

Aug 16, 2017

By Valdicleide Silva Mello

Nowadays the biodiesel use is obligate in Brazil, in order to reduce the emissions of fuel burn. However, it is important to analyze which percentage of biodiesel is necessary to keep or improve the lubricant action of fuel for diesel engine, as well which kind of biodiesel give better performance. Therefore, this work aims to analyze the parameters that keep the lubricant action of biofuels, by using the Box-Behnken design type to optimize them. In this design was evaluated the input parameters: the type of the biodiesel (soybean, sunflower and palm), the concentration (5%, 20% and 100%) and the temperature of contact (25°C, 40°C and 60°C). The analyzed output parameters were the percentage of film formation, coefficient of friction, wear scar diameter (WSD) of ball, these output parameters were obtained by HFRR tribometer and they were analyzed applying response surface methodology. With this methodology was possible to determine the simultaneous influence and the interactions between two or more independent variables investigated. The response surfaces generated for the coefficients of friction, WSD, film formation showed a higher lubricant action for higher levels of concentration of biodiesel. An increase in lubricant action was found to high and intermediate temperature.

Jul 31, 2018

By D. A. Aranda-Regino, C. Gómez-de-la-Garza, J. Ramírez-Cuellar, L. A. Leduc-Lezama

The Pickling Line Tandem Cold Mill (PLTCM) at Ternium’s Pesqueria plant with a 5 stands, 6 high configuration started in 2013. At the time of the start up the work roll specification and grinding practices were stablished following a low risk policy to be able to sustain any start-up associated accident. Once a stable operation has been achieved both these policies are being modified to improve productivity and reduce costs. The specified hardness of the rolls has been increased and efforts are being made to optimize the grinding according to the rolling campaign length and materials. The fatigue damage in work rolls, after rolling and its removal by grinding was followed by hardness measurements made at the end of the rolling campaign and after grinding. Softening of the rolls after rolling was found mainly in final stands to be related to the averaged stress experienced during the campaign, the original roll hardness was recovered after grinding. Hardness evolution was also followed after each grinding step finding that the total amount of grinding could be reduced. The grinding practice was modified accordingly for the first stands and the yield of work rolls in them has improved.

Oct 1, 2019

By Rafael Lopes

Os aços utilizados na fabricação do vergalhão CA50 conforme norma NBR7480 são usados em todo o Brasil. A grande aplicação deste tipo de produto é na indústria de construção civil em função de sua excelente resistência mecânica e soldabilidade. Estas características permitem o avanço na construção de grandes empreendimentos. Em 2009, a Votorantim Siderurgia na sua Unidade de Resende, iniciou a produção do vergalhão CA50 em escala, procurando aumentar a sua participação no mercado de construção civil. Foi identificada uma grande variação nos resultados de limite de escoamento nos ensaios de liberação de produto realizados a partir de amostras coletadas no início das bobinas de vergalhão CA50. Em função disso, foi feita a caracterização do limite de escoamento e microestrutura ao longo da bobina onde foi identificado que esta grande variação do limite de escoamento estava presente em toda a bobina. Desta forma, foram definidos os principais parâmetros do processo de laminação que poderiam estar influenciando na variação do limite de escoamento e realizado um planejamento de experimentos (DOE) para o vergalhão CA50 16,0mm, aço 1030, onde foram identificadas que a combinação da melhor distribuição da vazão de água nas Caixas d’água utilizadas no tratamento térmico de têmpera e auto revenido, somada à maior distribuição das espiras no pelo Formador e à ventilação do Stelmor no mínimo apresentaram resultados de limite de escoamento acima do mínimo especificado pela norma NBR 7480 com menor desvio padrão quando comparado aos parâmetros de processo que eram utilizados na produção do vergalhão CA50.

Oct 30, 2017

By Ernesto Gustavo Maffia

En la actualidad, el moldeo por inyección es una tecnología muy utilizada en el procesamiento del plástico pues permite fabricar formas geométricas complejas. Para fabricar los moldes se utiliza ampliamente la aleación C17200 (Cu-2%Be), pero están en desarrollo algunas alternativas con aleaciones base cobre libres de berilio, que tienen valores de dureza por encima de los 30 Rockwell C y buena conductividad. Las aleaciones base de cobre, tipo CuNiSiCr son las más adecuadas como reemplazo. El siguiente trabajo trata del estudio y desarrollo del proceso de fabricación, por fusión, colado y conformado, de una aleación tipo CuNiSiCr de alta dureza y buena conductividad para ser utilizada en la fabricación de moldes de inyección para la industria del plástico. Los resultados preliminares de esta investigación demuestran que a través del aumento sistemático en el contenido de níquel y silicio se consigue un aumento de la dureza (>32 Rockwell C) y una aceptable conductividad eléctrica (˜25%IACS). El fenómeno segregación interfiere fuertemente en los tratamientos termomecánicos, pues se forma una segunda fase interdendrítica, de características frágiles, que genera fracturas en el conformado. Los resultados demuestran que la aplicación del recocido total y control de la temperatura durante la forja minimizan este problema.

Aug 7, 2018

By Jan Lampke

Increasingly pelletizing discs are used for the recycling of dust and sludge. The applied pellet feed is highly variable, for example in terms of chemical composition, grain size distribution and raw density. These raw materials related factors lead to a destabilized pelletizing process, which initially must be homogenized through special mixtures, as well as the use of binders or additives. There are many possibilities to reach stringent restriction of material related target factors. On the one hand it is helpful to be flexible by changing the process parameters of the pelletizing disc. On the other hand, it is necessary to use a material-binder-formulation, which leads to a highly stable pelletizing process. The paper deals with an example of the use of agglomerating device, pelletizing disc, to prepare different dusts and sludges for material recycling. These dusts und sludges are mostly generated in metallurgical processes, e.g. sinterplant, blast furnace and steelworks.

Aug 16, 2017

By Armando Vazquez

This paper will provide an overall technology update on Tenova’s modular i BOF® technology package for improved endpoint detection (Carbon and Temperature), slop detection and auto-tapping control, with a primary focus will be on Tenova's Slop Detection System (SDS). Accurate Slopping prediction is a critical tool in the operation of a BOF. It provides the steelmaker with an additional protective system to increase yield & productivity while reducing operating costs. Tenova Goodfellow's i BOF® slop-detection technology uses lance vibration analysis with real-time alerts to give steel makers advance warning of the onset of a slop and a measurement of the slop severity. The system is designed to provide direct feedback control of lance position and oxygen flow rate, for rapid mitigation of potential slopping events. This paper will provide a summary on how the i BOF® technology package has been implemented, including trials and general results.

Jul 30, 2018

By Zou Zhongpping

Under the new normal state, blast furnace outputneeds to be adapted to the market demand, however the limitation in blast furnace output has significant impact on blast furnace operation and is prone to cause inactive furnace hearth and higher fuel ratio. To address such problems, some practices to maintain stable and smooth operation of blast furnace in case of output limitation are proposed based on data analysis philosophy, which allows the blast flow and hence the top pressure to be determined based on the hot metal output, and adequate kinetic energy of blast supply can be assured by adjusting the tuyeres. Matching between the oxygen enrichment and the pulverized coal injection is also proposed based on theoretical flametemperature, and burden distribution cycle calculation method is proposed, whichoffersnew approach for analyzing the change in burden distribution pattern.

Oct 30, 2017

By Sidiney Nascimento Silva

O trabalho descreve os principais resultados dos testes industriais realizados na Usina Presidente Vargas, CSN, Brasil, envolvendo a adição de um catalisador à mistura de carvões, em termos da qualidade do coque e do processo da coqueria. O catalisador em questão é o produto Thermact, que possui partículas nanométricas em sua composição, fornecido pela empresa Abhitech Energycon Limited, Índia. O catalisador foi dosado e adicionado à mistura de carvões via correia transportadora, na proporção, em peso, de 1kg de catalisador para 4.000kg da mistura de carvões. Os resultados dos testes realizados nas Baterias # 1, 4A, 4B e 5 com a adição de um catalisador à mistura de carvões, sinalizaram a viabilidade técnica e financeira da sua aplicação no processo da coqueria. Os principais benefícios decorrentes da adição do catalisador foram: i) aumento potencial da capacidade de produção de coque ao redor de 10% ou, alternativamente, melhoria da qualidade do coque - aumento de 1,4% do valor médio do índice de resistência mecânica a frio do coque, DI150/15, mantendo-se o tempo total padronizado do processo de coqueificação, visando à preservação das Baterias, ou ainda, a utilização de uma mistura de carvões de menor custo, sem prejuízos ao atendimento à especificação do coque para os Altos-Fornos; b) aumento da geração e redução do consumo de gás de coqueria, GCO; iii) aumento na produção de BTX (Benzeno, Tolueno, Xileno) e redução da produção de alcatrão na Planta de Carboquímicos; iv) limpeza do sistema “PROven”, “goosenecks”, tubos de ascensão e paredes dos fornos, sinalizando a sua viabilidade técnica e econômica.

Aug 1, 2018

By Christiano Gianesi Bastos Andrade

Clays with high content of smectite are denominated bentonites, and are widely used in industry as, for example, agents for bleaching of vegetable oils, animals and minerals. For this use, the smectite clays are treated with inorganic acid of high concentration at temperatures under boiling point, which provide the bentonite´s bleaching power. In the present study, a sample of smectite from Cubati, Paraiba, Brazil, was submitted to treatment under moderate conditions (90°C, reaction times of 1, 6, 12, 18 and 24hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5 M, acid solution/clay ratio of 1g/10mL), aiming to reduce impurities, responsible for the color of the clay, without causing significant changes in their structure. Thus, clay can be used in the cosmetics industry and other products with high added value. The treated clay was characterized by scanning electron microscopy (SEM), stereomicroscopy, energy dispersive X-ray detector (EDS) and X-ray diffraction (XRD). It was observed a bleaching in samples with time of 12h to 18h. With the DRX was possible to monitor the peak intensity of the clay structure and the sample with 12 hours of treatment was not significantly altered its crystalline structure, maintaining the peak clay at d001. The most pronounced changes in the bleaching occurred within the first 12 hours of acid treatment.

Aug 8, 2018

By Beatriz Pereda, Ana Clara Fonseca da Silva, Tiago Seixas Bittencourt

Reinforcing steel bars are usually specified based on mechanical properties with flexibility in chemical composition and processing. Most developments, in these steels, are normally focused on alloy and process design to reach minimum cost and conformity to specification. Processing routes using quenching and self-tempering (QST) and accelerated cooling are the most common. Microalloying with V and Nb have been used in rebar. When acicular constituents must be avoided, a combination of Nb microalloying with judicious control of cooling is one of the preferred options. Niobium can contribute to improvement in tensile properties through austenitic grain size control during hot working, precipitation hardening due to carbonitrides or clusters, and hardenability increase. In the present work the alloy design and development processes of a Nb microalloyed steel for rebars are presented. The designed steel has fulfilled the required specification and is under regular production. Austenitic grain size refining – when comparing with the “basic composition” normally used was observed, even without any change in the thermomechanical processing cycle. There are indications that precipitation hardening may also occur. Results indicate that Nb is a good alternative as a microalloying element in rebars.

Oct 1, 2019

By Horacio Destaillat

Desde hace aproximadamente 15 años se encontró por experiencia empírica que se puede “neutralizar” el efecto del plomo sobre la maleabilidad en caliente de cobre proveniente de la refinación térmica de chatarras mediante control de la composición química. Este hallazgo ha resultado de aplicación industrial. Si bien el contenido porcentual de plomo se reduce por refinación convencional y con cierta facilidad hasta 0,02 – 0,03 %, este valor es elevado [1] para laminar en caliente. Bajar el nivel de plomo hasta los valores exigibles por normas, requiere procedimientos especiales y costosos. La técnica cuyo mecanismo aquí se investiga, consiste en ajustar el contenido de plomo y estaño dentro de ciertas proporciones, ya que el balance de estos elementos, permite proceder sin problemas de fisuraciones a la colada y laminación en línea del cobre. Con el control de la composición química del sistema se logra que el plomo y el estaño se adhieran [2] sobre las partículas de eutéctico Cu-Cu2O. Esta disposición micro estructural en borde de grano explica la acción favorable del estaño en la maleabilidad. El procedimiento que aquí se describe no es aplicable a cualquier caso pues no funciona en materiales con contenido elevado de oxígeno (“Tough pitch”) ni en cobres desoxidados. Solamente lo hace en formas de baja sección que hayan sufrido enfriamiento rápido.

Aug 7, 2018