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By J. D. T. Steyl, C. A. Biley

"The chemistry of electrolyte systems containing iron remains generally poorly understood despite their prevalence in many natural and industrial processes, particularly in hydrometallurgy. These systems are typically challenging to study and model due to their affinity for complex formation and precipitation even at low pH. Recent developments in the hydrometallurgical processing of nickel laterites at Anglo American have called for a deeper understanding of the fundamental chemistry of the Fe2(SO4)3–FeSO4–H2SO4–H2O system. This paper details the development of an internally consistent, Pitzer ion-interaction model of this system, with explicit recognition of important contact ion pairs (CIPs). The primary application of this model is a thermodynamic framework for the interpretation of kinetic processes occurring during iron(III) reduction with SO2. Adopting a rigorous thermodynamic basis for the system chemistry facilitates the formulation of simple rate expressions that are capable of inherently capturing complex effects. While the iron(III) reduction case study remains the focus of this work, the developments have more universal applications and the thermodynamic speciation model can be extended into other systems containing acidic ferric sulfate.INTRODUCTIONIron is present in nearly all hydrometallurgical refining circuits typically as both a necessary and unwanted impurity and needs to be removed and disposed in a safe and efficient manner. This is generally performed by precipitation to form a range of solids such as hematite, goethite or jarosite. Numerous studies in the open literature have focussed on the removal of iron from refractory gold sulfide ore (Berezowsky & Weir, 1989; Berezowsky et al., 1991) and zinc pressure leaching (Buban, 1999; Ismael, 2003), and PGM matte sulfide circuits (Dutrizac & Monhemius, 1986). Moreover, since ferric iron is a strong oxidizing agent, it has been used extensively as a leaching agent for sulfide minerals (Dreisinger, 2006). Given the outlook of challenging economic conditions, declining ore grades and increasing levels of impurities, effective iron management is going to become increasingly critical to all hydrometallurgical processes.Against this background, and considering the widespread importance of acidic iron sulfate systems throughout natural and industrial processes, it is unexpected that the knowledge of the fundamental solution chemistry of these systems contains such significant gaps, particularly at the conditions typically found in hydrometallurgical applications. Existing literature describing the measurement and modelling of solution speciation in these systems have highlighted their significant chemical complexity (Magini & Caminiti, 1977; Magini, 1979; Lee & Tavlarides, 1985; Stipp, 1990; Papangelakis et al., 1994; Gil et al., 1995; Majzlan & Myneni, 2005; Kormanyos et al., 2008; Yue et al., 2014). Partially responsible for the lack of quantitative speciation measurements is the strong tendency of ferric to hydrolyse at even low pH (Flynn, 1984), complicating the laboratory study of such systems. Moreover, the large number of aqueous species that may co-exist simultaneously makes the study of individual species and the modelling of the numerous interactions between these species extremely difficult (Dry & Bryson, 1988; Stipp, 1990; Majzlan & Myeni, 2005; Kobylin et al., 2007)."

Jan 1, 2016

By C. D. K. Gauert

High-pressure waterjet technology is proposed as an alternative tool for selective underground mining of high-grade ore sections in stratiform orebodies showing a preferred ?bottom? or ?top? enrichment such as the Witwatersrand reefs and the Bushveld Complex platiniferous reefs. This technique, utilizing known mining technology together with more advanced machinery and additives as used in industrial and cleaning applications, may lead to an increased life-of-mine (LOM) for mining operations. A series of experiments was successfully carried out in a laboratory on Witwatersrand quartzite material, indicating acceptable cutting performance. Mining volumes by selectively cutting of reef portions are considered to be comparable to traditional drilling and blasting. Economic advantages of waterjet mining include energy savings due to the lower quantity of gangue rock to be hoisted to surface, as well as savings by a decrease in the usage of blasting materials. Capital expenditure of waterjet cutting, if applied on a broad scale, could be lower in the long term than that of conventional drilling and blasting methods. Mining by the application of high-pressure waterjet technology could become a competitive ?green technology? improving the economics and safety of labour-intensive mining operations. This paper suggests that waterjet cutting at an industrial scale can become a routine hard-rock mining technique in the future. Keywords waterjet cutting, high pressure, mechanized narrow reef mining, abrasive agents, costs, selective mining.

Jan 1, 2013

By James Tarr, Matthew Eichler, Brent Tardif

ANFO was being used as one of the blasting agents on a construction site in New England. Groundwater was encountered in numerous blast holes. The blasting contractor was employing typical explosives loading procedures for wet conditions. An abutter to the project complained that blasting caused her well water to have an odd taste and smell. Through testing, it was determined that there were hydrocarbons and nitrates in the well water. Several days later a second neighbor complained of foul tasting water; again it was determined that hydrocarbons and nitrates were present.

Jan 1, 2003

By A. Yaghini, Y. Pourrahimian

"Human factors (HFs) play an important role in the mining and mineral industry, affecting operational and maintenance efficiency and safety. Despite the introduction of new technologies and automation in this sector, it is well known that a significantly large proportion of total human errors occur during the operation and maintenance phase. A comprehensive literature review of HFs across several industries is provided. From this review, the impact of HFs on operation and maintenance is summarized, with a focus on what the mining industry is currently doing and what opportunities exist for additional improvements. Future research directions and themes are also identified.RÉSUMÉ Les facteurs humains (FH) jouent un rôle important dans l’industrie des mines et des minéraux, en ce qu’ils affectent l’efficacité et la sécurité de l’exploitation et de l’entretien. Malgré l’apparition de nouvelles technologies et de l’automatisation dans ce secteur, il est bien connu qu’une grande partie des erreurs humaines (EH) se produisent durant une phase d’exploitation et d’entretien. Cet article propose une analyse documentaire approfondie des FH dans plusieurs secteurs. L’impact des FH sur l’exploitation et l’entretien est résumé à partir de cette analyse, une attention particulière étant accordée à l’évolution de l’industrie minière et aux possibilités d’améliorer davantage ses activités. Sont également identifiés les futurs thèmes et voies de recherche.INTRODUCTIONDuring the past several decades, the mining industry has focused on improving equipment, machinery, and methods that have led to more advanced hardware and software, equipment with higher reliability and productivity, and other technological advancements. These actions have improved safety and productivity and have reduced casualties and maintenance workload. Although today’s mining equipment and machinery are technologically advanced and highly reliable, the risk of accidents is still relatively high and key performance indicators have not improved significantly compared to other industries (Sorensen, 2012). A prominent reason could be due to insignificant integration of human factors (HFs) as part of planning, operation, and maintenance activities. The current mining system is a people system, and inevitably HFs and human error (HE) figure prominently in all aspects of this industry. Even the most advanced technologies and innovations require operators and maintainers with significant knowledge and skill, which could increase the potential for HE."

Jan 1, 2018

By Cooper R. J

The essential features of the zinc concentrate roasting installation at the Risdon Works by the Electrolytic Zinc Company of Australasia Ltd. are given.The problem of maintenance of ignition in down-draught zinc concentrate flash roasters is discussed, and a solution offered.A successful and economical method of using by-product oxygen for raising the roasting efficiency of hearth roasters is described. Three methods of utilizing oxygen for the same purpose in flash roasting are detailed, and their relative merit, considered.INTRODUCTIONThe zinc sulphide concentrate used at the Risdon Works is roasted autogenously for removal of sulphur in two hearth roasters, and four flash roasters. The hearth roasters are of modified Skinner type with eleven hearths. They were designed, and are used, for roasting mixtures of relatively low sulphide content. Their design and operation have been described elsewhere (Forster, 1949).The flash roasters are down-draughted furnaces with cross-section and rabbling equipment based on the hearth roaster design, and the process is similar to that developed by the Consolidated Mining and Smelting Company of Canada Ltd. (Cominco) at Trail, B.C. (Stimmel, Hannay, and McBean, 1936).These furnaces are 20 ft. in diameter. They have three drying hearths through which hot gas is drawn from the combustion chamber by the burner fan. The combustion chamber is 2'1 ft. high above the collecting hearth (27 ft. in No. 4 unit), and the discharge hearth below it is 6 ft. high, so that a large gas offtake is possible. Four rabble arms for each hearth are carried on a central column. Dried, ground concentrate, and the air for roasting it, are fed to a burner...

Jan 1, 1958

By William R. Yernberg

The combined 76th Annual Minnesota Section of SME meeting and 64th Annual University of Minnesota Mining Symposium were held April 8and 9, 2003, in Duluth, MN. This year’s theme was “Stakeholders, Partners in Change.” The meeting included four keynote speakers, technical presentations and a tradeshow. Engineers, executives, mining managers and suppliers from throughout the United States and eastern Canada attended the meeting. Reflecting the theme of the meeting, all agreed that the mine owners, the government, the community and the employees are all “stakeholders.” They must be “partners in change” for the iron ore mining industry to survive in the region. Compared with past meetings, where improved technology was the primary focus, this year the focus was on the dramatic restructuring of the entire industry. As noted by several of the speakers, “This time, the change is not in technology.”

Jan 1, 2003

By Yushiro Hirai

Saganoseki smelter & refinery had operated two flash smelting furnaces from 1973, attaining 330,000 mtpy of copper production in 1989. In 1996, however, it carried out a "integration of two flash furnaces". That is, it doubled the feeding capacity to one flash furnace to shut down another furnace while maintaining the same production. Single flash furnace operation has successfully started in March 1996 accomplishing a great reduction of the total production cost. The production had reached to 350,000 mtpy in 1997, and further increased to 450,000 mtpy by executing the expansion program with single flash furnace in 1998. This paper introduces results of the single flash furnace operation and describes about an outline of the expansion.

Jan 1, 1999

By M. Tominaga

An industrial port complex was constructed on the west coast of Leyte Island The work was started in December 1981 and completed in May 1984. This port complex includes a 665 m long wharf and can accommodate vessels ranging from a 60,000 DWT ore carrier to a 4 000 DWT general cargo ship. It now handles materials for and products from a copper smelter with an annual capacity of 130,000 t and a fertilizer plant with an annual capacity of 900,000 t. The Wharf structures consist mainly of interlocked steel pipe piles, steel sheet piles and steel pipe Piles. Material handling equipment such as unloaders, shiploaders, etc. were installed on the wharf. Site survey, planning, engineering design and construction aspects of the port development are discussed in this paper with particular emphasis on the wharf structure.

Jan 1, 2010

By B. M. Monaghan

"The developments of the 1950s and 1960s have seen Canada become an international source of iron ore, trading in all geographical areas and hemispheres. Canada's production will significantly increase in the next decade. However, although the outlook is bright, iron ore producers cannot be complacent. Instead, we must weigh the factors that have brought about the development of the Canadian iron ore industry and examine the probable changes for the next decade that will affect its growth.Looking ahead in the 1970s, competition will be severe. Pressure on prices will continue as new sources of supply bid for long-term contracts and as steel producers continue to develop mines around the world. Rising costs will make these pressures more severe. We must balance the growth of the world's steel makers with the emergence of new supplies of iron ore. The iron ore industry is now part of a new era in which demand and supply are intermeshed, and the developments around the world are acting on the Canadian iron ore industry's future."

Jan 1, 1971

By Turker L

The leaching of Tellness (Norway) ilmenite concentrate in hydrochloric acid and mixed aqueous HCl-alcohol solutions at boiling temperatures was investigated. It was found that the alcohols methanol, ethanol and ethylene glycol all substantially increased the leach rate and in the case of methanol and ethanol this was achieved at lower boiling temperatures compared with aqueous HC.

Jan 1, 1986

By D. Ksinsik, R. Boisvert, D. Leblanc

Casting, cooling and crushing/sieving of ferroalloys has followed a well-established pattern in the whole ferroalloys industry for many years. Usually liquid metal or alloys are cast into flat open moulds of various shapes and forms, and after solidification the product is removed from such mould to further cool down to a temperature where subsequent handling steps are feasible. Common to all mechanical product fractioning is the generation of dust and fine size material with lower product value. For almost 10 years, Bécancour Silicon has investigated alternative roads to improve technology and/or reduce or solve problems related to those disadvantages. Since 1995 Bécancour Silicon operates a special silicon granulation plant targeted to product for the chemical treatment/conversion of silicon for silicones production. Prior to the development of the granulation process, various systems had been evaluated, among others the vibrating casting bed, now in operation elsewhere but judged inappropriate because of the tapping volumes to be handled at Bécancour Silicon and other disadvantages. After evaluation of all aspects of heat transfer, radiation, and conductivity in relation to transfer media and within the product, a novel system was designed and built.

Jan 1, 2004

By Jack Wright

The analysis of water produced with crude petroleum has interested oil producers since inception of the industry. Records of the first analysis of mineralized water produced from an oil-productive formation are obscure, and references to the first use of brine analyses to assist in solving problems of petroleum production are not available in the technical literature. However, many early reports of the Federal Bureau of Mines5-8 and Federal Geological Survey,9-11/ as well as articles in engineer and geological journals12-14/ placed special emphasis on the importance, interpretation, and application of water analyses. One of the earliest applications of water analyses, and still a major one today, is for identification of intrusive waters in oil wells. This may be done by comparing the chemical constituents of a sample of water indigenous to the oil-productive formation with those of samples from upper, water-bearing formations within the same general area. Some earlier investigators recognized the need for Analyzing samples of all waters encountered in drilling operations. Ambrose15/ stated, in part, "In wells being drilled, the engineer should grasp every opportunity to get a true sample of water from each sand. . .," and, "The waters of each oil field are chemically different from those of another field." The validity of the latter observation and the importance of the former one have been borne out by comparing the results of analyses of many samples and noting the differences in relative concentrations of like constituents of waters from the a geological formation in different localities or oil pools.

Jan 1, 1957

By J. C. Agarwal

Slags produced by modern smelting furnaces contain copper values which are unacceptably high for discard. The electric arc furnace is employed commercially to clean copper from flash furnace slags but the addition of highly oxidized converter slags to an electric furnace has created operational problems. Highly oxidized Noranda Reactor slags have not been processed successfully in a pyrometallurgical process. These slags, which contain large concentrations of copper (5 to 10 per cent), are treated in slag concentrators (controlled cooling, crushing and milling, and flotation) which produce a copper concentrate that must be resmelted. Though commercially operable, it will be shown that the slag concentrator has important process and cost disadvantages as compared to a pyrometallurgical process. In this paper an economic comparison is made between a pyrometallurgical process and the slag concentrator. For the analysis, five hypothetical smelting plants are considered. Each plant treats 1200 tons of copper concentrate per day and produces 109,000 tons of copper annually. The plant configurations used in this study are:

Jan 1, 1976

Surface subsidence that results from longwall mining can be large magnitude and can affect significant areas. Conventional methods for subsidence monitoring include leveling, global positioning system (GPS), and photogrammetric surveys. Remote sensing techniques, including aerial LiDAR, terrestrial laser scanning, and satellite-based differential interferometric synthetic aperture radar (DInSAR), are also used to measure deformation associated with subsidence. DInSAR data are different than data from conventional subsidence surveys. Images capture data over large areas (hundreds of kilometers), and each pixel (data point) in an image quantifies the average displacement over an area of square meters. DInSAR data can have fairly high time resolution; imaging periods typically range from weeks to months.

Jan 7, 2020

By R. E. Heithecker

In Kansas, almost every oil well drilled into a limestone formation is treated with hydrochloric (muriatic) acid upon completion. This is done to increase the potential capacity of the well and thereby increase its "daily allowable" production (see p. 9 ), to shorten the time required to produce the recoverable oil, and to increase the quantity of oil recovered ultimately from the reservoir. The porosity and. permeability of limestone formations seldom are uniform throughout the proved area, consequently the production capacities of completed wells vary considerably. Acid treatment of wells tends to increase production capacity and to equalize potential capacity. If offset wells already have been treated with acid, new wells usually are treated to protect the property on which they are drilled against drainage. Even though competitive conditions do not exist in a field, it

Jan 1, 1939

By Qingming Feng, Bo Huang, Dongbo An, Jinhong Zhang

A study of the application of mine tailings as precast construction materials through alkali activation has been carried out, focusing on efficiently activating mine tailings, reducing alkali consumption, decreasing curing time and improving compressive strength. Firstly, the effect of temperature on the alkali activation of mine tailings was studied. Secondly, the impact of additives, i.e., calcium hydroxide and aluminum oxide, on the compressive strength of samples was investigated. Thirdly, the impact of forming pressure on sample strength was studied. Test results showed that unconfined compressive strength (UCS) of 40 MPa was achieved with the geopolymerization products through optimization. Finally, to elucidate the geopolymerization mechanism of mine tailings, microscopic and spectroscopic techniques including SEM/EDX, XRD, and FTIR spectroscopy were used to investigate the microstructure and the elemental and phase composition of the geopolymerization products. The findings of the present work provide a practical method for applying mine tailings as precast construction materials through alkali activation.

By Qingming Feng, Bo Huang, Dongbo An, Jinhong Zhang

A study of the application of mine tailings as precast construction materials through alkali activation has been carried out, focusing on efficiently activating mine tailings, reducing alkali consumption, decreasing curing time and improving compressive strength. Firstly, the effect of temperature on the alkali activation of mine tailings was studied. Secondly, the impact of additives, i.e., calcium hydroxide and aluminum oxide, on the compressive strength of samples was investigated. Thirdly, the impact of forming pressure on sample strength was studied. Test results showed that unconfined compressive strength (UCS) of 40 MPa was achieved with the geopolymerization products through optimization. Finally, to elucidate the geopolymerization mechanism of mine tailings, microscopic and spectroscopic techniques including SEM/EDX, XRD, and FTIR spectroscopy were used to investigate the microstructure and the elemental and phase composition of the geopolymerization products. The findings of the present work provide a practical method for applying mine tailings as precast construction materials through alkali activation.

By P. W. Godbehere

"INTRODUCTIONMagnetic mill linings have been developed from an invention by Mr. Bertil Brandt, the originator of the Skega rubber lining. The OREBED magnetic mill lining is a concept in which rubber covered strontium ferrite permanent magnets are arranged on the inside wall of a mill shell so that they attract magnetically susceptible material be it ore, media or tramp, to form a protective layer over the magnets and to serve as an operating surface with indefinite life.Noranda Mines Ltd. through its associate Norcast Division of Noranda Metal Industries formed a joint venture with the inventors to market magnetic mill linings in North America. For the past twelve months trials have been undertaken in conjunction with Orebed Inc. to test and develop these linings for grinding mill applications at the Horne Concentrator. Two independent milling circuits are currently being operated, one treating a siliceous gold ore and the other a copper slag.This paper presents the results of the magnetic lining test programme to date."

Jan 1, 1983

By Jean J. Tancous

Chromium recovery from wet-blue offal trimmings and shavings can be done with substantial chemical cost gains by incineration at 600° C for 5 hr. Pretreating the offal with 0.5 M Na2C03 and air-drying prior to incineration produce Cr04 .By simply incinerating the offal, without pretreatment, an ash containing water insoluble Cr203 was produced. The Cr203 in the ash was purified by leaching with water. Chromium and crude protein were efficiently extracted from offal using 5 pct Na103, 5 pct H2S04, and 3 pct NaCl at 40° C. This procedure was effective but expensive. Satisfactory leather as to odor, appearance and shrinkage temperature was made from chromium recovered from wet-blue offal by incineration and by extraction. Chromium conservation is possible by recycling chromium liquors and by precipitating chromium from spent tanning liquors prior to combining these liquors with other tannery wastes. Combining chromium liquors with other wastes introduces contaminants that make chromium recovery and reuse difficult. Leaching sludges with H2SO4 produced marginal chemical cost gains. Leather tanned with these solutions had satisfactory shrinkage temperature but the sludge odors and iron contamination were objectionable.

Jan 1, 1979

By Michael Arnold, Jonathan Delgado

In 2017, Bauer Foundation Corp. (BFC) was awarded the contract to install the deep foundations for the new 17-story Hotel Tower and the Low Rise Casino Expansion at the Seminole Hard Rock Hotel and Casino in Tampa, Florida. The site was underlain by extremely challenging Florida Limestone geology and surrounded by occupied existing buildings and infrastructure. To overcome the challenges of the difficult subsurface conditions, and to successfully complete the foundation installation without impact to the surrounding buildings and casino operation, Langan Engineering (EOR) and BFC were required to modify both the design and installation techniques during construction. The scope of work included 147 temporarily cased drilled shafts to depths up to 230 ft (70 m) below ground surface (BGS), 76 permanently cased micropiles up to 200 ft (61 m) BGS, and more than 300 augered-cast-in-place (ACIP) piles up to 125 ft (38 m) BGS. Voids and zones of high permeability in the limestone created many challenges for execution of the foundation scope including ACIP piles overbreaks of more than 400% above neatline volume, and construction induced ground subsidence/collapses adjacent to structures supported on shallow foundations. This paper will discuss site limitations, design and construction challenges, difficult geology, varied soil conditions, and lessons learned. PROJECT The project is located at Seminole Hard Rock Hotel and Casino Tampa, Florida, as shown in Fig. 1. Seminole Tribe, the owner, started the construction of a new 17-story Hotel Tower and the Low-Rise Casino Expansion at the beginning of 2017.

Jan 1, 2018