Search Documents

By J. -M. Milazzo, T. Wallmach, S. B. Blancher, A. Amalric

In a FeNi electric arc furnace, the physical properties of the slag (chemistry, viscosity, liquid/solid/gas ratio) are of crucial importance in controlling the efficiency of the process. In this paper, we studied the slag crystallised on the walls of a semi-industrial furnace (freeze-lining), the slag rising through the burden during foaming phenomena, and the casted slag. The freeze-lining is the layer of oxides that crystallises on the refractory wall of a furnace, protecting it from chemical and mechanical aggression. It records changes in furnace conditions (slag chemistry, temperature, oxygen fugacity), which makes it possible to observe the impact of these elements. In the high reduction test, the freezing lining is composed of magnesian olivine. Switching to a low reduction process increases the Fe content of the olivine and causes orthopyroxene to appear, making the freeze-lining mechanically and thermally weak. Thermal incidents in the furnace cause significant slag foaming. This foaming is produced by a massive crystallisation of the olivine (due to the drop in temperature), and inducing an exponential increase in viscosity, preventing the free circulation of gases. These foaming episodes are also recorded in the freeze lining and form layers rich in gas bubbles, and therefore mechanically fragile. The slag casted and cooled in a ladle allows the first steps of slag crystallisation to be studied. Olivine is the liquidus phase, with a magnesium-rich core and an iron-enriched rim, contemporaneous with the orthopyroxene phase. The habitus of these phases is very similar to that found in komatiites for the same minerals. FeNi slag is therefore an industrial analogue that is easy to study and compare to komatiites. Keywords: Pyrometallurgy, ferronickel, slag, freeze-lining, characterisation, olivine, mineralogy

Jan 1, 2020

By T. Song, X. Wang, X. O. Xia, X. J. Luo, B. Chen

Interparticle breakage is the main crushing mode of an inertia cone crusher according to its working principle and feeding condition. In this paper the breakage behaviour of an inertia cone crusher is investigated, based on energy controlled compression combined with the vibration theory, rather than geometry controlled compression (form conditioned) which plays a major role in conventional eccentric cone crushers. The effect of feeding and operating conditions on breakage behaviour was described quantitatively from the perspective of energy consumption and product size distribution. The influence of feeding conditions, discharge size settings and vibration exciter speeds on the crushing process and product quality has been studied according to the results of laboratory crushing experiments. The results of the experiments show that the particle size of broken products becomes finer with the decrease of a discharge gap within the gap range selected by the experiment. The product size increases significantly when the gap approaches the upper limit of 6 mm. The variation of eccentric speed has a more prominent effect on reducing the product size compared with the change of discharge gap. The change in product size is not apparent when the eccentric speed rises to a certain level. The throughput of an inertia cone crusher is sensitive to the change of discharge gap, which increases linearly with the discharge gap and decreases with the eccentric speed. The change of feeding conditions has little influence on the crusher throughput. Keywords: Inertia cone crusher, interparticle breakage, energy consumption, product size distribution

Jan 1, 2020

By K. C. Naidoo

There are two main types of densifying cyclones currently available in the market, namely polyeurethane (PU) and ceramic. The PU densifying cyclones are currently used throughout the Grootegeluk complex and coal beneficiation in general. It has been identified that PU densifiers wear relatively fast depending on the operating pressure and need to be replaced frequently as a result. The motivation for this paper is to achieve an increase in the densifying cyclone lifetime through less wear and an increase in efficiency resulting in the ability to build higher relative densities (RD) more quickly. This will allow for a reduction in downtimes due to replacing densifying cyclones as well as building RD and a reduction in the operating costs associated with replacing worn densifying cyclones. Some of the major findings of the study indicated that the ceramic cyclone theoretically undergoes less wear than the PU cyclone, but since wear is application-specific and was evaluated, the wear on the polyurethane cyclone was found to be minimal. The RD differential is higher on the PU cyclones than the ceramic cyclones, showing that the PU cyclones perform better in a densifying application. This is the first test conducted on this application and type of cyclones. It should therefore be noted that having the PU cyclone significantly outperform the ceramic cyclone was not expected, due to the only change being the material of construction. This is an indication to take the material of construction into account when selecting cyclones as it can have a significant impact on the cyclone performance in specific applications. Keywords: Ceramic, cyclone, densifying, density, dense medium, polyurethane, wear

Jan 1, 2020

By B. K. Cross

This paper, which adopts a philosophical approach, attempts to analyse the contribution that the computer is capable of making in geological analysis, financial evaluation, and mine project control. Also examined are some reasons for non-utilization of these capabilities. As with most computer associated problems, the cause is primarily human and not mechanical. The paper gives one numerical example of the analysis of geological data and one of the evaluation of mine-design data. The values used in the examples are intended only to emphasize certain points and are not necessarily reproducible.

Jan 1, 1980

By D White, L. Lorenzen

Sampling and metallurgical testwork during various phases of engineering studies is of paramount importance for a robust processing plant design. When developing a process flowsheet, risks in achieving desirable financial outcomes are minimised by ensuring that appropriate sampling and adequate metallurgical testwork support the engineering and cost estimation at each phase of project development. The quality and type of samples used for metallurgical testwork are just as important as the metallurgical testwork itself. The key characteristic required of any sample is that it represents some defined portion of a mineral deposit. Representivity should consider the spatial orientation, lithology, alteration, degree of oxidation, mineralogy, and competency of the ore such as hardness and abrasiveness. Statistically representative sampling procedures and an appropriate metallurgical testwork program should be designed to bring metallurgical understanding up to feasibility study standard and to give a basis for process plant design. The authors have observed that the quality of sampling and quantity of metallurgical testwork carried out during the various phases of engineering studies are often insufficient to truly support a robust plant design. Some designs are based on benchmarks of apparently similar ore bodies or rely on buoyant metal prices supporting cash flows until rectifications can be implemented. The paper will discuss important aspects of sampling and testwork required for engineering studies in designing process plants. Keywords: Sampling, metallurgical testwork, studies, design

Jan 1, 2020

By J. L. Gaigher

A simple mineralogical regression model is described, which was devised in order to help the flotation plant cope with rapidly changing headgrades and feed mineralogy. Minerals in the feed were determined by means of quantitative X-ray diffraction and compared with plant performance parameters and flotation reagent consumption rates, using regression analysis. A mineralogical regression model for predicting recovery served to motivate flotation plant personnel and also set standards whereby flotation performance could be measured. The reagent consumption model indicated in which direction any or all of five flotation consumption rates should be altered. All practically measurable parameters, even those showing poor or no correlation, were included in the model, provision being made for the continuous update of a batch of data of 30 lines. Compared with the method of multiple linear regressions, the r2 is poorer at 0,41 (versus 0,50), but the mean standard error of estimate for both methods is identical at ± 6,6 units. The regression model is simpler than the method of multiple linear regressions, and although the accuracy of prediction is not high (41%), the mineralogical regression model proved to be successful in practice. Flotation efficiency, as measured by the mean ratio of head to tails grade, for the 9 month period after the mineralogical regression model was implemented on an hourly basis, improved from 2,8 to 3,2, which is equivalent to an improvement in average flotation recovery of 5% relative.

Jan 1, 1987

By P. Minkkinen, R. C. A. Minnitt

Particle size distribution analysis is important to many industries for assessing product quality, process efficiency, and compliance with contractual standards, while ensuring sample accuracy, and representativeness. Inaccurate particle size distribution results, arising from fines due to excessive handling can lead to penalties and buyer-seller disputes. A non-representative particle size distribution means samples will not accurately represent the chemical components either. Sampling blasthole cuttings poses challenges due to large material volumes, segregation, and uneven settling of particles in dense gold bearing ores. Commonly used sampling methods, such as spear or sectoral sampling, may lack representativeness. Particle size distribution analysis is crucial for evaluating sampling methods by comparing test sample representativeness against a reference standard derived from multiple particle size distribution analyses. Acceptable samples must fall within the 97.5% confidence intervals of the standard; deviations analyses lying outside these boundaries indicate a strong likelihood of segregation errors. A case study demonstrates this approach by using a 6.005 kg benchmark sample to assess two additional samples (1 kg and 5 kg), highlighting particle size distribution’s role in detecting sampling errors and refining protocols. An example of three test samples collected from reverse circulation drill cuttings compared to a standard reference sample is presented to illustrate a quality assurance/quality control procedure for reverse circulation drilling.

Oct 2, 2025

By D. Orynbassar, N. Madani

This work addresses the problem of geostatistical simulation of cross-correlated variables by factorization approaches in the case when the sampling pattern is unequal. A solution is presented, based on a Co-Gibbs sampler algorithm, by which the missing values can be imputed. In this algorithm, a heterotopic simple cokriging approach is introduced to take into account the cross-dependency of the undersampled variable with the secondary variable that is more available over the entire region. A real gold deposit is employed to test the algorithm. The imputation results are compared with other Gibbs sampler techniques for which simple cokriging and simple kriging are used. The results show that heterotopic simple cokriging outperforms the other two techniques. The imputed values are then employed for the purpose of resource estimation by using principal component analysis (PCA) as a factorization technique, and the output compared with traditional factorization approaches where the heterotopic part of the data is removed. Comparison of the results of these two techniques shows that the latter leads to substantial losses of important information in the case of an unequal sampling pattern, while the former is capable of reproducing better recovery functions.

Aug 1, 2021

Branch Minutes of the General Meeting held at President Steyn Gold Mine canteen on Wednesday, 10th May, 1978, at 4.00 p.m. Erratum We apologize to Mr J. G. Taylor for the error in one of his qualifications. Bio-engineering monograph The selection of papers presented at the International Bio-engineering Conference at the University of Cape Town organized by the South African Institution of Mechanical Engineers and held in April 1977, and which are appearing in The South African Mechanic al Engineer during April to June this year, will shortly be available in book form. Mathematics The Institute of Mathematics and Its Applications is planning the following conferences and symposia: The Nand F Proposals in Relation to Mathematics, 1st July, 1978: London School of Pharmacy. NIM reports Report no. 1917 The instrumental neutron-activation analysis of granites from the Bushveld Complex. (31st Mar., 1978.) Report no. 1951 Potentialities and limitations of four-parameter equations for the correlation of formation constants of metal-ion complexes in aqueous solution.(15th May, 1978.) Report no. 1963 An evaluation of the methods used at the National Institute for Metallurgy for the analysis of base-metal concentrates. (28th Apr., 1978.) Report no. 1964 The separation, by anion exchange, of noble metals on substituted cellulose. (28th Apr., 1978.) Guide To The Preparation Of Papers For Publication In The Journal Of The South African Institute Of Mining And Metallurgy The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal.

Jan 1, 1978

By D. Moradkhani, S. M. Javad Koleini, M. Abdollahy, F. Soltani

"The objective of the study was to determine the type and distribution of rare earth elements (REEs) in the phosphate flotation concentrate from the Esfordi flotation plant in central Iran, in order to understand their leaching behaviour. Samples of the concentrate were prepared and analysed using XRF, XRD, ICP, and EMPA. The Ce, Nd, La, and Y contents were 5608, 2227, 1959, and 679.7 mg/kg, respectively. The main REEbearing minerals in the concentrate are fluorapatite, monazite, and xenotime. Apatite is the chief mineral of the concentrate and the ratio of apatite to monazite is greater than 60. From EMPA analysis, monazite contains a much higher proportion of REEs than apatite, but more than 50% of the REE content of the concentrate is in apatite, as this is the main mineral constituent of the concentrate. During the leaching of REEs in the phosphoric acid production process, more than 99% of the total rare earth values report to the large amounts of phosphogypsum (CaSO4·2H2O) formed during the dissolution reaction. Accordingly, two process options are suggested for treating the Esfordi concentrate. In the first option, the concentrate is treated with 98% H2SO4 at 200–300°C. After digestion and water leaching, phosphorus and REEs are precipitated out of solution. In the second option, the concentrate is treated in a pre-leach stage. The process residue from the pre-leach stage is then subjected to acid digestion at elevated temperature for phosphoric acid production.IntroductionThe rare earth elements (REEs) comprise a set of 17 chemical elements in the periodic table, specifically the 15 lanthanides plus scandium and yttrium. REEs and alloys that contain them are used in devices such as computer memory, rechargeable batteries, cell phones, catalytic converters, magnets, fluorescent lighting, and many more (Krishnamurthy and Gupta, 2004). China supplies about 94% of the REE demand, with the remaining 6% coming from Russia and Estonia, the USA, India, Malaysia, and Brazil (Zhanheng, 2011). Increased industrial development in China has prompted the Chinese government to limit annual export quotas to approximately 35 kt of rare earth oxides (REOs), while non-Chinese annual demand is expected to reach 80 kt by the year 2015. This constriction of supply is being met by the development of many new rare earth mining projects, each of which has its own unique mining and processing challenges (Jordens, Cheng, and Waters, 2013). One of these projects is the Esfordi phosphate project, which is located in Yazd Province in central Iran. The concentrate from the Esfordi flotation plant contains 1.2–1.5% REEs."

Jan 1, 2017

By C. Hey

The cycloned gravitated tailings backfill system, also referred to as a soft or low density fill, has been implemented at Vaal Reefs. Inhibiting the success of the system was the problem of shrinkage after placement. The problem was overcome by a pressure fill technique which eliminated settlement, contained costs and allowed remote placement. The technique involves the preinstallation of disposable pipes which are filled cyclically until a residual pressure of 0,5 bar of active support is generated in the filled paddock.

Jan 1, 1988

By T. Bruce, R. C. A. Minnitt

Mining operations are generally reluctant to install high-cost sampling systems at operations that have been functioning for many years. The principal objection to installing appropriate equipment to extract correct and representative samples in process flows is the time and costs involved. The Theory of Sampling (TOS) provides a structured framework for identifying and quantifying the errors and bias associated with any sampling event, but this may be insufficient to initiate substantial investment in correctly designed sampling equipment. Financial losses arising from substandard sampling installations are usually disregarded because the value-add from a good quality sampling solution is invisible, but the cost is quite obvious. Depending on the needs, a less-than-perfect or fit-for-purpose sampling solution may be acceptable, provided the magnitude of sampling errors is understood and the assay results are interpreted accordingly. Categorical levels of acceptable accuracy and precision can be established depending on the sampling position in the mining value chain and the nature of the decisions to be made. The objective benefits of proposed fit-for-purpose sampling solutions should be presented to relevant decision-makers in such a way that adverse subjective decisions are countered so that appropriate solutions are implemented. Practical examples of the benefits from motivating the implementation of fit for purpose sampling solutions at sampling facilities around the world are provided.

Jul 2, 2022

By K. Sasaki, Y. Oriia, Shigeto Kuroiwa, H. Miki, Yuji Aoki, T. Hirajima, G. P. W. Suyantara

The effect of a sulfite reagent on the floatability of chalcopyrite and enargite was investigated in this paper. The flotation tests using single and mixed minerals were performed under various concentrations of sulfite. The flotation tests using a single mineral showed that the sulfite reagent depressed the natural floatability of both minerals at pH 9. Surprisingly, enargite was floated after the addition of potassium amyl xanthate (PAX) following the sulfite treatment, and the floatability of chalcopyrite depressed under a similar condition. X-ray photoelectron spectroscopy analysis results showed that the sulfate species increased after the sulfite treatment on both minerals. However, the addition of PAX removed this sulfate species and rendered the enargite surface hydrophobic. This phenomenon was not observed on the chalcopyrite surface. FTIR analysis and PAX adsorption studies were performed to support this finding. The flotation of a mixed mineral was in agreement with the flotation of a single mineral, indicating a possibility for selective flotation of chalcopyrite and enargite using the proposed method. Keywords: Flotation, chalcopyrite, enargite, sulfite, potassium amyl xanthate

Jan 1, 2020

By P. R. Jochens, A. A. Hejja

The effect of the reactivity of lime on desulphurization efficiency in the basic oxygen furnace by A. A. HEJJA,D. D. HOWAT, andP.R.jOCHENS Published in the Journal March 1973. DISCUSSION R. E. Leyman* The authors discuss in detail the effects of transport and storage at the steel plant on the reactivity of lime as measured by the DIN Reactivity Test. They attribute the deterioration in reactivity to the absorption of water vapour and carbon dioxide, but make no mention of the possible role of atmospheric sulphur dioxide in this respect. The significance of the mineralogical and surface characteristics of gold grains in the recovery process by C. E FEATHER and G. M. KOEN Published in the Journal February 1973. AUTHORS' REPLY TO DISCUSSION (Published in the Journal July 1973) H. P. Carlisle Mr Carlisle's questions and observations will be dealt with in the same order as they were raised. 1. How were the mass percentages of the grains determined from the sizes measured in polished section?

Jan 3, 1973

By D. D. Howat, J. van der Colf

This paper is the first in a series of three dealing with this subject and also with the rate of oxygen removal from the slags in the presence of solid carbon and with the physicochemical properties of the reduced slags. For selected members of the system, the melting temperatures and primary crystallization products were determined. as were the viscosity and the electrical resistivity of the corresponding melts. All the experiments were conducted in a neutral atmosphere. Where determined, the primary phase was found to be either perovskite or magnesium aluminium titanate. The composition variable exerting the most pronounced influence on viscosity or resistivity was found to be the basicity expressed as the mass ratio (CaO + MgO)jSiO,. The ratio CaOjMgO became important only at Iow basi<:ity values. Although generally there is a direct proportionality between log (viscosity) and log (resistivity), slags h&apos;lving either a very high silica content or a very high titania content have anomalously Iow electrical resistance.

Jan 1, 1979

By J. O. Jensen

A method is described for the determination of cyanide in gold slurries, based on amperometry. The measured current is proportional to the concentration of cyanide, and is not effected by pH or by the concentration of oxygen in solution. It is also unaffected by other ions that may be present in gold-leaching solutions, including sulphide, thiocyanate, and thiosulphate. The current depends on the temperature, and an activation energy of 17,9 kJ/mol was determined Since the current is controlled by the mass transfer of cyanide to the anode, it depends on the conditions of agitation. In tests on an operational gold plant, slurry was pumped directly from the top of the leaching tank, through the measuring cell and back into the tank. The results indicate that the instrument is a promising alternative to the instruments currently available. The readings from the instrument remained in calibration for at least two days, showing that the instrument would need to be re-calibrated by the operating staff at regular periods.

Jan 1, 1994

By Ralph H. Nafziger

This paper reviews the major deposits of lower-grade chromite in the world, and a wide variety of methods used for the recovery of chromium from them. Gangue materials in more coarsely sized ores can be separated by gravity means, whereas flotation techniques are required for finer-grained materials. However, unless there is considerable Iron In the ores, physical means cannot increase the Cr/Fe ratios. Chemical techniques such as hydrometallurgical methods, chlorination, roasting and leaching, and smelting are required for this purpose. A greater understanding of the physical properties of chromites and the chemical reactions that take place in the recovery operations is required before. the recoveries from lower-grade chromites can be maximized. More efficient recovery operations can be realized If It can be shown definitively that the reduction of chromites occurs via either a gas-solld or solid-solid mechanism, for example. The effects of specific impurities on the chromite reduction reactions need to be better understood, as do reagent and pH control in the flotation of chromite.

Jan 1, 1982

Book reviews Fiftieth Annual Report (1971) of the Safety in Mines Research Establishment, published by H. M. Stationery Office, London on behalf of the Department of Trade and Industry. Advances in extractive metallurgy and refining. This excellent volume, published by the Institution of Mining and Metallurgy, contains all the thirty papers presented at the International Symposium held in London in October, 1971. Electric Melting Practice by A. G. E. Robiette, Charles Griffin and Co. 412 pp. In recent years the application of electric furnaces to melting processes has expanded to such an extent that it has become a topic in its own right, quite distinct from the related subject of electric smelting which is still limited, for the most part, to those areas where inexpensive electrical power is available. Optimum use of manpower by A. J. van Zyl. The sixties represented one of the longest periods of sustained economic growth South Africa has experienced. At the same time it caused a certain amount of inflation and an acute manpower shortage.

By E. Uslu

The kinetics of the reduction of chromite from the LG-6 layer of the Bushveld Complex in Fe-Cr-C alloys were studied in the temperature range 15OO°C to 1680°C under an inert argon atmosphere. The rotating cylinder technique was used, and the rotational speed of the chromite cylinder ranged from 0 to 1000 r/min. The melt consisted of 30 to 80 per cent chromium and 2 to 8 per cent carbon. The initial chromium-te-iron ratios of the melts varied between 0,42 and 4,95. The reduction of chromite spinel was analysed in terms of the decarburization of the metal. It was found that decarburization increased with an increase in the temperature, the carbon content of the bath, and the rotational speed of the cylinder up to 400 r/min, after which it remained almost constant. Decarburization also increased with an increase in the chromium content up to about 50 per cent chromium but, at higher chromium contents, it decreased. In the early stage of the reduction, up to about 30 minutes of reaction time, the liquid-state mass transfer of oxygen was found to be the most likely rate-determining step. The apparent activation energy was calculated to be 84,864 kJ per mole of oxygen. In the later stage, diffusion of iron and/or chromium in the solid state is the most likely rate-determining step. The apparent activation energy for the diffusion was calculated to be 471,18 kJ/mol.

Jan 1, 1991

By R. S. Sanders, J. Schaan

Syncrude Canada Ltd. produces synthetic crude oil from Canada?s vast oil sand reserves by mining the oil sand, then separating and upgrading the ultra-viscous crude oil, or bitumen (~ 106mPa s @ 10ºC). At Syncrude?s Aurora Mine, about 16 000 tonnes oil sand per hour are mined and then transported 5 km by slurry pipeline to the extraction plant. The waste tailings stream is then transported about10 km by pipeline to a settling/sand storage basin. Oil sand slurries are reasonably concentrated (> 35%solids by volume), typically have a sand particle diameter between 0.18 and 0.3 mm, and are transported at reasonably high velocities (3 to 5.5 m/s). As one would expect, pipeline wear is a significant problem in this industry, in terms of both unplanned production outages and maintenance costs. In order to develop strategies to extend pipe life and to focus more on condition-based maintenance scheduling (as opposed to preventative maintenance), Syncrude has implemented an ongoing pipe wear measurement programme. Regular measurements of pipe wall thickness are obtained at various circumferential positions at a number of axial locations along each pipeline, using an ultrasonic scanning technique. In this paper, we show how wear rates vary as a function of axial location and circumferential position for oil sand hydro transport and coarse particle tailings pipelines. The specific positions at which peak wear rates occur are explained by considering the characteristics of the coarse particle slurry flows to which the pipelines are exposed.

Jan 1, 2007