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By P. M. Solozhenkin, O. I. Solozhenkin

Currently lead nitrate is used as the recommended activator in Au-Sb flotation. However, due to high levels of hazard, the application of lead nitrate constitutes a potential risk for human health and ecosystems. To mitigate the harmful impact of activators on the environment, further research on activation by alternative reagents has been launched to promote the efficiency of antimony ores. In the present study, adsorption of lead, copper and zinc cations has been investigated by nuclear quadrupole resonance (NQR), which has revealed copper and zinc cations penetration into the mineral lattice, although lead cations remain adsorbed on the mineral surface. However, the combination of zinc and copper cations leads to preferential volumetric adsorption of zinc in the mineral lattice and further surface adsorption of copper which positively affects the activation process. It has been established that activation of stibnite can be achieved effectively with the mixture of Cu2+:Zn2+=1:1 as much as with lead cations in antimony ore flotation. As a part of this work, the computational modelling has been used in prognosis of reagent activity evaluation (PRAE) for stibnite and aurostibite flotation by sulfhydryl collectors. The lower PRAE value the stronger the ability of a collector to form a stable complex with a mineral. PRAE has shown a strong negative trend to complex formation on the mineral surface of aurostibite and stibnite. Based on these studies, several collectors have been proposed for effective flotation. To verify the feasibility of proposed collectors tetramethyl (ethyl) thiuram disulfides (TMTD and TETD) have been used for flotation of stibnite, sphalerite, pyrite and arsenopyrite. Flotation performance has been improved significantly with TMTD that allows the avoidance of lead nitrate application and increases the recovery of antimony by 8,16%. Keywords: Stibnite, aurostibite, activation, lead, copper, flotation reagents

Jan 1, 2020

By P. C. Pistorius, D. Kruger, Y. Kacar

Because of its superior properties, stainless steel has been widely used for many applications. Nonmetallic inclusions can influence the quality of stainless steel products. A set of samples was used to track the response of inclusion composition during processing of a heat of titanium-bearing 18% chromium steel, from deoxidation after decarburization, to the solidified slab. The oxide inclusions responded as expected to additions of deoxidizers and calcium treatment, changing from silica to alumina and spinels, and then to calcium aluminates. The samples confirmed that titanium nitride can nucleate on liquid calcium aluminate during steel solidification.

Aug 1, 2021

By J. A. Maritz, D. F. Malan

Pillar strength is affected by pillar shape, but this has largely been ignored in past research studies. Bord-and-pillar layouts are typically designed using empirical strength equations developed for square pillars. Owing to the poor quality of pillar cutting, many hard-rock pillars have an irregular shape and it is not clear how this affects pillar strength. Furthermore, the strength of rectangular pillars in comparison with square pillars is also difficult to quantify. The ‘perimeter rule’ is widely adopted for rectangular pillars, but its applicability for pillars with irregular shapes has never been tested. We used numerical modelling in this study to investigate the effect of pillar shape on strength. An analytical limit equilibrium model of a square and a strip pillar also provided useful insights. For slender pillars, the strength of a long rib pillar is essentially similar to that of a square pillar. In contrast, for rib pillars with a large width to height ratio, there is a substantial increase in strength. The study found that the perimeter rule should not be used for irregularly shaped pillars. Displacement discontinuity modelling, using a limit equilibrium approach, is proposed as an alternative to determine the strength of these pillars.

May 3, 2023

By K. Wu, L. Li, D. W. Zhou, J. W. Yu

The presence of a fractured water-conducting zone (FWCZ) is of significant importance for the safety of underground mining under water bodies. When a coal mining area is covered with a thick layer of alluvial soil, the height, width, and distribution pattern of the FWCZ in the area shows unique features. The internal mechanism by which thick alluvial soil affects the FWCZ is still unknown. Using the Huainan coal mining area (HCMA) in China as a case study, we investigated the impact of thick alluvial soil on the height, width, and distribution pattern of the FWCZ through numerical simulation using the distinct element method, theoretical derivation, and data validation. The results indicate that a thick layer of alluvial soil inhibits the FWCZ height and increases the FWCZ lateral width. When the soil-to-rock ratio is greater than a certain value (the numerical result in this study is 15:18), the FWCZ height and width are affected by the thick alluvium significantly, and the thick alluvial soil alters the shape of the FWCZ from tall and thin to short and wide. The load exerted by the alluvial soil transfers downward to influence the FWCZ; however, this process is obstructed by the hard strata in the bedrock. Therefore, the vertical and lateral change trends show a similar step pattern. Our results can provide a basis for accurate calculation of the FWCZ height in mining areas with thick alluvial soil, to mitigate mine water hazards and increase the safety of underground mining in coal mines covered with a thick alluvium layer. Moreover, reducing the FWCZ height can help extend the upper extraction limit in coal mines covered with a thick alluvium layer, which reduces the thickness of the impermeable coal pillar and increases coal production.

Jan 1, 2016

By Richard F. Link, Jr. Koch

"A mathematical simulation model has been devised to guide the layout of surface or underground mine workings, drill stations, and drill holes that are established in order to search for tabular ore bodies. The ore bodies may be contained within veins, sedimentary beds (including reefs), or other tabular structures.Programmed for a time-shared digital computer, the model contains both stochastic and deterministic variables. Stochastic or natural variables include the number of ore shoots and their sizes, orientations, locations and values. Deterministic or controllable variables include (i) locations and costs of workings (for underground exploration); (ii) drill station locations and costs; and (iii) drill hole azimuths, inclinations, lengths and deflections (if any).For various assumptions about the natural variables, the model is run while the controllable variables arc changed deliberately. Thus, layouts are devised to determine the percentages of the total number of assumed ore shoots found at different costs. In order to choose among the various layouts, cost-effectiveness measures are calculated."

Jan 1, 2014

By E. J. Walls, W. C. Joughin

"In selecting a suitable method to sink a vertical shaft for underground access, a number of constraints influence the ultimate decision of where and how to develop the shaft, not least among these being safety, development and construction time, and cost. Two additional considerations stand out: these being geotechnical conditions and technology, the latter taking into account existing underground access. Assuming a project for which an existing underground excavation is available, it is tempting to build a shaft sinking project from the outset based on the raiseboring method, which has the potential to be the safest, fastest, and least expensive method provided that geotechnical conditions permit.And therein lies the rub: regardless of project time or cost constraints, when it comes to raiseboring a long (say, greater than 500 m), large diameter (greater than 4.5 m) shaft, the rock mass conditions ultimately dictate what method of shaft sinking will be feasible. Over the course of several studies for a particular project, several geotechnical analyses were carried out specifically for the purpose of developing a shaft by raiseboring. Risk analysis and experience showed that where the rock mass conditions indicated an unacceptably high risk potential, an alternative method needed to be considered, even if this meant increasing both the time and financial requirements.In this paper we present an overview of geotechnical investigation practices for shaft sinking. Decisionmaking thresholds for raiseboring or other methods of shaft sinking are discussed, including probabilities of failure, empirical rock mass classification, basic wedge failure, and back-analysis of a failed case. The design of appropriate support, and analysis of relative safety benefits for various shaft sinking methods, falls outside the scope of this work, and will be presented in a separate paper.IntroductionThe potential for rock mass failure during shaft development and construction affects whether a project is completed safely, on time and on budget. During the course of several studies to establish ventilation shafts for an underground expansion project, geotechnical analyses of rock mass stability and failure potential were carried out. The investigations were guided by the method of McCracken and Stacey (1989) together with insights from Peck and associates (Peck, 2000; Peck and Lee, 2007, 2008; Peck, Coombes, and Lee, 2011)."

Apr 1, 2019

By B. Nemutudi, X. Zhang, B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, S. Pikinini

The comparison study on adsorption of potassium normal butyl xanthate (PNBX) and sodium (nbutyl) dithiocarbamate (SNBDTC) on sperrylite mineral forms a basis in understanding the floatability improvement and paves a way for the design of collectors that may impact on a wide range of arsenide minerals. This study used a computational density functional theory (DFT) and experimental microcalorimetry approach to determine the adsorption energies of PNBX and SNBDTC collectors onto a sperrylite mineral surface. From a computational aspect, we considered the most stable surface plane of (100) surface, which had been found to give the lowest surface energy, compared to the other surface planes. It was observed that the PNBX and SNBDTC preferred to bridge on the As and Pt atoms through the S atoms. These findings showed that the collector adsorbed on the surface through both Pt and As atoms and indicated that the As atoms were significantly active in the adsorptions. We found that the adsorption energies were in the order: SNBDTC (–278.38 kJ/mol) > PNBX (–270.92 kJ/mol), indicating that the dithiocarbamate had stronger exothermic adsorption than the xanthate. From the microcalorimetry test it was also found that the SNBDTC was more exothermic than the PNBX and the adsorption energies were: SNBDTC (–473.50 kJ/mol) > PNBX (–331.13 kJ/mol). These results showed that the nitrogen atom in the SNBDTC collector had a great influence on the adsorption strength of the collector on the mineral surface. This is due to the electron deposition behaviour of nitrogen atoms compared to the electron withdrawing character of oxygen and as such the SNBDTC showed better collecting ability than the PNBX. These results paved the way for the design of collectors for sperrylite and other arsenide minerals and suggested that nitrogen in a collector may significantly improve the ability of the collector for improved recovery. Keywords: Computational modelling, microcalorimetry, SNBDTC and PNBX collectors, adsorption energies

Jan 1, 2020

By J. Ungar, F. X. McGarvey

The selectivity of ion-exchange sites varies with the matrix of the polymer, the nature of the site. and the method of application. The effect of these variables on the recovery of uranium is examined. with particular attention to vinyl pyridine and to symmetrical and asymmetrical quaternary ammonium sites. The effect, on the loading. of high concentrations of chlorides in the liquors is discussed. and other components of the liquors that may cause fouling of the resin are also considered. The discussion is supported by the results of tests conducted on various types of resins. The economics of the process is discussed briefly.

Jan 1, 1981

By D. T. Williamson, B. P. Gilbertson

Satellite observation of mine-dump vegetation by B. P. GILBERTSON, M.Sc. (Phys.) (Visitor) and D. T. WILLlAMSON, B.A., LLB., B.A. Hons. (Visitor) NASA's first Earth Resources Technology Satellite (ERTS-I) was launched on 23rd July, 1972, and has subsequently gathered multispectral imagery of most of Southern Africa from an orbital altitude of 900 km. Images of the Witwaters rand area have been studied in an attempt to differentiate between mine dumps having varying degrees of vegetative cover. At this stage it is clear that the various mine dumps can be located and identified, and differences in vegetative cover can be seen and measured. Patterns of vegetative growth, some characteristic to particular dumps, can also be seen.

Jan 2, 1974

By J. Ungar, F. X. McGarvey

The selectivity of ion-exchange sites varies with the matrix of the polymer, the nature of the site. and the method of application. The effect of these variables on the recovery of uranium is examined. with particular attention to vinyl pyridine and to symmetrical and asymmetrical quaternary ammonium sites. The effect, on the loading. of high concentrations of chlorides in the liquors is discussed. and other components of the liquors that may cause fouling of the resin are also considered. The discussion is supported by the results of tests conducted on various types of resins. The economics of the process is discussed briefly.

Jan 1, 1981

By Z. Luo, W. Chen, Y. Zhao, Y. Fu, L. Dong

The gas-solid dense-phase fluidised bed includes a complex multiphase fluid-particle system; different complex exchanges significantly affect the stability of the fluidised bed. To elucidate the characteristics of fluidisation in a gas-solid dense-phase fluidised bed, this study used experimental performance tests to obtain the static density characteristics, and the attachment and flow characteristic of the dense medium. The results indicate that the bulk density of the dense medium increases first and then decreases with the increase of particle size. The airflow rate difference is used to quantify the wall attachment characteristics of dense medium and the average pressure gradient in the axial direction of the bed is approximately 20 Pa/mm under the fluidisation results. At the same settlement location, with the decrease of fluidisation number, the settlement velocity of large and small particles becomes slower, the boundaries of settlement displacement and location probability are gradually disrupted, and the falling velocity of particles with a radius of 20 mm is faster than that of materials with a radius of 15 mm. This work also established a theoretical basis for regulating the stability and separation characteristics of gas-solid dense-phase fluidised bed. Keywords: Fluidised bed, different size particles, fluidisation characteristics, flotation bubbles, settling motion

Jan 1, 2020

By V. Jokovic

Hydrocyclones are the most commonly used classifiers in the mining industry. The reason for this is their low operating cost and a small footprint. Data from plant trials where screens replaced hydrocyclones indicated that lower bypass of fines and sharper separation could improve breakage rates, with a positive effect on flotation circuit performance throughput. Despite the importance of classification, hydrocyclones have not received as much attention as more expensive comminution units, and their technological progress has been incremental. Noticeable water split (Rf) reductions of a semi-inverted hydrocyclone have been reported in the past. According to theory, the hydrocyclone with reduced Rf will improve classification of fines. A classification study using semi-inverted hydrocyclones was conducted to determine if a hydrocyclone could be operated in a way that would minimise misclassified fines. The classification performance of a semi-inverted hydrocyclone will be presented in this paper and other potential applications will be discussed. Keywords: Semi-inverted hydrocyclone, water split, misclassification of fines

Jan 1, 2020

By H. M. Stewart, N. F. Dawson, J. P. Beukes, P. G. van Zyl, Q. P. Campbell, A. Jordaan, R. I. Glastonbury, L. N. Sadiki

"SynopsisThe physical properties of oxidative sintered pellets produced from typical South African UG2 ore are compared with the physical properties of pellets produced with conventional South African metallurgical-grade chromite ore (from the Lower Group 6 or the Middle Group 1 and 2 seams). A statistical evaluation of the cured (sintered) compressive strengths proved that pellets prepared from UG2 ore are likely to have the same, or better, compressive strength than pellets prepared from metallurgical-grade chromite ore. The cured abrasion strength of the UG2 pellets was also superior to that of the metallurgical-grade pellets. Scanning electron microscopy (SEM) backscatter, secondary electron, and elemental X-ray mapping were used to determine the reasons for the general superior strength of the UG2 pellets. The case study UG2 ore also required 13 kWh/t less energy for milling to attain the required particle size distribution prior to pelletization, which can lead to substantial cost savings. Results presented in this paper can be utilized by ferrochromium (FeCr) producers to better quantify the advantages and disadvantages associated with the use of UG2 ore for FeCr production.IntroductionChromite, a mineral of the spinel group, is the only commercially viable source of virgin chromium units. Geologically, commercial chromite deposits in the world are found in three forms, i.e. alluvial-, podiform-, and stratiform-type deposits (Murthy et al., 2011; Cramer et al., 2004). Alluvial deposits were formed by weathering of chromite-bearing rock with the subsequent release of chromite and gravity concentration by flowing water. However, these deposits are relatively small and of comparatively minor commercial interest. Podiform-type chromite deposits usually occur as irregularly shaped pods or lenses, and their distribution within a mineralized zone is usually relatively erratic and unpredictable, making the exploration of these deposits difficult and costly (Cramer et al., 2004). Stratiform-type chromite deposits occur as parallel seams in large, layered igneous rock complexes with more regular layering and lateral continuity (Cramer et al., 2004). The largest example of a stratiformtype chromite deposit is the Bushveld Complex (BC) in South Africa, which holds an estimated three-quarters of the world’s viable chromite ore resources (Cramer et al., 2004).Several chromite seams exist in the BC. The seams of economic interest are the Lower Group 6 (LG6), the Middle Group 1 and 2 (MG1 and 2), and the Upper Group 2 (UG2) seams (Cramer et al., 2004). The LG and MG seams are specifically exploited for their chromium content, while the UG2 seam is mined primarily as a source of platinum group minerals (PGMs) (Xiao and Laplante 2004). Extraction of the PGMs from the UG2 ore usually involves the liberation of the sulphide by milling and subsequent recovery of the PGM concentrate through flotation (Xiao and Laplante, 2004). Chromite in the PGM concentrate is undesirable; therefore, PGM recovery circuits are specifically designed to ensure maximum rejection of the chromite to the tailings stream. However, the chromite in the PGM tailings can potentially serve as feedstock for ferrochrome (FeCr) production, after beneficiation to increase the chromium content."

Jan 1, 2015

By B. S. Xakalashe, M. I. Khama, Q. G. Reynolds

The carbonaceous reduction of manganese ore is an energy-intensive process that releases large amounts of pollutant gases. In an attempt to circumvent the greenhouse gas emissions, this research investigates hydrogen as an alternative reductant. The reduction of manganese ore with hydrogen results in the structural changes in the intermediate products, which might limit the diffusion of the reactant gases through the pores. Computational fluid dynamics (CFD) models capture the structural changes and predict the rate controlling mechanism and this is key in designing the prereduction reactors. The current work uses CFD models to predict the degree of reduction in a shaft furnace under hydrogen reducing conditions. Manganese ore is described as a collection of scalar and tensor fields such as thermal conductivity of the porous medium, density, and viscous resistance. The results indicate that advection contributes significantly towards the overall transport of hydrogen to the reaction sites. Porosity of the final product was found to be higher than porosity of the raw material.

Mar 4, 2025

By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By J. Petersen, K. Shaik

The traditional route utilised for the recovery of Platinum Group Minerals (PGMs) in South Africa involves the concentration of ore by flotation, followed by smelting to produce a PGM rich matte, which is then digested hydrometallurgically to solubilise base metals and Platinum Group Elements (PGE). HCl/Cl2 is conventionally used for PGE dissolution from concentrated material, which is an aggressive reagent associated with high maintenance costs as well as environmental concerns. Of interest is the leaching of PGMs directly from mineral ores, low grade concentrates and tailings in a cyanide-ferricyanide system as a more sustainable alternative. This system has shown favourable Pt recoveries among the Pt minerals, but with sperrylite (PtAs2) displaying highly refractory behaviour. The dissolution of sperrylite is investigated in a cyanide-ferricyanide system in the context of an electrochemical study involving OCP, chrono-amperometry and cyclic voltammetry. This approach allows the assessment of leaching characteristics as well as the investigation of surface passivation, which is believed to contribute to poor Pt recoveries. Some evidence is presented that such passivation is related to the formation of arsenide species on the mineral surface. Keywords: Sperrylite, PGMs, cyanide, ferricyanide, electrochemistry

Jan 1, 2020

Alexander Sutulov. Mineria Ghilena 1545-1975 (Mining in Chile 1545-1975). Santiago, Centre of Investigation of Mining and Metallurgy, 260 pp. (In Spanish). G. B. Rothenburg. Speciality steels. D.S.A., Noyes Data Corp., 1977. 270 pp. Witbank Middelburg Branch A General Meeting was held at the Wit bank Golf Club on 20th April, 1977, at 17h30. Treatment of waste water An International Research Symposium on New Processes of Waste Water Treatment and Recovery is to be held in London from 6th to 8th September, 1977. It NIM reports Report no. 1708 An examination of the suitability of various reducing agents for the production of ferrochromium. (27th Feb., 1975; re-issued May 1977). Report no. 1724 The preparation and reduction of chrornite pellets containing a reducing agent. (14th Apr., 1975; re-issued Mar. 1977). Report no. 1854 The interaction of pyrite, oxygen, and xanthate. (8th Mar., 1977). Report no. 1876 The ultrasonic determination of the mud level in a thickener and the resin level in an ion-exchange column. (6th May, 1977). Report no. 1878 The electrochemical dissolution of galena in aqueous solutions. (5th May, 1977). Report no. 1881 n-Octylaniline, a new extractant for noble metals.(28th Mar., 1977). Report no. 1883 The determination of iron, chromium, titanium, and tungsten by X-ray-fluorescence spectrometry. (31st Mar., 1977). Report no. 1889 Entropy relations in the formation of complexes of silver (1), mercury (II), and cadmium (II) with llwnodentate liyaruls. (5th May, 1977). Mechanics of granular materials A conference on the above subject is to be held in London on 8th and 9th September, 1977, under the auspices of the Institute of Mathematics and Its Applications.

Jan 1, 1977

By C. S. Kucukkargoz, A. Bhalla

"The solid-state reduction of ilmenite concentrate with graphite was studied under argon atmosphere at temperatures between 1050°C and 1350°C. The rate of reduction increased with increasing temperature and decreasing particle size, with the maximum extent of reduction found to be 80% at 1350oC with a particle size in the range of -106 +90 µm. The activation energy for the reduction reaction was calculated to be 257 kJ/mole. The trivalent iron oxide was reduced first to divalent iron oxide and then to metallic iron. An annular ring of a partially reduced oxide phase containing metallic nuclei was formed around the core of ilmenite, which grew in size as the original ilmenite core shrank with progressive reduction. The reduction of titanium dioxide also took place during this stage, which produced the Magneli oxides in the form of TinO2n-1. The metallic phase had very high Fe and low Ti contents throughout the reduction, whereas the partially reduced oxide phase adjacent to the metallic phase was high in Ti and depleted in Fe. The metallic phase globules formed during this stage were small and are considered suitable only for leaching and not for other concentration processes. The core of the particle generally retained the composition of the original ilmenite. The purpose of this work was to remove iron and increase the titanium oxide content of the ilmenite to produce a high-titanium containing charge for subsequent smelting.IntroductionThe titanium-bearing minerals ilmenite (FeTiO3) and rutile (TiO2) are the primary natural raw materials used in industry to produce titanium metal and titanium-based products. The common titanium-bearing minerals are ilmenite, rutile, anatase, brookite, leucoxene, arizonite, and perovskite. Although the formula of ilmenite is commonly expressed as FeTiO3, the mineral can accommodate Mn and Mg, which are chemically bound in the form of (Fe,Mn,Mg)TiO3. Ilmenite concentrate can also contain Fe2O3 and Al2O3 in addition to the physically separable oxides such as SiO2 and CaO. The crystal structure of ilmenite is an ordered derivative of the corundum structure with a trigonal-rhombohedral symmetry. Fe2+ and Ti4+ ions occupy the octahedral sites, leaving the tetrahedral sites unoccupied. In each FeTiO3 unit, there are three O2- ions creating three octahedral sites, two of which are occupied by Fe2+ and Ti4+ (Wilson et al., 2005)."

Jan 1, 2017

By H. Jiang, W. Wang, Y. Zhao, J. Qiao, C. Duan

DEM simulations were used in this research to study the screening process of a novel variable amplitude equal thickness vibration screen (VAETVS). The response regularity of mass distribution and granular moving velocity at the different screen panels to feed rate was investigated and the predictive model for the unit area processing load was proposed. The influence of aperture size, the size variance, and the opening ratio on the mass passing-distribution and overall screening performance, respectively, were revealed. The results showed that the response model of the unit area load Ф to the feed rate Q can be concluded as Ф∝0.324×Q. The moving velocity of particles also showed a positive relevance to the feed rate, besides which the passing rate of fine-grained material at the feed end was negatively related to the aperture size, while the case was reversed in the feed end. The increase of aperture variance AV enhanced the passing ability of small particles at the feed end,and reduced the misplaced ratio of the large particles at the discharge end. A better screening efficiency can be obtained when the average aperture size of the entire sieve is 7.5 mm, with the aperture variance of 1 mm between the adjacent panels. When the combination of the opening ratio is 35-35-40, a better screening effect can be achieved. Keywords: Equal thickness screening, DEM, particulate velocity, mass distribution regulation

Jan 1, 2020

By А. V. Aksenov, S. G. Rybkin, А. Y. Senchenko

For gold plants in Russia, it is very complicated and costly to use cyanide leaching for efficient processing of gold refractory ores, where gold is closely associated with sulphide minerals and the significant amount of natural carbonaceous matter present. Oxidative roasting of gold refractory concentrates is a well-known method, making it possible to obtain a high recovery rate of precious metals to a target product. The use of oxidative roasting is limited in general by the expense of capturing and neutralising the harmful components of roasted gas, mainly sulphur (SO2, SO3) and arsenic (As2O3) oxides. This paper addresses testing and development of an optimised technology to process gold refractory gravity and flotation concentrates by means of oxidative roasting which stabilises arsenic as calcium arsenate. The process involves roasting of a gravity or flotation refractory ore concentrate in a mixture with lime and calcium chloride, with a supply of oxygen, and at 600-700°С. During the roasting a carbonaceous matter of the concentrate burns out and sulphide components transform into harmless calcium sulphate (CaSO4) and calcium arsenate (Ca3(AsO4)2), and iron passes into the form of hematite (Fe2O3). After disintegration, the roasting cinder is concentrated on a table to obtain a high-grade gravity concentrate and gravity tailings. The high-grade gravity concentrate is subject to smelting in a mixture with fluxing agents, which results in alloyed gold and slag. The gravity tailings are ground and reported to cyanide leaching. In the case of a flotation concentrate, the roast cinder is ground to minus 30 μm and subject to sorption cyanide leaching. High gold recovery (90-95%) of the target product and environmental safety are typical of the improved technology under consideration. Two national patents were granted for the methods developed to treat refractory concentrates bearing precious metals. Keywords: Gold concentrates, oxidative roasting, cinder, cyanide leaching, smelting, alloyed gold

Jan 1, 2020