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By Z. Zhang, J. Niu, H. Wang, Y. Xu, J. Shi

Tribo-electrostatic separation is a promising method for effectively utiliing low-grade magnesite resources by removing quartz and improving the grade of magnesite. To determine the chargeto- mass ratios of pure magnesite and quartz, a triboelectric measurement system was employed, and a laboratory tribo-electrostatic separation system was used to separate low-grade magnesite. The results showed that the maximum difference in charge-to-mass ratio between pure magnesite and quartz particles was observed after friction with polyvinyl chloride. The grade and recovery of magnesite increased with temperature and initially increased with increasing voltage, feed rate, and air flowrate before gradually decreasing. The optimal conditions resulted in a concentrate with 46.91% MgO content and 77.36% recovery, while the quartz content decreased from 7.02% to 1.95%. These experimental results demonstrate the effectiveness and potential of tribo-electrostatic separation in removing quartz and upgrading magnesite.

Apr 14, 2024

By D. Weijie, S. Kai, Y. Hu, X. Ning, M. Shiyi, W. Junpeng, Z. Guihong, L. Xianjie

Flotation is one of the most important processes in the copper production industry. The copper grade in the concentrate is a pivotal indicator of the flotation process performance. However, it is difficult to achieve real-time measurement through hardware sensors. Based on the production data provided by an industrial operation, a novel soft sensor based on multi-layer perceptron (MLP) is proposed for effective monitoring of this pivotal indicator. The proposed soft sensor uses the nonnegative garrote (NNG) to perform global variable selection for MLP, while a local search (LS) approach is incorporated to improve the model presented by NNG. Simulation results show that the proposed algorithm has higher prediction accuracy and better model simplicity than other algorithms. Furthermore, the variables selected are consistent with the field experience, and the developed model can provide reference of feedback control for the optimisation of the process. Keywords: Flotation process of copper ore, nonnegative garrote, local search, soft sensor, multi-layer perceptron

Jan 1, 2020

By T. Bhambhani, J. Jankolovits

Sphalerite flotation using copper sulfate has been performed in the industry for decades and the mechanism of Cu activation is well established. Despite its ubiquity, many practical questions surrounding copper sulfate persist. It is not clear how iron selectivity is achieved in zinc circuits given the propensity of iron sulfides to be activated by copper. Also, the large variation in copper sulfate dosages across different plants and ore types cannot be explained. Lastly, Zn flotation with greatly reduced copper sulfate dosages attracts significant interest and has been demonstrated in certain laboratory settings, but no information is available on why those laboratory solutions have not been adopted in plant practice. Flotation studies are presented that demonstrate that Zn flotation with very low copper sulfate dosages is possible when using certain novel collectors that are not practised in the industry. However, these reagent schemes are impractical because of a heretofore unappreciated and critical role that copper sulfate plays in Fe rejection. With both very low and standard copper sulfate dosages, copper sulfate influences both Zn flotation and Fe rejection. The results highlight the multifaceted role of copper sulfate in zinc flotation and the need to holistically consider complex systems’ behaviour to understand flotation reagent mechanisms and optimise plant performance. Keywords: Sphalerite flotation, metal activation, copper sulfate, iron rejection

Jan 1, 2020

By Q. Cui, B. Z. Zhou, Z. G. Song, Y. G. Zhu, G. B. Zheng

The complex refractory Cu-Pb-Zn polymetallic ore in Xinjiang, China is a massive sulphide ore with complex mineral components. In the past two years, the ore mineralogy has changed, resulting in a decline in metallurgy, with too much zinc reporting to the lead and copper concentrates. A detailed mineralogical study indicating the presence of secondary copper minerals, which could be activating the sphalerite early in the present circuit, was used to develop a novel reagent and flotation flowsheet termed “Pb-Cu co-flotation, Cu intensified flotation, Zn flotation”. It was tested and found to significantly contribute to improving the flotation performance of the ore. In the Pb-Cu co-flotation circuit, successful depression of pyrite and sphalerite was achieved using a BK612- Na2S based depressant system. Most of the galena and some of the Cu bearing minerals with excellent floatability were collected with the use of the selective collector BK906. The rest of Cu bearing minerals were floated in a copper Z200 circuit using a BK537-lime-zinc sulphate based depressant scheme. Zinc flotation from the copper tailing was performed in a SIBX circuit using lime as a pyrite depressant. Using the proposed flowsheet, overall Pb, Cu, and Zn recovery increased significantly to 88%, 87%, and 90% respectively. Keywords: Complex polymetallic ore, Cu-Pb-Zn, Pb-Cu co-flotation, particle size

Jan 1, 2020

By M. R. MacIver, M. Pawlik, S. Finora, H. Alizadeh

The dispersion of mature fine oil sands tailings (MFT) by the addition of sodium lignosulfonate was studied using contact angle measurements, optical scattering, and particle size measurements. Lignosulfonate caused the release of residual bitumen to the slurry surface and settlement of fines. Dynamic contact angle by captive bubble measurements were carried out on bitumen to determine the effect of the dispersant on the wettability of bitumen. Lignosulfonate caused a change in the aggregation state of the MFT and increased sedimentation of particles, as indicated by optical scattering measurements. Zeta potential measurements indicate that this change was caused by an increase in adsorption of lignosulfonate onto particles, which caused improved settling of the colloid. Ultraviolet Visible (UV) spectrophotometry and organic carbon content measurements showed that only a small amount of the reagent remains in the aqueous phase of the tailings, which is critical for decontamination of recycled water. Keywords: Oil sands tailings, bitumen recovery, dewatering, dispersion, surface chemistry

Jan 1, 2020

By C. C. Birch

Due to grade estimation uncertainty, two statistical errors can occur. The Type I error is where material is classified as ore and mined, despite the true value being below the break-even grade. This material is dilution. The Type II error is where the material is estimated to be below the cut-off grade and is classified as waste, although the true grade is actually above the break-even grade. This material is not mined and is lost. The uncertainty was assumed to follow a normal distribution in a previous study. For this study, estimated block values are compared to those determined after mining (the best estimate of the true grade). This actual data from four mines shows that the uncertainty follows a Laplace. There is no single solution regarding adjusting the cut-off grade away from the break-even grade, considering estimation uncertainty, that could be applied to all gold mines. However, adjusting the cut-off grade downwards (up to 22% for one mine) is noted when optimizing the profit considering grade uncertainties. This type of adjustment could open up significant mining areas and extend the life of the mine.

Jul 2, 2022

By M. Kumral, Y. A. Sari

Underground mining operations tend to have higher operating costs than surface mines. When metal prices decrease, profitability is jeopardized due to the high costs. Therefore, mining management harnesses new practices that increase operational efficiency. One way to manage this challenge is to invest in new mine planning practices. Stope layout optimization as a part of underground mine planning aims to identify a portion of the orebody in the form of production volumes (stopes) to maximize profit under roadway and stope dimension constraints. In this paper we propose a novel approach based on identifying ore-rich areas of the deposit and prioritizing their extraction through an iterative heuristic clustering approach. The proposed approach is compared with and validated by an exact method through a small mining example. The heuristics produced nearly identical results in a very short time. Finally, a case study was carried out using a larger data-set. The cluster-based iterative approach generated nearoptimal stope layouts in a computationally effective manner.

Mar 1, 2021

By Xiang-nan Zhu, Hao Zhang, Lin Li, Jun Qiu, Yue-xian Yu, Chun-chen Nie, Xian-jun Lyua

Waste printed circuit boards (WPCBs) are excellent metal resources. Mineralogical characteristics of different components in WPCBs were analysed in this study. Organic-enriched particles, fibreglass-enriched particles, associated particles and metal-enriched particles were obtained by density gradient method. Subsequently, the elemental composition, morphology, dissociation characteristics, functional group composition and phase composition of different components were analysed by X-ray fluorescence spectrometer (XRF), scanning electron microscopy and energy dispersive spectrometer (SEM+EDS), infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). Elemental analysis results show that Cu is mainly contained in metal-enriched particles. SEM+EDS analysis results demonstrate that ideal dissociation can be achieved when the WPCBs are broken to -1 mm. Organic matter particles are enriched with carbon and oxygen elements, while fibreglass particles and associated particles mainly contain Al and Si elements, verified by XRD analysis. FT-IR results show that hydrophilic and hydrophobic groups exist widely in all components, caused by widespread organic matter. This study reveals the important properties of different components in WPCBs, which is of great significance for the subsequent separation process. Key words: Waste printed circuit boards, mineralogical analysis, elemental composition, dissociation; phase analysis, functional group composition

Jan 1, 2020

By A. N. Clay, N. N. Moeketsi, S. Joubert

For many years, mine-impacted water has been regarded as a problem and linked to long-term environmental liabilities. However, this water can be a renewable and a sustainable resource, provided that it is managed in a responsible and sensible manner. South Africa’s National Water Resource Strategy (NWRS, 2013) considers water that can be used to contribute to economic activity to be a water resource. Although all water resources are considered as belonging to the State, government does not appear to have meaningfully explored the use of mineimpacted water to contribute to the country’s economic activity. Africa is blessed with more sunshine than anywhere else, apart from Australia, yet we see no rollout of vast quantities of solar panels to ensure every African family has access to affordable power. This suggests that governments are incapable of managing such a free resource. At the same time, apart from the equatorial areas, water is a seriously constrained resource and yet we expect the same entities to manage a commodity none of us can live without. This paper explores the conversion of mine-impacted water from waste to a resource and how the inclusion of other stakeholders (such as water users, landowners, and ordinary South Africans) could benefit the process.

Jan 2, 2022

By A. J. S. Spearing, M. Sharifzadeh, K. V. Jessu

Empirical pillar design methods are commonly used in the mining industry. The parameters within which these methods are valid are frequently unknown to the user or ignored. In addition, empirical design may not consider essential parameters such as blasting effects, orebody dip and the presence of geological structures, which all adversely affect the stability of the pillars. This can result in potentially serious pillar design strength over-estimates. Although the commonly based tributary area method is generally conservative, as the spans are seldom that large relative to the depth, failing to consider other relevant parameters can result in errors. Problems associated with an under-designed pillar can range from a local pillar collapse to a catastrophic chain reaction collapse (or run). Over-designed pillars are generally safe but reduce the extraction of the orebody, thus adversely affecting the profitability of the mining operation. We used laboratory tests and numerical modelling to understand the effects of pillar orientation, blasting and the presence of discontinuities on pillar strength. Reduction factors were developed with these models to be implemented in conjunction with the existing empirical pillar design methods. For any pillar or mine design, once it is implemented, the actual performance of the system must be checked regularly by observation and monitoring and adjusted if needed. The pillar design approach outlined in this paper can better optimize the pillar mining method by considering other generally ignored but important parameters, thus improving safety, productivity, and economic aspects.

Oct 1, 2022

By R. J. Davidson, W. D. Douglas, J. A. Tumilty

SYNOPSIS Two pilot plants operating on different types of carbon were used to generate steady-state adsorption data in the treatment of gold-plant solutions of high and low tenor. A pilot plant comprising three 4 m long columns and using 3 mm extruded activated carbon was used to treat pregnant solutions with a gold concentration of 5 to 8 g/t at pH 10 to 11,5. Column influent was pumped at a super¬ficial flow velocity of 0,5 m/min while the carbon was moved daily so as to effect gold loadings on the carbon of 5 to 10 k /t. With a carbon-bed depth of 12 m, an adsorption efficiency of 99,9 per cent was obtained in a bed depth of 9 m, which was subsequently reduced to 8 m when the depth of the carbon bed was reduced to 8 m. This improvement in efficiency was attributed to the reduced residence time of the carbon from 12 to 8 days. A corresponding decrease in adsorbed silica indicated that some silica fouling of the carbon had occurred. A second pilot plant, comprising a single column 6 m in length and using coconut-shell carbon of 1,0 to 2,4 mm, treated a solution with a gold concentration of 0,7 g/t at pH 8,0. Feed solution was pumped at a superficial flow velocity of 1,0 m/min while carbon was moved every 8 hours to give gold loadings of more than 5 kg/t. An adsorp¬tion efficiency of 99,5 per cent was indicated at steady state. Intermittent washing of the column with dilute hydrochloric acid was shown to have a beneficial effect on the gold adsorption and to reduce the pressure drop across the column. Intermittent washing with dilute sulphuric acid indicated that there had been some passivation of the car¬bon during the treatment of a solution with a gold concentration of only 0,2 g/t. Compared with other adsorption systems, the countercurrent moving bed appears to offer significant advantages in terms of metallurgical efficiency and capital investment. The inability normally associated with moving-bed systems to treat solutions containing suspended solids may be overcome to a degree by the use of relatively coarse extrud¬ed carbon.

Jan 1, 1985

The May General Meeting of the Institute was held in Kelvin House, Johannesburg, on 21st May, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present twenty-two Members, including Messrs F. P. Bath, M. Bareza, A. R. C. Fowler, D. M. Jamieson, C. M. Mavrocordatos, D. G. Maxwell and J. A. Nixon (Council Members), Messrs T. Davidson, G. L. Diering, E. T. Dunstan, D. E. H. French, K. Hodgson, O. A. E. Jackson, A. F. Lee, A. Louw, D. L. Starkey, R. K. Wheeler and M. Youngworth. Four Associate Members including Messrs D. Blair Hook and G. R. Still. One Student Mr N. A. Barcza. Thirteen Visitors, including Messrs S. H. Ash, D. L. G. Bayne, E. Bayne, S. Bell, W. S. Garrett, L. S. Gibbs, R. C. Hamilton, M. Maguire, D. Rose and J. D. van Niekerk. Total Present: Fourty-one. OBITUARY The Vice-President: "It is my sad duty to announce the death of the following member of the Institute: Thomas Spence Haldane, Member, who joined the Institute in 1924 and passed away on 21st December, 1968. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, those present stood and observed silence for a few moments. MINUTES The Vice-President requested that confirmation of the minutes of the previous meeting be held over as they would only be appearing in the Journal of the following month. He also requested that confirmation of the minutes of the 75th Anniversary Meeting be held over. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the under-mentioned candidates have been published in accordance with By-Law 5.2.2, and Council has elected them to membership of the Institute in the following grades: Members: Gideon Jacob Haumann, Peter John Cumming, Ian Stanley Dudman, Roderick Goldston Murchison. Associate Members: Francois Alwyn Beyers Fouche, Alan Marsh, Johannes Petrus van der Westhuysen, Waldo Edmund Stumpf, Ian Nicholas Ridley. Affiliates: Lutgerus Kolver Jooste, Roger Ainsley Ralph Kebble, Edward John Wainwright, Lewis William Davies. Graduate: Clive Graham Knobbs. MEMBER TRANSFERED TO A HIGHER GRADE From Student to Associate Member: Diethard OUo Eduard Fahrbach. I welcome the newly elected members to the Institute and congratulate the member who has been transferred to a higher grade." (Applause).

The May General Meeting of the Institute was held in Kelvin House, Johannesburg, on 21st May, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present twenty-two Members, including Messrs F. P. Bath, M. Bareza, A. R. C. Fowler, D. M. Jamieson, C. M. Mavrocordatos, D. G. Maxwell and J. A. Nixon (Council Members), Messrs T. Davidson, G. L. Diering, E. T. Dunstan, D. E. H. French, K. Hodgson, O. A. E. Jackson, A. F. Lee, A. Louw, D. L. Starkey, R. K. Wheeler and M. Youngworth. Four Associate Members including Messrs D. Blair Hook and G. R. Still. One Student Mr N. A. Barcza. Thirteen Visitors, including Messrs S. H. Ash, D. L. G. Bayne, E. Bayne, S. Bell, W. S. Garrett, L. S. Gibbs, R. C. Hamilton, M. Maguire, D. Rose and J. D. van Niekerk. Total Present: Fourty-one. OBITUARY The Vice-President: "It is my sad duty to announce the death of the following member of the Institute: Thomas Spence Haldane, Member, who joined the Institute in 1924 and passed away on 21st December, 1968. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, those present stood and observed silence for a few moments. MINUTES The Vice-President requested that confirmation of the minutes of the previous meeting be held over as they would only be appearing in the Journal of the following month. He also requested that confirmation of the minutes of the 75th Anniversary Meeting be held over. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the under-mentioned candidates have been published in accordance with By-Law 5.2.2, and Council has elected them to membership of the Institute in the following grades: Members: Gideon Jacob Haumann, Peter John Cumming, Ian Stanley Dudman, Roderick Goldston Murchison. Associate Members: Francois Alwyn Beyers Fouche, Alan Marsh, Johannes Petrus van der Westhuysen, Waldo Edmund Stumpf, Ian Nicholas Ridley. Affiliates: Lutgerus Kolver Jooste, Roger Ainsley Ralph Kebble, Edward John Wainwright, Lewis William Davies. Graduate: Clive Graham Knobbs. MEMBER TRANSFERED TO A HIGHER GRADE From Student to Associate Member: Diethard Otto Eduard Fahrbach. I welcome the newly elected members to the Institute and congratulate the member who has been transferred to a higher grade." (Applause).

By M. P. Brandt, T. P. Knoetze, I. I. M. Kessler

It has generally been accepted that the volatile mater in a coal is the factor that determines whether or not a specific coal dust is an explosion risk. This paper presents the results of an attempt to relate the explosibility index (Kex) of South African coals, as determined in a AD-litre explosion vessel, to the volatile mater content of the coal and the calorific value of the volatiles. A good relationship between the calorific value of the volatiles and the explosibility index was established, which makes it possible to calculate the violence of an explosion, as expressed by Kex, for South African coals. The Kex value is but one of a number of parameters that influence the explosion hazard in a specific colliery and cannot be used as the sole predictor of the propagation of an explosion underground. Other parameters include the ignitability of the coal, temperature, humidity, dispersibility of the dust, methane concentration, amount of incombustibles present, and ventilation.

Jan 1, 1993

By N. V. Moraka

Calls for transformation in the mining sector are legislated. Whilst the composition of boards in terms of gender diversity and equal representation has improved, little is known on how women directors experience boardrooms. This research investigated the experiences of South African women in male-dominated mining boards. It questions why women remain marginalised in boardrooms, even when they are qualified as the men in their respective fields. The experiences of South African women on male-dominated mining boards were investigated by means of a multiple case study using a qualitative research methodology. Interviews were conducted with 16 women and 12 men serving across six JSE-listed South African mining companies. The findings show that irrespective of their qualification and experience, women,s, contributions are often ignored, and they are assigned to more social roles. Regardless of race, all women experienced gender stereotyping. Strategies are required to ensure that board cultures embrace female talent, where women can effectively contribute to decision-making and maximize their talent. It is argued that gender and identity should be studied in relation to post-colonial history in African countries. Women have multiple, varying identities, and their experiences require a unique investigation that would enable strategies to overcome barriers, through the implementation of an appropriate diversity management programme.

Feb 12, 2024

By M. Izadi Yazdan-Abadi, S. H. Amiri, M. Ramezanizadeh, M. Bazmandeh

Iron ore concentrate is used as the fresh feed of pelletising plants. The green pellet properties depend on iron concentrate characteristics such as particle size distribution (PSD), specific surface area (Blaine value), iron grade, moisture content and grinding methods. The grinding methods affects particle size distribution and Blaine value. To find out the effects of grinding methods on pelletising process, green pellets were produced with concentrates that were reground by means of HPGR (high pressure grinding rolls) and ball mill. The Blaine values of ground concentrates in both types of milling were approximately 1400, 1600 and 1800 cm2/gr. The results of green pelletising tests on a pilot plant scale showed that at the same Blaine values, drop numbers of green pellets produced by ground concentrate inside HPGR were higher than the green pellets produced by ground concentrate inside a ball mill. Also, reground concentrates by means of HPGR, in comparison with ball mill, caused the production of green pellets, at higher wet and dry compression strengths. As a result, it was found that preparing the pelletising feed by means of HPGR led to more positive effects on the properties of green pellets. Keywords: Ball mill, HPGR, green pellet, drop number, wet and dry compression strengths

Jan 1, 2020

By X. Xiang, W. Xia, J. Yin

"TiCl4 slurry containing valuable metals is an unavoidable by-product of the titanium ore chlorination process. The recovery of these valuable metals, which include titanium, niobium, tantalum, and aluminum, is an urgent issue to tackle in the titanium industry. The results of this investigation show that the valuable metallic elements can be recovered from the slurry by evaporation in a sealed container and leaching with dilute hydrochloric acid. After evaporation at 200°C for 60 minutes, nearly 99% of the titanium was recovered in the form of TiCl4, which was formed by the reaction of the TiO2 in the slurry with AlCl3. After evaporation, metals like niobium, aluminum, and tantalum remained in the residue. By leaching with 2.1 mol/L HCl at a L/S ratio of 6:1 mL/g at 80°C for 60 minutes, the soluble metals, such as aluminum, iron, and copper were all removed from the residue, and the niobium and tantalum were further enriched in the leach residue. A concentrate containing 53.40 wt% Nb and 5.57 wt% Ta was obtained by washing the leach residue with dilute aqueous ammonia under stirring. A potential waste water purifying agent containing 263.75 g/L AlCl3 was produced by purifying the leaching solution with Al(OH)3 and modified polyacrylamide. IntrodutionTitanium tetrachloride (TiCl4) is an important intermediate in titanium metallurgy that is widely used in the production of titania and titanium sponge (Akhtar, Xiong, and Pratsinis, 1991). In conventional titanium metallurgical processes, high-titanium materials such as synthetic rutile and high-titanium slag are reacted with chlorine to produce TiCl4 in a fluidized-bed furnace. Accompanying elements, such as Al, Nb, and Fe also react with chlorine to form chlorides, which are mixed with gaseous TiCl4 (Anderson, 1917). In the condensation process, gaseous TiCl4 is refrigerated and high-boiling-point chlorides are precipitated in the liquid TiCl4 to form a slurry containing 50~60 wt% TiCl4 (Wang, Xiang, and Wang, 2012).Various methods have been proposed to recover TiCl4 from the slurry, including microwave heating and spray drying (Wang, Xiang, and Wang, 2012, Wang et al., 2010a). To date, the only way to recover the TiCl4 is to return the slurry to the fluidized-bed furnace. However, this causes fluctuations in the temperature in the furnace, resulting in incomplete reaction between titanium-rich materials and chlorine. Therefore, the slurry is often rinsed with water and neutralized by adding lime, which caused serious environmental pollution and wastes a valuable resource (Roy, Bhatt, and Rajagopal, 2003)."

May 1, 2019

By J. L. Havenga, L. J. van der Walt, J. T. Nel, H. Bissett

"SynopsisNew technologies used to manufacture high-quality components, such as direct laser sintering, require spherical powders of a narrow particle size distribution as this affects the packing density and sintering mechanism. The powder also has to be chemically pure as impurities such as H, O, C, N, and S causes brittleness, influence metal properties such as tensile strength, hardness, and ductility, and also increase surface tension during processing.Two new metal powder processes have been developed over the past few years. Necsa produces zirconium powders via a plasma process for use in the nuclear industry, and the CSIR produces titanium particles for use in the aerospace industry.Spheroidization and densification of these metal powders require remelting of irregular shaped particles at high temperature and solidifying the resulting droplets by rapid quenching. Spherical metal powders can be obtained by various energy-intensive methods such as atomization of molten metal at high temperatures or rotating electrode methods. Rapid heating and cooling, which prevents contamination of the powder by impurities, is, however, difficult when using these methods for highmelting- point metals. For this reason plasma methods should be considered.Thermal plasmas, characterized by their extremely high temperatures (3000–10 000 K) and rapid heating and cooling rates (approx. 106 K/s) under oxidizing, reducing, or inert conditions, are suitable for spheroidization of metal powders with relatively high melting points. Thermal plasmas for this purpose can be produced by direct current (DC) plasma arc torches or radio frequency (RF) inductively coupled discharges. In order to obtain chemically pure spheroidized powder, plasma gases such as N2, H2, O2, and CH4 cannot be considered, while Ar, Ne, and He are suitable. Neon is, however, expensive, while helium ionizes easily and it is therefore difficult to obtain a thermal helium plasma at temperatures higher than 3000 K. Therefore argon should be used as plasma gas. Residence times of particles in the plasma region range from 5–20 ms, but this is usually sufficient as 7–8 ms is required for heating and melting of titanium or zirconium metal particles in the 30 µm size range at 3500 K. In this study the melting and spheriodization of titanium powders was investigated by DC non-transferred arc and RF induction plasma methods. The powders were characterized before and after plasma treatment by optical microscopy and scanning electron microscopy (SEM) to observe if any melting or spheroidization had occurred."

Jan 1, 2015

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015

The November General Meeting of the Branch was held in the St. Helena Club at 8.00 p.m. on the 17th November, 1970. Mr J. N. Saunders (Chairman) was in the chair. There were also present six fellows, N. A. Honnet, C. J. Isaac, J. G. Kirchner, (Committee Members), J. M. Meyer, S. L. S. Swart and J. W. Wilson; seven members, D. V. Baum, M. de Lange, A. H. Edwards, G. J. G. Emere, E. R. Penny, G. P. Rundle, C. G. J. Vermeulen; six graduates, N. Mayer, H. Miller, E. J. Shillaber, P. J. H. Short, M. H. Smith, T. R. Stromsoe; five associates, M. Andriesse, A. E. Hooper, A. Paschalides, R. L. Solms, W. M. Todd; one student, J. C. Simms and 14 visitors. Apologies for absence were received from Messrs L. O. W. Leimer and G. Y. Nisbet. MINUTES OF THE ANNUAL GENERALMEETING The Minutes of the Annual General Meeting held on the 27th August, 1970, were taken as read. Their adoption, which was proposed by Mr N. A. Honnet and seconded by Mr J. G. Kirchner, was carried unanimously. MINUTES OF THE JULY GENERALMEETING The minutes of the General Meeting held on the 8th July, 1970, were taken as read. Their adoption, which was proposed by Mr C. J. Isaac and seconded by Mr J. G. Kirchner, was carried unanimously. GENERAL BUSINESS Members were advised that no more applications could be entertained for the visit to Western Holdings; they could, however, still apply to visit Welkom Mine and Harmony. TALK The Chairman invited Mr A. Paschalides to deliver his talk on 'Controlled blasting in stopes and new explosives developments'. The presentation proved to be of great interest to the meeting and lively discussion followed the talk. Mr N. A. Honnet proposed a vote of thanks to Mr Paschalides on behalf of all members of the O.F.S. Branch. CLOSURE The Chairman thanked Mr Paschalides for his talk and all present for their attendance, and as this was the last meeting for 1970 he wished all members a Merry Christmas and a Happy New Year. He declared the meeting closed at 9.30 p.m.