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By R. Barany

The heats of formation of anhydrous ferric sulfate and anhydrous indium sulfate were determined by solution calorimetry. At 298.15° K the heats of formation from the metal, rhombic sulfur, and oxygen were -615.6 ±O.7 kcal/mole for ferric sulfate and -649.6 ±O.6 kcal/mole for indium sulfate. Heats of decomposition at 298.15° K are given for the reaction that forms metal oxide, sulfur dioxide, and oxygen) and for the reaction that forms the metal oxide and sulfur trioxide.

Jan 1, 1965

By A. L. Engel

High extractions of lead, gold, and silver resulted from treatment of an oxidized, arsenical refractory ore by chloride volatilization. The ore was roasted in an oxidizing atmosphere at 1,000° C. for 1 hour. The chloridizing reagent was 300 pounds of CaC12?2H20 per ton of ore. Ninety-nine percent of the lead, 98 percent of the gold, and 96 percent of the silver, and only 6 percent of the arsenic, were volatilized. These results indicated that a satisfactory method could be developed for treating this type of ore. Recovery and separation of the volatilized values and developing metallurgical and operating data for this process require further investigation on a more extensive scale. Tests by gravity concentration, flotation, and cyanide leaching did not give satisfactory results.

Jan 1, 1958

By D. J. Bauer

A solvent-extraction system employing selective stripping of a pre loaded organic phase was investigated for recovering Sm203 from a light-group rare-earth mixture. The samarium concentrated in the organic phase, and a >99-pct-pure samarium oxide product was obtained at 76-pct recovery in a 20-stage operation using di(2-ethylhexyl) phosphoric acid (EHPA) as the organic phase. The stripping agent was a 1.5-pct hydrochloric acid solution containing 200 g NH4C1/1.

Jan 1, 1972

By William Seymour, L. D. Schmidt

A preliminary survey of coke and steel plants conducted by the Bureau of Mines in cooperation with the Office of the Solid Fuels Administrator for War and with the advice of the Coke Production Committee indicated that production of pig iron could be increased. appreciably if present blast furnaces were supplied with a more uniform coke.4/ Nonvarying percentages of ash , sulfur , and fixed carbon in the coke , together with uniform physical characteristics , such as size , strength , and porosity , would aid the blast -furnace operator greatly in his trial - and - error methods of obtaining maximum production . With nonuniform raw materials he must employ certain factors of safety in operation , such as an excess of coke , an excess of limestone , and operation of the furnace below the maximum rate . Even so , he often has trouble from iron not being up to specifications , hot tops , high blowing pressures , furnace hanging up , etc. The more uniform his raw materials (of which coke is probably the most important) , the nearer to ideally can he run his furnace and thereby save raw material and increase production . One cause of nonuniformity of the coke produced by ordinary American plant practice is the prevailing lack of precise control of the bulk density ' of the coal charge in the byproduct oven . This report summarizes the available information on the subject of bulk density of crushed coal and its control . It includes brief reviews of some of the literature , some results obtained at plants visited by the authors , and results of a few preliminary tests made at the Pittsburgh Station of the Bureau of Mines .

Dec 1, 1943

By Oliver Bowles

This report covers the character, properties, origin, occurrence, and uses of the traprocks and describes briefly the methods and equipment employed in quarrying and preparing them for market. Production of traprock occupies an important place in industry. In 1960 the output in the form of crushed stone reached nearly 58 million tons valued at $87 million. Traprocks are also shaped into blocks of dimension stone for monuments, building construction and decoration, and specialized products such as surface plates.

Jan 1, 1963

By R. L. Grayson, W. E. Wallace, J. W. Stephens, M. D. Attfield, P. S. Brower, V. Vallyathan, M. J. Keane, J. C. Harrison

Pure respirable quartz is a known pathogenic agent for lung disease. However, for mixed dusts, neither mineralogical nor in vitro cytotoxicity assays unequivocally predict the contribution of quartz to their pathogenic potential.First, although Coal Workers' Pneumoconiosis (CWP) and Progressive Massive Fibrosis (PMF) prevalence have been found to correlate with total respirable coal mine dust exposure, and with coal rank (Attfield and Morring, 1992), epidemiological studies generally have not found the quartz component of coal mine dust as measured by X-ray diffraction or infrared spectroscopy (each of which essentially measures the mass-percent quartz in a bulk sample) to be clear predictors of CWP prevalence or incidence (Walton et al., 1971). Second, the properties which distinguish the extreme fibrogenic potential of quartz are not revealed by conventional in vitro bioassay comparison with other silicate mineral dusts. As an example, quartz and kaolin (aluminosilicate) clay in vitro cytotoxicities are comparable for lavaged primary pulmonary macrophages.The studies discussed here address these two anomalies from a general hypothesis that the pathogenic activity of respired quartz particles is associated with properties of, and interactions with, the particle surfaces. One factor in the expression of toxic activity by a particle surface is the biological availability of that surface. Anomalous lack of correlation of disease prevalence with mass percent quartz in exposures to some mixed composition respirable-sized dusts suggests that individual particle surface features, invisible by bulk sample mass analysis, may alter the biological availability of a fraction of quartz particles in a dust. For pure-surfaced mineral particles, the comparably strong prompt membranolytic activities of quartz and kaolin in vitro suggest that upon deposition of such particles in the lung there must be other interactions with particle surfaces which distinguish quartz. This might be due to toxic surface-associated sites specific to silica, or to interactions of other sites on other mineral particles which affect the biological availability of their toxic functional groups. For example, alurninol groups on clays affect the availability or activity of adjacent silanol groups. Surface activities which distinguish quartz pathogenici ty might be manifest in one or more of the sequential interactions upon deposition in the lung; first with the pulmonary surfactant system, then with extracellular and phagolysosomal enzymatic digestive processes, or with subsequent cytotoxic processes.

Dec 1, 1995

By H. R. Shell, Robert C. Johnson, Wilbur H. Warwick

Alpha silicon nitride fibers , Si3N4 , were successfully grown in graphite crucibles by a new method utilizing silicates and silicon ( S in equations below) as sources of silicon and using carbon , aluminum , and silicon as reducing agents (R in equations below ) . The basic reaction mechanism is believed to be generally as follows : 1,300 - 1,500 ° C S + R + N₂ SiO + RO + N₂ › 3Si0 + R + 2N₂ _1,300 - 1,500° C 3RO + Si¸N • ( 1 ) ( 2 ) A build - up of coatings on the solid raw- material particles hindered the evolution of silicon or silicon monoxide vapor and thereby slowed down further formation of silicon nitride fibers . Free oxygen in the crucible caused the formation of amorphous silicon dioxide ( SiO2 ) fibers . This problem was solved by passing , entering , and exiting gases through layers of lump graphite inside the reaction vessel . The silicon nitride fibers grew best around 1,400 ° C. Nitrogen flow rates from 4 to 6 liters per minute were adequate . The fiber widths were generally only a few microns whereas their lengths sometimes reached one - quarter inch or more . Chemical and X- ray analyses indicated that bulk fiber samples were usually 80 to 90 percent Si3N4 . The fibers had good oxidation resistance to about 1,260 ° C. Thermal shock resistance was excellent . Electrical resistance was determined .

Jan 1, 1964

By Helen W. Lang

This report describes a monitoring system applied by the Bureau of Mines to provide rapid, continuous determination of the main constituents of exhaust gas during the Bureau's approval schedule testing of diesel engines for under-ground use. Commercially available continuous analyzers with strip chart readout are employed for nitric oxide (mass spectrometric), carbon dioxide (nondispersive infrared), methane (NDIR), carbon monoxide (NDIR), and oxygen (polarographic). Good correlation is obtained between the continuous instrumental results and those obtained by batch chemical and gas chromatographic methods.

Jan 1, 1969

By J. E. Tiffany, Z. C. Gaugler

In presenting this list of permissible explosives and blasting devices , the Bureau of Mines desires to call attention to pages 16 and 23 , outlining the conditions in use under which , and only under which , the explosive or blasting device is permissible . In view of publications recounting trade practice favoring the use of a blasting device without stemming , particular emphasis is placed upon condition 4 on page lt and condition 2 on page 23 .. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming .

Dec 1, 1943

By John Campbell, Miller. W. E., G. W. Jones

"INTRODUCTION Because of its interest in accident prevention, the Federal Bureau of Mines has cooperated with city officials and utilities in investigating the causes of explosions in sewers, manholes, and other underground spaces and has aided in the development of means to prevent such explosions. For several years this Bureau has cooperated with the Boston Edison Co. and the Boston Consolidated Gas Co. of Boston, Mass.,for the purpose of detecting and eliminating combustible and physiologically harmful gases in manholes in Boston and vicinity.These investigations 5/ have shown that combustible gases from the usual sources — leakage from gas—distributing systems and underground tanks and gasoline wastes — can be located and the dangerous conditions remedied by a well—planned, adequately supervised, systematic, and continuous manhole survey. However, other types of gas contamination, termed ""soil"" gases, are present in manholes at times and are more difficult to eliminate because they have no fixed origin and because seasonal and barometric chances affect their production and passage into the manhole. Soil gases usually are abnormally high in carbon dioxide and low in oxygen and contain varying amounts of methane. They are especially dangerous to men entering manholes because they lack sufficient oxygen to support life."

Feb 1, 1940

By J. R. Hauger, P. A. Romans, W. J. Niebuhr

With suitable instrumentation and techniques it is possible to determine the presence of tantalum in columbium to 20 ppm . This paper discusses the selection of X- ray spectrographic instrumentation and describes a technique for accomplishing the low level determination of tantalum . An ion- exchange method of separating tantalum from columbium is also described .

Jan 1, 1964

By Richard H. Oitto

The Bureau of Mines and Kaiser Steel Corp. are cooperatively demonstrating the shield-type roof support in the longwall mining of a 10-1/2-foot-thick coalbed at the York Canyon mine near Raton, N. Mex. As part of the demonstration, the shield supports have been successfully and safely moved from a completed longwall face to a new longwall face. When these shield supports were moved in 1976 they were the largest and heaviest longwall support system in use in U.S. coal mines. The shield supports, preparations for moving them, the actual move, and installation at the new face are discussed.

Jan 1, 1977

By K. K. Kelley, L. B. Pankratz

The heat contents of four silicate minerals -- akermanite , cordierite , gehlenite , and merwinite --were measured from 298 ° to around 1,700 ° K by the dropping method . The results were compiled into tabular and equation forms suitable for thermodynamic calculations . The heat contents of these compounds are nearly additive with respect to their constituent oxides .

Jan 1, 1964

By Jalna R. Zatko

The Bureau of Mines has developed and constructed an apparatus that is capable of measuring concentrations of high-molecular-weight polymers in solution at 10 ppm and less. A means for determining low concentrations of polymeric solutions was devised that was independent of slight fluctuations in solvent quality in order to measure polymers in effluent prior to recycling of the recovered solution. The concentrations of polymers ore related to a measured pressure drop observed during turbulent flow of the solution. Low concentrations of polymers of ethylene oxide and acrylamide (frequently used as flocculants for clay waste systems) in aqueous and salt solutions have been successfully measured on the apparatus constructed by the Bureau.

Jan 1, 1981

By E. V. Cilento, K. A. DiGregorio, R. C. Lantz

"An electro-optical method was used to quantify superoxide (SO) release from single rat pulmonary alveolar macrophages (PAM) exposed in vitro to respirable quartz and kaolin dusts and in vivo to quartz. Release was determined by measuring the reduction of nitroblue tdrazolium (NBT) to a diformazan precipitate at 550 nm from video-recorded images of individual cells. In vitro exposure to 0.025 or 0.05 mg/ml kaolin for 40 minutes resulted in no significant differences in either the total diformazan produced (max) or the maximum rate of diformazan production (R)./n vitro exposure to 0.025 mg/ml c1uartz decreased max 38 percent while no significant change was found using 0.05 mg/ml. However, R was decreased 31 percent and 24 percent for the low and high dose, respectively. In contrast, PAM obtained from animals exposed in vivo to quartz dust for two or four weeks in inhalation chambers exhibited increased production of diformazan. However, only PAM analyzed three days post-exposure showed significant increases, while PAM from animals sacrificed ten or 31 days post-exposure were not significantly different from control. The combined in vitro and in vivo quartz results might suggest that there is an initital acute response to exposure that decreases the ability of PAM to produce SO, followed by recruitment of production of PAM with increased SO producing capability. It appears that removal of animals from the source of exposure permits PAM to return to control levels of SO production by31 days. Whether this would be true for chronic exposure remains to be elucidated.IntroductionPulmonary alveolar macrophages (PAM) protect the lungs by phagocytizing foreign debris and bacteria.(1) This process involves ingestion as well as destruction of foreign matter. Phagocytosis usually is accompanied by a respiratory burst which increases cellular oxygen consumption leading to the release of highly reactive oxygen metabolites.(2) These agents have been implicated in the killing of bacteria by phagocytes, but they have also been shown to be toxic and,have been linked to cancer, emphysema, arthritis, diabetes, and other diseases.(3) Toxic effects may be a result of 1) an abnormally low production of metabolites, resulting in damage to lung tissue by the respired bacteria and/or dusts; or 2) an abnormally high production resulting in direct damage to lung tissue by metabolites themselves."

Mar 1, 1989

By R. D. Govier

The U.S. Bureau of Mines has developed a thin-film X-ray fluorescence technique to rapidly determine Cu, Ni, Co, Fe, and Cr in super alloy leach liquors. Total analysis time per sample was less than 15 min, as opposed to several hours for traditional wet chemical methods. Precision and accuracy were checked by replicate analyses of solutions similar in composition to leach liquors, whose analyte concentrations were well known. Coefficients of variation for all elements were found to be less than 2 pet. With the exception of the results for Fe, all relative errors of estimation were also found to be less than 2 pet. Bulk liquids are not introduced into the spectrometer; thus, the potential for damage to the instrument by leakage of corrosive liquids is eliminated.

Jan 1, 1989

By Robert W. Freedman

Vacutainers are employed by the Bureau of Mines and the Mining Enforcement and Safety Administration for sampling mine air and other atmospheres containing fixed gases, low-molecular-weight hydrocarbons, and products of combustion. Tests were conducted to study shelf life of evacuated samplers prior to sampling and also to check the stability of sampled gases prior to analysis. An unexplained phenomenon, slow accumulation of carbon monoxide in evacuated samplers, occurred after a few weeks' storage; levels were low but increased with time and could pose a problem for critical applications. Accordingly, attempts to halt CO release by additional means of treatment were made, and storage at low temperature was found to be effective.

Jan 1, 1978

By Oliver Bowles

Chalk is defined as a noncrystalline, soft, friable, fine-grained, light-colored type of limestone. It consists essentially of calcareous shells of minute organisms known as "foraminifera," although skeletal remains of molluscs, corals, and sponges are also present. Flint balls which are found so commonly in the chalk cliffs of Europe are regarded as segregations of the remains of certain organisms, such as radiolarians and sponges, that secrete siliceous shells or spicules. The famous chalk beds of northwestern Europe are of Upper Cretaceous age, a geological period that was particularly favorable for the develop- ment and multiplication of foraminifera. The distinguishing physical characteristics of true chalk never have been fully defined; probably its noncrystalline and colloidal properties are most important. The properties of chalk, whiting, and whiting substitutes are not well understood, and much re- search is necessary before definite reasons may be ascribed for the behavior of these materials under various conditions of use. The Bureau of Mines has undertaken a detailed study of chalk and similar materials to determine their exact properties and to establish a basis for classifying formations loosely designated as chalk occurring in various parts of the United States, but the results of this study will not be available for some months. Whiting is a pulverized, purified, and carefully sized chalk. Whiting substitutes consist of finely ground limestone or dolomite, ground marble (marble flour), white marl, and chemically precipitated calcium carbonate.

Jul 1, 1931

By L. B. Pankratz

Enthalpies above 298° K were investigated for four crystalline sodium borates by copper-block drop calorimetry. Determinations were made to 1,200° K for NaB02, 1,003° K for Na2B407, 1,005° K for NaB305, and 1,046° K for Na2Be013. No phase transitions or other thermal anomalies were found. The enthalpy determinations, when combined with known heats of formation at 298° K and other supplementary data, enabled the calculation of the heats and free energies of formation of the compounds to their melting points. Values of relative enthalpies, entropies, heat capacities, free energy functions, enthalpies of formation, free energies of formation, and equilibrium constants of formation were tabulated at even temperatures.

Jan 1, 1971

By Noel N. Moebs

The Bureau of Mines conducted five reconnaissance magnetometer traverses across a small abandoned chromite mine in the State Line district of Pennsylvania and Maryland to determine the geophysical response of the area. The results indicate that more extensive geophysical surveys of the region might establish some worthwhile guidelines for chromite exploration. While chromite only rarely can be detected directly by magnetic methods, there is a possibility that geophysical signatures in the adjacent host rock could provide some guidelines for further exploration. Prior to 1875, all the chromite produced in the United States came from the State Line district, and the potential for discovering additional podiform deposits could be significant. Virtually no state-of-the-art geuphysical or geochemical studies have been conducted in this district since World War II and sizable areas remain undeveloped and suitable for exploration. While the results reported in this paper are not supported by drilling, it may encourage others to investigate the area more fully for improved methods of detecting subsurface podiform chromite deposits. New theories on the emplacement of ophiolites also could contribute to an assessment of the chromite potential of the serpentinite belt.

Jan 1, 1991