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By W. E. Wallace, P. S. Raghootama, M. S. Seehra, C. A. Hill, M. J. Keane, P. Mike

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte hemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz, kaolin, and alumina dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect cf lecithin adsorption. Dust hemolytic potential versus media pH are presented. Fourier transform infrared spectroscopy and photoacoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis.Introduction Quarts dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and' progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction. In the alveolar spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, sagas other functions, mechanically stabilises the lung from collapse by reducing the surface tension of water in the alveolar sacs.(1) This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11% in dog lavage fluid). and phospholipids (about 88%).(2) Fhosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalaitoyl lecithin (DPL).(2) Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occuring upon deposition of a particle in a pulmonary alveolus.(3)"

Jan 1, 1988

By C. A. Herbert

Timber decay is due largely if not wholly to a fungus growth on the timber from which it derives' food; a warm, moist atmosphere is necessary for rapid growth. The decay is spread from infected timber to sound timber by countless microscopic spores or seeds given off by the fungus growth and carried by air currents or by long, cottonlike threads, which spread from timber to timber. Haulage roads in most mines in the central coal fields are also return aircourses; hence moisture and temperature conditions are ideal for the rapid decay of mine ties and mine timber. Possibly the return air, which contains a higher percentage of carbon dioxide than normal outside air, also stimulates the growth of fungi. Those familiar with coal mining have observed the more pronounced growth of fungi and decay of timber in poorly ventilated worked-out sections of mines where the air is moist and where usually the percentage of carbon dioxide in the air is considerably above normal.

Jan 1, 1934

By J. D. Tolman

In view of present interest in a revival of gold mining enterprises, papers dealing with the development of small gold properties are apropos. The present paper deals with the operation of a small gold property in the exploration and development stage, mining and milling 25 tons of ore daily, and indicates what may he expected in the way of mining costs under northern climatic conditions, by practicing rigid economy, at a property where disproportionate overhead costs are unavoidable bacause of the small rate of production. The output of this prospect is treated in a small amalgamation plant which has been described in a previous circular.. HISTORY Prospecting in the district was begun in 1909, and by 1911 the adjoining mines, Hollinger and McIntyre, were in operation. Actual work was begun on the Rochester claim in July, 1922, and carried on through 1924. The property was closed until 1928 when the present company took it over, together with the other holdings of the Canadel Mining Co. A small mill was started as a pilot plant on March 24, 1929, and is still in operation.

Jan 1, 1931

By P. D. Kovscek

The Bureau of Mines has tested a low-thrust water-jet-assisted rotary drill. This work was performed to evaluate the performance of a water-jet-assisted drill operated at thrust levels typical of a handheld manual-thrust operation. Prior work by the Bureau had indicated that using water-jet assist with high-thrust drilling applications would increase drilling rate. Small-diameter holes were drilled in five different types of rock. Thrust and water pressure were varied as the drill rate was monitored. The test results indicate that drilling rates increase with increasing water pressure and thrust. The water jet has more effect on reducing the specific energy when drilling in the harder rocks than in softer rocks. Variation in drill rate for a given rock sample is attributable primarily to the material heterogeneity within the sample. One rock type (Greenwich sandstone) could not be drilled efficiently with the water-jet-assisted drill.

Jan 1, 1988

By Knox Van Dyke, Vincent Castranova, Lixin Wu, Mark J. Reasor, James M. Antonini

"One of the proposed mechanisms involved in the pathogenesis of silicosis is that inhaled silica dust activates a ""respiratory burst"" in pulmonary phagocytes, such as macrophages and neutrophils. This increase in oxidative metabolism results in enhanced generation of reactive oxygen species which if produced in excess, would overwhelm natural defense mechanisms and cause damage to the lung parenchyma. This damage would then result in scarring, fibrosis, and decreased gas exchange.Weiss and LoBuglio' have listed several oxygen species produced by phagocytes which may be involved in cellular injury. These oxidants include superoxide anion, hydrogen, peroxide, hydroxyl radical, and hypochlorous acid. Superoxide anion (0;) is generated from molecular oxygen by the plasma membrane bound enzyme NADPH oxidase according to the following reaction:Once generated, superoxide anion can form hydrogen peroxide:In the presence of myeloperoxidase and halide, hydrogen peroxide can form hypochlorous acid:Superoxide and hydrogen peroxide can also form highly reactive hydroxyl radicals. Hydroxyl radicals can be generated slowly by the Haber-Weiss reaction:In addition. hydroxyl radical production can be catalyzed via the Fenton reaction:Hydroxyl radicals can also be generated from the reaction of superoxide and hypochlorous acid as follows:Recent investigations suggest that, in addition to the reactive oxygen species discussed above, nitric oxide may be a potential mediator of silica-induced toxicity.2-4 Nitric oxide (NO') can be generated by the cytosolic enzyme nitric oxide synthase according to the following reaction:NO synthase exists in two forms. i.e.. a constitutive. Ca2+-calmodulin-dependent form and an inducible. Ca2+-calmodulin-independent form. In pulmonary phagocytes. the activity of the constitutive form of NO synthase is low. However. NO synthase can be induced in macrophages and neutrophils by a variety of stimulants such as lipopolysaccharide. interferon y. chemotactic peptide, platelet activating factor, or leukotriene B4.3.5Once generated. nitric oxide can combine with superoxide anion to form peroxynitrite as follows:Peroxynitrite is a potent oxidizing agent. In addition, peroxynitrite can form peroxynitrous acid. which in turn can produce hydroxyl radical and nitrogen dioxide (all of which exhibit strong oxidizing potential) by the following reactions:Oxygen metabolites have been shown to cause lung damage in vivo.6 Such damage includes edema. leakiness of the alveolar endothelial/epithelial barriers, and airway constriction.7 Superoxide and hydrogen peroxide have been associated with membrane damage and cell lysis.8 These oxidants have also been associated with alteration of cytoskeletal structures at cell-cell junctions and elevation of transepithelial conductance in cultured monolayers.9 Macrophages or neutrophils can be stimulated by bacteria or phorbol myristate acetate to produce sufficient oxidant levels to lyse lymphoma cells.10 This cell killing is inhibited by catalase but is unaffected by superoxide dismutase. hydroxyl radical scavengers. or azide. i.e., an inhibitor of peroxidase. This implicates hydrogen peroxide as the active oxidant. Similarly. Weiss et al.11 have reported that hydrogen peroxide is critical in the death of cultured endothelial cells due to neutrophil activation. In addition. hydroxyl radicals generated by monocytes have been associated with cell injury.12 Lastly. peroxynitrite has been shown to oxidize sulfhydryl groups and to inactivate proteinase inhibitor making the lung more susceptible to damage caused by phagocytotic enzymes.' Therefore. a strong case can be made that activated pulmonary macrophages and neutrophils are capable of causing oxidant injury. This chapter presents in vitro and in vivo data indicating that silica is associated with the production of reactive oxygen species from these pulmonary phagocytes."

Jan 1, 1998

By Jr. Watts, B. K. Cantrell, D. H. Carlson, K. L. Rubow

"The use of diesel equipment in underground coal mines is controversial because ""whole diesel exhaust"" is regarded as ""a potential occupational carcinogen"" by the National Institute for Occupational Safety and Health (NIOSH). Threshold limit values (TLVs) are recommended for the gaseous pollutants; CO, CO2, NO, NO2, SO2, and some hydrocarbons emitted in diesel exhaust. There is, however, no TLV recommended for diesel exhaust aerosols (DEA) nor is there a standard method for sampling these aerosols.The University of Minnesota and the Bureau of Mines have collaborated to develop a personal diesel exhaust aerosol sampler (PDEAS) which utilizes size selective, inertial impaction and gravimetric analysis. During the field tests of this sampler, numerous air quality measurements were conducted in underground coal mines using diesel equipment. The objective of this report is to present these data and to assess the impact of diesel face haulage equipment on mine air quality.Air quality data were collected in four underground coal mines using continuous mining methods with diesel haulage equipment. Daily samples were collected at the section intake, haulageway, and on haulage vehicles. Both full-and partial-shift samples were collected using a variety of aerosol instruments, including the PDEAS and the micro-orifice, uniform deposit impactor (MOUDI) which sample the mine aerosol diesel exhaust fraction. Two of the mines were also monitored for the major gaseous constituents found in diesel exhaust CO, CO2, NO, NO2, and SO2. These measurements were made by either collecting bag samples for subsequent gas analysis or by Palmes dosimeters.The concentrations of CO, CO2, NO, NO2, and SO2, were well below regulated levels. The mine average DEA concentration determined by the PDEAS in the haulageway for the three mines surveyed using this instrument was 0.79 mg/m3, with a standard deviation of 0.19 mg/m3. DEA contributed 65% of the respirable aerosol, at this location. These results were the same as the mean DEA concentrations calculated from size distribution measurements obtained using the MOUDI. This was 0.78 mg/m3, with a standard deviation of 0.22 mg/m3."

Mar 1, 1992

By E. D. Gardner, Edmund Stein

"IntroductionMassive sulphides occurring in metal mines are inflammable and furnish the fuel for many mine fires. Actual sampling has shown that dangerous amounts of sulphur dioxide and hydrogen sulphide may occur in mine atmospheres after blasting in massive sulphides. Probably some .of the finer sulphide in the material being blasted burns while it is in contact with the flame from the explosion. It’s also possible that oxygen of the explosive enters into the reaction.That sulphide dusts are explosive under some conditions has long been suspected, but the theory has not been generally accepted as having been proved. Evidence now at hand appears to be conclusive that such explosions do occasionally occur in mine workings in massive sulphides. Information from several mines working in heavy sulphides shows that occasionally, sulphur dioxide in larger amounts than could be expected from the blasting alone are occasionally thrown out into the mine atmosphere during blasting. Accidents have occurred and lives have been lost by men being caught in such gases. Also it appears in a few cases that damage done to timber in stopes by concussions has been greater than could 112.ve been expected from the regular blasts. In most of these cases the unusually large amounts of Sulphur dioxide could only be accounted for by an explosion or by an ignition of sulphide dusts. When this occurs it is probable that the settled dust is stirred up by the first shot of a round, then the dust cloud is ignited by this or a succeeding shot.In one instance, the senior author, while wearing breathing apparatus, returned to a station to take a gas sample immediately after a raise round had been blasted, and encountered a heavy white fume or smoke that was corrosive to the skin and which forced a retreat. The sample, which was taken farther back in a greatly diluted atmosphere, showed a high percentage (0.18) of sulphur dioxide. The station and the raise which was just being started were very dry and the walls and floor of the station contained settled sulphide dust which apparently was ignited by the blast."

Mar 1, 1928

By Robert W. Geehan

"INTRODUCTION The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States since 1939. Many of the mines were developed.A preliminary examination of the Sultan mine was made in January 1945 by the author, who recommended investigation by drifting and crosscutting. The Bureau conducted a project at the mine from April to June 1946. Claims investigated are in sec. 20, T. 25 S., R. 58E., Mount Diablo base and meridian, in southern Clark County, Nev., about 7 miles southwest of Good-springs.The Sultan mine has been an intermittent producer of zinc-lead-silver ore since 1910. During World War II, ore was shipped to the Government stock pile at Jean, Nev., and to the International Smelting& Refining Co.'s smelter near Salt Lake City, Utah. Throughout the past year, ore has been milled and the concentrates have been shipped to the smelter."

Sep 1, 1947

By J. B. Cheung

The results of a program to demonstrate the technical feasibility of hydraulic borehole coal mining are presented in this report. The hydraulic borehole method of coal mining involves inserting a hydraulic mining device into a borehole that has been drilled from the surface into the underground coal bed. The borehole mining device issues a jet of water under high pressure, which breaks the coal. These pieces of coal, along with the water, form a slurry, which flows to the base of the borehole where it is pumped to the -surface. Phase I of the program encompassed the design, fabrication and factory-testing of a hydraulic borehole mining device. The program was successfully completed with the field tests being conducted at the Wilkeson-Carbonado Coal Field near Wilkeson, Washington. The technical feasibility of hydraulic borehole coal mining was demonstrated by mining 32 tons of coal at a depth of about 75 ft over a period of 4 hours.

Jan 1, 1976

By John Paul Gries

During World. War II, when the curtailment of imports led to an unprecedented demand for domestic mica, beryl, spodumene, and other pegmatite minerals, the Bureau of Mines and the Geological Survey entered upon a program designed to expedite mining of these minerals from the Black Hills area of South Dakota. The program involved napping, sampling, and drilling of many pegmatite dikes in the southern portion of the Black Hills and beneficiation conducted in the field and in the Bureau of Mines laboratories at Rapid City, S. Dak., Rolla, Mo., Salt Lake City, Utah, and College Park, Md. This report describes the occurrence and sampling of the Beecher No. 2 pegmatite, which was investigated as part of the general pegmatite study in South Dakota. Investigation of the Beecher No. 2 pegmatite was started on November 20, 1943, and terminated in the spring of 1944. During this period, the Bureau of Mines took a series of trench samples across the pegmatite at the surface for grain-count studies and chemical analyses. The Geological Survey mapped the geology of the deposit after it was exposed by trenching and stripping.

Jan 1, 1950

By R. R. Wells

This report summarizes the results of laboratory testing of copper-bearing magnetite ore from the Poorman, Bush & Brown, and Copper Center deposits, Kasaan Peninsula, Prince of Wales Island, southeastern Alaska. The ores contain minor amounts of chalcopyrite and pyrite. Intimate association of these sulfides with magnetite necessitates fine grinding for adequate liberation and rejection of copper and sulfur and for the production of high-grade iron concentrate low in objectionable impurities. Laboratory tests indicated that the optimum results can be obtained by flotation of ore ground to minus-100-mesh, with subsequent wet magnetic separation treatment of the flotation tailing. A summary of results obtained by this treatment of the three samples tested is shown in table 1.

Jan 1, 1957

By Richard A. Winters

In 1987, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 34,680-acre Lime Canyon Wilderness Study Area (NV-050-231) to evaluate its identified mineral resources. The Wilderness Study Area is in Clark County, NV, about 30 air miles southwest of Mesquite, NV. The area studied contains an estimated 44 million tons of indicated subeconomic resources of gypsum, an inferred subeconimic resource of limestone and dolomite, and occurrences of gold, copper, uranium, and zeolite. The Wilderness Study Area is underlain chiefly by carbonate rocks with lesser amounts of sandstone and shale. Metamorphic, granitic, and volcanic rocks also crop out within the area. Large portions of the area are overlain by alluvium. The Wilderness Study Area is within the Gold Butte mining district. Several gold mines with past production are nearby to the south of the Wilderness Study Area; one mine is reported in operation on a small scale. Several silver-bearing copper and zinc mines with past production are nearby to the east of the Wilderness Study Area

Jan 1, 1988

By Bernard Porter

The rate of the heterogeneous reaction between high-purity uranium metal and uranium tetrafluoride in molten lithium fluoride was measured. The apparent heat of activation for the reaction is 16.91 kilocalories per mole of UF4. A surface-controlled mechanism is suggested in which UF4 is adsorbed on the uranium metal surface. Additional UF4 reacts with the adsorbed species and the metal site to form an activated complex that decomposes to the product UF3. The reaction is an important source of metal loss in the electrowinning of uranium metal.

Jan 1, 1966

By A. B. Cecala

The Bureau of Mines has developed a pallet loading dust control system designed to lower the dust exposure of workers during the bag stacking process at mineral processing facilities. The system makes bag stacking much easier because the pallet height remains constant throughout the entire bag stacking cycle through the use of a hydraulic lift table. The system uses a push-pull ventilation technique to capture the dust generated during bag stacking. A low-volume, high-velocity blower system operating at approximately 150 cfm blows a stream of air over the top layer of bags on the pallet. The blower system is composed of two 3-in air jets (approximately 1,200-ftjmin velocity) directed toward an exhaust system on the opposite side of the pallet. As these air jets travel across the pallet, they entrain the dust generated during bag stacking. The exhaust ventilation system pulls approximately 2,500 cfm of air and dust through the exhaust hood. This exhaust air can then be dumped into a baghouse ventilation system, or filtered before being discharged outside the mill. During a laboratory evaluation, a 70-pct dust reduction was recorded for the bag stacker. The system was then evaluated in an actual working environment. The first field evaluation was performed at a silica sand operation in which one worker performed the entire loading and bag stacking process. This worker's dust exposure was lowered 76 pet when using the new pallet loading system. The second field evaluation showed only moderate dust reduction, but this was mainly attributed to an overriding problem associated with background dust and the cleanliness of the bags. From both the ergonomic and production standpoint, the system was well received by both the workforce and plant management.

Jan 1, 1988

By L. B. Pankratz

Thermodynamic data on the sulfides were reviewed, evaluated, and compiled at the Bureau of Mines Albany Research Center. Values for Cp°, S°, H°298 -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf are given in tabular form. Cp°, H° - H°298, ?Hf°, and ?Gf° are also expressed algebraically.

Jan 1, 1987

By Thomas L. Vandergrift

This U. S. Bureau of Mines (USBM) report evaluates three stress-transfer-modification concepts for their potential in reducing longwall gate road stresses and closures. In each of the three concepts - packwalling, gob infilling, and entry filling -support structures are constructed on the headgate side of the panel parallel with or inby the face line. When the headgate becomes the tailgate of the adjacent panel, these structures are in place to accept stresses transferred from the mined-out panel. Using the USBM nonlinear boundary-element program MULSIM/NL, baseline models of typical longwall stress transfer behavior were developed for both intermediate depth and deep mining conditions. These models were verified by comparing model results with field measurements and observations. The stress-transfer-modification concepts were then incorporated into the deep baseline model to quantify the effects of each concept on tailgate closure. Modeling results indicated that entry filling is the most effective concept in reducing tailgate escapeway closure. Using only 18 m3 of a weak fill per meter of face advance (7.3 yd3 per ft of face advance), tailgate escapeway closure was reduced by 33%. By improving the quality of the fill, similar results were achieved using 50% less volume.

Jan 1, 2010

By T. E. Gray

This report describes the preparation characteristics of the more significant coalbeds in Monongalia County, W. Va. It is one of a Bureau of Mines series planned to determine coals suitable for producing metallurgical coke, either as mined or after beneficiation. Over 9.5 million tons of coal was produced in Monongalia County in 1957, of which more than 7 million tons was cleaned mechanically in 8 cleaning plants. On January I, 1954 the Bureau of Mines estimated that 1,576 million tons of recoverable coal remained in the county in beds 28 inches or more thick.

Jan 1, 1960

By Wesley A. Grosh

The Valzinco mine, Spotsylvania County, Va., is a lead-zinc deposit with minor quantities of copper. The property was reopened n 1942 by Panaminas, Inc. The Bureau of. Mines, in an effort to increase the reserves of the deposit to justify greater production, diamond-drilled nine holes totaling 4,213 feet during 1943. Drilling by the Bureau delimited the original ore body and discovered another ore body on the hanging-wall side, which was being developed by the company at the close of the project.

Jan 1, 1949

By R. V. Higgins

This report presents the results of a study of water injection in the HX sub-pool fault block V-B, in the Upper Terminal zone, Wilmington field, California, and is based on data obtained to May 1957. An earlier report3/ describes the results of gas injection in part of the field. The principal purpose of the pilot flood was to determine whether a sand having a permeability of 1,200 millidarcys and containing oil having a viscosity of 17 centipoises could be waterflooded effectively. The results of a preliminary study by engineers of the Long Beach Harbor Department of oil recoveries from areas where encroaching edgewater was active and the results of an independent study by a consultant retained by the Long Beach Harbor Department were favorable to a trial waterflood. After these preliminary studies, a detailed petroleum-engineering exam-ination was made of the technical details. As a result, a peripheral flood was started in June 1953. The peripheral flood was deemed desirable because the producing wells are bottomed a short distance from the edgewater. The HX subpool was selected for the pilot test because it is an isolated section of the Upper Terminal zone and is separated from the adjoining pools by faults on the east and west and by edgewater on the north, south, and west. Several petroleum-engineering methods were applied to evaluate the performance of the waterflood, and all showed that injecting water stimulated oil production.

Jan 1, 1958

By G. W. Birge

As a part of its overall program of coal carbonization, the Bureau of Mines is studying the coking properties of coals that may be used for metallurgical purposes. The objectives of this study were given in detail in a previous report.2/ The inherent suitability of coal for metallurgical use depends primarily on (1) chemical composition, (2) preparation characteristics, and (3) carbonization behavior. The first two factors, as well as the available reserves, are considered in selecting coals for carbonization tests. The selection of coal beds in Westmoreland County for coking tests was based, in part, on estimates of the coal reserves by Dowd,3/ who estimated the recoverable reserves in beds 28 inches or more thick, in thousands of tons, as follows: [ ]

Jan 1, 1957