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By A. J. Davidson

A Cu-conducting solid electrolyte was used to develop the sensor. Instead of measuring the potential across the electrolyte from the reference material to the Cu-containing phase, a potential was applied and the stable current measured. This gave reasonable readings for copper-tin alloys, which agreed with the theoretical calculations, but was less satisfactory in the case of mattes because the surface area of electrolyte presented to the matte phase varied from sensor to sensor. To overcome this problem the potential was applied, the current was measured and then reversed and remeasured and the ratio of the currents was calculated. The current ratio is shown to be independent of the resistance of the electrolyte and the surface area of the electrolyte offered to the melt, but strongly dependent on the activity of the copper

Jun 21, 1905

By G. G. Roy, R Shekhar

Pachuca tanks are extensively used for the cyanide leaching of gold and the carbonate leaching of uranium, processes in which oxygen mass transfer plays a very important role. Experiments were carried out to clarify the effect of design and operating parameters on oxygen mass transfer. Parameters such as the ratio of tank height to tank diameter, the ratio of draught-tube diameter to tank diameter and the tank design were found not to influence oxygen mass transfer. Results also showed that equal superficial gas velocities may be used as a criterion for scaling up oxygen mass transfer in both full-centre-column and free-air-lift Pachuca tanks with clear water. A volume-averaged, volumetric gas-liquid mass-transfer coefficient (k'av) was used to characterise oxygen mass transfer in full-centre-column tanks. The axial dispersion model was used to determine k'av. The resulting model used only tank geometry and air flow rate as inputs for the prediction of k'av in industrial-scale tanks. Predictions from the model show clearly that "local" mass-transfer coefficients, measured at one or two locations, may not adequately represent gas-liquid mass transfer in industrial tanks. It is therefore necessary to obtain an estimate of k'av

Jun 18, 1905

By J. A. Hudson, X. D. Pan

A rock mass responds to excavation according to the properties of the intact rock, the network of contained discontinuities and the susceptibility of the rock mass to weathering. Large deformation often occurs when one of these components causes the rock mass to have a low strength relative to the stress conditions. Analysis of such large deformations forms a significant feature of current numerical modelling in rock mechanics. A practical large deformation problem of roadways in a coal mine is described, demonstrating the requirements for improving numerical techniques. The development of a numerical model is then summarised with particular attention to several concepts pertinent to large deformation analysis in geomechanics. A numerical case study is presented in which the developed finite-element model is used and the results are compared with the in-situ measurements. Conclusions are drawn for rock engineering that are also relevant to both civil engineering and mining engineering projects

Sep 1, 1991

By G. B. Harris, A. R. Laplante

Fine tungsten was used to mimic gold and fine and coarse silica and magnetite to mimic gangue. The optimum flow rate of fluidisation water varied from 1.7 l/min for fine silica to 5.6 l/min for coarse magnetite. Overloading at optimum flow rate was then investigated. With fine silica gangue no overload occurred under any of the conditions studied, and there was very little overload with fine magnetite. Coarse silica caused appreciable overload, but only after a significant bed of tungsten had been formed; with fine magnetite gangue the onset of overloading occurred earlier. Finally, with coarse magnetite severe overloading occurred almost immediately. Overloading was modelled using a first-order kinetic rate constant for erosion of the concentrate bed and a critical mass of constant above which it takes place. The results clearly demonstrate the importance of removing oversize to maximise recovery, particularly with a high-density gangue

Jun 18, 1905

By G. E. Christidis, P. W. Scott

The deposits were formed from low-temperature alteration of pyroclastic rocks. Properties investigated include their cation exchange capacity, swelling capacity, pH, rheological properties, the green and dry compressive strengths, shatter index, wet tensile strength, compactability and permeability. It was found that deposits with abundant opal-CT have poor physical properties. The rheological and swelling properties were found to be influenced by the bentonite grade (smectite content) and the degree of disaggregation of the smectite quasi-crystals. The only deposits of high grade which had good foundry properties were those with no opal-CT. Hydrothermal alteration was detrimental to the physical and chemical properties of bentonites in that it decreased the smectite content and the pH and changed the smectite layer charge and the lattice dimensions

Jun 18, 1905

By M. Bustillo, S. Ordonez

"Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The Mississippi Valley-type deposits occur in massive, homogeneous dolostones from which diagenesis has obliterated all primary sedimentary structures. The mineralisation forms irregular, lens-shaped stratabound bodies, mostly in the lower part of the dolostones. They are composed exclusively of sphalerite, galena, pyrite, marcasite and barite, with white sparry dolomite a common cementing phase. Mineral zoning can be recognised from pyrite and marcasite in the east to barite in the west. Sphalerite, the most common sulphide, occurs basically as colloform and banded crusts and galena as isolated cubic or skeletal crystals, mainly in the centre of the banded botryoidal sphalerite. The combined observations of the deposits' geology, geochemistry and ore petrology suggest a three-stage genetic model: carbonate sedimentation in a shallow-water environment; dolomitisation, probably after compaction, by fluids of connate origin and lateral evolution; and mineralisation by migrating solutions, perhaps related to oil-field brines, that originated in deep zones of the basin during diagenesis of the basinal mudrocks in the NE"

Apr 1, 1995

By B. Tiryaki, O. Z. Hekimoglu

Shearer drums are a critical component in the overall performance of coal shearers, with the cutting performance depending very much on the disposition of cutter tools on the drums (the tool-lacing arrangement). A series of practical and theoretical studies has been undertaken to investigate aspects of shearer drum vibration in terms of circumferential pick spacing. A number of commercially available drums were redesigned and the lacing patterns compared with those of the original drums under near-uniform conditions. Mine trials were carried out at the Middle Anatolian lignite mine in Turkey with drums fitted on Eickhoff type EDW-230 double-ranging drum shearers. It was found that the performance of drums could be improved if the concept of circumferential pick spacing was taken into account in CAD packages along with the existing design parameters such as cutting rate, reduced dust, low pick consumption and low down-time

Jun 19, 1905

By B. Denby

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. The design and scheduling of open pit operations are consistent problems encountered by the surface mining industry. Numerous techniques and algorithms have been developed to assist the mining engineer in the creation of optimum development strategies. Virtually all the practical techniques that have been produced have concentrated on one of the aspects (limit definition or scheduling) at the expense of the other. It has long been recognised, however, that the two activities are intrinsically linked and thus solving either problem independently of the other can only ever produce sub-optimal results as a whole. This has been termed the "circular reasoning problem". It has also been recognised that, for all practical-sized situations, solving both problems simultaneously is virtually impossible using conventional techniques due to the massive size of the search space involved. A technique is presented which is based on a self-learning genetic algorithm, which provides a combined pit limit and extraction schedule simultaneously in order to maximise the NPV (net present value) of the extraction. The theory is developed in two-dimensions and a number of examples of its application are presented. It is proposed that this approach is a highly efficient, heuristic technique offering the potential to transcend the circular reasoning difficulties of separate pit limit and extraction scheduling systems. Extension of the technique into three-dimensions and its application to realistic problem sizes are discussed

Apr 1, 1994

By R. J. Pine, J. S. Coggan

Distinct-element modelling has been used to study the mechanisms associated with observed deformation of the western face of the quarry. A complex failure mechanism involving distinct planar surfaces that was proposed for a slope failure in 1967 has been modelled and shown to be plausible. In addition, deep-seated flexural toppling may contribute to the slope instability. Modelling has confirmed the detrimental influence of a raised water-table on the stability of the slope and also indicates that the observed cyclic opening and closing of tension cracks may be attributed to seasonal rise and fall of the groundwater level

Apr 1, 1996

By D. K. Bose, R. H. Rakhasia, V. D. Shah, J. C. Sehra

A series of experiments was conducted to determine the effects of roasting temperature, soaking period and quantity of soda ash added. At a laboratory scale, under optimum conditions of roasting at 873 K for 2 700 s with soda ash 10 wt% in excess of stoichiometric, molybdenum recovery was 99%. The investigations indicate the technical feasibility of producing high-purity MoO3 by combining the roasting process with carbon adsorption/desorption. The process uses low-cost chemicals, can be scaled up readily and is free of the SO2 pollution generated by conventional roasting, as the sulphur content of the concentrate is converted to sodium sulphate

Jun 18, 1905

By M. V. Swain, N. Bristow, R. D. Dukino

During mining, crushing and handling the size of iron ore lumps decreases. Key factors in determining the amount and size of fines that are produced are the mechanical properties of the ore. In a continuation of earlier work on the same ores the mechanical properties of three Australian iron ores from Yandi, Koolan and Mt. Whaleback were determined. In particular, fracture toughness was investigated in greater detail by examining its relationship to crack length using the compact tension test. The elastic modulus and strength of the ores were also determined in flexure and compression. The results were interpreted using Weibull statistics, enabling the ores to be ranked according to strength and elastic modulus. These results, together with data on the mechanical response of the ores to stress and observations concerning the effect of mineralogy on cracking, provide a coherent understanding of the mechanisms involved when the ores fracture

Jun 18, 1905

By M. Moinpour, Y. K. Rao

The catalysed direct reduction of copper sulphide with carbon and lime was investigated in the range 850-1000 degrees C using Cu2S-CaO-C and Cu2S-4CaO-4C reaction mixtures. The effects of the catalytic additives K2CO3, Li2CO3, Na2CO3, NaF, Na2SO3 and the ternary eutectic (K,Li,Na)2CO3 were determined. Potassium carbonate, sodium fluoride and the ternary appear to be the most effective catalysts for the direct reduction process. The rate enhancement of the catalysed carbothermic reduction of copper sulphide in the presence of lime was explained in terms of the catalysis of the Boudouard reaction

Jul 1, 1991

By P. H. Morris

To achieve the full potential of sub-aerial co-disposal the properties of the co-disposed wastes must be known and understood. A description is given of the morphology and properties of waste deposits that were formed during 19 field trials of sub-aerial co-disposal at the dual Goonyella-Riverside mine in Queensland and at Hunter Valley No.1 and Warkworth mines in New South Wales

Jun 19, 1905

By A Cox

It has been demonstrated that all the cadmium from spent batteries, typically 4 g per battery, can be recovered by burning polyvinyl chloride waste to yield hydrogen chloride; this reacts to produce volatile calcium chloride, which can then be condensed and collected in a separate reactor. Alternatively, chlorine may be used to chlorinate the cadmium with equal efficiency. There is also a prospect of using very low concentrations of these gases, less than 1%, to effect the separation. The Cd was recovered more quickly when exposed to sustained, controlled flow rates of chlorinating gases, whereas when PVC was burnt most of the gas was produced in a very short time, not allowing complete reaction. This problem can be overcome by recirculation of the gas into the reactor. The technology is efficient and clean and the equipment used is simple, enhancing the prospects for a pilot-scale version of the process

Jun 21, 1905

By H. K. Taylor, B. Denby, L. D. Smith

Contributions by H.K. Taylor and G.A. Davis discuss the three papers published in Transactions IMM A, vols. 103 and 104, with responses by Smith and Dowd

Dec 1, 1995

By P. E. J. Pitfield, S. D. G. Campbell

The regional structure of shear and deformation zones in the belt, which is recognisable in plan view on Landsat TM images, is interpreted in terms of a conjugate-shear model. Gold mineralisation is related to this framework at a variety of scales. The principal recurrent structural geometries hosting deposits at mines such as Motapa, Durban, Charliesona, Cecil, Sunace, Turk group, Queens district, How, Peter Pat, Matabele Sheba, Goodenough, Old Nic and Bushtick are associated with shear zones and folds and include conjugate systems (shears, shear intersections, kink sets), side-step systems (en echelon segmentation, duplexes, monoclinal inflections, antiform-synform couplets) and interactions of the two. Linear sections of shear zones are generally poorly mineralised. The same geometries are identifiable on all scales from local to regional, so sections of regional structural lineaments or areas within mines should be prioritised for further investigation or development on the basis of the gold-bearing geometries observed to be dominant locally

Apr 1, 1996

By I. L. Bell

The ironmasters of America had asked the Iron and Steel Institute to visit the USA. The Council decided it was not possible to accept, but Mr. Bell visited; this is an account of his trip. Topics covered include transport, charcoal, coal measures, coal, anthracite, bituminous coal, flux, magnetic iron ore, specular iron ore, limonite, red hematite, clay ironstone, black band ironstone, smelting works, blast furnaces of Pennsylvania, Lake Champlain furnaces, Lake Superior furnaces, Cleveland furnaces, Pittsburg furnaces, Missouri furnaces, and those of the southern states. He goes on to describe Catalan hearths, malleable iron works, Bessemer works, the Blair steel process, and labour.

Jan 12, 1875

By H. R. Thorpe

A floating gold dredge operating in coarse alluvial gravels of the Grey River on the west coast of the South Island, New Zealand, generated high concentrations of clay and colloidal particles in the dredge pond, which entered the groundwater system. Sampling was carried out at depths down to 20 m and it was found that variation of the length of the flow path occurred because of the movement of the dredge towards the piezometers. The alluvial gravels, the suspended sediments, the groundwater system and the water chemistry were all studied. Sediment concentrations were found to be highly variable with depth, but the relative concentrations in the depth profile were generally consistent as the flow distance shortened. The sediments were extremely fine and travelled further through the gravels than predicted. Comparison of field results with the available theory of deep filtration in clean beds of porous media gives some basis for estimating the behaviour of fine sediments in other alluvial systems

Jun 19, 1905

By C. McCall, J. T. Knight, J. R. Ridley

Gold mineralisation in the gabbro sills is mainly stratabound to quartz- and Fe-rich, granophyric-textured units and is sited in undeformed, brittle quartz vein sets, which form pipe-like orebodies. Hydrothermal wallrock alteration consists of hornblende-plagioclase-calcite-quartz with minor biotite, garnet and chlorite and with arsenopyrite and pyrrhotite as the dominant sulphides. Geothermobarometric data suggest that gold was deposited at around 520 degrees C at 2.8-3.8 bar. Mineralisation is thought to have occurred during amphibolite-facies metamorphism. Fluid inclusion and isotope data indicate that gold mineralisation was the result of deposition from a low-salinity H2O-CO2-CH4 fluid of either metamorphic or magmatic origin. Although the Three Mile Hill deposit differs from others in the area in its wallrock-alteration assemblages, peak-metamorphic timing of gold deposition and distinct geochemical associations it forms a brittle stratabound ore body which suggests structural and gold-depositional mechanisms in common with those of the other gabbro-hosted gold deposits

Jun 18, 1905

By Boorder De, B. S. Panov, A. B. Westerhof, V. A. Korcemagin

Paper presented at the conference on Economic geology in Europe and beyond II, models for <mineral deposits> in sedimentary <basins>, held in Keyworth, UK, 13-14 April 1994. The Hg and Sb deposits of the Mediterranean and Circum-Pacific Belts are often found at elevated structural levels, suggesting that their preferential occurrence in young orogenic belts is not a fundamental metallogenic feature but merely reflects their chances of surviving post-orogenic peneplanation. In western Europe their emplacement appears often to be related to late orogenic extensional events accompanied by a notable increase in heat flow. Although Nikitovka and Almaden have quite different settings, both appear to be related to deep-reaching shears. Together with brittle fault zones at higher levels, these provided pathways for fluid phases that originated at least partially within the mantle. The Nikitovka deposits are located in the Donets segment of the 2 000 km Pripyat-Dniepr-Donets palaeorift in the East European Platform. Initiated in the mid-Devonian with a possible Precambrian precursor, its listric boundary faults displace the Moho from a depth of about 50 km north and south of the rift to 35 km along the axes of the Pripyat and Dniepr segments. The steep central anticline of the Donets segment, within which the main Hg-Sb district is located, is interpreted to be associated with a reactivated fault reaching into the upper mantle. The Almaden syncline, formed during the Variscan Orogeny, may be an older pull-apart basin or half-graben associated with the collapse of the Cadomian Orogenic Belt. It is situated on a major ENE-WSW-striking shear zone which may represent a Late Cadomian transfer zone reaching into the mantle

Apr 1, 1995