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By Graeme Lane, Yuqing Feng, Kaixi Jiang, Junwu Zhou, Zhengchang Shen, Tao Song

"Airlift reactors are used in a wide range of industries, such as hydrometallurgy, biochemical processes, chemical process industry and waste water treatment. With increasing superficial gas velocity three circulation regimes can be defined: no gas bubbles in the downcomer, gas bubbles remain stationary in the downcomer and gas bubbles in the circulating regime. In this paper a numerical modelling method was presented for gas-liquid flow in airlift reactors under different bubble recirculation regimes. Gas-liquid flow was modelled using the Eulerian two-fluid equations, and extra user defined subroutines were incorporated to consider the complex physics, such as bubble induced turbulence and turbulent dispersion force. Some alternative correlations of drag coefficient were used to capture the bubble distributions in the riser and downcomer of the airlift reactor, with consideration of the interaction between bubbles. As using constant bubble size is hard to describe global characteristics of the flow in airlift reactors for three circulation regimes, a model including multiple bubble sizes was presented to get more accurate simulation results of gas holdup and water velocity. Also, the inhomogeneous MUSIG model was used, as an exploration, to compute the complex flow regimes. The MUSIG model is a population balance method to predict the bubble sizes, taking break-up and coalescence into account. The modelling method was applied to a laboratory internal loop airlift reactor, and the simulation results were compared with the experimental measurements of Simcik et al. (2011) for gas holdup and water velocity. The three bubble circulation regimes were observed from simulation figures. Reasonable agreement was obtained over a range of operating conditions, and an improvement was demonstrated using the proposed methods."

Jan 1, 2014

By Shibayama A.

In this research, an investigation of a process to selectively remove arsenic (As) and antimony (Sb) contained in enargite (Cu3AsS4) and tennantite/tetrahedrite ((Cu1,Fe)12(As,Sb)4S13) copper resources by leaching and precipitation were performed. First in the leaching process, the target was to selectively leach As/Sb and reduce their contents in the ores to <0.5 wt% followed by a second process to remove As/Sb dissolved in solution for environmental control. Enargite ore contained 3.65 wt% As while tennantite/tetrahedrite ore contained 5.40 wt% As and 4.85 wt% Sb. Alkaline leaching using NaHS?NaOH media at varying experimental conditions (temperature, pulp density, time, reagent concentrations) were performed to investigate the process. As/Sb precipitation studies were also performed to control high As/Sb concentrations in leach solutions by using elemental sulphur (So). Results from leaching studies showed that over 99% of As/Sb in the impure copper ores can be removed and their contents in the final solids reduced to <0.5 wt%. It was also established that such very high leaching could be achieved at 80°C within 1?6 h and pulp densities as high as 1000 g/L. The study also revealed that leach solution containing very high As/Sb concentration ranging from 5 to 20 g/L can be used as fresh solution for leaching of fresh ores until concentrations exceeding 35 g/L when it was sent to precipitation circuit for As/Sb removal. Addition of elemental sulphur at 90°C and fast cooling to 30°C allowed over 60% As/Sb precipitation and removed as Na3AsS4 and solution with reduced As/Sb concentration to leaching circuit for continuous use. Keywords: Enargite; Tennantite/Tetrahedrite; Selective Leaching; Precipitation; Sodium hydrosulfide;

Sep 1, 2012

By P. Yu, L. X. Liu

"A mechanistic model for tumbling mills was developed during PhD studies at the JKMRC. The concept was presented at the IMPC of 2014, followed by progress in a sub-process of the model presented at the IMPC of 2016. Additionally, a number of papers on the sub-models and breakage function have been published. This paper provides a consolidated summary of the outcomes and status of the model. The overall model structure is presented along with the sub-models such as appearance functions, breakage rate functions, energy distribution, transport, and multicomponent grinding interaction model. The strengths and capabilities of the model structure as achieved to date are presented. The gaps in knowledge and sub-processes are also presented, providing a guide to the areas that require further research and development. It is proposed that the approach developed in this paper provides a structure that can accommodate future mechanistic, dynamic mill model evolution that can incorporate the latest research outcomes and provide a platform to test modelling improvements. This can assist in substantially improving the predictive mill modelling capability in the industry, the importance of which should not be underestimated for this workhorse of mineral processing.INTRODUCTION Grinding is almost the largest single energy-consuming process in the mineral processing industry, which was estimated that about 0.2% of global, and 1.3% of Australia’s electricity is consumed by comminution of gold and copper ores (Ballantyne and Powell, 2014). Although there are some relatively new grinding mills, such as stirred mills, vibrating mills and HPGRs (High-Pressure Grinding Rolls), etc., tumbling mills, as the traditional grinding facilities, are more extensively used."

Jan 1, 2018

By V. A. Luganov

Methods of treatment of pyrite concentrates differ, depending on the content of pyrite and non-ferrous metals: oxidation roasting, sulphatization roasting, smelting, direct hydrometallurgical treatment and so on. Existing technologies do not provide for high recovery of metals, expenses associated with existing technologies are high, and environmental issues, associated with the existing technologies need serious attention. We have developed universal technology of the activating-dissociating autogenous roasting of pyrite concentrates using air based, or air, enriched with oxygen, blow. The basic process is taking place in accordance with the following reaction: (1-x)FeS2 + (1-2x)O2 = Fe1-xS + (1-2x)SO2 +Q The products of this reaction are pyrrhotinized cinder and roasting gases, rich in SO2 (up to 18 % in case of air blow) and poor in SO3, that contain up to 1 % of elemental sulphur. Cinder contains different forms of pyrrhotite. These forms of pyrrhotite differ by its content (from Fe0.843S to Fe0.945S), thermodynamic, magnetic (from 4.10-1 to 3.6 SI units), flotation properties (with pyrite dissociation the ?-potential of the product is moving towards more electrically positive charge, from 0.95 for pyrite to 0.2 for dissociation products) and other properties that depend on the conditions of roasting. The combination of pyrrhotizing roasting with different methods of cinder treatment allows to increase the level of sulphatization of non-ferrous metals during the roasting; reduce the amount of blow used during the processing; reduce dust losses to the gas phase; reduce the capacity of gas cleaning system and increase resistance to corrosion of the gas-treatment system, used for the production of sulfuric acid from pyrites. This combination of treatments also allows to use magnetic separation and flotation for separation of ferrous and non-ferrous metal compounds during cinder treatment; perform de-arsenation of arsenic containing concentrates and by-products. Pyrrhotinized cinder may be treated by oxidizing and non-oxidizing hydrometallurgical methods. Keywords: Pyrite, polymetallic ores, sulphidization roasting, pyrrhotite, magnetic separation, arsenic sulphide

Sep 1, 2012

By Christopher Greet, Alfred Van den Bosch

"A range of media alloys with different chromium content has been developed for different milling applications. When selecting the grinding media alloy for a specific application, consideration must be given to the mineralogy of the ore as well as the water chemistry and mill operating conditions. The paper describes the influence of the microstructure of the alloy on the wear resistance and the influence of the chrome content on the pulp chemistry and downstream processing. It also provides information about the in-house tools which Magotteaux have developed to predict the media wear rate with different chromium content alloys and predict their flotation efficiencies that can be expected when the right alloy is selected for a particular application."

Jan 1, 2014

By Hong Zhong, Shuai Wang, Zhanfang Cao, Ting Dai

"Manganese is widely used in industries such as the steel industry and is now an essential element in modern industry. Technologies for the efficient and clean utilization of manganese resources must be developed and employed to ensure the sustainable growth of the manganese industry. Our research focuses on the use of beneficiation technologies to improve the grade of ores or the replacement of low-grade manganese carbonate ores with high-grade manganese oxide ores, and thus, to reduce reagent and energy consumption and the yield of electrolytic manganese residues from metallurgical processes; the study of leachate purification technologies; the study of electrochemical behaviors during electrolysis and energy-saving electrolysis methods; the development of chromium-free passivators as alternatives to the highly toxic potassium dichromate passivator; the non-hazardous treatment and resource utilization of electrolytic manganese residues and other manganese by-products; and the development of new manganese products. INTRODUCTION Manganese is widely used in the steel industry, nonferrous metallurgy, the chemical industry, electronics, batteries, agriculture, etc. Globally, more than 90% of manganese is consumed by the steel industry, and thus, it is said that ""No steel industry without manganese""(Banerjee et al. 2017, Zhang et al. 2017). Current manganese resources mainly include manganese ores, marine manganese nodules and waste catalysts. The total global output of manganese ore from land deposits is 18 million tons (metal volume), and the reserves, most of which is in the form of manganese oxide ores, are estimated to be 620 million tons (metal volume). More than 400 manganese ore deposits with a total reserve of 1.22 billion tons have been discovered in China. These deposits are predominantly manganese carbonate ores. Marine manganese nodules exist on the surface of the deep seabed at depths of 2000-6000 m. These nodules, which are also called polymetallic nodules, manganese balls, manganese aggregates and manganese tumors, are mainly composed of iron and manganese oxides. The total reserves of these resources add up to more than 3 trillion tons. Furthermore, the manganese in manganese-containing catalysts can be recycled after they become inactive."

Jan 1, 2018

By Junwei Han, Kai Xue, Wenqing Qin, Tan Xu, Fen Jiao, Lianbing Cai, Wei Liu

"The research aimed at solving the problem of the stacked spent magnesia-chrome refractories using in non-ferrous metal smelters, which contain various heavy metals and are considered as a hazardous waste. The purpose of the research is to recycle the spent refractories environmentally and economically using gravity separation and flotation to obtain metal concentrates for smelting and using chloridizing volatilization to remove the trace metals from tailings, providing raw material to reprocess magnesia-chrome refractories. In the course of the study, laboratory techniques for the preparation of experimental samples of spent magnesia-chrome refractories were developed including the sequence of operations of material grinding, gravity separation, tails regrinding, flotation, filtration and subsequent unification of concentrates, filtration and chloridizing volatilization of tails, and collection of volatiles. Laboratory tests carried out on several types of samples of spent magnesia-chrome refractories from different smelters showed that gravity separation provided increase in quality of concentrates including about 80% metals (including Ag, Pb, Bi) and flotation separation provided increase in recovery of concentrates under the condition of 200g/t of emulsified kerosene, and 500g/t of combined collector. Based on combined technology of gravity and flotation separation, about 90% metals were recovered from the refractories by a closed-circuit test and the total concentrates contained 40% metals, which can be returned to smelting process as a feeding. Because a small amount of metal in raw materials will seriously affect the performance of refractories, chloridizing volatilization is necessary for removing the remaining 10% metals from tails mixed 8% coke and 13% magnesium chloride at a temperature of 1200°C. Thus, the tailings can be reused as a raw material for new refractories.INTRODUCTION Magnesia-chrome refractory has been used extensively in various industries such as secondary metallurgy, non-ferrous furnaces and cement making due to their high temperature stability, low thermal expansion and outstanding erosion-corrosion performance at high temperatures (Gotod et al., 2005; Vezza et al., 1997; Gregurek et al., 2015). Generally, the magnesia-chrome refractories are produced from a mixture of magnesia and massive variety of chrome ores. However, massive chrome ores are being depleted throughout the world. Even more serious is that the heavy metal chromium (Cr) can transfer into soil and water, which will have an influence on the survival and development of human beings (Zhao et al., 2006; Jiang et al., 2004; Qintie et al., 2013). As a result, regulations treating spent magnesia-chrome refractories as potentially hazardous waste are being enforced, making their disposal difficult and expensive."

Jan 1, 2018

By A. Buchanan, M. Mirnezami, A. L. Restrepo, J. A. Finch, M. S. Hashemi

Settling rate studies on slurries from Cu/Zn flotation plants occasionally revealed two aggregation maxima at pH 8-10 and 10-12. From measurements on sphalerite and silica suspensions the double maxima were replicated by Zn ions (pH 8-10) and Mg ions (pH 10-12) corresponding to the presence of zinc hydroxide and magnesium hydroxide, respectively. A combination of chemical and electrostatic bridging by the hydroxides is considered to be the aggregation mechanism.

Jan 1, 2003

By Yuexin Han, Wenbo Li, Yan Shan, Yanjun Li, Shumin Zhang

"With the accelerating pace of resource extraction, the quality of resources is decreasing, and the old tailing dams which have served for several decades have become the focus of attention. The secondary recovery of valuable metals in the tailings is an important aspect of the comprehensive utilization of tailings. The average iron content of iron tailing is 8%-12% in China. The research aimed at exploring the low-cost and efficient technical route to recycle eastern tailings of Anshan iron mining area. The purpose of the research is to scientifically find the rational conditions of magnetizing roasting and to provide an increase in recovery and quality of concentrates. The eastern tailings of Anshan mining area belong to high silicon bearing iron tailings, iron mainly exists in form of hematite-limonite with an iron grade of 10.60%, the main component of gangue is SiO2 with a grade of 76.22%. In order to reduce the influence of the tailings on the environment, fluidized magnetizing roasting and low intensity magnetic separation for the eastern tailings of Anshan mining area were carried out to improve the utilization of the tailings. The results indicated that an iron concentrate with an iron grade of 65.30% and a recovery of 85.85% could be obtained under the conditions of gas flow rate 8 m3/h, H2 concentration 50%, fluidized magnetizing roasting temperature at 600? for 20s. Phase analysis, magnetism analysis and XRD analysis on roasted materials indicated that hematite-limonite could be transformed to magnetite during the fluidized roasting, then the effective separation of iron and gangues could be made easily by the weak magnetic separation. INTRODUCTION It is universally acknowledged that the grade of iron ore in China is low, the output rate of iron ore tailings is high, usually more than 60%. At present, the comprehensive utilization rate of iron ore tailings is low in China. Generally, the iron ore tailings are stockpiled in the tailings dam. The tailing dams not only occupy a lot of land, but also takes a lot of money to construct and maintain. In addition, the noxious substances in the tailings, such as residual flotation agents and heavy metals, have a severe impact on the ecological environment. There is little doubt that tailing dams have a visual impact on the environment due to their regular geometric shape. Iron tailings can be treated as compound mineral, which is an important component of comprehensive utilization of mineral resources, and is an has been widely concerned. Lots of scholars have done a large amount of research work on a large number of iron ore tailings. Since the iron mineral crystal grain size is fine and the iron grade is low, the iron tailings have failed to achieve good selection criteria."

Jan 1, 2018

By Gulsen Tozsin, Ekrem Kalkan, Taskin Oztas, Elif Agirman Akturk, Ercument Koc, Ali Ihsan Arol

Marble wastes are generated by quarries (marble quarry waste-MQW) and processing plants (marble cutting waste-MCW). The large amount of marble wastes is becoming serious problem for industry and environment because of discarded into rivers and lagoons, without any treatment. Marble wastes can cause environmental problem and economic loss if the waste is not used. However, this type of wastes has a good potential to be used as an amendment for the neutralization of acid soils. In this study, MQW and MCW were applied to an acid soil at different rates and their effectiveness on neutralization was evaluated by a laboratory incubation test. The results showed that soil pH increased from 4.71 to 6.36 and 6.84 by applications of MCW and MQW, respectively. It was suggested that MQW and MCW could be used as soil amendments for the neutralization of acid soils, and thus the negative impact of marble wastes on the environment could be reduced.

Jan 1, 2014

By P. M. Solozhenkin, V. N. Kovalev

Russia is a global antimony market leader. The three major antimony production provinces are Sakha Republic (Yakutia), Krasnoyarsk Territory and Trans-Baikal Territory. Russia’s largest antimony resources are Zhipkozhinsky and Solonechensky deposits in Sakha Republic (Yakutia) and Olimpiadinskoe deposit in Krasnoyarsk Territory. This work demonstrates the efficiency of computer programs and chemical technology aimed at the study of the behavior of collectors used in the processes of flotation of antimony, arsenic and Au (I – III) minerals. The most promising collectors for the flotation of ores containing antimony and gold on the basis of P(V) and compounds with S, O and N atoms were chosen. The mechanisms of interaction with the mixtures of two or three components of collectors were studied. High recovery of antimony and gold was reached in the processing of Au-Sb ores of Sarulah and Sentachan deposits in Sakha (Yakutia). X-ray radiometric methods of separation of antimony ores of Trans-Baikal Territory deposits were proposed. In order to choose the most cost-effective solvents for hydrometallurgical processing of Sb, Au-containing concentrates the method based on clusters formation between transition solvents and antimony minerals was suggested. The nature of Au losses was theoretically revealed in the sulfide-alkaline process. On the base of computer simulation, the formation of various complexes of (KAu) types was developed, for example, hydrosulphidic gold, thiosulfates of gold - Na3AuS4O6, antimony and arsenic gold, trithiostibate (III) and trythioarsenate (III) KAu were produced. The practice of processing of goldantimony concentrates to produce high-quality antimony trioxide and antimony-gold containing alloy (AGCA) regarding the special conditions of the Far North region, were analyzed. The affinage of AGCA was recommended. Creative project development of antimony industry in Russia in order to produce antimony compounds and pigments, including pyriform compounds and flame retardants (antipyrenes) is discussed.

Jan 1, 2018

By Zoran S. Markovic

The extensive laboratory investigations were carried out in order to determinate behavior of sulphide and nonsulphide copper bearing particles during the flotation. The present ore sample were contained 0.55% Cu with 20.1% of nonsulphide copper in it and gangue material with higher contents of alumina about 19.07%. In this paper will be presented some results such as: effect of particle size, pH and applied collectors. The main goal was in application of collectors S-7518, as well as mixture of KEX and Z-96. Z-96 is a product from Chemical Industry Zupa Krusevac which was used as auxiliary collector in mixture with xanthates. The best results were done with this mixture in ratio KEX / Z-96 as 77/23 % in area of oxidized minerals flotation, but the collector S-7518 was achieved better results in sulphide mineral flotation. The S-7518 has better selectivity between copper minerals and pyrite comparing to mixture of KEX/Z-96 in mentioned optimal ratio. Flotation recovery and copper grade in concentrate were studied by flotation kinetics tests.

Sep 1, 2012

By Bhargav Dhavala, Sristy Raj, Ashok Kumar, Suman Krishna Sit, Adity Ganguly, D. P. Chakraborty

"Tatasteel’s West Bokaro washery#3 is designed to deslime raw coal at 0.5mm; the oversize (+0.5mm) is beneficiated in dense media cyclones (DMC) while the undersize (-0.5mm) is beneficiated in froth flotation (FF) cells. Nearly, 80% of the raw coal feed reports to the DMC circuit consisting of four parallel streams. Presently, the performance of DMCs at washery#3 is interpreted by: (a) comparing the actual plant yield w.r.t the lab predicted yield and (b) misplacement of clean coal to middllings.However, the comparison between actual & lab predicted yield is fallacious given the fact that the lab predicts yield of the borehole sample while the feed received at the plant has different characteristics altogether due to the dilution during mining. To mitigate the said limitations, a quick diagnosis tool using the past data has been developed that will give a prediction of performance of different coal seams in the DMCs, inputs being feed ash to DMCs and stream wise feed specific gravity (coal & magnetite combined).The tool also will help in identifying the root cause on real time basis thereby helping the operator to take necessary corrective actions. The operator can intimate the mining personnel in cases of shale reporting to the feed as a result of dilution during mining. In events of higher standard deviations between the parallel streams w.r.t feed specific gravity, the operator can adjust the parameters accordingly to minimize the yield loss. INTRODUCTION West Bokaro came into existence in 1948, as an independent coal company, managed by M/S Anderson Wright. Tata Steel acquired the Company in 1956 to meet its requirement of metallurgical grade coal for Iron making. Subsequently, in 1976, it was made a division of Tata Steel. In 1974, when coal mines were nationalized, West Bokaro was exempted as it produced coal only for captive consumption of the Steel Works. The first washery of India was set up in West Bokaro. The business objective of the West Bokaro division is to produce clean coal at optimum cost for captive use in the steel plant of Tata Steel at Jamshedpur. The strategy is to reduce ash with minimum loss of yield so that quality of coal improves and yet the cost is beneficial vis-a vis imported coal. The primary product is the metallurgical grade coal for coke ovens, which converts coal into coke for use in the Blast Furnaces."

Jan 1, 2018

By Shuji Owada, Yang Geng, Natsuko Kuroki

Micro-bubble flotation is considered to be an ideal method for the separation of fine or ultra-fine particles, which are difficult to be separated with conventional flotation and other solid separation technologies. Micro-bubble flotation can increase the probability of bubble-particle collision more than conventional milli-bubble flotation. However, there are also some problems. For example, it is known that the rising velocity of micro-bubble is quite low; therefore, the flotation rate reduces. And also, the bubble-particle adhesion probability becomes lower than that of milli-bubble flotation, which is proved in our prior research. In this paper, we applied ultrasonic irradiation to the micro-bubble flotation system in order to solve the above problems and focused on the bubble-bubble and bubble-particle interactions. For clarifying the behavior of bubble-bubble interaction, bubbles behavior was recorded by high-speed camera under irradiation of various ultrasonic frequencies. As a result, in the case of bubble-bubble interaction, it is proved that bubbles are highly coalesced by ultrasonic irradiation especially in the lower frequency and it can enhance more precise separation. In the case of bubble-particle behavior, it is found that the floatability become higher with the ultrasonic irradiation of higher frequency, and it is indicated that ultrasonic irradiation might improve the bubble-particle adhesion probability. Additionally, it is also found that the apparent CMC of the micro-bubble flotation under the ultrasonic field become much lower with higher frequency than with lower frequency, and it is suggested that the dramatic improvement of hydrophobization is achieved.

Jan 1, 2014

By D. Whittles, S. Kingman, S. Bradshaw, N. Miles

The influence of microwave energy at high electric field strength on ore strength has been investigated. Two ores of varying mineralogy were treated in both multimode and single mode microwave cavities. After treatment, any change in strength relative to untreated ore was established. It was shown that in the multimode cavity reduction in strength was related to the applied power level. Results of tests carried out in the single mode cavities showed that, for both ores, reductions in ore strength > 50% could be achieved in very short periods (<1 second). Thermal stress analysis showed that the mechanism of microwave induced failure was the development of tangential stresses at the grain boundaries. It was concluded that operation at 915 MHz with high power and short residence times gives feasible scale-up possibilities.

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

Different hydro-metallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2. An innovative acid reductive leaching carried out in mild experimental conditions was here considered using agricultural and industrial wastes containing carbohydrates as reducing agents. The leaching process was investigated from a kinetic and equilibrium point of view in order to optimise the experimental conditions, develop a kinetic model and obtain high purity concentrated MnSO4 solutions. To study the leaching kinetic a Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis before and after leaching. Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydro-alcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions.

Jan 1, 2003

By Weiguo Xie, Malcolm Powell, Lian Liu, Ping Yu

"In order to develop a common mathematical and simulation platform for tumbling mills, a review of existing mechanistic models was made identifying the key aspects of grinding and slurry transport which are common to all tumbling mills. A mill model structure has been developed for all types of tumbling mills based on the population balance framework by incorporating breakage characteristics, slurry and solids transport, product classification and discharge, and energy consumption. A size-dependant breakage model developed by the JKMRC is applied. Transport is separated from breakage events and treated as a main sub-model in the new model structure. The model structure is based on dynamic time-stepping technique to enable dynamic simulation capability for non-steady-state simulation and control modelling. It is envisaged that the new model will cover a full range of milling conditions. It should enable a smooth transition between different mill types, such as from AG (Autogenous Grinding) to SAG to ball mill. The dynamic mill model structure developed here is the first step towards mechanistic modelling of grinding mills and provides great potential for the optimization of the comminution process."

Jan 1, 2014

By Nóra Schreithofer, Zoltán Jávor, Kari Heiskanen

"One of the challenges the mineral processing industry is facing is caused by the fact that water resources in mining areas are becoming very limited and the cost of water is increasing. The water sources in arid regions often have high salt content. Environmental regulations are forcing plant operations towards completely closing the water cycles within plants. This means that impurities (salts, reagents, ions dissolved from minerals, etc.) accumulate within the circuit that will affect the flotation performance. Water purification can significantly increase the operating costs therefore it should be carefully considered weather the impurities need to be completely removed or is there a tolerable level of impurities that can still be left in the process water without significant deterioration of the flotation performance? Several additional questions arise: what are the tools that help identify what is a tolerable level of impurities? How do the different impurities interact and what is their effect on the process? The effect of frothers on the dynamic properties of air/liquid interface in different size-scales has been extensively studied by the authors in the past. Based on these studies a frother characterization framework was developed that systematically examines the dynamic surface properties of the air/liquid interface in relation to the bubble size. This work can be considered as tool that could be used for the above mentioned purpose. The present study investigates weather the same frother characterization framework can be applied for systems where both frother and different types of salts are present. Nasfroth 240 was used as a frother, in combination with structure-breaker KCl or structure-maker NaCl and CaCl2. Bubble size measurements in laboratory scale mechanical flotation cell and laboratory flotation column and dynamic surface property measurements (dynamic surface tension and dilatational elasticity) were performed. The results highlighted the addition of salt to the frother solutions significantly decrease the bubble size and increase the froth high. The coalescence behavior of bubbles showed correlation between the D32 and ionic strength of salts. The results highlighted that the studied structure maker and structure breaker salts effect the dynamic surface properties in different way."

Jan 1, 2014

By L. Muhr, Y. -T. Tang, M. -O. Simonnot, B. Laubie, R. -L. Qui, Z. Chour

"Agromining aims at recovering metals from different secondary resources with hyperaccumulating plants. These natural plants can selectively concentrate metals at very high level and can be transformed to produce commercial compounds. The classical strategy to recover metals from hyperaccumulator plants is based on hydrometallurgy. It consists of: i) burning the plant to obtain ash, which is a very rich bio-ore without organic matter, ii) transferring the target element(s) into aqueous solution by acid leaching and iii) purifying the leach liquor to obtain the target element(s) in the desired form. This method has enabled us to obtain nickel salts, nickel oxide, zinc and cadmium from different plants. However, it is not possible to apply this approach to recover rare earth elements (REEs) from the fern D. dichotoma, growing on mine tailings in South China. Actually, this plant is very rich in silicon: plant burning gives an amorphous ash, very stable despite severe leaching conditions. Therefore, the strategy has been changed and processes are currently developed to extract REEs by direct leaching of the biomass, without burning the plant. Several conditions (i.e. leaching solutions) have been investigated, showing that a good extraction yield was obtained with HNO3 0.5 N (around 84%). This yield was increased to 99% by adding a complexing resin into the leaching solution. After two-steps of elution, results have shown that is possible to recover 75% of the REEs at 81% purity.INTRODUCTION The demand of rare earth elements (REEs) (including 15 lanthanides, yttrium and scandium) has been growing sharply over the past years, because of their industrial applications. REEs are essential elements for emerging technologies, and are used for example in permanent magnets, lamp phosphors or rechargeable batteries. China is the main producer, and the market supply became tense in 2010 when this country decided to limit exports of these elements. Exploitable mineral resources, as well as REE separation capacity are concentrated in a few countries (e.g. USA, Australia, Malaysia, France), which increases the supply risk. Therefore, these elements are considered as critical raw materials (CRM) for many countries and especially for EU (Fortier and Gambogi, 2017)."

Jan 1, 2018

By B. Vasanthakumar

In this study, the effect of adaptation of B.subtilis to sphalerite and galena with respect to the selective flotation of sphalerite from the sphalerite-galena synthetic mixture has been examined. The changes in the surface charge of the mineral and the bacterium, cell wall components and the profiles of secreted proteins are discussed. The flotation recovery of galena increases with the increase in the adaptation cycle of B.subtilis to sphalerite and galena, while the flotation recovery of sphalerite is independent of the adaptation cycle with either mineral. From the gel electrophoresis analysis, the protein profile for the unadapted and adapted cells is found to differ distinctly and this may be attributed to varying molecular weight fractions arising from different growth conditions. Electrokinetic measurements showed shifts in the iso-electric points of not only B.subtilis but also of the chosen minerals after adaptation. Additionally, the zeta potential of B.subtilis is found to become less negative after bacterial adaptation to the chosen sulfide minerals, while it showed an increase in the magnitude of surface negative charge after various enzymatic treatments. The change in the surface morphology and cell wall components such as phosphate, uronic acid and acetylated sugars of the bacterial species during adaptation to sphalerite and galena has been assessed. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite can be preferentially floated from galena in the presence of the insoluble fraction of lysed B.subtilis cells initially adapted to sphalerite, with a high selectivity index. Keywords: bioflotation, b.subtilis, mineral adaptation, sphalerite, galena

Sep 1, 2012