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By Phillip J. Mackey, Susumu Okabe

Copper mining and smelting has been carried out in Japan for over 13 centuries and in fact stretching back into antiquity. In 1889, the first electrolytic copper refinery in Japan based on Elkington’s principles was started by Furukawa Mining at Honjyo in downtown Tokyo based on the multiple or parallel system. Within two decades, a number of other copper refineries had begun operation. Interestingly, but perhaps not surprising given Japan’s long history of copper production, this first refinery in Japan commenced just ten years after the first refinery in the USA (1879), and not long after the first plants in Europe. By 1935, as a result of growth in copper demand, there were six domestic copper electro-refineries in Japan with an installed capacity of 97,800 tonnes/a, while actual production was 71,200 tonnes/a. Since about 1932, the majority of these plants were based on the more common parallel or multiple system. In 1946, just after World War II, domestic production capacity had dropped considerably to 29,000 tonnes/a, however with reconstruction, capacity and production expanded rapidly, with production reaching 81,000 tonnes/a in 1955, 187,000 tonnes/a in 1960 and 307,000 tonnes/a in 1965. The introduction of the first refinery and the early ones that followed and subsequent developments are discussed in this paper. The major technical achievements during the high growth period from 1945 to 1963 included: the use of fire- refined anodes; the introduction of newly-developed rectifiers; the introduction of lead-lined or vinyl-lined concrete cells; improvements in the electrolyte heating system; application of improved anti-corrosion materials and the introduction of heat-insulating surface coverings. In 2018, Japan’s refined copper production totaled 1,595,000 tonnes of copper, with Japan ranking third in the world after China and Chile. INTRODUCTION In 2018, Japan’s refined copper production totalled 1,595,000 tonnes of copper and Japan ranked third in the world for refined copper after China and Chile (Wood Mackenzie, 2019). There are now eight copper refineries in Japan which provide Japan’s production of refined copper. These plants are listed in Table 1 (Wood Mackenzie, 2019), also showing the production trend since 2013; in general, production over this period has been relatively steady. The Toyo plant is now the 7th largest copper refinery in the world after several large plants as rated by capacity in China, Russia and India (ICSG, 2019).

Jan 1, 2019

By F. Parada L

Two copper concentrate with medium and high enargite content were leached in a 3 L autoclave reactor under conditions based on the CESL process. Copper, arsenic, sulfur and iron were checked in all the experiments and antimony, zinc and molybdenum were evaluated in selected tests. The 98% of the obtained copper extraction is agree with others authors, but the behavior of arsenic, iron an sulfur have some differences. The solid residue was characterized by chemical analysis, DRX and QEMSCAN®. Finally a comparative analysis with neutral roasting as an option for the treatment of this concentrate is done.

Jan 1, 2014

By Ming’an Wei, Qifu Duan, Chengtie Wang, Jianmin Wu, Erdenet Mining Corporation, Lusheng Zhou, Wenjian Wu

"The development and industrial applications of magnetic liners have been around for decades. A Swedish company SKEGA first introduced the rubber magnetic liner, and then followed by the Chinese metal magnetic liners. Traditionally, both liners were used in secondary and regrind ball mills, especially for ores containing magnetic materials. Mostly steel balls or equivalent forged balls, usually below 60 mm in diameter, were used as grinding media. With the development of mineral resources over the years, SAG mills and larger ball mills have become the dominating components for comminution circuit design globally. Due to the larger ball mills and thus larger grinding balls (up to 80 mm) especially in non-ferrous metal industry, the application of magnetic liners has been very limited. Based on the new development of materials, the HMR Group Limited has been exploring new designs of magnetic liners which led to the invention of the Nano Steel Magnetic Liner (NSML). Recently, NSML had a successful application in a 5.5m x 6.5m ball mill with 80 mm balls at the Erdenet Copper Mine in Mongolia. Although the first set of liner had a service life of 12 months, the design of the second set was modified and improved to accommodate the operating conditions, which is expected to reach least 24 months service life. The original manganese steel liner only had about 8 months liner life.1. IntroductionMineral processing is an essential operation for the development and utilization of mineral resources. The effective concentration of various useful minerals depends on sufficient liberation of the mineral particles in the ore. The crushing and grinding process such as ball milling are the most common way to achieve proper liberation size. Mill liner is an eternal topic for the operations, not only because it protects the equipment, but also affects the mill grinding efficiency and availability. In recent years, magnetic mill liners have been developed that can easily meet the production targets with numerous benefits, such as zero maintenance, reducing specific energy consumption and improving grinding efficiency."

Jan 1, 2016

By G. Zeng

Although the solubility of oxygen in zinc electrolyte is less than 9 mg/L, the effect on deposit stability and zinc-dust consumption can be significant. Sodium sulfite is used to deoxygenate the electrolyte. The effect of the sodium-sulfite concentration on cobalt removal is investigated. The results show the reduction of sulfite to elemental sulfur that adhered to the zinc dust surface forming a passivating layer, and small amounts of sodium sulfite have no effect on cobalt removal. The optimum amount of sodium sulfite is 100 mg/L. It is an important consideration in purification circuits to use sodium sulfite as an additive to cobalt cementation.

Jan 1, 2005

By BARRY BANNATYNE

Non-swelling bentonite has been quarried in Manitoba by Pembina Mountain Clays Limited since 1941. It occurs in several thin layers near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation, and is quarried from the narrow outcrop belt along the slope of the Manitoba Escarpment. It is marketed both as natural and activated bentonite for a variety of specialized uses. Percolation of acidic water through bentonite has produced a naturally activated bentonite with good absorbent properties; these properties are enhanced by treatment with sulphuric acid to produce an activated bentonitefor decolourizing petroleum and vegetable oil.

Jan 1, 1984

By C. B. Webber

"Sherritt Gordon's experience with rubber mill liners began in 1964 at the Lynn Lake Farley Mine and continued at the Fox Mine in 1960, and the Ruttan Mine in 1973. This paper describes the history of the performance of rubber mill liners at the three mine operations.LYNN LAKE - FARLEY MINEThe Lynn Lake Farley Mine, which ceased production in 1976 due to exhausted ore reserves, was a 3500 T.P.D. copper-nickel operation; consisting of two parallel rod mills followed by three stages of ball mill grinding. A circuit modification in 1964 necessitated one of the tertiary ball mills to be used as a pyrrhotite regrind mill. This 8' x 5' Hardinge conical mill drawing 225 HP was initially installed with steel liners and lifters. After several months of operation a routine inspection revealed severe channeling and washing behind the liners which was threatening to erode the ball mill shell. It was thought that the highly acidic condition in the mill, due to grinding 100 º6 pyrrhotite, was accelerating the wear of the steel liners. At this time it was decided to reline the mill with rubber liners to see if the wear problem could be relieved, and in December 1964 a set of Skega rubber liners were installed."

Jan 1, 1981

By Daniel L. Cluff

The Canadian mining industry needs to find viable alternatives to the conventional cemented pastefill/hydraulic methods of backfilling open stopes for underground mines located within a permafrost zone. The harsh environment and the isolated location of a mine north of 60° impose additional challenges to standard backfill methods and opportunities to the technological and operational issues related to the use of frozen fill. Underground open stoping mining methods require the placement of fill material to enable the controlled recovery of ore from secondary and tertiary stopes. The typical design of the fill material requires the specification of inert material, water and binder. The permafrost conditions provide the additional parameter of subzero temperatures for backfill design and process control. The paper presents the results of an experimental field study, using large size samples, to determine the strength capacity of frozen backfill. The experimental work was performed utilizing rockfill and tailings material with moisture content consisting of water and ice crystals. Preliminary results indicate that the mixture of rockfill, tailings and moisture, develops strength that meet the demanded requirements for open stoping. A thermal equilibrium modelling analysis is presented in the paper.

May 1, 2008

By C. M. Campbell

In his report on the Coal Resources of Southern Vancouver Island, Mr. J. D. MacKenzie stated that: "For various reasons it has been imagined that the coal deposits of Vancouver Island are extremely large and readily available." "Unfortunately," he added, "neither of these assumptions is correct." The chief disability under which the Island mines now labor does not concern the extent of the deposits. There is ample coal for the present demand. It does, however, concern the availability of the coal. If it were readily available the fuel-oil competition would not be serious and there would be no competition with Alberta, American, Welsh, or Australian coal along the Pacific Coast, for Vancouver Island coal could be produced at a price that would cut out all competition. The outstanding operating difficulty common to all Island mines is the extreme irregularity of the coal seams. To most people a coal seam is synonymous with uniformity, and in most coal seams a condition found at one point will be repeated at other points in the same seam throughout the basin. The accompanying drawings show how very far this is from being true in the Cassidy mine, which, in many respects, is typical of Vancouver Island mines. Figure I is a plan covering about 160 acres of the Douglas seam, the only workable seam in this part of the district. The area shown represents what has been the best producing part of the mine and indicates the very large percentage of the seam where the coal is either entirely lacking or so small in amount that it cannot be profitably recovered.

Jan 1, 1924

By R. D. H. Wigmore

"The title of this paper probably sounds quite simple and self-explanatory. The problem, however, was not a simple one, and proved somewhat baffling and expensive over a period of years. After outlining the problem, and the methods which were used to overcome it, we will present our solution, or perhaps it would be more accurate to say the partial solution which we reached.We have in the cyanide circuit at Upper Canada two Dorr Single Tray Thickeners with 30 ft. diameter wood stave tanks 12 ft 4 1/ 2 in. deep. In the years prior to 1948, when the tonnage was 250 to 280 tons per day, two stage thickening was practised. As the tonnage was increased to 450, 500, and finally 560-600 the thickeners were used in parallel.Some settling problems were encountered, and in those days the means to combat these problems were very few. The only remedy was to dump in pounds and pounds of lime. Then along came a few reagents, and the writer remembers one in particular, - 11 Carboxel11 (carboxymethlycellulose). When water or solution was added to this reagent, the result was a gooey mass somewhat resembling tapioca. One drawback was that it stayed in this state, and didn't go anywhere. A method was finally developed of containing the mass (or mess) on a fine screen, and dissolving some of it was a fine spray of solution. The only thing the writer recalls was that it was not a very effective settling agent.Shortly after this time, along came the new flocculents, first a few, and then many, and our settling problems were over.But when the settling problem was solved at Upper Canada, some other problems were creeping up on us."

Jan 1, 1965

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By Jaeheon Lee

"Biooxidation of gold ores or concentrates could be a very attractive alternative to pressure oxidation (POX) or roasting to liberate the gold grains from various sulfides. Crushed heap bioleaching was successful in US and many operations using tank bioleaching of gold concentrate are currently running around the world. Many parameters need to be considered during the project of sulfidic refractory gold ore process. Capital and operation costs are among the most important ones. Run-of-mine heap biooxidation could be very inexpensive and the smaller the crush size (particle size), the more expensive the capital and operating costs for biooxidation application are expected. The capital cost of biooxidation could be a fraction of the cost for building POX plant or roaster and the operating cost could be 1/3 of POX or roasting depending on the method utilized. A new biooxidation process, Sand Farming, is introduced as an alternative to POX and tank biooxidation process. A relatively coarser particle size (P80 = 650 µm) of the process benefits the low cost of grinding against the conventional grinding size (P80 = 75 µm) for other options. The cost of Sand Farming is less than 40% of that of pressure oxidation with comparable gold recovery from the downstream process. This paper will review the laboratory scale testwork for various biooxidation process of sulfidic refractory gold ores and concentrates and provide the economic evaluation showing the biooxidation could be the most economic method without much sacrificing the overall gold recovery. INTRODUCTIONThe decreased availability and lower grade of raw materials has motivated industries to consider recovering values utilizing low cost process options. The process may treat high grade concentrates or submill grade ores that cannot be processed economically by conventional milling-flotation or leaching. Sulfidic refractory gold ores/concentrates have been economically processed by roasting, pressure oxidation, and biooxidation in stirred tank reactor. The process selection is based on a series of studies including multi-year long ore characterization and metallurgical investigations."

Jan 1, 2016

By S. Z. R. Pinkney

Positron Emission Tomography (PET) is a medical technique that produces three dimensional images of the body, commonly to aid diagnosis and treatment of tumours. PET has been developed by the University of Birmingham in order to track particles in an opaque system which is known as Positron Emission Particle Tracking (PEPT). The object to be tracked is irradiated. As the radionuclide decays positrons are produced; when these collide with electrons a pair of concurrent parallel back-to-back gamma waves are emitted and detected, from which the position of the object can be calculated. Stirred media mills are used for particle size reduction. The mill is usually operated at high solids loading with grinding media and has a polyurethane or polyurethane-lined steel pot and is thus opaque. For this study grinding media has been directly irradiated and tracked using the PET camera during the grind. The stirred media mill can be divided into cells of equal volume known as voxels. The fraction of the total time the irradiated media spend in each voxel can be shown in an occupancy diagram. The mean velocity and kinetic energy of the media for each voxel are calculated and also plotted. In occupancy and kinetic energy plots colour indicates the value of the voxel, in dimensionless time and Joules respectively. The arrow in velocity plots shows direction and length of arrow indicates magnitude of the mean velocity for the voxel. From these diagrams and further data analysis a detailed understanding of the flow patterns, media behaviour and high energy areas of the mill can be developed. Variables considered were the tip speed of the impeller and density of the grinding media. It was found that the grinder has three distinct regions: above, at and below the impeller with each region having its own flow patterns and velocity and kinetic energy profiles. These are different for each variable and so are used to characterise the grind. Tip speed and density of the grinding media were shown to both affect the velocity of the media and the proportion of time spent in the each region of the grinder.

Aug 1, 2013

By H. Ardehali, P. Lind

Many gold deposits also contain significant quantities of deleterious elements such as arsenic. Several biological pathways are possible for arsenic exposure; special care and caution must be used while undertaking metallurgical testwork on ores and concentrates that contain high levels of arsenic. Laboratory precautions pertaining to handling of airborne dust concentrations, necessary personal protective equipment, and effluent treatment are discussed.

Jan 1, 2014

By A. L. Karyakin

The report focuses on the process measurements of the mass of rock in the bucket power shovels and dragline excavators. The mathematical models are suggested of AC and DC electric drives of excavators. These models are a basis for calculation methods of the electric drive electromagnetic torque. The design schemes of mechanical equipment of excavators considered to account the situation of bucket in the plane of the boom. The methods of static moment allocation and identification of the excavator technological operations are developed. The results of the work are experimentally tested on power shovels with bucket capacity of 12 and 18 m3.

Aug 1, 2013

By J. W. Merks

"The accuracy of a measurement on minerals and ores can be assured by applying suitable and unbiased procedures but its precision is a function of the number of primary increments and their mass, the number of lots per consignment or samples per shift, and the number of measurements on analysis fine samples.Experimental data will be used to show how the variance components for sampling, sample preparation and analysis contribute to the total variance on which precision statements for the final measurement are based. This type of experiment should not only form part of quality control programs at mines and smelters, but also underly the criteria on which the design of manual sampling regimes and mechanical sampling systems for bulk solids and slurries should be based.Sampling systems and regimes can only be adjusted and optimized if the variance component for each step in a quality evaluation process is measured. Knowledge of precision characteristics lies at the core of effective loss prevention and control programs."

Jan 1, 1985

By Nathan Deisman

Coupled reservoir geomechanical simulations have become a key component of caprock integrity assessments for SAGD operations. This work demonstrates the differences of stress evolution when considering coupled versus uncoupled reservoir simulation. Coupled simulation involves the use of a reservoir and a geomechanical simulator with feedback to each simulator to update reservoir or geomechanical variable (permeability, porosity, relative permeability, pressure, temperature, saturations). Uncoupled simulation only passes the pressure and temperature to the geomechanical simulation with no reservoir simulator updating. Therefore, it is possible to complete uncoupled simulations exclusively with no knowledge of geomechanical flow property evolution. However, it is important to understand the differences between the stress evolution in each model for caprock integrity analysis. A single geological model was selected and parametric analysis was completed while varying the geomechanical the production injection pressures (1600 kPa, 1900 kPa, 2200 kPa) for a reservoir with an initial pressure at the injector of 1300 kPa. The results of the six uncoupled and coupled models are compared through the changes in mean stress, shear stress, and strength with focus on geomechanical assessment of caprock integrity.

Jun 1, 2012

By S. Simukanga, J. Masinja, P. A. Bepswa, A. N. Mwale

Screening is an important operation in dry and wet closed circuit mineral processing applications. Most of the operations have seen the benefits of using fine wet screens in primary grinding sections where the product is relatively coarse, and screens can handle the tonnage. Although many models are available, most of them are confined to dry and wet coarse screening applications. Most models do not give good predictions for wet fine screening. To facilitate model development, pilot plant tests were performed using a single deck Derrick Screen at aperture sizes of 45µm, 75µm, 106µm, and 150µm. Experimental data for a range of feed solids concentrations and flowrates was collected and used to calibrate the performance of the screen under the different operating conditions. The results showed that the performance of the screen deteriorated with an increase in feed solids concentration, and, similarly with an increasing feed flow rate. The percentage of fines carryover also increased with the reduction aperture size. The carryover was even more pronounced at higher feed rates and solids concentrations. A model was developed for predicting the performance of fine wet screening. Data from the test work was used to compare the actual and predicted results, and to calibrate the model. Additional independent data was used to validate the model and assess its limitations. This model will give an expected screen performance based on the initial feed conditions. It incorporates screen design parameters that allow for an estimation of a suitable screen size for a desired performance based on given feed conditions. This paper discusses; the results from the test work performed, the model development and its limitations.

Jan 1, 2016

By Masaru Kato

The plated gold being used by the electronics industry can be broadly classified into two categories: soft gold and hard gold. Soft gold is used for circuit metallization and for bonding semiconductor chips, while hard gold is indispensable as the contact material on electrical connectors, electromechanical relays, and printed circuit boards. The traditional baths from which to plate soft gold as well as hard gold contain the cyanide complex, [Au(CN)2]-, as the source of gold, which liberates free cyanide ions during the plating. The free cyanide is not only highly toxic but also attacks photoresists used to delineate circuit patterns and bonding pads. For these reasons, non-cyanide baths are in use to plate soft gold, whereas hard gold can be plated only from cyanide baths at present. In this presentation, the current status of both electrolytic and electroless non-cyanide processes for plating soft gold will be reviewed.

Oct 1, 2003

By D. Milne

Laser profilometers exist for obtaining very accurate two and three dimensional profiles of joint surfaces. The application of this technology is not commonly applied to the collection of field data on discontinuity surface roughness. Rugged and portable field devices are not commonly used and the value of the possible field data that can be collected has not been well recognised. This paper reviews commonly used field techniques for assessing discontinuity roughness, discusses the value of this data and presents a new laser profilometer design for field application.

May 1, 2009

By Heidi Fauser

The aim of the project was the development of an electroforming process for the production of medical implants out of gold. To prove the applicability of this technology, tympanostomy tubes were chosen as demonstrators. These barbell-shaped tubes are usually produced mechanically; of silicone or, for higher therapeutic demands, of metal ? gilded silver or gilded stainless steel. Gold electroforming of the tubes as an alternative manufacturing process would reduce the expenditures for the mechanical preparation and lower the corrosion susceptibility significantly. To obtain electroformed gold tubes of the desired shape, the following steps are necessary: fabrication of a negative template by drilling holes with countersinks in an insulated aluminium sheet, electroforming process, removal of the aluminium by using a sodiumhydroxide solution. For the optimisation of the shape and surface quality of the tubes respectively the simplification of the manufacturing process, various parameters were tested, e.g. aluminium quality and sheet thickness, type of insulation layer, substrate processing, hydrodynamic conditions, type of electroforming electrolyte, electrodes position, etc. The manufactured tubes were characterised in view of thickness distribution, hardness, surface roughness and purity in comparison to mechanically produced reference tubes. From the results obtained during the project it can be concluded that electroforming processes can be easily adopted for the manufacture of medical implants. The time-consuming electroforming process is by far compensated by the simultaneous production of an arbitrary number of implants.

Oct 1, 2003