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By Rashid Bashir

Shaft sinking through solid rock, which contains little or no water, poses little difficulty. However, when loose, water-bearing strata have to be contended with, water control measures, and pumping facilities are needed. Shaft sinking in Athabasca Basin requires sinking through water bearing sandstone which can be highly fractured. Intersection of local zones of extensive fracturing results in the potential for high water inflows with pressures up to 5 Mpa. Grouting is carried out ahead of each shaft sinking interval as water control strategy. In the grouting method, liquid cement is forced into the water-bearing earth under very high pressure. Shaft sinking performance which can be quantified in terms of rate of advance is highly dependent on the days spent at each interval grouting before sinking can advance to the next interval. This paper presents the shaft sinking experience in Athabasca basin and how some of this is translated into Geoscientific Investigations for Future Shafts. A comparison of Geoscientific data collected from future shafts at McArthur River and Millennium Mines is compared to historical data collected from pilot holes, where shafts have already been sunk. The paper concludes with the strategies for better integration of hydrogeological, geotechnical and geophysical data.

Aug 1, 2010

By J. B. De Hart

In the September issue of the Bulletin, 1923, there is a paper by J. A. H. Church on "The Spontaneous Combustion of Coal in Mines", which is more or less a general discussion of the subject. Mr. Church gives a list of mine fires which have occurred in Alberta. Of the total of thirteen fires, six are attributed to spontaneous combustion. Of these six fires, it will be noted that five are in thick pitching seams. These fires occurred in the following mines during the years shown, at Frank in 1909; at Lovett in 1916; at Cadomin in 1920; at Yellowhead in 1922, and at Cadomin in 1923. Every one of these fires has occurred, as Mr. Church points out, in a seam of over 12 feet in thickness, and furthermore not one of these fires has been extinguished, although in every case large sums of money were expended and considerable risks . taken in fire fighting. Now it is quite evident from these facts that mines working seams of this nature are faced with a very grave danger and it behooves us to study the matter and endeavor to arrive at some practical method of preventing the loss of our coal mines from this cause.

Jan 1, 1924

By Rashid Bashir

The presence of groundwater in the form of large aquifers can have an important influence on investment decisions for underground mines. The design for such mines requires development of special mining methods, and mine dewatering infrastructure to avoid hazards during shaft sinking and underground development. The costs associated with mine drainage control and Mine Dewatering Systems (MDS) are relatively small compared to the huge consequential losses that can occur in case of an uncontrolled inflow and subsequent flooding of the mine. The design of MDS needs consideration of accurate prediction of the maximum uncontrolled inflow rate, availability of the system during an uncontrolled inflow while the inflow is mitigated, and decision on pumping system technology to have capability to operate under water. The research presented in this paper provides a theoretical framework for a reliability based design procedure which takes into account the uncertainty in the estimate of the maximum uncontrolled inflow, performance of the system during the period of an uncontrolled inflow and a methodology to decide on appropriate pumping technology considering the reliability of the system and available underground storage. The reliability based mine design procedure integrates the ideas of Effective Reserve and Hydraulic Reliability Index to come up with a unified methodology for design of Mine Dewatering Systems.

Aug 1, 2010

By B. Farabi Khoshmehr

In the present study the effect of Silicate Sodium oxidation agent concentration and Plasma Electrolytic Oxidation (PEO) treatment time were investigated on properties of oxide layer on Aluminum alloy. The phase composition and surface morphology of PEO films were evaluated through x-ray diffraction (XRD) and scanning electron microscopy (SEM). Pin on Plate abrasive machine were used to investigate of were resistance of coating. The results showed that oxide layer which formed on Aluminum surface consist of high temperature a- Al?O? and ?- Al?O? phases. The diffraction peak intensity and percentage of these phases were increased by increasing silicate sodium concentration. Microscopic studies revealed a porous surface for PEO coating. This was affected by silicate sodium concentration and oxidation time. The wear test results showed that the weight loss of PEO coating was reduced due to improvement of their wear resistance.

Oct 1, 2011

By J. B. Mawdsley

From the view point of the mining engineer, the square-set method of stoping as practised at Butte, Montana, is one ?of the outstanding features of well conducted mining operations in that camp. The following information was obtained in the course of two months underground work in the Granite Mountain mine, during the summer of 1920, which is one of the properties of the North Butte Mining Company, situated on the well known Speculator vein. Most of the information was derived from personal observation and from discussions with various miners and with members of the staff. Geology The copper mining area of the Butte district is some two miles long by one and a half miles wide, a mineralized area in a great batholith of monzonite granite, locally known as the Boulder batholith. This extensive body of granite is traversed by several series of mineralized fault-fissures which differ in strike but generally dip steeply. Geologists agree that following the formation of the fissures, alkaline solutions ascended and decomposed the felspathic portions of the granite in the immediate vicinity of the fissure walls, and that these alkaline solutions were followed by cupiferous solutions which filled the fissures and replaced the granite next to the walls. A zone of oxidized ore, varying in thickness from 10 to 400 feet, overlies a sulphide zone containing chalcocite, enargite, bornite and chalcopyrite, with a small amount of quartz gangue. The veins are from 3 to 100 feet in width and contain, on the average, 3 per cent of copper, 2 ounces of silver, and 15 cents in gold per ton.

Jan 1, 1925

By O. Bernal

The Sociedad Minera Cerro Verde S.A.A, a subsidiary of Phelps Dodge Mining Company, operates a copper mining facility located in southern Peru. This "mine-forleach" operation currently produces 90,000 mtpy of copper cathode from secondary sulfide ore utilizing crushing, leaching, solvent extraction and electrowinning processes. The leach solution handling and application rates have undergone constant development over the years. This paper discusses the improvements in leach application designed to: 1) satisfy the needs of the "lixiviant request rate", which requires the use of application rates as low as 3.5 L/h/m2 and as high as 15 Llhlm2 with variable rest periods according to the leach kinetics, and 2) alleviate the poor solution distribution on the surface of the leach heaps inherent to drip emitters. Low application rates result in poor surface solution distribution and the formation of upside down cones of dry, non-leached material in the top meter of stacked ore, with heavy jarosite and iron salt precipitation; moreover, ferric iron is lost as insoluble precipitates. On the other hand, high unit flows associated with poor agglomerate quality can lead to uneven solution flow patterns within the heap leading to solution short-circuits, fines migration, and ponding with adverse effects on acid consumption and recovery.

Jan 1, 2007

By Lloyd A. Clark

"The kuroko deposits, which are extremely variable in size, comprise both stratiform layers of clastic sulphide particles and cross-cutting vein and disseminated components. The ores lie on the flanks of rhyolitic lava domes which have risen from a postulated subvolcanic magma chamber that provided cupriferous hydrothermal solutions and also acted as a heat source driving ground-water convecting cells. The polymetallic sulphides precipitated initially in explosion craters, pipe fillings and feeder veins as rising hydrothermal solutions mixed with sea water. As sulphides clogged the plumbing system, minor phreatomagmatic explosions produced layers of sulphide fragments on the adjacent sea floor. One to ten repetitions of this process produced multiple fragmental sulphide beds. Each deposit formed in a relatively short space of time, because only minor tuff beds are intercalated in spite of active volcanicity in the region. In this model, the heated ground waters convecting through thick piles of acidic pyroclastic rocks leach the zinc, lead and barium later deposited as kuroko ores. As the subvolcanic pluton cools, the supply of silica and copper wanes and the minor counter-circulation cells above the pluton are replaced by main cell fluids bearing zinc, etc. This change in solution flow is abrupt rather than gradual, as the plumbing system is somewhat disrupted by the magmatophreatic explosions that create each ore layer.IntroductionKnowledge of the kuroko deposits ha s greatly expanded during the 25 years since modern recognition of their volcanogenic origin. However, one aspect of the ore s, which may be of unique importance in their genesis, has received little attention. That is the fragmental character of much o f the sulphide ore, which was briefly referred to in a previous publication (Clark, 1971) and is examined in more detail by Barton (1978). Most researcher s have concentrated their attention on or e deposition above and beyond the vent, which is inconsistent with the geology."

Jan 1, 1983

By W. Petruk, D. R. Morris

"The lead concentrate produced from the volcanogenic base metal ore of Brunswick Mining and Smelting in New Brunswick contains major to trace amounts of iron, zinc, cadmium, arsenic, antimony, copper, silver, selenium, tellurium, bismuth, sulphur, tin, indium, mercury and manganese as impurities. When the concentrate is sintered some of these impurities enter a variety of oxide phases, whereas others precipitate as metals. In the lead blast furnace the oxide phases decompose and the impurities recombine 10 form new phases, most are eventually discharged to the slag. The metals of the sinter remain as metals in the lead blast furnace where even more are produced, and are discharged largely with the lead bullion,IntroductionMany lead concentrates are produced from volcanogenic base metal ores . Such ores contain a wide variety of trace minerals and trace elements , therefore, concentrate s obtained from them will contain the trace elements as impurities . The impurities in the lead concentrate from one such ore, the Brunswick No. 12 deposit of Brunswick Mining and Smelting Corporation (BM S) in the Bathurst area in New Brunswick , were studied as pan of a larger investigation that was conducted to determine the extent of chemical reactions of the sinter within the lead blast furnace(1,2) The lead concentrate was investigated to identify the host mineral s for the impurities, the lead sinter was studied to identify the host phases, and frozen products from different depths within the BMS blast furnace at Belledune, New Brunswick were studied to determine the behaviour of the impurities.T he investigation was performed by pre pa ring polished sections o f the samples and studying them with a reflecting microscope, a scanning electron microscope (SE M) equipped with a Kevex energy dispersive X-ra y analysis system, a microprobe, and a Quantimet 720 image analyzer. The samples were also analyzed by X-ray diffractometer, and individual grains were analyzed by the Debye-Scherrer X-ray powder film method."

Jan 1, 1985

By R. Ricketts, D. G. Vanderveer, F. Kirby

"A program of mapping, sampling and testing to determine the potential of the aggregate resources throughout Newfoundland and Labrador was commenced in 1978. A 6-km-wide corridor parallel to all transportation routes was selected as the study area.The study consisted of a preliminary surficial interpretation followed by field mapping and sampling. Granular resources were sampled at a 500-m interval and non-granular materials were sampled at a 1.5- to 2-km interval. Data were gathered on landforms and stratigraphy as well as a field description of the sample and deposit types. Particle-size and lithologic analyses of the samples were also conducted.The locations of samples and deposits were mapped on 1:50,000 topographic base maps and summarized for publication at a 1:250,000 scale. Surficial geology maps were produced at a 1:50,000 scale. A computer program is being developed for the search and retrieval of field data.The first phase of the Inventory of Aggregate Resources program is nearing completion and to date has collected information on approximately 9,500 samples throughout Newfoundland and Labrador. This data will be used to provide f or the effective management of these vital non-renewable aggregate resources.The mineral aggregate industry in Newfoundland and Labrador is very competitive, but undercapitalized when compared to other provinces. The demand for aggregates is forecasted to increase to in excess of23 million tons per annum by the year 2002.In terms of over-all mineral production, the extraction of sand, gravel and stone has a significant impact when compared to other minerals in terms of value and tonnage produced.IntroductionThe province of Newfoundland has approximately 18,000 km of coastline. A large proportion of the population lives in coastal communities where, traditionally, beaches have been a major source of construction materials. Beaches have, therefore, often been subjected to overutilization, resulting in erosion of back beach areas or adjacent headlands."

Jan 1, 1982

By Erwin L. Zodrow

"For 25 chemical elements in electrostatically precipitated fly ash (Lingan coal-fired power station), concentration changes are studied as a function of increasing proportions of fines (ash particle diameter less than 45 micrometres). Elements that are involved when concentrations increase as the proportions of fines increase are likely to escape into the atmosphere. These are Th, U, As, S, P, Sb, Na, Ag, Zn, Pb, Ni, Ba, Sc, AI, Mo (and Bi, Ge, Ga, F and Li), i.e., more or less highly volatilized elements. Of the less volatilized metals such as Fe, Ca, Cu, Ti, K, Co, Mn (and lanthanides), certain portions presumably also escape as stack emissions. Diadochy and spinel formation in bottom slag is presented as an emission-reducing agent for certain metals.IntroductionThe Lingan coal-fired power generation plant, owned and operated by the Nova Scotia Power Corporation, produces annually about 140,000 metric tons of ash (the residual mineral content after burning coal). The tonnage is based on a 15 per cent average ash content of Cape Breton coal.For purposes of this report, samples of the hard, fused slag (bottom slag) that is accumulated at bottoms of boilers, and electrostatically precipitated fly ash (ep ash), were collected and investigated. Bottom slag is a minor component of the produced ashes.The ashes were surveyed and the presence of over 75 major, minor and trace elements is reported. From this survey, 25 elements were selected to establish elemental enrichment/depletion trends when the proportions of the less than 45 micrometre <45µm) fractions in ep ashes increase. The results are significant in that, taking the case of elemental enrichment, the elements involved are likely to escape into the atmosphere, i.e, highly volatilized elements. Depletion trends for elements are presumably associated with less volatilized elements during coal-firing. Quantification of the emission of atmospheric pollutants is not considered part of this work. ""Igneous"" minerals generated during coal combustion include spinels (found mainly in the bottom slag), quartz, glass and mullite."

Jan 1, 1982

By I. A. Cameron, F. Ham, R. Sriram

"Planned increases in electric furnace productivity and higher matte temperatures needed for the Sudbury Smelter&apos;s S02 Abatement Plan, require an improved matte tap hole. Since startup in 1978, the matte tap holes have been incrementally improved by the addition of copper cooling blocks around the refractory tap blocks. These improvements provided a tap block life of about 100 taps per campaign.In July 1993, a prototype matte taphole was installed in Number 2 Electric Furnace to develop the technology to increase tap hole service life. The design was based on a heat transfer model of the tapping process to determine candidate refractory materials and cooler arrangements. The prototype tap hole features increased copper cooling, high conductivity refractories and extensive instrumentation. Eight trial campaigns are reviewed outlining the performance of silicon carbide and graphite refractories and typical heat loads during tapping.IntroductionFalconbridge Limited operates two 36 MYA, 6 electrode submerged arc electric furnaces in Falconbridge, Ontario. The furnaces, commissioned in 1978, smelt a partially roasted nickel-copper calcine, to produce matte for converting and slag for discard. Additional details of the smelter are available in the literature(1-4).Each furnace was equipped with two matte tap holes located in the furnace end wall. Early in the campaign, matte tap holes were identified as a weak area in the furnace which could be improved. From 1981 to 1987, incremental improvements were made to the design by the addition of water cooled copper blocks. In 1993, a prototype matte tap hole was designed and installed in Number 2 electric furnace to develop the technology to increase tap hole service life. Improved service life is required to meet planned increases in electric fWl1ace productivity and the higher matte temperature needed for the smelter&apos;s S02 Abatement Plan.This paper reviews matte tap hole development since 1978; outlines the prototype matte tap hole design, refractory selection and installation; and details the performance of the prototype tap hole during the first eight campaigns."

Jan 1, 1995

By Liu Liching, Yan Hongjiu

"In China, the electromagnetic induction initiating system f or blasting engineering has been greatly developed in recent years. With this system, the total number of detonators that may be blasted in each round has been increased from 420 to 940 as a result of the invention of a powerful exploder, and the length of leg wires of a detonator has reached 12 metres. These developments make the new system suitable for blasting engineering of medium scale. Another attractive feature of this system is a set of testing instruments which have been invented that enable a final check of the system to be made before firing as in normal electric blasting. This paper reports on these developments.IntroductionThe initiating system for blasting explosives is one of the key factors to the success of blasting engineering, along with the progress of explosives and blasting technology. Today, we have initiating systems which may be divided into two groups: electric and non-electric. The earliest initiating system was non-electric. Many mines, as well as many projects where rock excavation was involved, were blasting non-electrically before the new nonelectric initiating system came into use in the 1970s. Electric and non-electric initiating systems are the two main initiating systems which are now being widely used, each having its advantages and disadvantages. In electric blasting, the blasting supplies and the blasting circuit can be checked before it is used or fired and, therefore, is regarded to be more reliable. In many large-scale blasting engineering where reliability of the initiation is of great concern, a checkable initiating system is preferable. The electric initiating system is not considered to be as safe as the non-electric initiating system due to its inability to choose proper ignition energy. Therefore, a non-electrical initiating system would be preferable where a hazard of stray currents or static electric energy exists. At this stage of development, one would say it would be advantageous to develop a new initiating system."

Jan 1, 1988

By Wayne D. Goodfellow, William M. Luff, Steven J. Juras

Brunswick No. 12 is a vent-proximal massive sulfide deposit that formed above a feeder pipe with associated hydrothermal alteration. Because of the replacement of bedded sulfides deposited above the hydrothermal vent, individual sulfide lenses show the following vertical and lateral zoning outward from the vent complex: massive pyrite-pyrrhotite-ehalcopyrite core interlayered pyrite-sphalerite-galena (pb-Zn ore zone) - bedded pyrite. The feeder zone which underlies the Cu-rich core consists of an anastomosing network of pyrite-pyrrhotite-chalcopyritequartz veins with variable and generally minor contents of ferroan carbonate, Fe-rich chlorite, sphalerite, galena and arsenopyrite. Hydrothermal alteration of felsic igneous rocks hosting and adjacent to the feeder pipe is represented by an inner zone (zone I) characterized by sulfide stringers, Fe-rich chlorite, muscovite, quartz, and ferroan carbonate that formed at the expense of feldspars and what was probably glass; outer zones (II and III) are represented by Mg-rich chlorite and muscovite formation, and the albitization and silicification of K-feldspar. Accompanying these alteration trends is a marked decrease of Na + Ca, and an increase in Fe + Mg + C03 in zone I, and increases in Mg + Na in the outer zones. The classic zoning of metals within the sulfide lenses, the formation of a feeder pipe below the vent-proximal sulfide core, and the hydrothermal alteration of felsic volcanic rocks cut by the feeder pipe all support a vent-proximal origin for the Brunswick No. 12 deposit. Furthermore, restriction of sulfide stringer mineralization to the footwall sequence, the folding of the stringer zone by an F, fold, and the difficulty of long distance mass transfer of metals from the sulfides into the host rocks all argue against a tectonic origin for the stringer zone. All of the evidence indicates that the feeder pipe formed during the ore forming hydrothermal event, but has been distorted and in some areas detached from the overlying massive sulfides during subsequent deformation.

Jan 1, 1992

By H. Stocker, C. E. Makepeace

"This paper presents the statistical analyses of several sets of data acquired in several programs of sampling of radon daughters in uranium mines. The measurements were taken over periods of days or weeks for given locations or location occupations within these mines. Because the sampling applies to specific intervals of time and specific locations, a method is suggested f or the eventual application of a monitoring program which would be suitable on an annual basis for these locations. The present data and analyses thereof are not justifiably applicable to a monitoring regimen on an annualbasis, without a number of additional assumptions.The aim of the present analyses of concentration measurements is the determination of the minimum number of measurements required to achieve an annual radon daughter exposure estimate, for individual workers, having an error no greater than 50% at the 95% confidence level. The criterion of accuracy is taken from a statement in the American National Standard, Radiation Protection in Uranium Mines (ANSI NI3.8-I973), and is currently used, in somewhat modified form, as a guide to uranium mining licensees in Canada. Uncertainties associated with occupancy time are ignored in the present analysis. IntroductionOne of the principal aims of any scheme of radiation protection is that of improving the accuracy of exposure estimation for workers. The example presented here is from the area of radon daughter exposure estimation for uranium miners. The conventional means of estimating workers&apos; exposures is grab sampling of radon daughter concentrations combined with occupancy time weighting in the various work and travel locations. Uncertainties exist in each of these components, and in an environment of highly variable radon daughter concentrations (such as an active uranium mine) one is always uncertain as to the representativeness of the grab sample (compared to the average concentration) unless a sophisticated monitoring scheme has been implemented based on previous experience in such an environment.Improvements in the accuracy and precision of employee radon daughter exposure records depend, primarily, on three factors;"

Jan 1, 1980

By H. Clare Horwood

"In the Little Long Lac-Sturgeon River area of Thunder Bay district, Ontario, most of the known ore deposits occur in fractures, shear zones, and zones of brecciation, in folded sedimentary rocks . In two or three instances, however, deposits occur in Keewatin greenstones and in later granitic rocks of probable Algoman age.The principal regional features in the area are the long narrow bands of Keewatin volcanic rocks and Timiskaming sedimentary formations that extend east from lake Nipigon to Long Lac, a distance of about 65 miles. The belts continue to the east for many miles beyond Long Lac and probably for some distance to the west under the waters of lake Nipigon. They are intruded in places, particularly in the north, by large masses of diorite, granodiorite, and granite. Small intrusive masses of diorite and porphyry also occur in many localities throughout the area.The Little Long Lac-Sturgeon River mining area is the youngest camp in Ontario and has been in production only since 1934.The district is readily accessible from the branch line of the Canadian National railway between Longlac station on the main line and Port Arthur, and from the Trans-Canada highway No. 17. Both these means of communication traverse the area in a general east-west direction parallel with the principal structural trend of the rocks of the region.In the Little Long Lac section discoveries were made by W. W. Smith in 1931 (Hard Rock property) , by T. A. Johnson in 1932 ( Bankfield property) , by T. A. Johnson and T. Oklend in 1932 (Little Long Lac property) , by F. MacLeod and A. Cockshutt in 1933 (MacLeod-Cockshutt property) , and by George and Frank Papineau in 1935 (Hutchison Lake property).In the Sturgeon River section discoveries were made by Powers and Silam in 1925 (Northern Empire property), T. A. Johnson in 1931 (Dik-Dik property) , and by Russell and James Cryderman in 1935 and 1936 (Sand River and Leitch properties)."

Jan 1, 1954

By M. Roy, Y. Roux, R. McIvor

"La Compagnie Minière Québec Cartier at Port Cartier. Quebec, utilizes six parallel wet grinding open circuit ball mills to grind iron ore concentrate for the pellet making process. In an attempt to improve grinding efficiency, a mix of 605 25 mm (1 in.) and 405 38 mm (1 ½ in.) grinding balls was charged to mill D while the opposite mix was used in all the other mills. Because media costs were higher for mill D, it was necessary to find out if the smaller balls provided a net economic benefit. Therefore, a test program was undertaken to determine the relative efficiency of the charge in mill D compared to the other grinding mills. Mill F was chosen for comparative efficiency measurements.The first problem was to choose a suitable definition of grinding efficiency. In management&apos;s view, previous attempts to quantify milling performance using population balance modelling were ineffective because they were unable to relate breakage rate functions to grinding circuit economical in any meaningful way. Work index analysis was also not favoured because of a number of complicating effects, including the fineness of the feed and product streams and open circuit grinding.It was decided to adopt a recent innovative approach which had been successfully applied to closed-circuit ball milling. For ""functional performance analysis of ball milling"" (McIvor et al., 1990; McIvor et al., 1991), a size criterion is first chosen to define ""fines·&apos; and ~&apos;coarse particles"". In this case 45 microns (325 mesh) was chosen to distinguish fines from coarse material. The relative grinding efficiency of each ball mill environment would then be ~e cumulative grinding (disappearance) rate of coarse (plus 45 nucrons) material per kilowatt hour of energy applied to the coarse material in the mill, divided by the grindability (measured in the laboratory) of the coarse material in the mill feed.Because the disappearance rate of coarse particles is also the production rate of fines, the following equation can be written for the efficiency of the mill environment, Effe, as defined above:"

Jan 1, 1994

By B. Grinbaum

The solvent extraction of Cu from acidic leach solutions is carried out using oxime extractants. The mechanism can be described as liquid ion exchange, where a labile H+ in the oxime replaces Cu++ ion from the pregnant leach solution. The process is reversible and, at high acidity, the copper is stripped back to the aqueous phase. As the extraction proceeds, the acidity of the aqueous phase increases and the equilibrium may shift against the extraction reaction. This phenomenon may become significant in leach solutions with high copper concentration, where large amounts of acid are transferred from the solvent into the aqueous phase. An efficient way to increase the recovery of copper consists of splitting the extraction into two circuits, and either neutralizing with lime or extracting the excess acid of the intermediate raffinate. In the second case, the acid can extracted using a solvent, which can be stripped with a base, e.g., NaOH or ammonia. A third option is direct neutralization with soluble basic salt, e.g., Na2CO3, within a single extraction battery. The choice of the preferred process depends on the specific process demands and on the relative availability and price of the raw materials and by-products price.

Jan 1, 2007

By A. C. Atenas

The majority of refineries that operate with traditional starting sheet technology ?starting sheet- uses a relatively low current density of 250 A/m2. Industrial tests at high current density with conventional technology were carried out in Refinery of Potrerillos, getting satisfactory results that are similar the results obtained with permanent cathode technology. The series of copper refining electrolyses electrolysis trials were carried out between 300 to 325 A/m2. Electrolysis conditions, in accordance with industrial practice, were kept constant in all sets of experiments and were as follows; 45 g/L Cu 2+, 210 g/L H2SO4, 62 °C, electrolyte circulation of 14-18 L/min. The same Dosing dosing of Additives additives used in permanent cathode technology was required in these tests. In general, only not importantminor operational modifications were necessary in comparison to normal practice in the Refinery to assure the good results. Different quality of starting sheet and anodes were examined. The test included starting sheets from smelter and laminated process. Results indicate that the charge physical quality of the electrodes and the control of the process during the two first days of operation are the keys to get the best results.

Jan 1, 2007

By G. Viramontes-Gamboa

Approximately 70% of world copper reserves consist of the mineral chalcopyrite, and much international effort has focused on its study. Ultimate objectives include the development of environmentally friendly alternatives to smelting, and technologies to treat low-grade ores, for which concentration and smelting are economically unviable. Unfortunately, chalcopyrite leaching is inefficient in H2S04-Fe2(S04)3-FeS04 solutions, which is considered to be the most desirable oxidizing medium for leaching of copper sulfides, since the chemistry is well known, corrosion of industrial equipment is negligible, subsequent copper recovery by SXlEW is well established, and environmental impact is minimal. The main reason for this inefficiency is the self-passivation of chalcopyrite. We have devoted considerable effort in the understanding of this phenomenon, and have developed a predictive electrochemical methodology capable of establishing a priori the precise range of potentials within which chalcopyrite leaches and where it is passivated. Since potential control is a critical parameter in chalcopyrite leaching, this experimental methodology can be very useful for establishing the best conditions to leach chalcopyrite. In this paper, the scientific foundations of this predictive experimental technique are presented, and its practical application is demonstrated by comparing its predictions with leaching experiments from the literature.

Jan 1, 2007

By A. Singh

Deformation structures after tensile and compression tests on Mg926Zn64Y alloy extruded at 250°C and 400°C are studied, in as-extruded and heat treated conditions. The icosahedral phase particles stimulate recrystallization during extrusion, resulting in fine grain size. Tensile and compression tests at room temperature show comparable yield strength, with a yield asymmetry ratio up to 0.98. c-type dislocations are observed in the grains near the submicron size icosahedral phase particles. The source of these dislocations is believed to be dissociation of <c+a> type non-basal dislocations. No dislocation pile-ups on icosahedral phase particles are found. {10 1 2} type twinning occurs in compression.

Jan 1, 2006