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By K. S. Raja, F. Battick, B. Pesic

"CeO2 doped with lower valence cations, such as Y3+, Sm3+, Gd3+ etc. is considered as electrolyte material for low temperature SOFC. Doping introduces additional oxygen vacancies and improves ionic conductivity. This work describes the preparation of yttria-calcia doped-ceria precursor material, its sintering in DC and AC field methods, and characterization of sintered electrolytes with respect to the ionic conductivity. Doped precursor materials were prepared by a controlled co-precipitation process. Sintering of prepared, pelletized particulates was carried out using three different methods such as: 1) conventional; 2) spark plasma sintering; and 3) an alternating current field at 1125°C (AC assisted sintering). The mechanism involved in the conductivity improvement as a function of defect density, grain boundary area and phase stability will be discussed. INTRODUCTIONThe performance of SOFCs depends highly on the properties of materials. Subtle variations in the composition, microstructure, or density of SOFC components can considerably alter the power output capabilities of fuel cells. Early SOFCs utilized zirconia based electrolytes but efforts in lowering the operating temperatures of SOFCs have prompted investigations into several other oxygen ion conductors – often modified with dopants to either promote the formation of oxygen vacancies or to stabilize a vacancy rich high temperature phase – such as bismuth oxide, lanthanum gallate, and ceria.The transport of oxygen ions through the electrolyte first begins with diffusion into the material. While this is generally a surface kinetics phenomenon, it is safe to say that it is highly dependent on oxygen pressure and vacancy gradients. The role of the cathode in SOFCs is to reduce oxygen at the electrolyte surface creating an O2– ion gradient which induces permeation into the material. Once inside and under the influence of a potential field, O2– ions migrate by a vacancy hopping mechanism, Catlow, C.R.A. (1990), effectively exchanging positions throughout the matrix until they reach the anode and react, thus leaving the matrix."

Jan 1, 2012

By J. C. Allan

THE purpose of this paper is to outline the pogress made in the development o the gravity separation method o ore dressing known as Sink-and-Float, which, in the opinion of the writers, has now reached a stage justifying the claim that this new method marks a highly important advance in the technique . The essential feature of the newest development of this process is the extremely accurate separation achieved. This is responsible for higher extraction in the sink-and-float unit on coarse sizes and, in consequence, for substantially higher overall recoveries. Whilst this is the most remarkable feature of the new process, it has further important contributions to make to ore dressing under the following heads: (1) The introduction of the sink-and-float separator as a buffer helps to iron-out irregularities in the mill feed. By supplying a concentrate of constant grade to the flotation section, the process also indirectly improves overall recovery. (2) The addition of a sink-and-float unit to an existing mill results in substantial increase in capacity at low per ton capital cost. (3) Where the plant can be installed underground for the pre-treatment of low-grade ores, there is a saving in hoisting costs, and excellent 'fill' is provided near the point of use. ( 4) Low-grade mixed oxide-sulphide copper ores may be pre-concentrated, thereby producing a flotation feed sufficiently rich to render the oxide residue from such flotation economic for subsequent treatment by leaching or other methods. (5) Application of the process eliminates hard gangue constituents which cause high grinding costs, or gangue constituents which adversely affect flotation. The plant is compact and easily controlled. No highly skilled operators or expensive reagents are required, and the labour and power per ton are low. The separator is extremely flexible, working equally efficiently on any throughput up to its maximum capacity.

Jan 1, 1940

By K. Parameswaran

This paper builds on presentations made at the Conference of Metallurgists (COM) 2015, COM 2017 and Extraction 2018 and associated papers published in the respective conference proceedings. Based on the classic Brundtland Commission definition of sustainable development as “development that meets the needs of the present without compromising the ability of future generations to meet their own needs,” the paper describes how metal mining can be compatible with sustainable development and how sustainability considerations have been applied in the primary copper industry, using several examples of sustainable mining practices from ASARCO LLC operations. Finally, the paper discusses how these considerations might be used in the future by discussing the need for developing a sustainable development strategy and how this strategy can be aligned with the United Nations Sustainable Development Goals. INTRODUCTION The primary copper industry comprises: mining (also referred to as “extraction”); mineral processing (also referred to as “beneficiation, “milling” or “concentration,”) which includes leaching, solvent extraction (SX), crushing, grinding, froth and flotation operations; and metallurgical processing which includes smelting and converting; refining, which includes fire-refining or anode refining and electro-refining; and electrowinning (EW). There are two routes for producing refined copper: hydrometallurgical and pyrometallurgical. The hydrometallurgical route comprises mining (open-pit and underground), mineral processing (crushing and grinding — for heap leaching only; leaching and SX) and metallurgical processing (EW). The pyrometallurgical route involves mining, mineral processing (crushing, grinding and froth flotation) and metallurgical processing (smelting, fire refining and electro- refining). The primary copper industry is capital, water, resource and energy intensive with the potential for significant environmental impacts, if the environmental aspects are not properly managed. ASARCO LLC (Asarco) was organized in 1899 as the American Smelting And Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co-products. Grupo México, S.A.B. de C.V (Grupo México) acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, selenium and tellurium. Asarco operates three open-pit mines and mills, two leach, SX-EW plants, a copper smelter in Arizona and a copper electrolytic refinery in Texas.

Jan 1, 2019

By K Morrison

Different individuals have calculated the boundary stresses around elliptical openings in an infinite elastic medium for various conditions of loading. With caution, such calculations are useful in indicating stress trends in mining. This paper illustrates an application to caving operations and suggests that abnormal field stress would have an adverse effect. Introduction GELDART and Udd (1), applying elastic theory, confirmed, and set out graphically, the stress distributions on the surface of elliptical openings with axis ratios varying from 1.0 (a circle) to infinity (a crack). The loading conditions varied from uniaxial to hydrostatic, and inclinations for the opening, with respect to the stress axis, varied from 0° to 90°. As most mine openings can be generalized into this elliptical conception, the usefulness of the presentation lies in the fact that given reasonable estimates for the stress ratio, the axis ratio, and its inclination, then the trend in stress concentrations as an opening develops can be readily approximated.

Jan 1, 1964

By F. Qi, T. Frišcic, C. Mottillo

"One of the principal goals of modern industry is to minimize the environmental impact and increase the materials- and energy-efficiency of transforming raw materials into valuable products. This paper will highlight our latest laboratory-scale research in low-energy, low-solvent reactivity of metal oxides and their conversion into popular metal-organic frameworks (MOFs), zeolitic imidazolate frameworks (e.g. Basolite® Z1200 component ZIF-8), and metallodrugs (e.g. bismuth subsalicylate, active component of Pepto-Bismol®). Mechanochemical ion- and liquid-assisted grinding (ILAG) and ""accelerated aging"" techniques will be presented, along with novel low-energy and solvent-free approaches, inspired by geological weathering processes, for converting metal oxides into metal-organic materials. INTRODUCTIONThe development of environmentally-friendly processes, which would in the same time be more materials- and energy-efficient than the existing ones, is one of the central concerns of modern chemical research. In that sense, the focus of the chemist has been mainly on the preparation of carbon-based organic molecules and adaptation of traditional organic synthesis to the recently delineated ideals of Green Chemistry. However, there is a growing realization within the chemistry community that significant energy, materials, and ecology-related benefits can be achieved and, indeed, targeted in the transformations of materials that are typically associated with inorganic chemistry and minerals processing. The principal aim of this highlight contribution is to illustrate how, through the use of approaches associated with solventfree chemistry and mechanochemistry (James et al., 2012), one can develop a clean and efficient system of chemical and materials transformations involving oxide precursors that normally belong to the realm of inorganic chemistry and mineral processing. In particular, this contribution will provide an overview of the recently developed mechanochemical and solvent-free reactivity of metal oxides towards small organic molecules. These mechanochemical reactions, including the methods of liquid-assisted grinding (LAG, Frišcic & Jones, 2009) and ion- and liquid-assisted grinding (ILAG, Frišcic, 2010), have so far provided a radically different means to construct advanced metal-organic materials (e.g. porous metal-organic frameworks, [MOFs] or metallodrugs) by rehabilitating metal oxides as precursors, eliminating the use of bulk organic solvents, and avoiding the use of high temperatures."

Jan 1, 2012

By James S. Redpath

"AbstractThis paper is an attempt. to outline the present status of underground mining contracting in Canada, and to present certain facts concerning the writing and administration of underground mining contracts which, hopefully, may be useful to those intending to engage a mining contractor . The paper is based on the author' s experience as a contractor and also as a consulting engineer advising others in the purchase of contractors' services.HistoryIN THE early days of mining contracting in Canada, the contractor was primarily a labour contractor. He was expected to bring a good crew of men that normally followed him, and to perform certain work under his own direct supervision. The owner usually looked after all other details including financing, payrolls, withholding taxes, etc , computing and paying the contractor his profit. In the pre-World-War II years, most work was done on this basis.Over the years, the contractor was called on to supply more in the way of services, and the present-day situation evolved.Labour contracts are still used, but now the contractor is expected to carry out his own administration. Most contracts now call for the supply of special tooling required to do the work. In most cases, some, if not all, supplies are the contractor 's responsibility and , in a growing number of cases, the contractor is responsible for such items as design and surveying. The ultimate in this direction is the execution of projects on a turnkey basis. Under this system , the contractor carries the project to a stage where it is turned over fully operational to the owner."

Jan 1, 1977

By Grant Small, Jessica Kinal, Christopher J. Greet

"The conversion from an electrochemically reactive grinding media (forged steel) to a more electrochemically inert alloy (high chrome white iron) not only reduces the wear rate of the grinding media, but also has an impact on the grinding chemistry. Typically the grinding chemistry becomes more oxidising, with less reducing Eh values and more dissolved oxygen in the pulp. There is also a decrease in the EDTA extractable iron, which is an indication of the change in the media corrosion. These changes are indicative of alterations in the surface chemistry of the minerals that the operator is trying to separate. For porphyry copper ores the changes in the pulp and surface chemistry not only affect the copper sulphide minerals, but also impact the iron sulphides (i.e. pyrite and pyrrhotite). Generally, with more oxidising pulp chemical conditions during grinding there is an increase in the oxidation of the iron sulphides which renders their surfaces hydrophilic, thereby depressing flotation. This leads to improved selectivity for copper sulphides against iron sulphides.INTRODUCTIONPorphyry copper deposits are the dominant source of copper that is mined today to satisfy global demand. These style of deposits typically contain one percent copper mostly as chalcopyrite, but may contain other copper bearing minerals (for example, bornite, chalcocite, azurite, malachite), small quantities of pyrite and quartz. Porphyry copper deposits also contain economically significant quantities of gold, silver and molybdenum. Interestingly, the majority of the world’s porphyry copper deposits are concentrated along tectonic plate boundaries (Figure 1)."

Jan 1, 2016

By D. F. Kidd

Introduction In a companion article, Surveys at Great Bear Lake, 1931, R. C. McDonald has described the general character, topography, and climate of the Great Bear Lake-Coppermine River area and the main means of access (l). The present paper will largely be confined to the geological features of the district. In the last two years, the rocks of the region have received considerable attention, and papers including references to .the geological succession have been written by Knight(2), Duncan(3), Norris( 4), Reid(5), Cameron(6),and Kidd(7). The writer confined his field-work during the 1931 season to the district between LaBine point and Hunter bay and northwest to the head of McTavish arm. Brief trips were made down the Sloan river from McLaren lake, 25 miles northeast of Hunter bay, to that place, to Dowdell (Sixty-six) point, the south point of Echo bay, and to the region north of the Dismal lakes and west of the Coppermine river. The inner part of Echo bay, which is the area discussed by Reid and Cameron, has not been seen by the writer and the geology there will not be discussed.

Jan 1, 1932

By J. W. Rogers, S. K. Schwartz

"The Cape Breton Development Corporation (CBDC) is a federal Crown corporation which operates two coal mines (Phalen and Prince Collieries), a coal preparation plant, a railway, a central workshop and a deep water shipping facility.The Sydney coal field consists of 11 major seams, which range from 0.8 m to over 3.7 m in thickness. Of the 2.4 billion tonnes of known coal resources in the field, approximately 550 million tonnes can be mined with present mining technology. These parameters define reserves which extend more than 8 km beneath the ocean to a depth of 1200 m. With today’s design and present high production faces, the colliery life is projected at approximately 20 years."

Jan 1, 1996

By J. van Deventer

Volatile gold prices in the face of rising costs for mining and refining is causing the mines to look for new ways to reduce costs and increase recoveries. This task is complicated by the fact that the gold in hereto unexploited reserves is associated with increasingly complex ores - either preg-robbing, refractory, associated with high concentrations of copper, or all of the above. Ion exchange resins can play a significant role in this quest for improvement. Although ion exchange resins have been used in Former Soviet Union (FSU) countries for the recovery of gold for many decades, it is still not widely used in the Western World. Synthetically manufactured ion exchange resins can be tailor-made to suit the chemical and mechanical characteristics of a specific application. As such, ion exchange resins can be used in a variety of solution matrices (e.g. cyanide, thiosulphate and acid), and process designs (recovery from clear liquor after solid-liquid separation or directly from the leached pulp). In this paper, a number of applications are discussed along with a review of recent developments in ion exchange technology.

Jan 1, 2014

By Charles Kingsley

THE PRESIDENT (DR. C. B. KINGSTON, member C.l.M.M.) expressed regret that neither of the authors of the paper was able to be present to submit the paper in person. In their absence, it would be introduced formally from the Chair. It was a clear, straightforward account of a fine piece of shaft sinking, cleverly conceived and boldly executed. He referred briefly to the distribution and nature of the Dome ore-bodies and stated that, for both the miner and the metallurgist, the mine had provided a wide range of problems of unusual interest. Discussion on the paper was then invited. MR. THOMAS PRYOR said the paper was most opportune, because the subject of internal shafts did not appear to be fully treated in current mining literature. Many members were not familiar with Canadian gold deposits and it would be of interest if the authors could give a brief description of the location of the ere deposits of the Dome mine. This information would doubtless explain why a new internal shaft was needed in a position which required such an exceptionally long cross-cut to connect it to the main hoisting shaft to surface. It would also add to the value of the paper if the authors would give some idea of the duty expected of the new shaft in terms of tons of rock hoisted and of trips engaged in the transport of men and materials, and it would be helpful if figures could be given of the total capital cost of the hoists and subsidiary excavations at the shaft top, and of the cost per foot for sinking and lining the shaft below the collar. Turning to details of the paper, one was favourably impressed by the care given to the provision of a good travelling way for men in the main cross-cut, as shown in Figure 1. It was by no means always that one could walk in comfort and safety in a working where there was a 20-in. ventilating pipe in the roof.

Jan 1, 1939

By M. Hajian Heidary

In this investigation, effect of pressure depth on the globulizations of AZ91 magnesium alloy was studied. Cylindrical samples of AZ91 alloy with 1 cm and 2cm in height and 2.5cm in diameter (H/D = 0.4 and 0.8) were prepared, then the samples were hot pressed at 10 and 30% strain at a constant temperature of 200°C; subsequently reheated at 555°C in different times. Results obtained from optical microscopy (OM) showed that the thickness of the samples and consequently, depth of strain affected regions have remarkable effect on the degree of globulization. In addition, it was found that at a constant strain and holding time, structure of thinner samples is more globular than thicker ones.

Jan 1, 2007

By Walter E. Montgomery

ACCIDENT-PREVENTION work in years gone by has been carried on by many mine managers as a philanthropic movement, but in recent years they have come to realise that Safety is good business and pays tangible dividends. Let us begin with the word itself. We are told that an accident is "any-thing occurring unexpectedly, undesignedly, or without known or assign-able cause'. It is further explained that it is any 'unpleasant or unfortunate occurrence involving injury, loss, suffering, or death", and, finally, "any unintentional or non-essential circumstance". We admit that accidents are unfortunate, unpleasant, unintentional, and they generally happen undesignedly and to a great degree unexpectedly, but to say that they happen "without known or assignable cause" leads us to believe that the word 'accident' is often misused. Would it not be more correct to say that a man suffered a "personal injury"? The word 'accident' in its proper sense implies something over which no one has any control, but when the majority of all so-called accidents are analysed we arrive at the incontestible fact that some act or action, previous or present, was the underlying cause. As long ago as the year 1556 this fact was mentioned by Georgius Agricola, who, in writing a paper on metallurgy, aptly stated, "It remains for me to speak on the ailments and accidents of mines, and of the methods by which they can guard against these, for we should always devote more care to maintaining our health, that we may freely perform the functions of our body, than to making profits". Farther on, Agricola relates in more detail, "Sometimes workmen slipping from ladders into the shafts break their arms, legs, or necks, or fall into the sumps and are drowned; often, indeed, the negligence of the foreman is to blame, for it is his special work both to fix the ladder so firmly to the timbers that they cannot break away, and to cover so securely with planks the sumps at the bottom of the shafts, that the planks cannot be moved nor the men fall into the water; wherefore the foreman must carefully execute his own work. Moreover, he must not set the entrance of the shaft-house toward the north wind, lest in winter the ladders freeze with cold, for when this happens the man's hands become stiff and slipping with cold, and cannot perform their office of holding. The men, too, must be careful that, even if none of these things happen, they do not fall from their own carelessness'.

Jan 1, 1938

By Rafic Moubarac

FRP (Fiberglass Reinforced Polyester) equipment has been used in different and several applications during metals processing and extraction, and the hydrometallurgical process. Case histories of such equipment will be shown of major projects worldwide.

Jan 1, 2015

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb/Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb/Zn ore was traced to a pH effect. In the pH range 9.5-11 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH) 2 is suggested, the Fe++ions being derived from superficial oxidation of pyrite in the ore.INTRODUCTIONGalena and sphalerite commonly occur together. The usual practice is to float galena first followed by the flotation of sphalerite after activation with copper (II) sulphate. If ores contain pyrite it is depressed by maintaining an alkaline pH (9- 10) and using NaCN as depressant.In flotation tests with a Pb/Zn ore from Polaris selective flotation of galena could not be achieved consistently as a considerable amount of sphalerite, even though unactivated, floated. A systematic study was carried out to determine the cause of this problem. This led to the unexpected finding that sphalerite floated in the alkaline pH range 9.5-11.0 without preactivation with Cuso 4 . This paper describes the results of this study and discusses a possible mechanism of the flotation of sphalerite."

Jan 1, 1987

By T. W. Wong, M. A. Whitney, A. Hadadzadeh

Uniaxial compression tests were performed on cylindrical specimens, 10mm in diameter and 15mm in height, machined from an extruded AZ31B magnesium billet. The tests were conducted under isothermal conditions to a true strain of 0.5. The study compares macroscopic flow anisotropy between the extruded (ED) and transverse (TD) directions in the temperature range of 300°C to 500°C, and strain rate range of 0.001s-1 to 1s-1. Compression of ED specimens at low strain rate (0.001s-1) exhibited axisymmetric flow, and no significant differences were observed between geometries of specimens deformed above 350°C under the same strain rate. Deformation of TD specimens at low temperature and/or low strain rate resulted in elliptical cross-sections, with the anisotropy of flow being less significant at higher temperatures. Other studies performed using rolled plates have proposed that pyramidal slip and cross-slip at higher temperature eliminate the effects of initial texture, while the dominance of prismatic slip at lower temperatures will result in anisotropic flow. It is believed that the initial fiber texture common among extruded HCP-structured materials plays a role in the anisotropic deformation behaviour observed in the extruded specimens

Jan 1, 2015

By J. P. Cooney

Placer Dome is learning from experience in Latin America, Asia and Africa, as well as in North America, that contributing effectively to sustainable human progress in the areas of its operations presents unending challenges to think creatively, communicate effectively and remain culturally sensitive. People must be better off in terms of their economic circumstances, their social conditions and the quality of their natural environment not only during the life of the mines, but after mines close. Stakeholders, all those who are directly or indirectly affected by a mining project, should be able to participate in decisions which affect them. The development of sustainability strategies, the monitoring of sustainability performance and the implementation of sustainability programs are best done in partnerships with governments, communities, nongovernmental organizations and multilateral development institutions. Ultimately, the success, if not the survival of mining, will depend on our ability to get the sustainability equation correct.

Jan 1, 2000

By D. N. Madge

The use and development of industrial process control computers in the mineral industry during the 1970's has been sluggish. This cautious approach is due to lack of commitment by senior management. The lack of commitment is due to several reasons: variable mineral processes and technologies, market fluctuations, and excessive costs and inadequacies of applicable products supplied by computer vendors.

Jan 1, 1979

By John Canterford

Quay Magnesium Limited (QMG) listed on the Australian Stock Exchange in late September 2004 having raised approximately A$30 million with the object of designing, constructing, commissioning and operating a 15,000 t/a magnesium alloy production facility in Nanjing, China, Site construction commenced in February 2005 with installation of all major components completed by the end of October 2005, Hot commissioning was simultaneously commenced with the final stages of installation, leading to the first stage of continuous ingot casting by mid November 2005, Since that time ramp-up to the name plate capacity has been undertaken, This presentation highlights some of the more significant technical and logistical hurdles that have had to be overcome in order to meet the high quality product specifications required by a range of QMG customers.

Jan 1, 2006

By Min-Yuan Cheng

Heavy rainfall and typhoon oftentimes cause the collapse of hillslopes across mountain roads. Disastrous consequences of slope collapses necessitate the approach for predicting their occurrences. In practice, slope collapse prediction can be formulated as a deterministic classification problem with two class labels, namely ?collapse? and ?non-collapse?. Nevertheless, due to the criticality and the uncertainty of the problem, evaluating the collapse susceptibility of an area is a challenging task. This study proposes a novel Artificial Intelligence (AI) approach, named as K-Nearest Neighbor Based Bayesian Classifier (KNNBC), to deal with slope collapse assessment. In the proposed model, Bayesian inference is used as a framework to achieve probabilistic prediction of slope collapse. Meanwhile, K-Nearest Neighbor (K-NN) is employed as a density estimation technique. Equipped with probabilistic outputs, the K-NNBC is able to yield predictions with different levels of confidence and diminish misclassified cases. Experimental results point out that the proposed model is very helpful for decision-makers in slope collapse assessment and disaster prevention planning.

Aug 1, 2013