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By W. H. De Blois

Introduction In the contact process for ?the manufacture of sulphuric acid, sulphur dioxide gas - produced by the burning of sulphur or of sulphur-bearing ores, or as a by-product in the treatment of sulphide ores - is made to combine with the oxygen of the air to form sulphur trioxide, which then only requires the addition of water to form sulphuric acid. The substance, as for example platinum, causing this combination is usually referred to as a catalyst, a convenient term, in the definition and explanation of which many pages have been written. Catalysis is now a comparatively common means of effecting chemical combination, but if the question were raised here tonight as to what actually goes on when this apparently innocent third party unites the parties of the first and second . part, without itself being altered in any way, I am afraid even our most learned members would have to confess their inability to entirely explain the phenomenon; for although the subject is under investigation, there is still much to learn. The contact process, however, is one of the outstanding achievements in chemical engineering. ? From the standpoint of the difficulties involved and the time absorbed in their solution, it probably stands alone in the field of technical chemistry. In fact, the manufacture of sulphuric acid has, from the earliest days, been surrounded with problems which have interested the ablest chemists. The Chamber System Although this paper has particularly to deal with the contact process, it may not be amiss to refer briefly to the chamber system, which was, and still is, a most important factor in the sulphuric acid industry.

Jan 1, 1927

By P. C. Thurston, T. Setterfield, D. H. Watkinson

"The Maybrun copper deposit IS In a succession of pillowed basaltic flows in the Wabigoon sub-province, northwestern Ontario. The rocks have primary flow morphologies and remarkably well-preserved crystallization textures, including quench-textured plagioclase, in spite of metamorphism to the amphibolite facies. The sulphide assemblage chalcopyrite-pyrrhotite-cubanite with minor sphalerite and pyrite is primarily in interpillow spaces and is stratabound. Basaltic rocks immediately enclosing the copper sulphide minerals have an enrichment in Fe, Mg and K and depletion in Ca and Na relative to surrounding flows. The Maybrun deposit is interpreted to have formed contemporaneously with volcanism and alteration, and was subsequently metamorphosed with the enclosing basalts.IntroductionThe association o f significant base metal accumulations with mafic submarine flows in the Archean is as yet poorly documented. Such deposits, where noted, have typically been small, and are therefore commonly over looked. The Maybrun Mine, a 2.6 x 106-tonne copper deposit in pillowed basalt, has many similarities with large, well-documented volcanogenic deposits. Given the interpretation of the Maybrun Mine to be volcanogenic in origin, there is n o reason why similar processes could not produce large deposit s. This is an important realization in an area where Archean submarine mafic rock s are very common, but frequently are examined only superficially. As gold commonly occurs in deposits such as Maybrun, even modest-sized deposits may be economic. The basalts at Maybrun are remarkable for amphibolite-facies rocks because of their extremely well-preserved delicate volcanic textures, including quench textures.The Maybrun Mine is one kilometre south of Atikwa Lake, in the Wabigoon sub-province of the Superior structural province, 75 km southeast of Kenora, northwestern Ontario, at longitude 93°35'W, latitude 49°25'N (Davies, 1973). Archean metavolcanic and metasedimentary rocks and intrusions underlie the area. Goodwin (1970) concluded that the mafic and minor felsic metavolcanic rocks, as well as the overlying metasedimentary rock s, were an eastward extension of the lower cycle of the Keewatin type section for the Lake of the Woods area. He estimated that the stratigraphic thickness of Keewatin rock s in this area is about 6900 m, of which 87% is basalt. The flows contain numerous interlayered sills, predominantly of basaltic composition; they have been extensively folded, faulted, metamorphosed to amphibolite facies and intruded by numerous felsic bodies, most importantly the Atikwa Batholith."

Jan 1, 1983

By P. Mpofu

In this work, the modification of interfacial chemistry of colloidally stable kaolinite clay dispersion has been carried out to improve its flocculation performance and dewatering behaviour. Synergistic action between dispersion pH, hydrolyzable metal ion and high molecular weight polymeric flocculant structure type (anionic polyacrylamide-acrylate copolymer (PAM) and non-ionic polyethylene oxide (PEO)) was found to play a pivotal role in inter-particle bridging, the enhancement of the settling rate and extent of consolidation of the pulps. Flocculation with PEO led to higher settlings rates in acidic than alkaline pH, whilst for PAM, the maximum dewatering rate was achieved in the neutral pH range 6 - 7.5. Upon shear, the PEO flocculated pulps showed dramatic improvement in consolidation to 40 wt%, the extent of which was greater at lower than high pH values. For PAM-based pulps were however, not shear-responsive, lower sediment solid contents of 15 - 23 wt% was observed between pH 3 and 11. Hydrolysable metal ions, Mn(II) and Ca(II), used respectively at pH 7.5 and 10.5 in conjunction with PAM and PEO, significantly enhanced the settling rates and consolidation of the pulps. The findings exemplify the strong links existing between pH-mediated particle surface chemistry. polymer structure-conformation, inter-particle bridging and dewaterability of kaolinite dispersions.

Jan 1, 2004

By C. Liu

Corrosion behavior of the stir zone in a friction stir weld of dissimilar A12024/AZ31 alloys was investigated in the immersion test in distilled water (pH=6) for different times. Microstructures and the distribution of chemical elements were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Due to the difference in the corrosion potentials between A12024 and AZ31, the AZ31 alloy constituent in the stir zone was susceptible to the corrosion attack in the distilled water. The corrosion attack was found to occur in the narrow region of the AZ31 alloy adjoining the A12024 region, where there was a low ratio of anode-to-cathode surface area. The corrosion attack became more severe in the AZ31 alloy regions with increasing immersion time. The A12024 alloy region in the stir zone of the weld was protected by cathodic reactivity due to sacrificial anode AZ31 alloy.

Jan 1, 2007

By H. S. Fowler

The Consolidated Mining and Smelting Company has been in the business of mining and exploration since its incorporation in 1906. The Company has reports written as early as 1890. Consequently, its files contain a very large number of reports, and also of maps, of ail descriptions. REPORTS Before describing the filing of maps, a brie{ note on our general system of filing reports will perhaps clarify the discussion. Reports of a non-periodic nature, primarily those based upon examinations by field engineers, are separated from all other data and filed in what we know as the Mine Series System. Each property on which reports are written is given a serial number, known as the Mine Series Number. This serial number is assigned at the time the first report is filed and it remains permanently identified with the property, regardless of its state of activity. Our mine series numbers now total over 5,000. The serial number for a property may be found by referring to an alphabetical index of properties. MAPS We found it necessary to divide maps into two groups: (1) Maps of properties (2) Maps of areas

Jan 1, 1944

By T. M. Ruff

A GPS-based traffic awareness and collision avoidance system has been implemented at mines with long, narrow access roads to help avoid accidents involving two approaching vehicles or vehicles following too close. A simple display in the cab of each outfitted vehicle gives an indication of oncoming traffic and a voice announcement indicates the type of vehicle that is coming as far out as 300 meters. Advanced warning of approaching vehicles is increasing driver awareness, especially around blind corners and in adverse weather such as heavy fog, snow, or rain. Speeding alarms have also been implemented and are especially critical as a vehicle approaches reduced speed areas near single-lane bridges or tight curves. A description of the system, safety improvements seen since its introduction, and implementation challenges will be discussed.

Aug 1, 2013

By Z. F. Zhou, X. Y. Zhou, V. G. Papangelakis, Z. D. Jankovic, S. M. Ulyanov, S. N. Lvov

Recently developed flow-through electrochemical techniques (1,2) were employed for measuring pH in high concentration aqueous solutions and geothermal brines. The pH values of (1) 5.0 mol kg-1 NaCl + x mol kg-1 HCl, (2) 3.0 mol kg-1 of NaCl + 0.5 mol kg -1 of KCl + 1.0 mol kg-1 of CaCl2 + x mol kg-1 HCl (x < 0.1 mol kg-1), and (3) mixtures of Al2(SO4)3-H2SO4-H2O, MgSO4-H2SO4-H2O, and NiSO4-H2SO4-H2O solutions have been measured at temperatures from 100 to 280°C. The obtained experimental data and their thermodynamic analysis demonstrated that the electrochemical system can be used for on-line pH monitoring of high concentration aqueous solutions with an accuracy of ±0.1-0.3 pH units over a wide range of temperatures. Greater deviation exists in real laterite leach solution measurements due to in situ precipitation of Na-alunite. The system is excellent for research and process development work. Further work is needed to ensure robust operation under pressure leach conditions of laterites.

Jan 1, 2004

By D. B. Stewart

This paper reports on an investigation undertaken to determine the exhaust gas temperatures of operating underground mining equipment. The effectiveness of platinum catalytic purifiers is discussed. From exhaust temperatures, it is concluded that LHD engines are highly loaded, haulage truck engines are moderately loaded and utility vehicle engines are lightly loaded.

Jan 1, 1979

By N. Dahata

B206 aluminum?copper alloy has a potential for wider use in the automotive industry due to its light weight and relatively superior mechanical properties as compared to aluminum-silicon alloys. The possibility of casting this alloy via Lost Foam Casting (LFC) has not been investigated in detail. Therefore, the effects of foam types (T170B standard untreated EPS and T175-brominated EPS), coating types (Styro Shield 5553 and Styro Shield 5554), copper level (4.5 wt % and 5.0 wt %) and titanium levels (0.5 wt % and 0.25 wt %) were related to fillability, microstructure and microporosity. The metal velocity in T175 EPS pattern was higher than that in T170B EPS pattern. For T175 EPS pattern, the total solidification time was 3% higher and the loss of temperature for decomposition of EPS was lower than those in the case of T170B EPS pattern. The grain size, porosity level and maximum pore size were quantified using Light Optical Microscopy (LOM) and image analysis. The casting with T175 EPS pattern showed larger grain size relative to that with T170B EPS pattern. The porosity level and the maximum pore size decreased significantly when the titanium level was increased from 0.05 wt % to 0.25 wt %.

Jan 1, 2007

By M. R. Hudec, M. A. Nikolinakou, P. B. Flemings

"We model the shale response to the large deformations associated with salt bodies, and we identify the implications of the stress changes for hydrocarbon exploration. We employ both the static and evolutionary approach, and show that while the static one can model actual geologic geometries, only the evolutionary approach can provide a detailed description of the stress history of shales, which is essential for predicting stress, porosity, and pore pressure and, more generally, for understanding Earth processes related to salt-hydrocarbon systems.INTRODUCTIONDuring the last two decades, understanding the stress, material behavior, and pore pressure in shales around salt bodies has become increasingly important. The energy industry routinely drills near salt (Beltrão, Sombra, Lage, Fagundes Netto, & Henriques, 2009; Meyer, Zarra, Rains, Meltz, & Hall, 2005; Seymour, Rae, Peden, & Ormston, 1993), because a significant number of hydrocarbon reservoirs around the world are found in layers dipping away from salt diapirs.Salt is a viscous material that cannot sustain deviatoric stresses. Under differential loading it flows, changes shape, and eventually relaxes to an isostatic stress state (Urai & Spiers, 2007). Therefore, emplacement of a salt body and its viscous relaxation process may cause significant deformation of the surrounding sediments, perturb their state of stress and create local overpressures (Dusseault, Maury, Sanfilippo, & Santarelli, 2004; Seymour et al., 1993). As a result, drilling near salt is particularly challenging, and problems leading to additional expense or even abandonment are common (Bradley, 1978; Dusseault et al., 2004; Meyer et al., 2005; Seymour et al., 1993; Willson et al., 2003).Historically, salt and the evolution of its cross section to the present day geometry have been studied using kinematic restorations (Rowan & Ratliff, 2012). This approach aims to explain the present geologic section through a sequence of plausible past sections; however, it does not model the constitutive response of the wall rocks, hence it cannot provide any prediction on their state of stress. Similarly, largestrain numerical studies (Albertz & Beaumont, 2010; Chemia, Schmeling, & Koyi, 2009; Goteti, Ings, & Beaumont, 2012; Gradmann, Beaumont, & Albertz, 2009) have focused on the rheological evolution of salt systems without modeling the geomechanical response of the sediments."

Jan 1, 2015

By John T. Whetton

"FROM 1850 when the annual production was around 50 million tons, coal output in Great Britain expanded rapidly to 225 million tons in 1900 and 287 million tons in 1913. However, during the First World War, countries which had previously bought large quantities of coal from Britain sought other sources of sup-ply or developed their own coal re-sources. Thus from the record figure of 73 million tons exported in 1913, Britain's coal exports declined until in 1938 they stood at 39 mil-lion tons. An important reason for this was the development of oil engines for marine propulsion. Today, nearly all the navies and mercantile shipping in the world have turned to oil engines. Sometime in the future, however, it is reasonable to expect nuclear power to replace oil.During the Second World War, coal output in Great Britain and manpower at the mines were reduced considerably and in 1.945, 175 mil-lion tons were produced by 709,000 miners. Exports were meagre, only 8.""7 million tons went to foreign consumption. During the severe winter of 1947, inland demand for coal exceeded production and exports were prohibited. Even importation of coal was required to meet inland demand. These were years when the coal industry of Great Britain made immense efforts to secure maximum output irrespective of economy. The energy needs of Great Britain appeared insatiable; but had it been possible to export, the nationalised mining industry could have made huge profits as there was a world shortage of coal. However, home needs were considered to be the priority and many overseas markets were lost. Other producers moved in and secured long-term contracts. Not only was the British export market lost, but also the nationalised industry had to sell the imported coal at the same prices as home-produced coal and suffered losses up to of:3 per ton. Bence, at a time when the National Coal Board might have ac-cumulated a reserve fund to cope with less prosperons times, it was having to spend large sums of money securing sufficient coal for inland consumption. This was a time when intensive efforts in the mining industry, comparable with those of many industries and establishments inclusive of the armed services during the war, would have produced a greater amount of coal and have been of immense value to the country as a whole."

Jan 1, 1960

By Hamidreza Soltanzadeh

The injection of CO2 into a reservoir or aquifer can potentially result in deformation, induced fracturing and fault reactivation in the injection zone and/or the rocks that surround it. This paper reviews the data collection and geomechanical analyses performed to assess these potential hazards for the Heartland Area Redwater Project (HARP), in which CO2 sequestration is being considered in a carbonate (Leduc Formation) reef. A three-dimensional mechanical earth model (3D MEM) was developed using available geophysical log data from several wells. The geomechanical response to CO2 injection was studied using a finite element numerical model based on the 3D MEM and pore pressure distributions predicted using a reservoir simulator. The modeling results suggest that the potential for induced fracturing and fault reactivation is low and the maximum predicted ground surface heave is less than 2 cm. Sensitivity analyses conducted with a 2D geomechanical model that was extracted from the 3D model confirm that this conclusion holds true even when a reasonable measure of uncertainty in rock mechanical properties, ambient pore pressures and horizontal stress magnitudes is accounted for.

Jun 1, 2012

By R. W. Davis

INTRODUCTION CHURCHILL river was named for John Churchill, first Duke of Marl-borough and third Governor of the Hudson&apos;s Bay Company, in the latter part of the 17th century, some fifty years after the ill-fated Danish expedition, led by Munck, had abandoned the site of the now famous seaport of Churchill, as a worthless, cold, disease-ridden country. No other attempts were made to explore the interior until the river basin became a part of the grant to the Hudson&apos;s Bay Company and began to play its part in furnishing the luxury of fine furs to civilized people as it had furnished the necessities of food and dress for untold centuries to uncivilized natives. This was the sole contribution of the region to the economic life of the country for some two hundred and fifty years, until 1926, when the power site at Island Falls was discovered by engineers seeking a cheap power source to make possible the development of the great ore-body at Flin Flon. DRAINAGE BASIN OF CHURCHILL RIVER The river is some 1,325 miles long. Rising in the headwaters of the Beaver river, in east-central Alberta, it flows in an easterly direction across Saskatchewan and northeasterly across Manitoba to Hudson bay, through a remarkable basin of some 115,500 square miles, only 6,000 square miles less than the area of the British Isles. A journey down this river leads one through three distinct belts of country, each vastly different from the others geologically and in surface characteristics. For the first five hundred miles the river flows through a basin of 36,000 square miles of the great central-plains country, which is covered with fertile soil and carpeted in its southern part with prairie grass, which gradually gives way to the mixed forests of poplar, spruce, birch, and jackpine in the northern and eastern sections: About midway across Saskatchewan, bald-headed knolls and ridges begin to make their appearance as the river meets the western margin of the Canadian Shield. Then, for some seven hundred miles, it passes through country underlain by the pre-Cambrian rocks of the Shield, which continue to within one hundred miles of Hudson bay. Here the character of the country again changes to a low, clay plain underlain by sandstone, and through this &apos;clay belt&apos; the river flows between steep clay banks, to empty into Hudson bay.

Jan 1, 1935

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Nov 1, 2011

By D. Lascelles, J. A. Finch, E. El-Ammouri

Flotation separation is expected to be related to the degree of dispersion of the pulp. For instance, highly aggregated systems may show reduced selectivity, reduced entrainment and increased flotation rate. In an attempt to test the impact of aggregation on flotation, we have taken advantage of the effect of Mg ions. Using combinations of Mg2+ and pH gave a wide variation in aggregation of several Cu-Zn ores (measured by settling rate) and corresponding flotation response was determined by batch tests. The trials were conducted on-site at Louvicourt and Agnico-Eagle. In a majority of cases a similar trend in aggregation and flotation selectivity (grade at given recovery) was observed. At Louvicourt, improved selectivity with increasing aggregation at pH 10.5 was found. At Agnico-Eagle, an analogous association between aggregation and selectivity was observed at pH 11.5. It is suggested that aggregation influences particle entrainment, the increased effective particle size reducing gangue recovery and hence improving selectivity.

Jan 1, 2004

By A. W. Lovett

"THE last two years have been years of recession or, perhaps, years of marking time, depending upon whether the observer is a pessimist or an optimist. There has been a slackening in the industrial tempo that has been reflected in many ways in the national economy. As one of the chief barometers of economic health, the consumption and supply of energy reflect this slowing up.These same two years have also seen significant changes in the relation between the sources of energy. In periods of declining demand, it has happened in the past that coal, as the basic or residual source of energy, has shown the effects to a greater extent than the other energies. In these two years, however, in addition to this usual effect, there has been the acceleration in the Joss of market to diesels in the railway consumption category and the continuing decline in domestic consumption. The story of these years is presented in the statistical tables that form the foundation of this paper. Statistics, particularly in the form of tables, are rather dry and are sometimes difficult to follow but the overall developments are illustrated by graphs which present a more striking picture."

Jan 1, 1959

By G. Goodlad

This paper describes some of the main aspects involved in implementing the European “Equipment and Protective Systems for Use in Potentially Explosive Atmospheres” (ATEX) Directive (No.94/9/EC) in the British mining industry by the year 2003. It provides a brief background to the Directive and considers its main objective of removing all barriers to trade in Europe. It outlines the need for the European Standards making bodies to write new editions of the ’explosion protection concept standards’ and for manufacturers to adopt new quality management procedures and develop new versions of equipment in conformity with the ATEX categories of “M1” or “M2.” Finally, it assesses the possible future relationship between the European enforcing authorities, manufacturers and users of explosion protected equipment.

Jan 1, 1999

By K. Hambrice, E. Fauveau

"When it comes to measuring the level of bulk solids, liquids, and everything in between, guided-wave radar technology now offers more level-detection capabilities than ever before. For an ever-widening range of previously hard-tomeasure products such as molten sulphur, liquid ammonia and petrochemicals, guided-wave radar transmitters provide accurate level measurements even under harsh chemical environments, wide variations in operating temperatures and pressures, and low dielectric constants.Great strides have been achieved in making these units easier to configure to a variety of process applications coupled with the simplicity of integrating these devices with most digital communication protocols. These improvements come as welcome relief to process engineers within an expanded range of level applications across several different industries that seek solutions to measuring the contents of tanks, silos, hoppers, bins, mixing basins, and vessels.Because radar transmitters have no moving parts, radar has already established a dominant niche in level measuring that quickly distances itself from mechanical means, which do not hold up as well in dirty service. Radar achieves its nonmechanical level detection capability by measuring the time of flight of the transmitted signal.Known more accurately as time domain reflectometry (TDR), the process involves sending microwave energy down into a vessel. When the pulse of radar energy reaches the product (indicated by a change in impedance), part of the pulse is reflected back toward the transmitter.A receiver measures the exact duration of time between the transmitted and reflected signal — the “time of flight.” The device analyzes this time and ultimately displays the level of the product as a distance in feet, metres, or other engineering units."

Jan 1, 2003

By W. J. Adams

It is recognized that within life cycle assessment that the eco-toxicity potentials (TPs) derived for metals require additional research to improve their reliability. Current models used to develop TPs do not include important fate process for metals such as speciation and bioavailability. Toxicity potentials are standard values used in LCA to enable a comparison of potential toxic impacts between substances. Huijbrechts (2001) calculated toxicity potentials for 181 substances utilizing the USES model for six impact categories, i.e. freshwater aquatic ecotoxicity, marine aquatic ecotoxicity, freshwater sediment ecotoxicity, marine sediment ecotoxicity, terrestrial ecotoxicity and human toxicity (not considered here). Marine ecotox potential for metals is typically high using this approach, whereas most open ocean metal concentrations are very low. A sensitivity analysis of the USES-LCA model was undertaken using copper as an example. Results indicate: fate processes on the global scale are driving the marine water and sediment TPs for copper most; the second most important fate parameter is sedimentation from the water and burial in deep sediment layers; inclusion of speciation and bio-availability processes would be very beneficial; more accurate estimates of input parameters should be used, and the PNECwater and PNECsediment and all partition coefficients for metals should be updated in the model.

Jan 1, 2007

By J. E. Nesset

"As an alternative to conventional dewatering by vacuum filtration and oil-fired rotary dryers, Brunswick Mining conducted extensive pilot-scale testwork on its copper, lead, zinc and bulk concentrates using a Larox Oy (Finland) automatic pressure filter. The results showed that pressure filtration readily produced final cake moistures of 6-8.5 per cent on this very fine sulphide material.An in-depth analysis examines pressure filtration in terms of metallurgical performance and projects energy savings of 78 per cent for pressure filters over the current dewatering operation. Potential energy and operating cost reductions are also estimated.IntroductionVacuum filters followed by oil-fired rotary dryers are one of the most common means of dewatering mineral concentrates. They represent, however, a level of technology which is exceedingly wasteful in terms of manpower, space utilization equipment and fossil fuel dependence. In addition, the use of thermal dryers is leading to increased environmental concerns both in plant and out.These were the primary factors which prompted Brunswick Mining to consider alternative dewatering methods as the existing equipment came up for replacement and upgrading. In late 1979, company engineers were encouraged by automatic Larox pressure filters seen at several Scandinavian operations. Subsequent laboratory tests by the manufacturer (Larox Oy of Finland) on several concentrate samples were sufficiently promising for Brunswick and Noranda to lease a trailer mounted filter-lab unit and a technician from Larox for a five-week period. Extensive on-site testwork on all four Brunswick concentrates (zinc, lead, copper and &apos;bulk&apos; lead-zinc) confirmed the potential of pressure filtration."

Jan 1, 1982