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By Y. Wang

Phosphates and fluorides are used as regulators for the removal of silicates from diasporic-bauxite both in direct and reverse flotation. While using dodecylamine chloride as a collector, micro-flotation studies showed that sodium hexametaphosphate has stronger depressing power on diaspore than on silicate minerals with increasing sodium hexametaphosphate concentration at pH 6.5, but sodium fluorosilicate shows poor depression on diaspore with increasing sodium fluorosilicate concentration at the same pH. Zeta potentials of diaspore and silicate minerals become more negative both in the presence of sodium hexametaphosphate and sodium fluorosilicate. Adsorption density studies indicated that the adsorption density of sodium hexametaphosphate on diaspore is much higher than that on silicate minerals at the concentration of 75 mg/L. FTIR spectroscopy studies show that sodium hexametaphosphate interacted with the Al atoms exposed on the diaspore and silicate minerals surfaces to form P?O?Al bonds through the P02 groups. It is possible that sodium fluorosilicate interacted through F- or [SiF6]2- with silicate minerals surfaces based on the analysis by AES.

Jan 1, 2006

By Jun Deng

The aim of this paper is to study the scientificity and reliability of three coal gas indices used to predict coal fire disasters, namely Graham?s ratio, CO/CO2 ratio, Litton ratio and their different characteristics and service conditions. Data from a programmed temperature experiment were applied to check their veracity and accuracy. Each index performed well in detecting the level of a fire. We conclude that it is better to redefine the definition through experimentation before applying a given index. Integrated analysis of the results can provide reliable reference data for predicting spontaneous combustion of coal.

Aug 1, 2013

An optimized long-term mine planning determines the best order of material extraction, so that the Net Present Value (NPV) becomes maximum. In the case of oil sands surface mining, one of the key constraints in NPV maximization is the volume of tailings slurry that will be generated downstream. Specifications of tailings slurry are also important from environmental perspective. Moreover, most of the material that will be used for the reclamation of tailings ponds in later periods is generated in extraction and processing of oil sands. In this paper, an integrated optimization framework is proposed to maximize the NPV of the produced oil sands, with respect to tailings capacity constraints and reclamation material requirements. A mixed integer linear programming (MILP) model is developed to find the optimal solution for long-term mine planning problem. The proposed model is coded in Matlab and has been run using CPLEX for verification. The results for real-case oil sands dataset show that the optimal production schedule meets material requirements for reclamation, tailings volume is within tailings capacity range in all periods and the production schedule follows the predetermined horizontal direction.

Aug 1, 2013

By A. F. Gregory

"AbstractA resumé of aerial radiation survey studies performed by and for Eldorado Mining and Refining, Limited, since 1943 is presented. Flight tests were initiated in 1947 and were followed .by intensified use and study of Geiger counters and other radiation detectors. Development of an aerial scintillation counter began in 1948, but •a sensitive large crystal unit was not available for exploration purposes until 1950. Modifications of this unit have been used in all subsequent surveys.For the Eldorado detector, several limiting conditions were established for successful radioactivity detection, the most important being that natural vein exposures can only be assuredly detected .at distances less than 150 feet. Sedimentary and pegmatitic radioactive occurrences can be detected at much greater distances. A helicopter investigation technique appears to •have •a useful prospecting potential.IntroductionAerial radiation surveys were first proposed in the early 1940's. However, it was not until 1949 that airborne detectors were extensively used in the search for radioactive minerals. Eldorado has flown about 50,000 miles of exploration flights, exclusive of tests, using a variety of •detectors and aircraft. Considerable data have •been gathered for .the evaluation of the several techniques employed. Much of the early work was performed with the co-operation of the National Research Council of Canada ( 1). More recent work was done in conjunction with the Commercial Products Division of Atomic Energy of Canada, Limited. The Development Department of this latter corporation designed and built the scintillation counter used in recent Eldorado surveys."

Jan 1, 1955

By D. D. Downing

This paper is a review of material selection considerations concerning protective coatings in the mining industry. The discussion will cover both capital-dollar projects and maintenance requirements. Emphasis will be on industrial finishes for structural steel and process equipment subjected to aggressive atmospheres. The presentation will cover the total needs of a job, emphasizing not only the owner's requirement for a cost-effective system during plant operations, but also taking into consideration the short-term requirements of general contractors, steel fabricators, erection firms and paint contractors.

Jan 1, 1979

By Ron Zevenhoven

In Finland one opportunity for large-scale CO2 capture, utilisation and storage (CCUS) is CO2 mineralisation, i.e. mineral carbonation. A process route under development towards industrial application involves production of magnesium hydroxide or sulphate from serpentinite rock (serpentine = 3MgO·2SiO2·2H2O), followed by conversion either in a pressurised fluidised bed (PFB) reactor, giving magnesium carbonate, or in an aqueous solution process giving magnesium hydro-magnesites. Iron present in the rock is typically obtained FeO(OH). Results obtained with these process routes and progress towards industrial demonstration is addressed, process heat integration and operation on flue gases (without CO2 pre-separation!) being key features for economic viability. A process route utilizing calcium-containing slag by-product from iron- and steelmaking under development towards large-scale application is the so-called slag2pcc concept. It converts an industrial by-product into valuable material, reduces use of natural material and streams to landfills while binding CO2 produced by the process generating the slag. Using ammonium salts, calcium is extracted from steel converter (BOF) slags and subsequently carbonated in a two-stage aqueous process (at ambient temperatures and pressures). Precipitated calcium carbonate (PCC) is produced while regenerating the ammonium salt. Process performance and scale-up while guaranteeing a certain PCC quality are presented.

Jan 1, 2015

By N. Afrin

The microstructure and tensile properties of AZ31B-H24 magnesium (Mg) alloy after friction stir welding (FSW) were evaluated. The grain size was observed to increase from approximately 5 µm to about 9 µm after FSW. The obtained Hall-Petch type relationship showed a strong grain size dependence of the hardness values. While the FSW led to about half of the yield strength of the base magnesium alloy, the ultimate tensile strength after FSW could reach about two thirds of that of the base alloy. The hardening capacity of the FSWed samples was about twice of that of the base alloy. The strain hardening exponent of the base alloy was found to be about 0.1 whereas it became larger than 0.3 for the FSWed samples. After yielding the base alloy showed a high initial and almost constant work hardening rate, corresponding to linear hardening stage II, followed by stage III with a decreasing hardening rate. Stage II linear hardening was observed to be absent in the FSWed samples.

Jan 1, 2007

A direct comparison has been undertaken between laboratory wind tunnel experimentation and computational fluid dynamics simulation of a 3D manufactured analogue for a body of fractured broken rock, created with CAD/CAM techniques. Detailed descriptions of the ?design? of the analogue (using a discrete element analysis multi-body simulator), its manufacture (using computer aided design and 3D printing technology) and the laboratory experimentation (inserting the physical analogue into a laboratory scale wind tunnel) are presented. The agreement of the results of direct experimental observations on the manufactured analogue with the values from CFD simulations of those experiments justifies the utilization of a CFD environment for the practical investigation of geometric factors controlling air flow and heat exchange in complex assemblages of broken rock blocks. The ultimate goal is described, that of developing functional relations between bulk properties of such assemblages (such as their porosity and bulk density) and the low-level geometric factors that dictate the air flow behaviour, such as the equivalent perimeter length of the cross-sectional area available for flow, or average flow path tortuosity. A practical application area of the work in the mining context is also described; equivalent continuum air flow and heat transfer constitutive models developed on the CFD tool from such functional relations are useful in characterization of seasonal heat storage in large scale bodies (approximately 1 km3) of broken rock.

Aug 1, 2013

By C. J. Hartley

"Scandium oxide can be recovered as a by-product from process streams in a number of chemical and metallurgical plants including TiO2 sulphate pigment, Ni/Co laterite, zirconium oxychloride and uranium operations. The feed materials available for processing can be either mid or end of process streams containing many species in solution. This paper describes the strategies available to limit coextraction of elements into scandium containing streams from TiO2 pigment production and the removal of these elements to deliver high purity scandium oxide.A critical part of process development is to work within the constraints of the main process in terms of introducing new unit processes and producing minimal additional process intermediates and residues. This requires flexibility in designing flowsheets and plants to find novel process routes that avoid production of intermediates and/or the introduction of reagents that can compromise the main process operations.Bloom Energy has developed novel solvent extraction processes for the extraction and refining of scandium oxide that minimise impacts on core process streams within TiO2 pigment plants. The additional unit processes are designed to have minimal contact with pigment plant process streams to produce a concentrate that is refined to nominal 3N purity scandium oxide in a simple, small scale commercial plant."

Jan 1, 2016

By A. Brown

The swift decline of coal during the period of unprecedented expansion in the Canadian economy is a phenomenon deserving careful examination, because the underlying forces contributing to this decline may have broader implications in our national economy. At the present level of technology, coal is more difficult to process, transport and utilize than liquid and gaseous fuels. Fundamentally, it is a matter of limitation in technique. Because coal is a vast store-house of energy in Canada, the reduction of these limitations is in the long-term national interest.

Jan 1, 1967

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

Numerous data in the literature confirm that the chemical composition and consumption of grinding media influence electrochemical properties of flotation suspension as well as effectiveness and selectivity of upgrading processes. During a milling process, attrition of grinding media is observed. Depending on the susceptibility to abrasion, the grinding media influence, to a different extent, the redox potential, pH as well as flotation efficiency. As a result, different upgradeability of sulfide minerals is observed. The paper presents laboratory scale flotation results, obtained for the copper sulfide ore from Polkowice Region of KGHM Polska Miedz S.A. in Poland ground in the presence of forged steel, highchrome iron and stainless steel as the grinding media. The investigated flotation feed contained 36 g/t (ppm) of silver and 1.86 % of copper. Several flotation tests were conducted using fixed amount of frother and a mixture of sodium ethyl and isobutyl xanthates as the collector at three different doses of 75, 100 and 125 g/t. A comparison of the obtained results confirmed that the application of grinding media with different chemical compositions influenced the electrochemical properties of the suspension and recovery of silver and copper in the final concentrate. The highest values of redox potential were observed for the stainless steel as the grinding medium. Moreover, in the presence of this type of grinding media, regardless of the collector dosage, the best silver upgrading was observed. For the forged and high-chrome iron media, the recovery of silver depended on the collector dosage. It is indicated that higher levels of the redox potential, together with smaller amount of iron released from the grinding medium, improve the flotation of the silver-bearing mineral compounds from the copper sulfide ore.

Jan 1, 2016

By J. Graham Eby

"This paper describes the development and some typical applications of Wemco's large-capacity flotation machines, the No. 120 and the No. 144, with volumes of 300 and 500 cubic feet, respectively. During the 1960's, it became obvious that low-grade orebodies would be mined at high tonnage rates - plants and grinding mills would be larger, which would create a demand for larger flotation equipment. To meet this demand, Wemco developed a single-mechanism, 300-cubicfoot cell, having five times the volume of the standard No. 66 cell. The average production rate of the No. 66 cell on porphyry copper ore was 100 tpd per cell; and it was our intention that the No. 120 (300-cu. ft) cell would handle 500 tpd per cell, with at least equal metallurgical results and power consumption per ton. The success and industry acceptance of the No. 120 cell has since led to the development of a larger cell, the No. 144, having a volume of 500 cubic feet."

Jan 1, 1972

By George Brien, O&apos

The history of the lighting of mine workings dates back to the early part of the 18th century, when small candles known as tallow dips, were used. These were set or held in a lump of wet clay. When looking for gas the flame of. the candle was reduced to a mere glimmer by surrounding the wick below the flame with clay. The candle was then very cautiously raised from the floor toward the roof, the observer screening the brighter portion of the flame with his hand and watching for the first appearance of the pale blue cap above the flame, even at that time, known to indicate the presence of gas. When this appeared the candle was lowered quietly and its flame extinguished before attempting to drive out the gas. A very common and dangerous practice adopted at that time was to get rid of the gas by firing it. This was done by a person selected for his nerve rather than for his caution. Dressed in a? suit of dampened sackcloth or leather, this man well termed a "fireman", would lie prone on the floor of the roadway and light the gas above him by raising his candle fastened to the end of a long stick. If he survived, which was not always the case, he would withdraw promptly to fresh air after the flame had passed over him.

Jan 1, 1924

By M. H. Rana

"A survey of our knowledge in the field of rock mechanics is presented from the viewpoint of applications in the mining industry. Aspects of rock mechanics of special interest to the industry are enlarged upon, with emphasis on the avoidance of over-generalization. The relationship between fundamental and practical rock mechanics is discussed, and the need for cooperation between the university and industry to further our knowledge of -useful rock mechanics is emphasized. An attempt has been made to establish the scope of rock mechanics, as applied to problems in the mining industry. This is brought about by projecting rock mechanics as a tool to be intelligently used rather than magic, capable of producing ""miracles."" Continued education is important for individuals engaged in the application 0f rock mechanics in the mining industry. The scope of this education is discussed from a viewpoint of better communication between industry and the education and/or re-search establishments engaged in this work.Finally, the dangers of over-emphasis on rock mechanics are mentioned, but a justification of the in-vestment in rock mechanics programs in mines is also presented."

Jan 1, 1966

By Eurípides do Amaral Vargas Jr., J. A. de Mello Franco

"It is frequently necessary to excavate a tunnel for Civil Engineering purposes, or wells for petroleum exploitation, in laminated rock mass like schists or phyllites or in highly foliated gneisses. The determination of the pre-existing in situ stresses is essential, in order to assure the stability of these excavations. In most cases, the pre-existing triaxial stress field is arbitrary in relation to the tunnel or well axis. For these rock masses the concept of Generalised Plane Strain can be correctly utilized.There are closed form solutions for the calculation of stresses in anisotropic rock masses under Generalised Plane Strain conditions (Lehknitskii, 1981 and Hong , 1994). Based on these analytical solutions, established for the cases of Generalised Plane Strain, a synthetic problem will be formulated: the theoretical in situ stress tensor acting on this rock mass will be determined, with the aid of Bayesian Inverse Problem Techniques, as developed by de Mello Franco (2009). Additionally, the reliability of results obtained will be evaluated, in accordance with the research performed by this author. INTRODUCTIONThe Inverse Problem Technique, as developed in the paper, is based on the definitions and concepts obtained from the current literature and used for the solution of Inverse Problems, but the innovation to be presented is the utilisation of Bayesian Techniques and the determination of the reliability of the results obtained. This will be shown in a synthetic example where the determination of the in situ stress tensor, from strain measurements in a drill hole is supposedly performed. It is assumed that this drill has its axis arbitrarily placed in relation to the rock mass. Generalised Plane Strain conditions will hold for use with problem. The equations of Beltrami – Mitchel, in agreement to Lekhnitskii (1981) and Ong (1994), will be used in this synthetic case, for calculating strains, hypothetically measured in the hole before the final excavations. Finally a synthetic example for the determination of the in situ stress in a fully anisotropic rock mass, based on Bayesian Techniques and its reliability, developed in de Mello Franco (2009) is presented."

Jan 1, 2015

By J. W. Bingay

The expansion of the mining industry, with other industries, of course, is dependent upon a supply of fresh capital from year to year. Mining is a speculative form of investment, though there is a wide range of risk as between indiudual undertakings. All of the leading financial writers, nowadays, agree that expansion is being seriously interfered with by the unprecedented load of taxation Canadians are carrying. Individuals have less for investment and corporations are obliged to defer necessary expenditures in order that the demands of the taxing authorities may be met. Naturally, speculative investments such as mining exploration suffer first. Undoubtedly, a great deal of cash raised by taxes, if left in the hands of individuals and corporations for investment and expansion, would have been far more beneficially used and would have developed the country more than any use made of it by the government, in the way of bonusing new industries, or the undertaking of large schemes of development. Government undertakings of this nature are often entered into without a proper knowledge of cost and probable return. Expert expenditure of the same sums by business men or corporations undoubtedly would generally produce more prosperity for the country as a whole. The absolute necessity for lower taxation is being increasingly known to the public at large, and eventually it is hoped that our governments will see the economic impossibility of continuing the present rate of expenditure. The successful Finance Minister of the near future will not be the one who can borrow the most money.

Jan 1, 1924

By H. A. ?ye

The ISO TC 226 (Materials for the production of primary aluminium) has presently issued more than one hundred standards on the materials: alumina, pitch, petroleum coke, carbon anodes, carbon cathodes, ramming paste, fluorides and refractory). The object of the standardization work is to find methods that both material producers and smelters will accept. Methods that are specific for the operational conditions have been developed in addition to more traditional room temperature methods. Examples of important properties under operational conditions are: Air and C02 reactivity of anodes, Equivalent temperature for baked anodes, Sodium expansion of cathode blocks, Shrinkage and Rammability of paste, Penetration of electrolyte into refractories.

Jan 1, 2006

By A. R. Farkoosh, J-P. Fortin, M. Pekguleryuz, S. Bagherpour

"Titanium aluminides are structural intermetallics which offer an attractive combination of high temperature strength and light weight. For such properties, these intermetallic alloys have become front-runners in replacing nickel-based superalloys used for several high temperature applications. These alloys are produced from metallic titanium, aluminum and master alloys involving an expensive and difficult process. A low cost alternative to current industrial production method is the new modified aluminothermic process which directly reduces titanium oxide (TiO2) to titanium aluminides. Nevertheless, this process has itself significant challenges in achieving alloys free of oxide inclusions; the close densities of the slag and the titanium aluminides makes slag/molten metal separation a challenging task. Usually, the alloy produced requires a second refining step. In this study, thermodynamic calculations based on CALPHAD method were performed to determine the solidification path and an attempt has been made to develop a criterion to increase the density deference between the slag and the alloy by alloying with appropriate elements. Furthermore, scanning electron microscopy (SEM) and x-ray diffraction (XRD) techniques were utilized to examine the microstructure and phase selection of three Ti-Al alloys produced by the aluminothermic reaction, including the as-cast, refined in a controlled atmosphere and inert-gas-refined alloys. The composition range of the alloys studied was restricted to the a2-Ti3Al + ?-TiAl phase field (Ti-30Al) in the binary Ti-Al phase diagram leading to a lamellar structure with different complex intermetallics as shown in Figure 1.INTRODUCTIONTiAl based alloys are promising structural materials for high temperature aerospace and automotive applications. This is due to some attractive properties such as low density, high specific strength, high specific stiffness and high temperature strength retention (Wen-bin, Xue-wen, Hong-fei, & Yong-feng, 2011). These alloys have become leading candidates to replace Ni-based super alloys in gas turbine engines. Replacement of Ni-based super alloy parts with titanium aluminides is expected to reduce the structural weight of high performance gas turbine engines by as much as 20–30% (Kothari, Radhakrishnan, Sudarshan, & Wereley, 2012)."

Jan 1, 2016

By Chr. Krause

Within the scope the collaborative research centre 599 (Medical University of Hanover, University of Veterinary Medicine Hanover, University of Hanover) the behaviour of the degradation of magnesium materials as implants are investigated by using animal experiments (rabbits). Thus extruded cylindrical pins from the magnesium alloys MgCa0.8%, WE43 and LAE 442 were implanted intramedullary in the tibiadiaphyses. The implantation duration was 3 and 6 month. After the explantation 3 point bending tests were carried out to investigate the possible changes of the mechanical properties. Clearly changes in dependence of the implantation duration could be determined. The three magnesium alloys show a decrease of the mechanical resistance with an increasing implantation time. To evaluate the degradation process, wich is the reason for the changes, micrographs and element analyses (EDX) have been accomplished after the 3 point bending tests. The micrographs show for all used magnesium alloys corroded surfaces but no preferred corrosion on the grain boundarys. The element analyses show beside a layer which is rich in calcium and phosphorus an agglomeration of rare earth elements in this layer. With these results a using of magnesium alloys as a material for implants can be announced.

Jan 1, 2006

By M. T. Shehata, R. W. Revie, M. Elboujdaini

Environmentally assisted cracks in linepipe steels are initiated either as a result of stresses in combination with environmental effects, as in stress corrosion cracking (SCC), or as a result of trapped hydrogen in the steel, as in hydrogen-induced cracking (HIC). To understand better the mechanism of the crack initiation process, key metallurgical and environmental elements that can affect the cracking phenomena were investigated and are reviewed in this paper. The complexity of both cracking phenomena results from the dependence of SCC and HIC on multiple metallurgical, mechanical, and environmental parameters that may all influence both crack initiation and propagation; e.g., composition, microstructure and non-metallic inclusions in the steel, applied stress, water chemistry in the field, and ionic concentrations in the groundwater near the pipe surface to name a few for SCC. In addition, for HIC phenomena, one can add the concentration of H2S in the fluids transported in the pipe as well as concentration of CO2, pH, etc. In this paper, cracking of linepipe steels is analyzed critically, with particular attention to the crack initiation process. The paper is divided into two parts: The first part covers SCC and the second covers HIC.

Jan 1, 2005