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By Warren A. Sheaffer

THE chief uses for copper are as a conductor of electricity and as the chief component in brasses and bronzes. For such uses, the copper must be of very high purity. H the impurities are zinc, iron, lead, arsenic, or antimony, they can be removed to a great extent by fire-refining. H, however, gold, silver, nickel, or cobalt are present, electrolytic refining is necessary. Electrolytic refining must be preceded by fire-refining and hence all impure copper must be fire-refined. The electrolytic refining of copper is most efficiently carried on when the impurities in the anodes are at a minimum. Some of the impurities tend to deposit with the copper at the cathode, while others remain in solution, decreasing the conductivity of the electrolyte and thus increasing the voltage necessary for refining. Since these dissolved impurities must be removed by continuous purifications, the amount of impurity in the anode copper should be reduced by furnace refining to some predetermined limit. Anode furnace operation aims to reduce these impurities to a minimum beyond which the cost of further furnace refining would exceed that of removing the remaining small amounts of impurities from the electrolyte. The anodes should have a fine-grain internal structure because any pieces of metal becoming detached from the anode during the electrolytic refining are inconvenient to remove from the cells and may cause short-circuits. Impurities tend to disrupt such a structure and thus form zones of weakness during corrosion. When the impurities are reduced to a satisfactory mini-mum, the anode, due to having a fine-grain structure, will corrode uniformly over the entire surface area exposed to the electrolyte. Oxides of the impurities may be volatile, in which case they pass off as flue gases, or they may form viscous slags having a lower specific gravity than molten copper, thus permitting their removal by skimming. Some impurities can be oxidized by introducing air into the bath. Due to the large solubility of oxygen in molten copper, oxygen is distributed uniformly throughout the bath and thus comes into intimate contact with all impurities. The oxides which are insoluble in molten. copper are removed either as flue gases or as slag.

Jan 1, 1942

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By R. S. Adhikari

The changes in defects patterns or in element condition index during visual inspection of bridges are primary concerns for inspectors. This paper presents a new approach for change detection of defects in bridges by identifying changes in texture patterns through spectral analysis of digital images. The commonly used method for change detection is image differentiation. This subtraction method requires images to be of same size, scale, and rotation. However, no two images are same in real practices. Thus, image registration is required to align images and to produce change maps. This process is tedious and it is difficult often to achieve a good registered image. But, the change detection task can be readily modeled in frequency domain for texture patterns discrimination and also for quantifying their properties. This paper proposes a novel approach for change detection by transforming digital images into Fourier spectrum. In new coordinate system, 1-D signature functions can be drawn which facilitates easy comparison of textures in different directions. The proposed methodology provides useful tools for comparison of inspection history graphically and quantitatively. In practice, expensive sensors are used to detect subtle change in defect patterns. The proposed method can be used to detect any subtle change in defect patterns using digital images at much lower cost.

Aug 1, 2013

By N. W. Hendry

ABSTRACT Exploration by geophysical methods and diamond drilling of an occurrence of chrysotile asbestos, located ten miles east of Matheson, Ontario, was commenced on March 25th, 1949, by the Canadian Johns-Manville Company, Limited. The asbestos is associated with a narrow sill-like body of basic and ultrabasic rocks which strikes northwesterly across portions of Munro and Beatty townships. To date, asbestos zones of commercial interest, many hundreds of feet in length, width, and depth, have been outlined by diamond drilling along a 2-mile length of serpentine. The fractures occupied by the asbestos veins are closely associated with the regional faulting in the area. The mining of the first occurrence, or A orebody, will be by open-pit methods. Milling will commence at a rate of 50 tons an hour. INTRODUCTION OCCURRENCES of chrysotile asbestos in Munro township have been known at least since 1914 and references to them appear in reports published by the Ontario Department of Mines in 1915 (1) and 1919 (2). J. G. Ross (3) in his excellent publication on Chrysotile Asbestos in Canada, mentions an occurrence in Munro township. The area was first mapped in detail by J. Satterly, of the Ontario Department of Mines, in 1944, and brief mention is made of chrysotile asbestos in Satterly's preliminary report (4), which was published the following year.

Jan 1, 1951

By J. Gogal

Cameco's Cigar Lake Operation (CLO) started commercial uranium ore production in 2015. Initial mining was focused in areas of the ore body with relatively low concentrations of elements of concern (EOCs). As mining progressed into areas of the ore body that were richer in EOCs, some statistically significant behavior of certain analytes was noted in the water treatment circuits. It was ultimately found that the CLO ore body natively hosts numerous alkyl arsine compounds in addition to inorganic arsenide minerals. The alkyl arsines were found to be recalcitrant to typical adsorption on ferrihydrite, with the degree of recalcitrance associated with the degree of alkylation. A number of changes to the process circuits and water balance were performed and planned in order to inhibit the transport of alkyl arsines from the ore stream into the process water stream, and to optimize the overall site water usage. In some instances, the interactions of equipment in conjoined circuits of the process had controlling effects on the behavior of the overall circuit. Work continues to iterate upon the capital design features in order to further tighten the water balance, and to optimize water usage and operating costs.

Jan 1, 2020

By N. Katsikaros, A. Lewis-Gray, P. Richards

"To optimize gold recovery in complex leach-to-electrowinning processes, Gekko Systems developed the Gekko resin exchange column (G-REX) as an intermediate step, using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin. Operational experience has been gained at the Castlemaine Goldfields Ballarat gold mine. In near-continuous operation since 2008, the Ballarat plant treats unclarified concentrate leach solution. The extension of this technology to higher throughputs and more complex chemistry is discussed.RÉSUMÉ Afin d’optimiser la récupération de l’or dans des procédés complexes impliquant la lixiviation suivie de l’extraction électrolytique, Gekko Systems a développé la colonne Gekko de résines échangeuses d’ions (G-REX) comme étape intermédiaire, à l’aide d’une résine hautement sélective pour la récupération de l’or qui permet d’isoler les métaux contaminants. Gekko détient la licence exclusive pour la résine AuRIX®100 produite par Purolite, et la colonne G-REX a été spécifiquement conçue pour cette résine. C’est à la mine d’or Ballarat de Castlemaine Goldfields que l’expérience opérationnelle a été acquise. L’usine de Ballarat, en exploitation quasi-continue depuis 2008, traite une solution concentrée non clarifiée de lixiviation. L’extension de cette technologie à des capacités supérieures et à une chimie plus complexe est examinée."

Jan 1, 2017

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001

By C. J. Havard, G. C. Taylor, D. G. Cook, N. C. Ollerenshaw, D. K. Norris

"The area encompassed by this report is the eastern and northern Cordillera, shown on the composite map accompanying these background papers. It extends from the 49th pm•allel to the Arctic Ocean and from the Rocky Mountain and Tintina trenches to the Interior Plains. The Mackenzie delta is included in the discussions because of the implications of the bedrock geology of the Arctic Plateau and Coastal Plain on the hydrocarbon and mineral potential beneath it.The eastern and northern Cordillera forms the back-bone of the Western Canada sedimentary basin and from it most of the principles of orogenesis and epeirogenesis relating to the understanding of the structural, depositional and fossil record of the basin have been derived. It may be divided roughly into two parts, reflecting basic differences not only in structural style but also in mineral potential. The more easterly and younger rocks generally contain hydro-carbons, coal and non-metallic minerals; the more westerly and older rocks contain metallic and industrial minerals."

Jan 1, 1970

By J. F. Liu, L. Chen, C. P. Wang

"Calcite-cemented joints abound in the rock masses of Beishan area, which is the most potential area for the high-level radioactive waste (HLW) disposal of China. The mechanical properties of Beishan granite containing a calcite-cemented joint with a dip angle of 82° was investigated under uniaxial compression and the acoustic emission (AE) characteristics were also studied in this paper. Compared to intact granite, the calcite-cemented joint caused a decrease more than 50% in uniaxial compressive strength and a decrease more than 90% in shear strength. The Young’s modulus was also decreased, while the circumferential deformation of jointed granite was sharply increased. The AE monitoring system successfully recorded the process of micro-crack development and the results indicated that the risk of rock-burst could be reduced due to the appearance of calcite-cemented joint.INTRODUCTIONThe properties of jointed rocks differ considerably from that of intact rock. Due to the difficulties in specimen preparation, analogue experiments with artificially prefabricated fractures are often used to study the mechanical behavior of jointed rock (Chen et al. 2012; Kulatilake et al. 2001; Singh et al. 2001). However, natural joints are not quite similar to the artificial fractures and it is necessary to investigate the mechanical behavior of jointed rocks. Xie et al. 2011 studied the mechanical properties of marbles with natural joints by uniaxial compression tests and found that the uniaxial compressive strength of jointed rock is greatly decreased. With the unaxial compression tests, Jacobsson 2005, 2007 tested the intact and jointed granites, which were taken from the potential site for high-level radioactive waste (HLW) disposal of Sweden. However, no significant difference in strength or modulus was found. The above research results are inconsistent and it indicates the complexity of the mechanical properties of natural joints."

Jan 1, 2015

By J. J. Laffin

In the pursuit of comfort and safety, the wonders of science have given us controlled heating and cooling, thus enabling us to enjoy all the aspects of present-day living to an extreme never previously •envisaged. Man's attempt to conquer the elements largely involves con-trolling the temperature around him. Without having conquered this aspect, his body energy would be consumed in trying to maintain physical comfort, rather than being invested in the explorations which have resulted in man's control over the forces of nature. The indirect methods used to obtain the most agreeable temperature environment were developed because of the natural tendency to strive for increased safety, convenience and comfort. Until the twentieth century, when heat generated by atomic fission became a reality, man's only source of heat, except for that of the sun, came from his discovery of fire.

Jan 1, 1962

By R. Glenn Madill

Western Canada is defined, for the purposes of this paper, as that part of the Dominion bounded approximately by the 95th and 141st meridians of longitude and the 49th and 80th parallels of latitude. It is comprised of Manitoba, Saskatchewan, Alberta, British Columbia, Yukon, and that portion of the Northwest Territories lying to the west of the 95th. meridian. The first magnetic observations made in Western Canada were in the interests of navigation by sea. Observations were made by Captain Middleton in Hudson bay at Churchill and York Factory in 1725, and along the Pacific coast by Captain Cook in 1778 and Captain Vancouver in 1792. The first systematic magnetic survey in Western Canada was made between 1819 and 1826 by Sir John Franklin in his widely distributed explorations. It is of interest to find that while the first magnetic declination observations made in Hudson bay and along the Pacific coast were purely in the interests of navigation, the next investigations, which were made in the Western Arctic, included measurements of inclination and force with those of declination. There was a valid reason for this more complete research into the magnetic field as the construction of declination charts depended on the position of the north magnetic pole. Halley promulgated a theory 1683 that " the globe of the Earth may be regarded as one great magnet, having four magnetic poles, two of them near each pole of the equator, and that in those parts of the world which lie near any of those magnetic poles the needle is chiefly governed thereby, the nearest pole being always predominate over the more remote" . The position of a magnetic pole may be defined as a point where the inclination is 90 degrees and the horizontal force zero. It is obvious that the position cannot be' defined by declination observations alone since, for some distance from the magnetic pole, .the horizontal force is too weak to give directive force sufficient to effect the pointing of a compass.

Jan 1, 1948

By A. P. Craig

"I HAVE BEEN looking forward to addressing this particular audience about Trans-Canada Pipe Lines because you men, more than most, understand the problems of the pioneer. Trans-Canada Pipe Lines qualifies as a pioneer on two counts: it is certainly pioneering a completely new industry in Canada -the long-distance transmission of natural gas -and it has at least a few of the problems that are expected and normal to any pioneering venture.This morning, I’m going to try to give you a sketchy picture of our project and a brief report on its current status and our progress to date; and then a broad picture of Canadian markets for natural gas.The physical characteristics of the Trans-Canada Pipe Lines project have been discussed so often that I am not going to take the time today to quote a lot of statistics on pipe sizes, miles, tons of steel, etc. Suffice it to say that this project, estimated to cost approximately $350,000,000, will be the longest large-diameter gas pipe-line ever built anywhere.Let me try to paint a broad picture of this great national project, using only a few basic 'round' figures.First, it involves exploration for and development of the natural gas fields in Alberta and other provinces -the cost of which will run into hundreds of millions of dollars.Then comes the gathering, stripping, and cleaning of the gas before it can be delivered to Trans-Canada. This will cost close to $100 million.Next we have the Trans-Canada Pipe Lines project for transmission of the gas to Eastern markets -estimated to cost $350,000,000 during the first three to four years and making natural gas economically available to one-half the population of Canada."

Jan 1, 1955

By W. R. Bacon

"The Canam property is in southern British Columbia, 24 miles southeast of Hope. It is reached by 5 miles of road from Mile 26 on the Hope-Princeton Highway.Between the years 1930, when the property was discovered, and I 938 development work by The Consolidated Mining and Smelting Company of Canada, Limited included some open-cuts and six adits totalling 2,700 feet in length. Canam Copper Company Ltd. explored the property intermittently from 1947 to 1955 by diamond drilling and underground work, including driving No. 10 adit. From surface down to the level of No. 10 adit, about 1,250,000 tons of ore has been outlined with an approximate grade of 1.25 per cent copper, 0.8 ounce silver per ton, and 0.01 ounce gold per ton. The ore in the upper part of the deposit also contains a little molybdenum and a little uranium.In June, 1955 Canam Copper Company Ltd. made arrangements to have the property brought into production under the direction of Mogul Mining Corporation Ltd. of Toronto, and a new low level adit has been started.GENERAL GEOLOGYThe principal rocks on the Canam property are chert, cherty argillite, and argillite. They are considered to be Jurassic or Lower Cretaceous in age. Although massive bands to 150 feet in thickness occur, these rocks are in general thinly bedded. Conformable bands of pyrrhotite, a fraction of an inch in thickness, are not uncommon in the well-bedded rocks, and fine tourmaline can be observed in various places.The sediments strike slightly west of north and dip quite steeply, generally eastward; however, sharp divergences from this general attitude are fairly common.Dark grey dioritic sills, in which slender prismatic crystals are conspicuous, are fairly common in the sediments. In general the sills are less than 25 feet in thickness, but a few are as much as 100 feet thick. Under the microscope the sills are seen to consist largely of amphibole (pargasite) and plagioclase (near An50)."

Jan 1, 1949

By Malcolm Black

Introduction The circumstances under which the gold mining industry was forced to curtail operations a few years ago are well known to all. The effect of those circumstances is particularly noticeable when one enters some of the larger mills that were designed, in better times, to treat relatively large tonnages. On their grinding floors one will observe that a number of grinding units are lying idle, and the ravages of rust are everywhere in evidence. The same applies to other equipment throughout these mills. In 1941, we found it necessary to reduce tonnage considerably in the Wright-Hargreaves mill. With the assumption that a lower tonnage would be of long duration, we began to focus our attention on some of the idle equipment with a view to re-arrangement of the flow-sheet for greater economy of operation. In an article by the writer published in the Engineering and Mining Journal (March, April, and May issues, 1939) , it was pointed out that in designing this mill there was a very limited floor space available. The choice of thickening equipment was imposed solely by the necessity for space: conservation. Thickening by gravity would have required 5,000 square feet of floor space, whereas Genter thickeners required only 1,200 square feet. As a consequence, the Genters were chosen. The decision to add flotation to the circuit was made primarily to save space. On a cost-plus-tail basis, 80 to 100 hours agitation on all pulp would produce similar overall results, but would require much more space.

Jan 1, 1948

By W. R. Hargrave

"Mining OperationsOre will be mined by open pit techniques. Because of the high grade of the deposit and the low strip ratio, mining rates are small relative to most other open pit operations.The ore deposit is located in the valley of the main fork of Red Dog Creek. The bulk of the deposit is located on the southwestern flank of the creek, but mineralization does traverse the creek in both the north and east directions.Erosion has exposed the orebody in a number of locations, and has resulted in oxidation of the mineralization closer to the surface. Although much of this oxide material is very high grade, it leaches readily and, at least in the initial phases of the operation, will be stockpiled and not treated in the concentrator.During construction, 2.3 million mt. (2.5 million st.) of overburden and waste will be stripped from the orebody to expose ore for initial operations. Competent non-mineralized waste will be used to build roads and waste dumps, but the bulk of material removed consists of oxide or ice-rich soils and weathered rock which is not suitable for construction.The annual ore mining rate will be 1.9 million mt. (21. million st.). The strip ratio will start off at 1.2 to 1, falling to 1.0 to 1 by year 5 and ultimately to 0.8 to 1.Bench heights are set at 7.6 m (25 ft). Pit slopes will vary depending on the material present in the wall. The slope, through competent waste and the sulphide package, was set at 45 degrees. This is flattened to 26 degrees (i.e. 2: 1) through overburden and Upper Kivalina shales. The Kivalina Shales are an ice-rich shale whose carbonate matrix has been leached out and which exhibits little or no strength as it thaws. In addition, a 100 ft containment berm will be left in the wall below overburden and Kivalina."

Jan 1, 1989

By Lachezar Tsotsorkov

Being a mining company, Assarel-Medet has a significant impact upon the environmental components. In order to meet the legal requirements and the requirements stipulated by the effective permits as well as to reduce the environmental imprint throughout the years, the policy of the company to implement a number of projects to improve the environmental components quality and the environmental state in the company?s region. The projects associated with atmospheric air quality management and reduction of the impact exercised by Assarel-Medet JSC by implementing various measures to eliminate the potential sources of the impact, preventive and rehabilitation initiatives as well as organizational and administrative activities are among the most important ones. A stable improvement of atmospheric air quality in the region and minimization of the company impact upon the ground air state in the region was observed in the period from 2005 to 2012 due to the applied measures. This project is a contribution to the environmental protection, in particular to atmospheric air protection, by applying integral monitoring and modeling methods to identify the negative impact by the mining companies and plan measures to reduce and restrict it as well as to improve the quality of the environment and living area of people working and living in the impact range as an element of sustainable development.

Aug 1, 2013

By James H. Cobbs

Blind boring of shafts is becoming an increasingly important part of shaft sinking. Blind-bored shafts have reached diameters of 25 It in Europe and 16-1/2 ft in the United States. Much of the technology developed for blind boring has evolved from the technology of drilling wells for oil and gas production. Blind boring offers economic advantage in a number of situations where conventional shaft sinking either is extremely difficult or very expensive by virtue of large-capacity aquifers which must be penetrated, unstable ground or where very rapid sinking is required. In sedimentary rocks, blind boring is cost competitive with conventional sinking, in diameters of about 12 ft or less. Blind boring is not competitive with raise boring where conditions are favourable for raise boring. Blind boring does, however, offer greater flexibility than raise boring and can be performed in situations where raise boring is inefficient or impossible. Combination machinery has been developed to perform both blind boring and raise boring, so that the machine can be used effectively in situations where only the near-surface portions of the shaft are unfavourable for raise boring. Development work is being supported by the United States Bureau of Mines for blind boring equipment capable of boring shafts up to 30 feet in diameter.

Jan 1, 1979

The use of QemSCAN in providing mineralogical input to detailed ore and product characterization has proved of immense value in recent years. In this paper, a brief review of selected Cu-case studies is presented to demonstrate the versatility of automated, quantitative mineralogy by QemSCAN. This versatility ranges from measurement and analysis strategies through to data processing and presentation. As a rapid diagnostic service, it is common to find that only grain size, the degrees of liberation and/or ore mineral modal mineralogy are of interest. By contrast, the detail afforded by the simultaneous determination of both gangue and ore minerals can alert mineral engineers to fatal flaws and attributes deleterious to processing that are directly a function of silicate and other gangue mineralogy. Examples of the latter effects include the influence of micaceous minerals and acid consuming species, while the former include fluorine minerals, which can provide both processing and environmental challenges.

Jan 1, 2007

By Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

At the present time of depletion of reserves of high grade rare earth deposits, it has become necessary to involve low grade raw materials in the production. Among the rare-earth deposits in Kazakhstan, the most advanced one is Kundybai. The mineralogical composition of ore is represented by the minerals: a-quartz SiO2, kaolinite Al2(Si2O5)(OH)4, muscovite KAl2(AlSi3)O10(OH, F)2, albite Na(AlSi3O8), rutile TiO2, and hematite Fe2O3. It contains: 59.1–68.5% SiO2, 19.1–28.4% Al2O3, 7.2–10.3% Fe2O3, 0.51–0.84% TiO2, 0.10–2.32% CaO, 0.39–2.10% MgO, and some other elements. Rare earths are located in the clay part (kaolinite, goethite) in the ion-adsorbing form, and they are represented by the main ore mineral churchite - YPO4·2H2O. In the ore the amount of rare-earth elements (total REEs) varies from 210 to 600 ppm. Elements of the cerium group predominate (La, Nd, Ce, Sm, Pr) and the yttrium group is represented by Y, Gd and Dy. Extremely thin intergrowth and accumulation of REEs in clay minerals cause difficulties in their recovery using flotation and gravitation beneficiating methods. The purpose of this work is the development of an extraction method for the main mineral components of ore with transfer of the total REEs into the solution with high extractive efficiency. Results of the experimental work into high-temperature processing (hereinafter referred to as sulphatization) of ore by sulphuric acid with subsequent dual-mode water leaching of the sulphate product (sinter) are presented in this manuscript. The influence on the ore sulphatization process of some physical and chemical parameters: liquid-to-solid (L/S) ratio (0.36–0.86 cm3/g), temperature (100 – 500°?), concentration of sulphuric acid (3.0–18.62 mol/L) and duration (0.5–2.5 h) was studied. Optimal technological parameters of the process were determined to be: L/S ratio 0.36–0.46 cm3/g; temperature 500°?; concentration of H2SO4 9.0 mol/L; soaking time 1.5 h. Under these conditions it is possible to obtain extractions of ~ 85% REE, as well as 58% aluminium and 10% iron. XRD and IR-spectroscopy analyses were used to determine the material constitution of sulphated cakes obtained under optimal conditions. It was found that the primary minerals are quartz and muscovite; however different sodium aluminium silicates and albite minerals are present as well. In the future, it is proposed that the leach residue cakes are processed into precipitated silica (“white soot”).

Jan 1, 2016

By T. Banerjee, Y. Dumais, R. Lemire

"Agnico Eagle LaRonde produces over 300,000 ounces of gold annually, along with silver, zinc and copper by-products. The LaRonde plant consists of a conventional SAG and Ball mill circuit, followed by flotation. Load management is imperative for maintaining stability in grind size and ensuring consistency of the flotation feed. In flotation, the mass pull profiles of the cells and reagent dosage rates need to be managed to maximize recovery, while maintaining product quality. This is achieved by controlling the air, level and reagent addition set-points across the circuit. However, disturbances such as feed size distribution, ore hardness and mineralogy make it challenging to maintain efficient control using traditional control techniques. LaRonde therefore worked to develop a progressive control strategy, targeting stability and optimization. This started with a year-long instrumentation upgrade campaign, focusing on optimizing the performance and reliability of plant-wide instrumentation. The process was then optimized, leveraging AwaRE advanced controllers running in closed loop with PARC modules embedded within the PLC. The installation of 8 PFC cameras in flotation changed the flotation operation from a level and air control based strategy, to one that controls mass pull. This new control philosophy has allowed the plant to effectively manage mill load, improving grind size and providing increased throughput with better flotation performance.INTRODUCTION Background Since 2015, Agnico Eagle LaRonde has been conducting an optimization campaign to maximise the performance of plant assets leveraging instrumentation and control. The grinding and copper flotation circuits were identified as the areas having the greatest opportunities and value proposition for advanced control. A disciplined approach was followed to design and implement a progressive control solution to achieve operational excellence."

Jan 1, 2018