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By B. Hagemeyer

The trend to higher solids paper coating and to neutral/alkaline papermaking is causing an above average growth in the use of calcium carbonate as both a paper coating and a paper filling pigment. These developments are expected to continue well into the 1990s. Thus, calcium carbonate will account for a somewhat larger percentage of total paper pigment volume. Nevertheless, overall growth in paper tonnage coupled with an increase in filler pigment percentages will create a demand for larger quantities of other pigments as well. Kaolin will continue to be the dominant paper pigment by far, with continued growth though at a somewhat slower rate than calcium carbonate.

Jan 1, 1986

By J. A. Bleeck

A discourse on the relationship between industrial minerals and paper production, concentrating on high grade, ultra fine ground calcium carbonate (mean particle size less than 2 microns) and precipitated calcium carbonate. The scope of the paper encompasses four basic areas relevant to the topic: 1. A tutorial overview of the papermaking process with an examination of various industrial mineral components in that process; 2. A discussion of basic technological topics pertinent to the utilization of carbonate in paper with emphasis on the relative aspect. Of natural ground calcium carbonate (GCC) and synthetic precipitated calcium carbonate (PCC); 3. An overview of paper and carbonate market, in both the United State, and Europe with emphasis on (a) current status and future growth trend. Of such market., and (b) discussion of the major influences on growth and development of such market.; and 4. Identification and discussion regarding the principal producers in calcium carbonate markets serving the paper indu.try in Europe and North America.

Jan 1, 1993

By T. S. McGahey

The southeastern region of the United States has long been a major market area for coarse and medium particle size natural ground calcium carbonate fillers. The primary market for calcium carbonate in the southeast traditionally has been as fillers in building materials such as carpeting, joint cement and roof shingles. In these applications the economic value of the calcium carbonate in the final product is weighted more toward lessening the cost of the final product, as opposed to contributing any desirable physical characteristics. For example, in carpet backing applications the calcium carbonate filler does little more from a physical standpoint than add weight and body to the backing adhesive. The important factor in the use of calcium carbonate in carpet backing is that it can be used at high loading levels to replace the more expensive latex binder, thus lessening the cost of the final product. It is estimated that calcium carbonate producers in the southeast sell in excess of 200,000 tons (181,436,000 kg) annually for use in latex compounds for carpet backing applications.

Jan 1, 1986

By M. Bleeck

Calcium carbonate (CaCO3) is one of the most ubiquitous and versatile minerals found in the earth's crust. Its availability, attractive physical properties and relatively low processing cost make CaCO3 the most widely used filler material today. It is mined in three different forms - chalk, limestone and marble. Each physical form of CaCO3 has different qualities due to differences in postdepositional geology. But the chemical composition remains the same, with CaCO3 an inert component of the finished product. In the past, the paper industry largely left CaCO3 by the wayside, as it cannot withstand the acid-based papermaking process. But conversion to an alkaline system by many US mills changed this picture. Carbonate suppliers have put time and effort into research and development, demolishing barriers and creating new possibilities for what is a simple, natural product. By controlling particle size, size distribution and particle charge, the industry uses ground calcium carbonate (GCC) as a performance enhancer and as an extender for more expensive ingredients. It is estimated that the United States uses 3.6 to 4.1 Mt/a (4 to 4.5 million stpy) of CaCO3. Consolidations and mergers are taking place in the industry. Of the 12 major GCC producers in operation nine years ago, seven are left. Mineral Technology (US) is the dominant precipitated calcium carbonate (PCC) producer with more than 50 satellite plants worldwide. Other producers include Georgia Marble (French); Franklin Industries (US); OMYA (Swiss); J.M. Huber (US); ECC (English); and Filler Products (US). Global Stone PenRoc (Canada) is the only newcomer. In addition to this group, there are three small producers left in North America, each with a capacity of less than 100 kt/ a (.110,000 stpy). The trade organization operating as the Pulverized Limestone Division of the National Stone Association renamed itself the Pulverized Mineral Division, to increase its membership pool. The US paper industry is a predominant GCC con¬sumer, using approximately 800 kt/a (882,000 stpy) at an approximate cost of $130/t ($1.43/st). European paper mills pioneered alkaline papermaking. In the early 1960s, they began using GCC as filler and soon thereafter added GCC to their coating formulations. A decade later, the North American paper industry followed suit. The conversion from acid to alkaline paper production benefits the economic and performance aspects of the industry. Less pulp is needed, paper machine maintenance and effluent treatment costs are reduced, and sheet strength, opacity and brightness are increased. Perhaps most important to the reader, the sheet is desensitized to ultraviolet light, extending the paper's archival ability. CaCO3 can provide the papermaker with additional control of his paper. For example, PCC has long supplied the tobacco industry with a means to slow down the burning rate of cigarettes. Due to enhanced performance with regard to bulk and opacity, filler PCC use has risen to 1,500 kt/a (1,650 stpy) in the United States, at an approximate price of $130/t ($143/st). The majority is produced onsite at the paper mill, using "satellite plants." This concept reduces freight cost because only quicklime (CaO) is shipped to the mill, not CaCO3 slurry. The future of CaCO3 is encouraging. The amount of natural ground CaCO3 used is expected to double by the year 2005 to approximately 8 Mt (8.8 million st) worldwide. Acid papermaking practices will feel an increasing pressure to convert to an alkaline process as larger volumes of GCC containing paper enter the recycling market. CaCO3 reserves are plentiful. They will supply the ever growing demand for increasingly sophisticated paper. The plastics industry is supplied with almost 900 kt/ a (990,000 stpy) GCC at an annual growth rate of 4% to 5%. The price of a functional, inorganic filler, surface modified for the plastics industry, has an average selling price of $220/t ($243/st). GCC represents the most common filler, creating a product with higher gloss, better dielectric properties, impact resistance, weatherability and shrinkage control. CaCO3-filled plastics surround us - auto hubcaps and dashboards, shower enclosures, floor tiles, wire coatings, microwave dishes and Tupperware. The caulking and sealant industry is an enormous GCC user, with annual consumption requiring 1.13 Mt (1.2 million st) at about $44/t ($48.50/ st). Caulking and sealant may be highly filled with GCC yet undergo no adverse flow effects, with a narrow particle-size-distribution filler decreasing the binder demand. The CaCO3 industry, as well as the carpet industry, are more or less tied to the growth rates of the construction industry. It is estimated that the carpet industry uses some 680 kt/a (750,000 stpy) of GCC at about $25/t ($27.50/st). The paint industry uses approximately 300 kt/a (331,000 stpy) at a 1 % to 1.5% annual growth rate. Here, too, GCC is the dominant filler. It is used to enhance flow characteristics and color uniformity. It also extends costly titanium dioxide, creates sheen and controls roughness, hardness and tack. More CaCO3 should be used in the future as industry shifts from solvent-free or water-based formulations that can accommodate higher GCC volumes. CaCO3 is not imported or exported in any great quantity. Most areas have reserves of their own and the selling price is relatively low. Even so, quality varies from deposit to deposit. As our needs become morespecific, it remains a challenge to provide varying industries with a fitting product.

Jan 1, 1998

By M. Tapper

If one considers that prehistoric man's first house may have been a limestone cave, calcium carbonate may be the most timeless of all building materials. Fanciful history aside, CaCO3 has been used for countless applications in human habitats. After all, tine marble block and tiles have always been the hallmark of eloquents and style. Mortars and cements derived from limestone have held together the very blocks of our civilization. In modem times, synthetic polymers are blended with ground limestone to produce everything from pipe, floor tile, cultured marble and house siding. All of these miracles of our technology contain CacO3 of various sizes and in varying amounts. This paper will discuss some of the critical attributes of CaCO3 which make it suitable for the new building products that have helped increase our standard of living. The vehicle of discussion will be a residential, single family house.

Jan 1, 1993

By S. K. Mishra, R. L. Lytton, D. Sinn, D. Saylak

Calcium chloride is widely used for dust control on unpaved roadway surfaces, in base course stabilization, full depth reclamation and for total reconstruction of asphalt roads. Fly ash produced from coal-burning electric power plants have also been used in road construction. This paper examines the synergistic effect of calcium chloride and fly ash on compaction density and strength development of unpaved roadways. A mathematical model has been developed which provides excellent agreement with the experimental data. Based on these results, the potential of calcium chloride - fly ash treatments for typical mine road construction is discussed.

Jan 1, 2004

By Y. I. Rabinovich, S. C. Brown

In the Florida phosphate industry, fatty acid collectors are used to separate phosphate ore from silica during the rougher flotation stage. However, the presence of multivalent ions (in particular Ca++) in the processing water has been reported to result in the activation of silica with respect to oleate adsorption, rendering it floatable. Hence, adequate separation may not be achieved during the rougher flotation stage. In this study, the direct measurement of surface inter-action forces via atomic force microscopy was used to delineate possible mechanisms for calcium activation under phosphate flotation conditions at oleate/calcium concentrations both above and below the calcium dioleate precipitation limit.

Jan 1, 2004

By Quanjun Liu, Rongping Lin, Rongdong Deng

Arsenic contamination significantly affects the quality of copper concentrates, presenting challenges during smelting processes. Considering that covellite and enargite have similar surface properties, they are difficult to separate by flotation, resulting in copper concentrates with excessive levels of arsenic. To address this issue, this study systematically investigated the flotation separation of covellite and enargite in microflotation and bench-scale flotation tests using calcium lignosulfonate as a depressant, with the results indicating that calcium lignosulfonate can be used to separate covellite and enargite because it enables the separation of arsenic-bearing copper minerals into high- and low-arsenic (As 0.57%) copper concentrates. According to contact angle and adsorption tests, scanning electron microscopy–energy dispersive spectroscopy, and X-ray photoelectron spectroscopy, the differential adsorption of calcium lignosulfonate onto covellite and enargite is the primary reason for their distinct flotation behaviors in the presence of calcium lignosulfonate. The selective depressive effect of calcium lignosulfonate provides a novel approach for improving the flotation separation of arsenic-bearing minerals from copper sulfide minerals.

Feb 28, 2024

By A. B. Kinzel

ALTHOUGH calcium carbide and other compounds of calcium, as well as a number of calcium alloys, are well known and are the basis of important industries in the of United States, calcium metal has been thought of as something of a rarity and has received comparatively little attention from industrial metallurgists. The metal may he made in a number of ways, but the electrolytic deposition of calcium from a molten calcium chloride bath was the first process to be used for its commercial production and is still the standard procedure. Calcium metal has elicited little interest among nonferrous metal producers, as the demand has been relatively small and its production restricted to only a few plants, exclusively in France and Germany.

Jan 1, 1941

By B. S. Terry

Experiments have been conducted to assess the feasibility of capturing bearing emissions arsenic with CaO during the roasting of enargite (Cu3AsS4). Enargite/CaO mixtures have been heat treated in air, nitrogen or oxygen for various times and the products of reaction analysed by X-ray diffraction and cleaned analysis. The results show that substantial capture of arsenic can be achieved via the formation of calcium arsenates and/or calcium arsenides. In addition significant capture of sulphur is achieved by the formation of calcium sulphate andlor sulphide. Complete conversion to copper sulphide with total removal of arsenic can be achieved within 30 minutes at 700°C. Further heat treatment in air or oxygen leads to the formation of copper oxide and copper oxysulphate. Without optimisation of reaction conditions, it has proved possible to achieve retention of in excess of 85% of the arsenic content of enargite in the form of calcium arsenates.

Jan 1, 1994

By S. M. Narbekova, L. V. Semushkina, Zh. A. Aldybayeva, A. A. Mukhanova, D. K. Turysbekov, N. K. Tussupbayev

More complex and heavy-concentrating oxidized and mixed sulphidic oxidized ores are involved in production because of increasing needs for non-ferrous metals. Extraction of the oxidized minerals of non-ferrous metals general in current technologies. The problem is solved to oxidized polymetallic ores the preliminary selective sulphidization is the oxidized surface of the components by means of hydrogen sulphide, sulphide and calcium polysulphide, and also element sulphur, etc. The task was to study details of flotation of the oxidized lead-bearing ore of the Zarechnoe deposit (Kazakhstan) with calcium polysulphide as sulphidation. According to chemical analysis initial samples of the ore contain, %: lead – 4.8; zinc – 0.1; general iron – 0.81. Phase structure lead is characterized by the oxidized form of 57.76-64.5 %; by sulphidic status of 25.5-32.64 %, and by plyumboyarosite of 19.0-23.02 %. Researches on flotation beneficiation of oxidized lead-bearing ore are conducted. Sulfidizator gave to grinding, on flotations there were used the collector (butyl xanthogenate of sodium) and frother (T-80). Experiments were conducted with a new sulphidizator – calcium polysulphide. The latter is obtained by interaction of CaO calcium oxide with sulfur and water at high temperature with component mass the following ratio S:CaO:H2O =10:5:85. Extent of mill initial ore was optimised (88.42 % of - 0.071 mm grade). For the optimum mill mode the studies on matching of an optimized consumption of sulphidizators are performed. On basic technology with application of sulphide of sodium as a sulphidizator at optimum mill, the lead concentrate with the content of lead 64.4 % at extraction of 86.6 % was received. The content of cerussite in a concentrate was about 14.9 % at extraction of 82.1 %. With application of calcium polysulphide as a sulphidizator the lead concentrate with the content of lead 68.0 % at extraction of 88.0 % was received. The content of cerussite has made 16.0 % at extraction of 85.0 %. Application of a new sulphidizator allows to increase extraction of lead in a concentrate from 64.4% to 68% and cerussite extraction – from 82.1 % to 85.0 %. The possibility of application of calcium polysulphide as a sulphidizator instead of conventional sulphurous sodium was established.

Jan 1, 2018

By B. R. Davis, Neale R. Neelameggham, R. E. Brown

The element Calcium element has a unique place in the production of etals, intermetallics and other compounds. The unusualness arises from the fact that we have several possible reductants – metallic calcium, calcium carbide, calcium cyanamide and calcium hydride. A review of how metallic calcium is manufactured and utilized is presented. The difficulties involved in producing the metal in large quantities and price implications are noted. . Fundamental thermodynamics of how these act as reductants are shown, along with the historic application of these in metal production during the past century and a half. Alternate applications as to how to control the cost of the reductant is indicated, such as the numerous attempts in making low cost titanium utilizing direct or indirect calcium reductant.

Jan 1, 2014

By S. S. Vasan, K. A. Natarajan, J. M. Modak

The biological removal of calcium from a bauxite ore in the presence of the soil bacterium Paenibacillus polymyxa is demonstrated. A column bioreactor that can be either operated in a fluidized-bed (FB) mode for coarser particles or in a total-recycle-slurry (TRS) mode for finer particles was designed, fabricated and tested for this purpose. For the efficient removal of calcium from the ore to the required levels, leach solution should not be allowed to accumulate in the reactor. Therefore, the solution needs to be drained out periodically. Cascade leaching was found to be more effi¬cient. A direct correlation between pH changes in the leach solution and calcium solubility could be made. More than 85% of the calcium could be removed through cascade leaching.

Jan 1, 2000

By Butt C. R M

Resurgence in Au exploration during the past decade has been characterised by a considerable emphasis and dependence on geochemical procedures. This has been made possible, firstly, by marked improvements in analytical sensitivity over those previously available and secondly, of particular importance to exploration in Australia, by a better understanding of the distribution of Au in the regolith, which has led to the optimisation of sample media. These developments have given exploration companies the ability to seek and detect subtle and widespread geochemical signatures of concealed Au mineralisation and provided an enhanced capability to interpret the data. As a consequence, several new discoveries have been made, even in areas that have been intensively explored in the past. In the deeply weathered Yilgarn Craton (WA), and in equivalent areas elsewhere in Australia and overseas, Au has accumulated in the upper lateritic gravels and duricrusts of the regolith, probably during humid climatic periods in the Tertiary. The laterites may not only be Au ores in themselves, but research by CSIRO and CRC LEME has shown them to be very important sample media, (eg Anand and Smith, 1992). In many areas, however, the laterite has been eroded and hence is unavailable as a sample medium and chemical modification under more and conditions since the Tertiary has leached Au from the upper saprolite. This has greatly increased the difficulties of exploration, particularly where reliance was placed on sampling between 2 and 15 m of the surface. Further research, however, has demonstrated that, despite this leaching, recent remobilisation of An has caused it to concentrate in a specific soil component, pedogenic carbonate, usually in the top I - 2 m, thereby giving surface expression even to mineralisation that is concealed by over 20 in of leached overburden. Secondary carbonates, commonly referred to as calcrete, may precipitate as calcite and/or dolomite in regoliths where the average annual rainfall is less than about 600 mm. Pedogenic carbonates are those that form in unsaturated (vadose) soil horizons. They are widely distributed in the Gawler and Yilgarn Cratons. In the Yilgarn Craton south of about 30¦S ('the Menzies Line'), they are seemingly more abundant over more basic rocks and towards the south east (Figure 1). In contrast, groundwater calcretes form in saturated (phreatic) environments, typically in the axes of major drainages north of the Menzies Line. These are known to accumulate economically-significant grades of U but not, apparently, An.

Jan 1, 1997

By R. B. Stein

"Countercurrent decantation circuits(CCD) are often employed in hydrometallurgy to effect solids-liquid separation in combination with a barren solution wash to reduce losses of valuable solution component(s) from the tails. Bechtel Corporation uses its BEMSIM flowsheet-modelling PC computer program to simulate a CCD circuit where the ""dirty"" wash solution contains significant amounts of soluble components. An algorithm successfully models this condition and is simplified to a single expression when the wash solution is a ""clean"" solution containing no solubles. The CCD calculation module is compared to operating data from uranium and nickel-cobalt CCD circuits.IntroductionHydrometallurgical process schemes have often relied on countercurrent washing methods to reduce soluble losses of valuable product in the tails. Commonly used equipment to effect this operation is a CCD circuit of N thickeners in series, where a slurry is fed to thickener I and a wash solution to thickener N; clear pregnant solution overflows thickener I and washed tails exit as underflow from thickener N. CCD circuits of this type are typically employed when the solids tend to slime heavily and where a filter is not economic.A typical CCD circuit usually employs from two to five thickeners and can employ either a ""clean"" washing solution of, say, pure water or else the hydrometallurgical circuit may generate a ""dirty"" barren solution containing an appreciable amount of soluble component which may be advantageously returned to the process as CCD wash solution. Various authors have treated the case for clean washing solutions (Svarkovsky 1977, Merritt 1970). For the case of dirty wash solutions, an algorithm has been developed to enable efficient modelling by the BEMSIM computer program, because the need for an accurate method to calculate soluble losses is required when performing an economic trade-off analysis of the value of product lost in the tails as a function of the number of thickeners."

Jan 1, 1990

By Janice K. Means

The purpose of this paper is to provide the seminar attendee with: information on pipeline construction, operation and standards to better equip him (or her) to analyze the ultimate effect of blasting stress on pipelines; an introduction to the analysis of blasting effects to pipelines using the American Gas Association analysis method; and; supplemental sources useful in the analysis of blasting effects to steel pipelines, and, in particular, on natural gas pipelines.

Jan 1, 1992

By D. Limpitlaw, A. Alsum, D. Neale

"Ecological footprint analysis (EFA) was first described in 1996 as a measure of carrying capacity appropriated by human activities. EFA is a resource and emissions accounting tool designed to track the demand on the biosphere’s regenerative capacity. Ecological footprints are increasingly used as indicators of organizational and corporate environmental performance and product sustainability. There is a compelling argument to develop an EFA tool for mining companies.To determine the size of a mine’s ecological footprint, land requirements for all categories of consumption and waste discharge must be summed. This land is only made up of the ecologically productive land and water in various classes (cropland, pasture, forests etc.) required on an ongoing basis to provide all energy and material resources consumed and absorb wastes.A challenge in conducting an EFA for a mine is the shortage of accessible data. Undertaking an EFA for a corporation or individual site entails compiling consumption and emissions data (which can be used for other reporting applications). The footprint results themselves highlight the most critical aspects of an organization’s impact on the environment and provide a platform for focusing actions and for educating the workforce to improve their contribution to best-practice operations. This paper discusses the benefits and challenges of undertaking an EFA for a mining company, and provides examples of the various components of ecological footprints associated with mines, as well as showing how an EFA can be used to understand and communicate some of the impacts associated with mining activities.IntroductionFundamental biophysical and economic limits are now being experienced in many countries around the world. Herman Daly, a former World Bank economist, described this scenario as ‘uneconomic growth’, where the costs of growth exceed the benefits (Daly, 2005). This occurs when the economy’s expansion encroaches excessively on the surrounding ecosystem, sacrificing natural capital. Under such conditions the sacrificed natural capital is more valuable that the resulting economic growth. Consequently, the world faces largescale threats to sustainability and especially to the viability and continued existence of the ecosystems that support human settlements (El Zein et al., 2014). In recognition of this sustainability imperative, mining companies are increasingly concerned with their ecological footprint (EF)."

Jan 1, 2017

By R. F. Hewlett

All ore reserve estimates are based on some system for assigning an area of influence to each drill hole. Commonly used methods of calculation are the polygonal, triangular, statistical analysis, and cross-sectional. Each of these methods is based on different volumetric considerations and the weighting of grade with tonnage varies with each method. Because the characteristics of each mineral deposit are different, a preliminary survey of these characteristics should be made for each individual deposit to determine which method or methods should be used. In this project the several methods were not only compared with one another, but also against actual production records. Basic data was derived from a mined out portion of the Silver Bell pit near Tucson, Ariz. All calculation was carried out on a digital computer, and the first step was development of computer programs which would yield the desired information. The second step was the coding of input data into punched card form. Cost and speed of computer operation were measured, and these results are given with the computer program summaries on page 38.

Jan 1, 1961

By Catherine Johnson, Kelly Williams

Advances in high-speed video imaging make it possible to see the refraction of light due to the high-density gradient at the shock front without the need for parabolic mirrors or additional light sources necessary for Schlieren or shadowgraph imaging. The average shock front velocity between two points can be calculated by dividing the change in position by the elapsed time between the images. Using the Rankine-Hugoniot relationship demonstrated by Swisdak the peak overpressure of the shock wave can be calculated from its velocity eliminating the interference of the gage and mount

Feb 1, 2020

By E Cunha, D Roldao, TáTamantini, J F. C L Costa, T Webber, C Monteiro

The main problem of geostatistical simulations is to reproduce the real characteristics of the mineral deposit when there are few conditioning data. In this case, the geological interpretation, based on structures, geophysics and geological maps, plays the major role in terms of resource evaluation.The paper investigates the use of principal component analysis (PCA) to help classify multiple geostatistical categorical simulations considering the similarity among them and the interpreted model, herein referred as training image (TI).An iron deposit with four lithological facies, in a specific horizontal plane, was used as case study for two-dimensional (2D) simulations. Sequential indicator simulations (SIS) was used to obtain ten equally probable 2D images, which were generated and compared against the interpreted model (TI).In this study, 11 random variables are comprised by the vector of ten SIS realisations plus the training image (TI). The similarity between the TI and each SIS realisation is measured using the angle between the TI and SIS vectors projected in the new coordinate systems (PCA factors). It is possible to order the SIS realisations from the highest to the lowest PCA factor taking into account the TI similarity.The visual analysis of the images shows coherence in the PCA results as a method to measure similarity. This methodology can be used as a post-processing tool to rank simulation results and to select the ones which better represent the prior known geology or to compare the quality of different methods of simulation.

Sep 26, 2011