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By P. V. Avotins, D. R. Nagaraj, S. S. Wang

Xanthates and dithiophosphates are the most commonly used collectors in the flotation of sulfide minerals. Other reagents such as thionocarbamates, mercaptobenzothiazoles (MBT), mercaptans and xanthogen formates occupy niche positions in industrial collector use. Over the last ten years there has been much activity by chemical companies to develop new collector compositions. The new collectors are aimed at meeting specific process needs such as recovering an increment of valuable metals, improved sulfide separations, increased flotation kinetics, and reducing reagents costs. A review of the patent literature shows that American Cyanamid (Cytec), Dow Chemical, Phillips Petroleum, Sentrachem Ltd., Henkel, Montan Chemicals and Elf Aquitaine, among others, have been active in sulfide collector research. Several companies have achieved considerable success in laboratory and plant tests of the new collectors; however, commercial acceptance for plant usage has been slow. Those most advanced have been plant tested extensively and some are in day-to-day use. The new collector types in this category are: Modified thionocarbamates, dithiophosphinates, organic sulfides, trithiocarbonates, monothiophosphates, and modified thioureas. Others such as substituted mercaptobenzothiazoles and monothiophosphinates have been tested in the laboratory. The chemistry of collectors developed in the last 10 years, their preparation, physical properties and their potential for commercial use are reviewed in this paper.

Jan 1, 1994

By K. S. E. Forssberg, K. Hanumantha Roa

Batch flotation tests are carried out with phosphatic material from LKAB, Sweden containing carbonatic and siliceous gangue while using sodium oleate as collector and sodium silicate as modifier. The pulp liquid is analysed for oleate, silicate, carbon dioxide, calcium, magnesium and phosphorous after each flotation test under different reagent conditions and flotation pH. Theoretical calculations of thermodynamic chemical equilibria in apatite-calcite-sodium oleate-sodium silicate system have been carried out with the help of SOLGASWATER computer program. During the calculations, the chemical variables are maintained similar to the operating chemical variables in flotation. A comparision between the experimental and theoretical chemical equilibria has been made and the flotation behaviour of apatite is discussed with reference to the theoretically calculated pulp model.

Jan 1, 1993

By Y. M. Jiang

From underground instrumentation data and from direct observation of longwall panels, it was demonstrated that growth of the main-roof overhang causes an extremely high roof weighting on the face supports. This can result in catastrophic effects on the supports when the roof-weighting intensity far exceeds the support capacity. In this paper, a comprehensive study was conducted on the characteristics of main-roof breakage and its effects on shields at different locations along the face. The study was based on monitored shield data, theoretical analysis and finite element analysis. With the help of theoretical analysis and numerical modeling, stress distribution and redistribution in the main roof were analyzed to define the main-roof failure modes and to understand the maximum roof-weighting intensity imposed on the shields. From this study, it was found that the effects of main-roof breakage on shields are chiefly related to the shield's initial-setting condition and to the final failure mode of the main roof.

Jan 1, 1996

By F. F. Aplan, T. H. Wentzler

Limestone is potentially a low cost material for the neutralization of acid mine drainage and other acidic waters such as steel pickling liquor. Unfortunately, when limestone is reacted wit9 these waters containing large amounts of Fe , Fe+3, and SO4-2 , a coating of gypsum and iron hydroxides form on the surface of the limestone inhibiting further neutralization reactions. The nature of these coatings, their morphology, composition and thickness were evaluated using the scanning electron microscope and microprobe, and the kinetics of limestone dissolution was studied both in the presence and in the absence of the reaction-inhibiting coatings. These data were then correlated with the solution chemistry.

Jan 1, 1992

By V. G. Papangelakis, G. P. Demopoulos

The high temperature (180-200 OC ) pressure oxidation (02 - HzSO4) process for the recovery of gold from refractory concentrates (FeS2/FeA8S) is simulated with the aid of a computer model. The model centers on the continuous operation of a multi-stage horizontal autoclave. In particular the effects of key process parameters controlling the autogenous operation of the autoclave are critically examined. The building elements of the model are (i) the continuous particle size distribution function of the concentrate, (ii) the residence time distribution function of the slurry and (iii) the shrinking core kinetics. Conversion is calculated on the basis of the segregated flow model. For the calculation of the particle size distribution at the exit of each compartment the population balance model is employed. The effects of feed rate, feed preheating, cooling, autoclave configuration and rate limiting regime (chemical reaction vs. gas-liquid mass transfer) on the autogenous steady state operation are discussed. Finally optimum reactor design and operation criteria are indicated.

Jan 1, 1990

By K. Sasaki, T. Murakami, S. Akibayashi, Q. Wei

A numerical analysis and an experiment were done on groundwater flow past a bore hole with a cylindrical obstacle at its center. Flow around the obstacle in the bore hole was studied in detail. Two dimensional governing equations to simulate this flow were written for the hydraulic head and seepage velocity in a porous medium and for the vorticity, stream function, and velocity in the bore hole. These equations were non-dimensionalized and solved by using the alternating direction implicit and successive-over-relaxation finite difference methods. Flow visualization experiments and velocity measurements in the bore hole were done with a two dimensional model composed of a porous medium. The numerical analysis procedures were validated by a comparison of numerical and experimental results. Effects of the Reynolds number and obstacle size on flow in the bore hole are clearly shown in the velocity and streamline profiles. The quantitative relation between the seepage velocity in the porous medium and the velocity of flow around the obstacle in the bore hole also were estimated.

Jan 1, 1996

By B. K. Mishra, R. K. Rajamani, A. D. Joshi

The liners are the most important part in the SAG mill operation. Hence, the liners and their design parameters are primarily studied to see its effect on SAG mill operations. Effective liner designs are directed to reduce downtimes, which is needed for the replacement of worn liners. There exists constant chance of improvement in the capacity of mill by studying the effect of liner design on the charge motion inside the mill. This need is satisfied by three-dimensional discrete element code "Millsoft", which uses Discrete Element Method (DEM) to analyze the motion of charge. This simulation of SAG mill keeps track of all the moving bodies like ball and rock and observes its interaction with liners and lifters. The recent work done on this software helps generating mill to more reality by putting conical wall at feed and discharge end, over the earlier flat walls. Millsoft is an effective tool to watch the change in the motion of the charge due to different types of lifter bars and different design parameters. It was concluded that by simply increasing chord length between the lifters and increasing the face angle of the lifters, capacity of the mill could be increased. On the other hand, this software can also be used to get power draft at the respective mill design.

Jan 1, 2002

By W. R. Dearman, N. Turk

A seismic fissuration index (K) is defined as the ratio of the difference in the P and S wave velocities obtained when a dry rock specimen is tested both under a load equal to half the uniaxial compressive strength of the rock (Vo) and without an applied load (Vd) to the velocity obtained without an applied load (Vd), as K = (Vo - Vd)/Vd. A similar seismic fissuration index is also proposed for classifying the dry rock mass in terms of field seismic velocities. The field equation is extended by including the intact rock seismic velocities. K is found to be related to the porosity of rocks. The proposed equation can equally be used for characterizing saturated rocks, using S-wave velocities. However, the time average equation should be used for characterizing saturated rocks, using P-wave velocities, even though this equation gives upperbound estimates of the rock material and fracture porosities.

Jan 1, 1986

By S. Mason

Many organizations are realizing that continual improvement in health and safety relies on addressing the potential for various forms of human error. Of these, rule violations are often the most frequent form associated with accidents. These occur when an individual (or individuals) deliberately contravenes established and known safety rules. They have been associated with up to 90% of the accidents and other incidents in some industries, and yet they rarely receive the systematic attention they deserve in the promotion of safety. This paper presents underlying motives that cause violations. These can vary significantly from mine to mine and from job to job. Managers need some measure of the attitudes of the violators to determine the underlying motives behind the violations if they are to determine effective strategies for promoting safe behavior. Questionnaires form the starting point to address attitudes and the motives behind rule violations. The choice of the most suitable questionnaire, how- ever, will vary from organization to organization. Guidelines on the choice of questionnaire are offered.

Jan 1, 2000

By F. W. Petersen

In the precious metal industry, activated carbon is used extensively for the recovery of gold and silver from cyanide solutions, particularly from slimy pulps and unclarified solutions. However, carbon can easily become fouled by inert particles in the pulp, thus decreasing the activity or gold loading of the carbon. This paper attempts to quantify the distribution of fine inert particles in activated carbon. Furthermore, a possible mechanism for the intrusion of fines will be postulated. Precipitated silica and ground silica sand were used to simulate pulp conditions and their loadings on activated carbon were determined by ashing. The kinetics of intrusion of fines into the pores of carbon were relatively fast, and were dependent on the concentration in the pulp. Results indicated that particle size of the solids and zeta potential of the fines influenced the loading of inert species on carbon. Scanning electron microscopy and secondary ion mass spectrometry showed a decrease in solids concentration to the centre of the carbon particle.

Jan 1, 1995

By Charles D. Litton

This report describes a smoke particle detector which utilizes a novel three electrode configuration and 5.0 [] source of Americium 241. The detector operates on the principle of diffusional charging by a region of unipolar molecular ions. The detector is sensitive to particle concentrations in the range of 10 to 5 20 ug/m3. The detector is intended for use primarily as an early warning fire detector but has the potential for other applications of particulate monitoring. In particular, this report adresses the potential use of the detector for monitoring diesel particulate matter (DPM). To assess the viability of this application, particle size data obtained from in-mine sampling of both DPM and dust were used to derive detector sensitivity functions for DPM and dust as a function of their mass concentrations only. These sensitivity functions are dependent upon the average diameters and size distributions of the DPM and dust. Using the derived sensitivity function for DPM, experiments were conducted in a ventilated tunnel where the true DPM mass concentrations, measured using a Tapered Element Oscillating Microbalance (TEOM) were compared to the mass concentrations calculated using the detector sensitivity function. The agreement between the two measurements was good, indicating that with additional experiments, coupled with in-mine evaluation of the detector, refinement of the device for use as a continuous monitor for DPM appears feasible.

Jan 1, 1989

By C. H. Rawlins

The total amount of ferrous slag generated in the U.S. is about one-third the amount of iron ore mined, thus ferrous slag can be considered a significant mineral body for processing. Steelmaking slag contains up to 30 wt.% metal of which only the >25mm fraction is commonly recovered. A grinding study was conducted of BOF, EAF, and LMF slags using the Bond Work Index method to determine grindability to 106µm. Work Index values obtained were 13.8-24.9 kWh/ST, depending upon the slag type and composition. Steel particles were magnetically recovered from the crushed and ground samples for size-by-size analysis, yielding up to 18 wt.% of the slag weight recovered as magnetic. The recovered material, as characterized by inert gas melting, was found to be 61-96 wt.% metallic.

Jan 1, 2008

By Shaning Yu, Yosry A. Attia

The purpose of this work was to investigate the feasibility of using column flotation as a floc separation technique. In this study, the ultrafine coal (minus 25 microns) slurries were cleaned by using the Integration of column flotation with selective flocculation. It was found that using column flotation as a floc separation technique during the "cleaning" stage, achieved much better results than that either using column flotation as a rougher separation technique for coal flocs, or using It directly to recover the ultrafine coal from the slurries without adding selective flocculant. Thus, the ultrafine coal slurries were first separated by selective flocculation process to reject a certain amount of the dispersed ultrafine ash minerals, and to aggregate the ultrafine coal particles as flocs. Thus, the entrainment of ultrafine ash minerals Into the coal floc-froth concentrate during flotation could be considerably reduced. Subsequently, the coal flocs were further "cleaned" by column flotation. The experimental results Indicated that this approach was technically feasible and particularly suitable for a slurry containing a large amount of ultrafine particles. The effect of flotation time, and collector dosage on column flotation of coal flocs were also Investigated and reported In this article.

Jan 1, 1988

By Misra M., P. Grimes, Chen. S.

The combustion of petroleum products produces emissions which contain oxides of nitrogen (NOx), hydrocarbons (HC), and particulate matter (PM) which have adverse health and environmental effects. In recent years there has been increasing interest in the use of water-fie1 emulsions as a substitute for conventional fuels. Emulsified fuels are emulsions of water in fuel, which are typically made of 10 to 20 percent of water mired with certain additives and fuel. Studies have shown that the emulsified diesel can significantly reduce the emissions of NO, PM and car- bon monoxide and increase the fuel efficiency. In order to produce a stable diesel emulsion, the development of an effective surfactant additive is critical. The stability of diesel emulsions is influenced by many factors, including size distribution of the droplets, the viscosity of the continuous phase, the physical properties of the interfacial film, and temperature. This paper describes a method to produce emulsified diesel and combustion results obtained from various tests. It has been found that the diesel emulsion made with this additive package was stable during the test, and the emissions were lower in NO, CO, and PM compared to the baseline diesel.

Jan 1, 2005

By R. Y. Wan, Corby G. Anderson, L. Ernest Krys, M. C. Fuerstenau

Since 1942, refractory precious metal concentrates at the Sunshine mine have been processed for antimony metal recovery using a novel leach-electrowin method. This is counter to most antimony production facilities where pyrometallurgical techniques are usually relied upon. The key step for removal of the antimony has been an ambient pressure alkaline sulfide leach. In 1990, a comprehensive laboratory study was undertaken to better understand this process. Factors studied included temperature, agitation, concentrate regrind, alkaline species concentrations, sulfur species concentrations and solids concentration. Details of these studies, as well as a brief description of Sunshine metallurgical processes, will be presented.

Jan 1, 1993

By Ian Sheppard, John J. Chen

This paper describes the development of the underground mining methods employed for narrow silver-lead-zinc orebodies at the Isa Lead Mine. Cut-and-fill methods were the chief underground mining methods for the narrow orebodies at the mine over 35 years ago. Benching methods were introduced approximately two decades later, and quickly replacing the cut-and-fill methods. The cut-and-fill methods and the benching methods are briefly reviewed in the paper. The benching methods and technologies have been continually evolving and one of the recent achievements is a multi-lift benching method. The multi-lift benching method is described in detail.

Jan 1, 2001

By Gerald J. J. Aleva

Lateritization is a surface and near-surface process enhanced by a humid and warm climate and by good drainage. It closely follows the development of the regional landscape. The cyclic landscape development on the Guiana Shield is accompanied by a progressively thicker and more evolved laterite mantle the older, and hence in most instances the higher the planation level. The known, economically interesting bauxite and aluminous laterite eposits of the Shield are restricted to the remnants of the oldest of the Cainozoic planation levels (level I1 and 111).

Jan 1, 1984

By L. G. Sobral, J. E. Hoffman, T. J. Keefe, A. J. Monhemius, O&apos

The kinetics of electrodeposition of gold from dilute solutions of alkaline KAu(CN)2 at different gold and free cyanide concentrations on a gold rotating disk electrode were investigated by use of a steady-state linear potential scan technique. The design and performance of a laboratory electrowinning cell with a reticulated nickel cathode, operating in the flow-through mode, for the removal of low levels of gold ions from aqueous cyanide media is described. During the batch recirculation of oxygen-free gold cyanide solutions, the gold concentration was reduced from 10 ppm to <0.5 ppm with current efficiencies of up to 80%. The influence of solution flow rate through the cathode and of the pore size of the reticulated nickel foam is discussed. The removal of gold ions from solutions of low ionic strength was also investigated.

Jan 1, 1993

By Richard R. Klimpel

The author was the banquet speaker at the 48th Annual MPD meeting, sponsored by the SME Colorado Minerals Processing Section, May 14-16, 1998, in Colorado Springs, CO. Here are his remarks. It has been an exciting experience to have spent 34 years involved with the process of generating patented technology eventually leading to commercialization. In today&apos;s terminology, this process is called technology transfer. I have had the unusual experience of being involved doing basic research as an inventor while also being responsible for managing new product development and commercialization. In addition, I worked for 31 years before my retirement for a large research-oriented company, The Dow Chemical Co. In 1995, the company spent more than $1 billion dollars on research and development. The last three years of my career have been spent working with a research-oriented university, The University of Florida. And I have worked as a consultant helping several companies to optimize their products and processes. It is on this cumulative experience base that the preparation of this article is based.

Jan 1, 1998

By Danqing Xu, A. W. Khair

This paper presents an analysis of mechanism of secondary fragmentation and respirable dust generation due to regrinding. In continuous miners, the recovered coal and uncleaned coal from the previous cutting cycle have to be transported through the circumference of the cutting drum, subjecting the coal to regrinding. Such regrinding comminutes the coal material utilizing kinetic energy, thus creating a great amount of respirable dust. The mechanism of a single particle subjected to regrinding is analyzed. A mathematical model is developed to describe regrinding in field conditions. The important factors influencing the comminution process are discussed in detail. Utilizing three types of coal seams, laboratory experiments are being carried out with an Automated Rotary Coal Cutting Simulator (ARCCS) to quantitatively evaluate the effects of some particular parameters, such as cutting velocity, depth of sump and properties of coal material, on breakage and on the amount of respirable dust generated. An orthogonal fractional factorial experimental arrangement is used to optimize experimental design. Preliminary experimental results are presented.

Jan 1, 1991