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By S. B. Kim, J. Hong, K. Park, W. Kim, H. Kim, Y. Han, J. Choi

"For the first time, the influence of stearyl trimethyl ammonium chloride (STAC) as a collector, on the flotation behavior of lepidolite (Uljin, South Korea) was systematically examined in Denver Sub-A cells. Flotation tests were carried out by varying amount of STAC (50–200 g/ton), feed size (-65, -100, -150, and -200 mesh), and solution pH. The impeller speed of 1000 rpm, flotation time of 10 min and AF-65 (a frother) of 250 mL/ton were invariably applied. In order to complement flotation experiments, zeta potential measurements and XRD analysis were conducted. XRD results showed that the ores were mainly composed of lepidolite, muscovite, quartz, calcite and albite. In addition, zeta potential results showed that isoelectric points were about 2.5, 2.3, and 9.7 for quartz, albite, and calcite, respectively, and lepidolite was determined to be less than 2. Overall, the results of 3-stage flotation showed that Li2O grade and recovery tended to increase with increasing STAC dosage and decreasing feed size. In addition, Li2O grade increased with decreasing pH. The results were explained by the extent of the interaction between STAC and each mineral.INTRODUCTION A great number of potential applications of lithium are being developed currently by the thermonuclear fusion power generation industry(1,2) as well as by the battery and fuel cell industry(3). Even though lithium is mainly consumed in the form of lithium metal and some lithium compounds, about 10% of total lithium production is consumed directly as mineral concentrates by the ceramic industry for the manufacture of special ceramics and mica based glass-ceramics(4). Granitic pegmatites normally contain feldspars, quartz, and mica in addition to lithium-bearing minerals such as spodumene (LiAl(SiO3)2), petalite (LiAlSi4O10), and lepidolite (KLi2Al(Al,Si)3O10(F,OH)2). The amount and grade of metallic minerals tend to gradually decrease and become lower, leading to the increase in the price of base metal or metallic compound(5). Accordingly, recent studies have been extensively devoted to developing the technique to improve the grade of metallic minerals from low grade metallic ores(6,7). Nevertheless, studies regarding the improvement of Li grade from lepidolite ores are very scarce. Lepidolite is a phyllosilicate mineral of the mica group and is often associated with other minerals such as calcite, muscovite, feldspar, and quartz, which need to be separated for lepidolite enrichment(8). Many studies have reported the flotation techniques for separating calcite, muscovite, feldspar, and/or quartz from various targeting minerals(9-11); however, there has been no attempt to investigate physico-chemical properties of lepidolite and its separation from such types of gangue minerals through flotation. Hence, in this study, for the first time, flotation has been carried out for the quaternary ammonium salts (stearyl trimethyl ammonium chloride (STAC, (CH3)3CH3(CH2)16NCl))-lepidolite system based on only the electrokinetic property of minerals that consist of lepidolite ores without adding any depressant to get an initial insight on its flotation behavior. The experimental variables that influence the lepidolite flotation such as amount of collectors, feed size and solution pH have been also examined."

Jan 1, 2015

By K. Hebbar, R. G. Reddy

The viscosities of various FeO-SiO2 slags were calculated using a previously developed structural-based model. Using hole theory and the atomic pair model, an expression was derived to relate the viscosity to temperature and the fraction of the bridging oxygen in silicate melts. The deduced equation was successfully applied to predict the viscosities of FeO-SiO2 slags in the composition range of 0.1 < XSi02 < 0.423 for several temperatures. The calculated data agree well with the experimental viscosity data.

Jan 1, 2002

By Gopalan Ramadorai

This paper presents a review of halogen solvents used in the processing of precious metals. Reagents of widely varying chemical structures, such as chlorine gas, calcium and sodium hypochlorite, chlorine dioxide, iodine and bromine have been used for precious metal extraction. None of these chemicals are a replacement for cyanide: however, each of these chemicals present an opportunity for use in processing a specific type of ore. The ore and chemical must be matched to each other for success. Recovery of metal from the leach solutions also offers challenges.

Jan 1, 1994

By George H. Klein, B. Kent Merritt, Anthony Crisci

During the past decade, over 114-km (71-mi) of 0.25-m (10-in) to 3.7-m (144-in) finished diameter tunnels have been driven below Metropolitan Houston as part of a major program of water and wastewater improvements. This large effort has seen the introduction of midwestern technology with over 18-km (11-mi) of man-entry pipe jacking and European and Japanese technology with over 21-km (13-mi) of microtunneling. Owing to the high water table; a stratigraphy consisting of stiff fissured clays containing numerous layers, channels, and lenses of water-charged sands and silts; and active faults, many challenges existed for designers and contractors alike.

Jan 1, 1991

By W. A. Rickelton, A. J. Robertson

The ability of triisobutylphosphine sulfides to selectively recover silver from acidic sulfate solutions containing zinc and copper is described. Selectivity is explained in terms of the concept of hard and son Lewis acids and bases. Silver is stripped from the solvent using a novel strip feed (thiosulfate salt), and the recovery of metallic silver from the strip liquor by electrolysis or cementation is suggested. The high selectivity of extraction for silver and the utility of the stripping reagent are demonstrated in continuous, countercurrent, mini-plant tests. Important reagent properties, such as hydrolytic stability and low aqueous solubility, are discussed.

Jan 1, 1988

By Harold E. Goetzman, Blair R. Benner, Shaolin Zhong, Rodney L. Bleifuss

A commercial high pressure roller press (KHD 90125) was installed at the Coleraine Minerals Research Laboratory for testing in October, 1994. Pilot plant evaluation of the high pressure roller press has shown that it can be used as an alternative to the rod mill for the comminution of taconite. A series of pilot plant tests were run to compare roller press products to rod mill products in a simulated taconite flowsheet using magnet separation and closed circuit ball milling. Further investigation of a hybrid grinding system, roller press crushing followed by ball mill grinding, indicate that the combination may represent the most energy efficient system for taconite processing.

Jan 1, 1998

Projections of coal reserves in Central Appalachia are essential for long-term planning in the region. Annual production is declining in states such as Virginia. And minable reserves for the Central Appalachian coalfield are challenged by difficult geological, mining and market conditions. To project coal mining longevity in this region, interviews with mining companies were conducted to determine and assess technical and economic factors that affect coal seam minability. This information was ap- plied to seam and coal reserve data developed by state and federal governments. The results were analyzed to determine the effects of various factors on the overall minable coal reserve base.

Jan 1, 1998

By E. William Rossi, Audrey F. Glowacki, Richard L. Unger

The U.S. Bureau of Mines has developed a graphics-based computer model to assess operator visibility for continuous miners, shuttle cars, and scoops. Using digitized drawings of the machine, the program can analyze visibility for both 5th percentile female and 95th percentile male operators. This model was used to predict 95th percentile male operator visibility for two shuttle car designs. These results were then compared to those obtained from a manual assessment of visibility using the actual shuttle cars. The methods showed good correlation except for several cases which were attributed to imprecise digitization of the machines.

Jan 1, 1992

By George F. McKeregahan

Phosphate production of the Central Florida Phosphate District has been predominantly from the unique and lucrative Bone Valley Formation, with local and minor amounts coming from the underlying Hawthorn Formation. As the Bone Valley is depleted, replacement production will move progressively into areas of total Hawthorn Production. Significant changes in the characteristics and make-up of the deposit dictate required modifications in mining and beneficiation. Failure to tailor technology to fit the deposits of the future will result in vast "reserve" losses. In the Southern Extension of the Central District - two distinct "ore types" exist. These are presently referred to as the upper (high grade) zone and the lower (low grade) zone. The upper zone is somewhat similar to the Bone Valley Formation and will respond favorably to present beneficiacion practices. The lower zone is strikingly different and its response to conventional beneficiation is not acceptable. The major differences are in grain size distribution and mineralogical make-up of these grains. The Hawthorn differs from the Bone Valley by exhibiting lower grades, lower tonnage yield per acre foot, lower pebble percent of product, higher mining ratios, higher slimes (-150 mesh) content and deeper mining depths. Physical characteristic changes include more frequent occurrences of competent bands or lenses of "limerock" which are submarginal in value.

Jan 1, 1983

By L. B. Rothfeld, R. L. Dolzani

This paper presents preliminary results of a US Bureau of Mines (USBM) study of potential costs of compliance with possible federal regulations for copper heap and dump leaching. The regulations could arise under amendments to the Resource Conservation and Recovery Act (RCRA) and/or the General Mining Law. Estimates are given for the cost of compliance with possible technology standards that would require the use of liners and closure caps regardless of terrain and underlying geology and hydrology. This cost is compared to the cost of compliance with 1992 state requirements for terrains typical of those found at existing copper leach sites in the southwestern United States. Incremental compliance costs are found to widely exceed screening criteria used by the US Environmental Protection Agency (EPA) to denote significant economic impact.

Jan 1, 1995

Acid mine drainage is still a common problem in the northern Appalachian high sulfur coal region despite mining and reclamation practices applied to control it. Mining companies must treat water with alkali to raise pH and precipitate metals in order to discharge the water into receiving streams. Common chemicals used to treat drainage are limestone, hydrated lime, soda ash briquettes, caustic soda, and ammonia. Each chemical has advantages or disadvantages under specific conditions. A simple spreadsheet program was developed to evaluate costs of treating acid mine drainage across several specified water quality parameters and time horizons. Caustic soda and soda ash were shown to be cost effective for treating low flows and low acidity over short time periods. However, as quantity of water increased, quality decreased, and time horizon increased, the ammonia and hydrated lime systems were found to be much cheaper than caustic soda.

Jan 1, 1991

By Lei Chen, Michael L. Free, Ravindra Bhide

The incorporation of particles into metal matrix materials is important to many technologically important areas. Particles that are incorporated into a metal matrix have a significant effect upon the properties of the resulting composite. Proper selection of particles and incorporation densities can lead to optimal composite properties that can be modified as needed for various applications. This paper discusses the parameters that affect the particle incorporation density in electrodeposited metal matrix composite coatings as well as a deterministic model that can be used to predict the effects of such parameters on particle incorporation density.

Jan 1, 2003

By James W. Evans

It appears that all extractive processes involve, at one or more points, fluids (gases or liquids) and that the flow of the fluid is an essential part of the functioning of the process. Usually that flow is turbulent and the turbulent flow frequently determines the rates of mass and heat transfer as well as other important phenomena such as bubble/droplet breakup and coalescence, particle suspension, etc. Over the past decade many attempts have been made to model turbulent flows in metallurgical unit operations. The present paper summarizes some of that work. Amongst the operations considered are agitated leaching, ladle metallurgy, electrowinning/refin- ing, induction furnaces, Hall cells and electro- magnetic casting. Where possible, comparisons are made between model predictions and experimental results.

Jan 1, 1990

By K. N. Han

The kinetics of gold dissolution in iodide solutions with oxygen in an autoclave was investigated. The leaching process was described by a gas-liquid-solid heterogeneous reaction. The effects of stirring speed, temperature, oxygen partial pressure and lixiviant, concentrations on the overall leaching rate was investigated. It was found that the dissolution of gold could be represented by a heterogeneous chemical reaction. Under the conditions studied, the apparent activation energy ranged from 34.7 to 54.3 kJ/mol. Experimental findings were in good agreement with the kinetic model proposed.

Jan 1, 1998

By H. Soto, G. Barbery

The effect of particle size on the flotation of coarse particles is analyzed. It is concluded that turbulence and the presence of the froth layer are detrimental to the recovery of coarse particles during conventional flotation. A counter-current column cell is proposed to avoid these two factors. In this column, a net upwards flow of water is prevalent, such that no froth is allowed to form on the top. Also, the levitation of heavy bubble-particle aggregates is helped by the ascending water current. Preliminary work at laboratory level with kilogram-size samples indicated that under similar conditions recoveries in the column were much higher than in conventional cells. Flotation results obtained with coarsely sized phosphate and quartz samples are presented. One interesting feature of this type of column is very fast flotation kinetics. Thus, a short column (only 55-cm collection zone) yielded, full recovery of floatable values.

Jan 1, 1992

By Anand Kumar, Debasis Deb, V. N. S. Prasad. M, A. K. Mishra

Shield leg pressure data from all shields and shearer locationwith time stamp from a mechanized longwall face are monitored and recorded in a surface computer. These data contain random noise due to power failure, leakage of legs, bad sensor reading and other maintenance or geo-mechanical problems. An algorithm is developed to detect mining cycle parameters such as setting and final pressures and duration of the cycle from these data for the analysis of periodic roof weighting phenomena. The intensities and persistence of periodic roof weighting are the vital information to the mine management to take judicious decision on longwall operation. The paper presents details of the algorithm which identifies 96% of mining cycles from the noisy data belonging to consecutive 5 months or 410 m of face advancement. Based on this analysis, 2 types of periodic roof weighting phenomena are detected, namely, (i) normal type—having peak intensity of 75 to 90% of yield pressure, interval of occurrences of about 10 to 15 m with persistence of 3 to 4 m and (ii) severe type—peak intensity over 90% of yield pressure, interval of 25 to 40 m with persistence of over 10 m. It is envisaged that these phenomena have direct relationship with main roof thickness, its overhung length and material properties.

Nov 19, 2020

By Howard M. Graff

The Inland Steel Company operates five underground iron mines in the Lake Superior District. The two largest of these, from the standpoint of productive capacity, are the Sherwood Mine in Iron River and the Bristol Mine in Crystal Falls, both on the Menominee Range of Michigan. It is at these two mines that we have had our principal experience with belt conveyor installations underground, .At the Sherwood Mine, which has an annual capacity of about 450,000 tons, the first conveyor belt installationwas made in 1947 when conveyors were installed in the main haulage drifts on the 1200 ft, level, It was estimated at that time that approximately 5,000,000 tons would be mined from the stopes above the 1200 ft, level and. that if all this material could be moved to the shaft by belt conveyor, the entire cost of operation, including maintenance and the amortization of the equipment, would be about $,05 per ton, which was slightly more than half of what the cost would have been by conventional tramming methods employing locomotives and cars. Now, ten years later, the 1200 ft, level is almost completely mined out and we have actually removed. 5,200,000 tons and. the average cost of transporting this material to the shaft by belt conveyor has been $.095 per ton. Since there has been a substantial increase in hourly rate of pay and also in the cost of materials since 1947, we feel that the anticipated savings were very nearly realized., The 1200 ft, level installation at the Sherwood consisted of two 36" trunk line conveyors 815 feet long and 380 feet long, respectively, deliverying ore to the shaft. These in turn were fed. by three lateral 36" conveyors which paralleled the sides of the orebody, These gathering conveyors passed under draw points to which ore was brought from the stopes by mea S of scrapers or shaker conveyors, Shaker conveyors were used for a number of years in conjunction with the conveyor belt system of haulage but it was finally concluded that with this particular type of ore, the maintenance on shaker conveyors was excessive. Therefore, more recently, we have gone back to scrapers for the shorter distances and. are using belt conveyors in the scraper drifts for the longer distances. After this belt system had been in operation for about three years, it had proved to be so successful that it was decided to proceed with the same system or. a new level to be opened up 200 feet below. Instead of sinking the shaft and driving a horizontal drift to the orebody on the 1400 ft, level, an inclined conveyor drift was started near the shaft at the 1200 ft. level and driven downwards toward, the orebody at a slope of 15 degrees. The conveyor installed in this inclined drift is 36" wide, 990 feet long, is powered. by a 100 hp motor, and is capable of delivering 300 tons per hour to the 1200 ft, level shaft pocket. It is fed by lateral horizontal conveyors on the 1300 ft? 1400 ft., and 1425 ft, sub levels. Wien the inclined drift was started, the rock was scraped from the breast directly to the rock pocket at the shaft. As the distance increased., double scraping was employed, until the advance had reached 350 feet, At this point a portion of the final conveyor was installed, with a scraper slide near the breast, T e drift was then advanced be scraping on to the conveyor until a sufficient distance had been driven to permit the installation of an additional 200 feet of conveyor. This proved to be a very efficient and economical means of moving the development rock to the shaft and obviated the need of using cars or an inclined skip way, At the present time 85 percet of tie entire mine output is being mined below the 1200 ft, level and is delivered to the shaft via the inclined conveyor. The system appears to be working as well and as economically as did the conveyor systemonthe 1200 ft, level.

Jan 1, 1958

By J. P. De Carvalho, R. Dimitrakopoulos

An actor-critic reinforcement learning approach is presented to improve the production of an industrial mining complex by defining shovel allocation and adapting the short-term plan given grade-control decisions. Blasthole data updates the simulated orebody models, which are input into a stochastic grade-control method based on a spatially constrained clustering approach that minimizes the profit-loss function. These aspects are embedded in a discrete-event simulator that defines the material flow from faces to processors. A case study at a copper mining complex shows the methods’ ability to adapt to new information, improving the quality of the material feed and increasing cash flow by 23% compared to a baseline case.

Jun 25, 2023

By B. W. Cavender

"World-class manufacturing" (WCM) techniques can be applied in milling operations to substantially improve productivity and reduce costs. Through the use of "just-in-time" and "total quality control" practices, WCM methods establish an environment for continual and rapid improvement in all aspects of production operations, with particular gains in product quality, costs, flexibility, employee involvement, and responsiveness to customers. This paper examines WCM techniques that can be utilized specifically in the mill, and their influence on plant configuration, organization, and scheduling practices; equipment selection and maintenance methods; training; the role of supporting staff; and methods of data collection and analysis.

Jan 1, 1993

By M. E. Buzon, M. E. Gunter, B. D. McNamee

A Google search on talc asbestos yields more than 500,000 hits due to the growing number of civil lawsuits in this area. Historically, the litigation was centered on amphibole-containing industrial talc. There was no debate these talcs contained amphiboles, but the issue was the definition of asbestos and whether the amphiboles had an asbestiform habit. Ultramafic-hosted talcs, however, are formed in such a way as to not favor the formation of amphiboles in the talc, but they can occur in the surrounding black-wall. In these deposits, the serpentinite host rock is in direct contact with the talc, therefore, allegations can be made that non-asbestiform amphiboles or non-regulated serpentine group minerals can occur in the final products. We analyzed talcs from both metamorphosed carbonate- and ultramafic-hosted talc deposits using polarized light microscopy (PLM), scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), electron microprobe (EPMA) with wavelengthdispersive spectroscopy (WDS), transmission electron microscopy (TEM) with EDS, and powder X-ray diffraction (XRD). Compositions of minerals determined by EDS alone are not sufficient to confidently identify asbestos, despite common practices by some researchers. We emphasize, using both historical samples, and analyses of currently contested minerals, the importance of determining both the structure and composition of a mineral, as well as defining its morphology, before concluding whether it is asbestos.

Jan 1, 2018