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By Bruce K. Cantrell, Winthrop F. Watts

The U.S. Bureau of Mines and others have conducted a number of occupational exposure surveys since the publication of the International Agency for Research on Cancer report of 1989(1), which labeled diesel exhaust as a probable human carcinogen. These surveys have assessed diesel exhaust exposure using measurement of diesel aerosol and/or specific polycyclic aromatic hydrocarbons as indicators of exposure. This report reviews, available diesel exhaust aerosol and gas measurement techniques. Measurement of human exposure to toxic agents is the first step in determining the exposure-dose-response relationship. It is a fundamental step in risk assessment. Measuring exposure to diesel exhaust pollutants is particularly challenging due to the complexity and variability of exhaust components. This paper reviews current occupational health standards for diesel emissions and available diesel exhaust gas and aerosol measurement techniques. Although surveys in mines have primarily assessed diesel exhaust exposure using diesel particulate matter (DPM) some exhaust gas measurements have been used as indicators of exposure. DPM is emphasized because it is a major component of diesel exhaust, is suspected to make a major contribution to the health hazard, and is measurable. OCCUPATIONAL HEALTH STANDARDS Occupational exposure surveys of diesel exhaust frequently measure regulated pollutants, or pollutants that are suspected carcinogens, even if no permissible exposure limits (PELs) have been established. In the United States, various organizations recommend a range of allowable values for diesel exhaust gaseous constituents, including carbon monoxide (CO), carbon dioxide (CO2), sulfur dioxide (SO.), nitrogen dioxide (NO2), nitric oxide (NO), and formaldehyde (HCHO). Table I summarizes these recommended levels, showing 8-hour or 10-hour time-weighted-average values where available; where these are not available, 15-minute short-term [ ]

Measure the daily exposure of individual miners to alpha particles emitted by radon daughters (radioactive decay products of the radon gas present in the mine atmosphere). Approach A dosimeter worn by a miner counts alpha particle emissions from radon daughters, RaA (Polonium 218) and RaC (Polonium 214), collected on a filter, and stores the gross count for later readout. How It Works A pump draws air into the detector assembly where radon daughters are collected on a filter. The detector, a solid state surface barrier type, is mounted in the filter head behind a thin mylar disc which serves as a moisture barrier. When a radon daughter decays and its alpha emission strikes the detector, the alpha particle causes a pulse of electrical charge in the detector. The circuits used to condition and count the electrical pulses generated in the detector are represented by the other blocks shown in the simplified block diagram. Each pulse is first amplified.

Jan 1, 1979

By J. L. Ellenberger

The National Institute for Occupational Safety and Health (NIOSH) has continued the research role of the former US Bureau of Mines (USBM) to engineer techniques that will reduce the hazards in the mining workplace associated with coal bumps. Recent research focused on a longwall coal mine in Utah with overburden greater than 750 m (2,500 ft) containing several massive sandstone units. The primary field instrumentation at the site was three-dimensional, full waveform, autonomous microseismic arrays placed underground and on the surface in order to surround the active multi-panel longwall district. The purpose of these arrays was to help investigate the strata mechanics associated with the redistribution of stress and the associated gob formation of the longwall. Specifically, the seismic arrays were used to determine the timing and location of the failure in the strata surrounding the active mining. Overall 13,000 seismic events were detected and located with on-site processing during the five months the panel was being mined, including a magnitude (ML) 4.2 event. Of these, a smaller subset of 5,000 well-located events was selected during post-processing to form a consistent data set for analysis in this paper. From this data set, it was observed that the seismic events generally occurred in advance of the longwall face, both above and below the panel, consistent with failure of the strata in the forward stress abutment zone. Also, the occurrence of the ML 4.2 seismic event within 150-180 m (500-600 ft) of a deep cover longwall face with no associated bump caused a re-evaluation of the nature of the connection between seismic activity and coal bumps.

Jan 1, 2002

By Donald P. Tuchman, Robert P. Vinson, Linda J. McWilliams, Steven E. Mischler, Jon C. Volkwein

A personal dust monitor (PDM) was developed to measure respirable coal mine dust mass to provide accurate exposure data at the end of a work shift. Additionally, the new monitor continuously displays near-real-time dust exposure data during the shift. The PDM uses a tapered-element oscillating microbalance to measure the mass of dust deposited on a filter and continually displays the cumulative exposure concentration data. The accuracy and precision of the instrument was determined by comparison to gravimetric filter samplers in the laboratory and in four mines. Laboratory results with different coal types and size distributions showed that there is a 95% confidence that the individual PDM measurements were within ±25% of the reference measurements. Mine test results indicate that data taken with adjacent PDM and reference samplers are indistinguishable. The technology proved durable enough to successfully measure 108 shifts of data out of 115 attempts in the mines. Under these specific test conditions, the PDM demonstrated that it was convenient to wear, robust, provided accurate data, provided timely data that could be used to prevent overexposure, and was easy to use.

Jan 1, 2004

By R. E. Head, Virgil Miller

"Under existing conditions in the treatment of oxidized lead ores containing small quantities of molybdenum no provision is made for the recovery of the molybdenum. Considerable quantities of this important element are lost in the slags of the lead smelters and constitute an economic waste. There is little or no probability that slag dumps containing molybdenum in small quantities could be economically treated for the recovery of the element, and steps for the prevention of waste in this respect must be taken prior to smelter treatment.Wulfenite, lead molybdate (PbMo04), and molybdite, molybdic ocher (Mo03), are the molybdenum minerals most abundantly found in deposits of oxidized lead ores. Wulfenite contains 39.3 per cent molybdenum trioxide and 60.7 per cent lead oxide; molybdite contains 66.7 per cent molybdenum and 33.3 per cent oxygen. Plumbojarosite, argentojarosite, cerussite, and occasionally anglesite are commonly associated with wulfenite ores, and the oxidized iron content is usually fairly high.The recent discovery and development of a body of wulfenite ore in the Star district near Milford led to a cursory microscopic examination of samples of the ore, followed by a few preliminary tests which had for their object the separation and recovery of the lead and molybdenum in separate products.The microscopic examination showed that the samples used in the work were composed of wulfenite, plumbojarosite, and a small quantity of cerussite, and indicated that the iron content was quite high. The ore was porous and yellowish-brown; crystals of wulfenite appeared to be quite uniformly distributed through it, and this mineral and plumbojarosite (Pb0.3Fe203.4S03.6H20) apparently accounted for the major part of the lead content, although lead"

Sep 1, 1928

By L. C. Marchant

Results of detailed analyses of four cores from the Threemile Canyon area in the P. R. Spring tar sand deposit in Utah are reported by the Bureau of Mines. The cores were obtained by the Utah Geological and Mineralogical Sur-vey as part of a l7-corehole evaluation program in the P. R. Spring, Hill Creek, and Rim Rock tar sand deposits. Average properties of the oil zone in the Threemile Canyon area as deter-mined from these cores are as follows: Oil saturation, 67.4 pet of pore volume; porosity, 29.2 pct; permeability before oil extraction, 133 millidarcies; and permeability after oil extraction, 2,855 millidarcies. Average net thickness of the oil zone is 23.8 ft and average depth to the top of the oil zone is 189 ft.

Jan 1, 1974

By Andrew B. Cecala, Edward D. Thimons, George W. Klinowski

The U.S. Bureau of Mines has designed and evaluated total mill ventilation systems at two different mineral processing operations. Both systems have proven very effective at reducing respirable dust levels throughout the mill in a cost-effective manner. A 25,500-cfm system installed at a clay processing mill provided approximately 10 air changes per hour. This system reduced respirable dust concentrations by approximately 40 pct throughout the mill building. The second evaluation was performed at a silica sand operation. Tests were performed with 50,000 and 100,000 cfm of ventilation to the mill building, corresponding to 17 and 34 air changes per hour. Average mill-wide respirable dust reductions were 36and 64 pct, respectively. Not only did these systems reduce respirable dust concentrations and increase visibility throughout the mills, they were also easy to install and required minimal maintenance. A total mill ventilation system provides a general purging of the mill air; the system should be viewed as a supplemental technique to assist other dust control systems in operation.

Jan 1, 1993

By Erica E. Hall, Robert H. Peters, Charles Vaught, Jon C. Volkwein

Coal Workers Pneumoconiosis is the leading cause of death due to occupational illness among coal miners. This disease is caused by miners’ exposure to respirable coal mine dust. A Personal Dust Monitor has recently been developed to provide near real time feedback to miners regarding the number of milligrams of respirable coal mine dust in the air they breathe. This paper was prepared by the National Institute for Occupational Safety and Health to document coal miners’ reactions to this new device, and how they make use of the information it provides. Structured interviews were conducted with 30 coal miners at four mines. A four-stage conceptual model of miners’ decision processes with respect to how they interpret and respond to the dust exposure numbers from their personal dust monitor is proposed. The stages are: Diagnosis, Action Planning and Intervention, Evaluation, and Institutionalization. The interview responses provide considerable support for the model. Most miners paid attention to Personal Dust Monitor feedback and made efforts to reduce their dust exposure. Their efforts included: changing where they positioned themselves, making ventilation system improvements, and using respirators more often. The 29 miners who reported having experience wearing both the old and new type of dust monitors were asked which dust sampling system they preferred. Eighteen (62%) preferred the new monitors, 7 (24%) preferred existing monitors, and 4 (14%) had no preference. The most frequently cited advantage of the new monitor is its ability to provide relatively quick feedback on dust exposure. Miners provided several suggestions for improving the design of the instrument.

By R. V. Ramani, V. T. Burgos, J. A. McClay

Cost Systems Cost systems are organized methods of collecting, allocating, and accumulating resource utility expressed in terms of money. There are two major spheres of cost accumulation: financial accounting and cost accounting. Financial accounting deals primarily with historical costs and provides a means of measuring and recording cost events which have al¬ready taken place. While there are no legal requirements to control the methods of recording and reporting cost data in the United States, the procedures in use are guided by professional organizations such as the American Institute of Certified Public Accountants. The final pro¬ducts of financial accounting practices are the income statement and balance sheet which describe the financial status of the organization under study. Cost or managerial accounting is an expansion of financial ac¬counting procedures, providing more detailed cost breakdowns on present operations with one objective being the projection of present costs into the future. The projection process tends to limit the accuracy of the information; however, to management and project justification per¬sonnel, data on future operations tends to be of greater value. The basic principle behind cost accounting is the cost cycle. As products are developed from raw materials, the value of the work-in¬process increases due to the cost input of the various fabricating ele¬ments. Thus, from the basic input elements of facilities, labor, and raw materials, costs are added to each unit of production as a function of the work performed on that unit.

Jan 1, 1975

By Barbara Fotta

According to the Bureau of Labor Statistics (BLS), workforce estimates of median age suggest that the median age of the mining workforce, which has been experiencing overall declines in numbers of employees, is rising more rapidly than for the overall U.S. civilian labor force. In the absence of detailed demographic data for the mining industry, the current study uses injury and illness data reported to the Mine Safety and Health Administration (MSHA) to examine differences, over time and by commodity, in the proportions of injured or ill workers aged 45 years and older. These data indicate that from 1988 to 1998, the percentage of injured or ill older workers (aged 45 years and older) have been steadily increasing. The most notable increase occurred at coal mining operations where the proportion of injured/ill older workers increased from 24 to 44 percent. A more detailed breakdown of the industry by commodity for 1998 showed the highest proportions of older injured/ill workers (over 40%) occurring in coal, iron ore, alumina mills, cement, and trona operations. In coal operations, as the employment size of the mine operation increased, so did its proportion of older injured/ill workers. Also, higher proportions of older injured/ill workers were observed at surface coal work locations than at underground locations. The distribution of older injured/ill miners by occupation for several select commodities shows the highest proportions for supervisors, electricians, mechanics, and surface equipment operators, and the lowest proportions for surface laborers and for underground coal roof bolters and scoop operators. With few exceptions, older injured workers have the highest median number of days lost per injury when examined by type of mining operation and by occupation. Given the high proportions of older injured or ill workers in many sectors of the mining industry, health and safety programs must consider the physiological changes associated with aging when evaluating job tasks and the working environment.

Jan 1, 2004

By Maria I. De Rosa

Table 10 and figure 4 show the number of fires and fire injuries occurring at the surface of underground metal/nonmetal and stone mines by state during 1990-2001. Table 10 also shows the injury risk rates, employees' working hours, and lost workdays. A total of 12 fires occurred in 11 states; 5 of the fires caused 5 injuries. The yearly average was one fire and 0.42 injury. Five fires with two injuries occurred at metal mines, five fires with two injuries occurred at nonmetal mines, and two fires with one injury occurred at stone mines. None of the fires involved contractors. The Ewhr value was 58 x 106 hr (Irr = 0.017), and the LWD value was 75. Nevada had the most fires (two fires and no injuries). Ohio, New Mexico, Missouri, South Dakota, and Idaho each had one fire with one injury. Of these states, Missouri had the highest injury risk rate value (In = 0.25). Table 11, partly illustrated in figure 5, shows the number of fires, fire injuries, risk rates, employees' working hours, and lost workdays by time period. The number of fires decreased during most of the six time periods. The number of fire injuries and employees' working hours decreased during all of the periods. The Irr values follow patterns similar to those shown by the injury values. Tables 12-17 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 6 shows the major variables related to fires for 1990-2001. Table 18 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By George E. Fasching

The Bureau of Mines has developed a pulse counting system with improved energy resolution and having dual channels to process pulses at different rates and a pulse pileup detector for channel selection. Pulse input is delayed until the detector determines if any pulse is so closely followed by a second pulse as to constitute pulse pileup. If no pulse pileup is detected, the slower channel is selected; this clips the pulse to a wide pulse width to retain good energy resolution. If pulse pileup is predicted, the fast channel, with correspondingly shorter pulse width, is selected to improve resolution with respect to time. Output of the two channels is transmitted to a pulse height analyzer for interpretation. The pulse processing system can process count rates above 300,000 counts per second with little loss in energy resolution.

Jan 1, 1974

By M. J. Ferrante

The Bureau of Mines determined the enthalpies of Ni3S2 relative to 298.15 K to provide new thermodynamic data for advancement of mineral science and technology. Enthalpies were measured with a copper-block calorimeter from 298.15 to 1,197 K. A solid-solid transition was found at 834±1 K, with an isothermal heat absorption of 13.32 kcal/mol. The temperature of this solid-solid transition was accurately measured by differential scanning calorimetry. Because Ni3S2 does not melt congruently, the heat of fusion of 4.70 kcal/mol was obtained by extrapolation of enthalpy measurements from the solid and liquid phases to approximately 1,064 K. Tabulated values are given for the relative standard enthalpy, heat capacity, entropy, and Gibbs energy function between 298.15 and 1,800 K. Enthalpies are also given in equation form and combined with data from the literature to derive values of standard enthalpies of formation and Gibbs energies of formation. Similar calculations were made for the reaction of crystalline and liquid nickel with gaseous diatomic sulfur for Ni3S-2(c, l).

Jan 1, 1982

By Gordon H. Dechman

This Bureau of Mines report presents an iterative approximation method for microseismic source location that was developed to adapt microseismic techniques for rock structure analysis to investigations of surface problems, such as slope failure in an open pit mine. The source location method and two derivative location algorithms are described in detail, and the speed and accuracy of the two algorithms are compared.

Jan 1, 1977

By Wilbur I. Duvall

The borehole deformation gage and overcoring techniques developed by the Bureau of Mines form one of the primary methods of determining in situ rock stress. This report describes a least squares method of calculating the average rock stress components in the horizontal plane from more than three diametral deformation measurements in a vertical borehole. This least squares analysis provides a means of determining the multiple correlation coefficient, the variance, and the scatter for a set of deformation measurements. From this information, confidence limits can be calculated for the secondary horizontal principal stresses and their directions. The material presented in this report can be used as a guide to the development of least squares solutions for stress measurement techniques other than the borehole deformation method. Since the statistical information that results from the least squares method is extremely useful in the interpretation of results, it is recommended that a least squares analysis be used on stress measurement data whenever possible.

Jan 1, 1979

Provide blasting-resistant, quickly reusable stoppings for large mine openings. Approach Stoppings are assembled using roof-to-bottom panels of brattice held together by Velcro seams that peel open when struck by a strong air blast. How It Works The Velcro seam is designed to open when exposed to forces lower than would normally damage the brattice. When the seams partially open, they relieve the blast air overpressure to prevent damage to the brattice panels and their anchoring devices. A stopping is returned to service by reclosing the Velcro seams. To hang a brattice panel, its top is stapled to a board, and wrapped once or twice around it. That assembly is then attached to the roof with bolts. The length of the board should be a foot less than the width of the panel to allow for the sealing seam on each side of the panel. The boards are installed end-to-end in an approximately straight line across the roof of the mine opening.

Jan 1, 1979

By Charles L. Kimbell

This study is intended to serve three roles. First, it represents a global overview and summary to supplement and complement the five regional companion volumes of the 1991 edition of the Minerals Yearbook International Review. In this regard, it also extends previous time series under this title that appeared as the introductory chapter to the international volume of the Minerals Yearbook from the inception of that volume in 1963 until it was subdivided into separate regional volumes in 1989. The basic statistical presentations herein generally contain data through and including that for 1991, although in a few instances the most recent statistics are those for earlier years because more recent, comprehensive global statistics simply are not yet available owing to delays in data collection and processing in some countries and continued governmental suppression of data in others. The second role of this study is to provide an update to the coverage of events impacting the world's mineral industry that have occurred between the end of 1991 and the preparation of this study. Inclusion of this update is almost essential because of the potential effect of some of these events on global mineral industry activities.

Jan 1, 1993

To restore ventilation and prevent the accumulation of explosive or toxic gases by quickly installing substitutes for stoppings blown down by an explosion. Approach Temporarily replace blown down stoppings with a parachute-shaped brattice which can be erected in minutes. How It Works The self-sealing brattice is secured to the roof, ribs and floor by anchoring its nylon edge strip at several points using extensible poles, shads, or available projections such as roof bolts. The air pressure in the entry pops open the chute of lightweight sailcloth, forcing it tightly against floor, roof and rib. See Figure 1. This emergency brattice has been tested at two locations in the Bureau's Experimental Mine at Bruceton, Pennsylvania. In a test last December, one MESA inspector wearing full rescue apparel (including self contained breathing apparatus) installed a self sealing brattice in an entry at the Bruceton Mine. Although he did not have any previous experience with the device, he easily erected it in slightly less than 10 minutes, using two extensible supports (pogo sticks). Research to improve and refine the self-sealing brattice is continuing.

Jan 1, 1977

By Maria I. De Rosa

Table 55 and figure 19 show the number of fires and fire injuries for stone mills by state during 1990-2001. Table 55 also shows the injury risk rates, employees' working hours, and lost workdays. In all, 118 fires occurred in 33 states. Seventy-six of the fires caused 82 injuries (including 8 fires and 6 injuries involving contractors). The yearly average was 9.8 fires and 6.8 injuries. The Ewhr value was 873 x 106 hr (In = 0.019), and the LWD value was 1,911. Missouri had the most fires (16 fires and 9 injuries), followed by Pennsylvania (15 fires and 14 injuries), Michigan (9 fires and 5 injuries), and Virginia (7 fires and 5 injuries). Of these states, Virginia had the highest injury risk rate value (In = 0.09 1). Table 56, partly illustrated in figure 20, shows the number of fires, fire injuries, risk rates, employees' working hours, and lost workdays by time period. The number of fires and fire injuries decreased during most of the periods, with a sharp increase during the last period. The number of employees' working hours increased throughout the periods. The In values follow patterns similar to those shown by the injury values. Tables 57-63 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 21 shows the major variables related to fires for 1990-2001. Table 63 shows the fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By L. H. Banning

The Bureau of Mines conducted pioneering batch and laboratory cyclic tests that simulated plant operation in developing a procedure for acidulating phosphate rock with fluosilicic acid. Both high-grade deslimed phosphate rock and low-grade phosphate rock samples were treated. The most promising results were obtained by acidulating des limed high-grade material. In a series of seven cyclic tests, 85.4 percent of the P20S was recovered in solutions. The average P2O5 content of the phosphoric acid-monocalcium phosphate solutions of the first step was 156 grams per liter, and the average fluorine content was 4.7 grams per liter. Residues had an average fluorine content of 30.7 percent and contained 83.9 percent of the total fluorine in the charge materials. Some fluorine was lost by volatilization.

Jan 1, 1975